TY  - JOUR
A1  - Steyrleuthner, Robert
A1  - Di Pietro, Riccardo
A1  - Collins, Brian A.
A1  - Polzer, Frank
A1  - Himmelberger, Scott
A1  - Schubert, Marcel
A1  - Chen, Zhihua
A1  - Zhang, Shiming
A1  - Salleo, Alberto
A1  - Ade, Harald W.
A1  - Facchetti, Antonio
A1  - Neher, Dieter
T1  - The Role of Regioregularity, Crystallinity, and Chain Orientation on Electron Transport in a High-Mobility n-Type Copolymer
JF  - Journal of the American Chemical Society
Y1  - 2014
U6  - https://doi.org/10.1021/ja4118736
SN  - 0002-7863
VL  - 136
IS  - 11
SP  - 4245
EP  - 4256
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Schubert, Marcel
A1  - Collins, Brian A.
A1  - Mangold, Hannah
A1  - Howard, Ian A.
A1  - Schindler, Wolfram
A1  - Vandewal, Koen
A1  - Roland, Steffen
A1  - Behrends, Jan
A1  - Kraffert, Felix
A1  - Steyrleuthner, Robert
A1  - Chen, Zhihua
A1  - Fostiropoulos, Konstantinos
A1  - Bittl, Robert
A1  - Salleo, Alberto
A1  - Facchetti, Antonio
A1  - Laquai, Frederic
A1  - Ade, Harald W.
A1  - Neher, Dieter
T1  - Correlated donor/acceptor crystal orientation controls photocurrent generation in all-polymer solar cells
JF  - Advanced functional materials
N2  - New polymers with high electron mobilities have spurred research in organic solar cells using polymeric rather than fullerene acceptors due to their potential of increased diversity, stability, and scalability. However, all-polymer solar cells have struggled to keep up with the steadily increasing power conversion efficiency of polymer: fullerene cells. The lack of knowledge about the dominant recombination process as well as the missing concluding picture on the role of the semi-crystalline microstructure of conjugated polymers in the free charge carrier generation process impede a systematic optimization of all-polymer solar cells. These issues are examined by combining structural and photo-physical characterization on a series of poly(3-hexylthiophene) (donor) and P(NDI2OD-T2) (acceptor) blend devices. These experiments reveal that geminate recombination is the major loss channel for photo-excited charge carriers. Advanced X-ray and electron-based studies reveal the effect of chloronaphthalene co-solvent in reducing domain size, altering domain purity, and reorienting the acceptor polymer crystals to be coincident with those of the donor. This reorientation correlates well with the increased photocurrent from these devices. Thus, effi cient split-up of geminate pairs at polymer/polymer interfaces may necessitate correlated donor/acceptor crystal orientation, which represents an additional requirement compared to the isotropic fullerene acceptors.
Y1  - 2014
U6  - https://doi.org/10.1002/adfm.201304216
SN  - 1616-301X
SN  - 1616-3028
VL  - 24
IS  - 26
SP  - 4068
EP  - 4081
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Albrecht, Steve
A1  - Vandewal, Koen
A1  - Tumbleston, John R.
A1  - Fischer, Florian S. U.
A1  - Douglas, Jessica D.
A1  - Frechet, Jean M. J.
A1  - Ludwigs, Sabine
A1  - Ade, Harald W.
A1  - Salleo, Alberto
A1  - Neher, Dieter
T1  - On the efficiency of charge transfer state splitting in polymer: Fullerene solar cells
JF  - Advanced materials
KW  - organic solar cells
KW  - charge generation
KW  - geminate recombination
KW  - charge transfer states
KW  - driving force
KW  - excess energy
KW  - morphology
KW  - spectroelectrochemistry
Y1  - 2014
U6  - https://doi.org/10.1002/adma.201305283
SN  - 0935-9648
SN  - 1521-4095
VL  - 26
IS  - 16
SP  - 2533
EP  - 2539
PB  - Wiley-VCH
CY  - Weinheim
ER  -