TY  - JOUR
A1  - Marquardt, Dorothea
A1  - Xie, Zailai
A1  - Taubert, Andreas
A1  - Thomann, Ralf
A1  - Janiak, Christoph
T1  - Microwave synthesis and inherent stabilization of metal nanoparticles in 1-methyl-3-(3-carboxyethyl)-imidazolium tetrafluoroborate
JF  - Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
N2  - The synthesis of Co-NPs and Mn-NPs by microwave-induced decomposition of the metal carbonyls Co-2(CO)(8) and Mn-2(CO)(10), respectively, yields smaller and better separated particles in the functionalized IL 1-methyl-3-(3-carboxyethyl)-imidazolium tetrafluoroborate [EmimCO(2)H][BF4] (1.6 +/- 0.3 nm and 4.3 +/- 1.0 nm, respectively) than in the non-functionalized IL 1-n-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4]. The particles are stable in the absence of capping ligands (surfactants) for more than six months although some variation in particle size could be observed by TEM.
Y1  - 2011
U6  - https://doi.org/10.1039/c1dt10795j
SN  - 1477-9226
VL  - 40
IS  - 33
SP  - 8290
EP  - 8293
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -