TY  - JOUR
A1  - Sarhan, Radwan Mohamed
A1  - Koopman, Wouter-Willem Adriaan
A1  - Pudell, Jan-Etienne
A1  - Stete, Felix
A1  - Rössle, Matthias
A1  - Herzog, Marc
A1  - Schmitt, Clemens Nikolaus Zeno
A1  - Liebig, Ferenc
A1  - Koetz, Joachim
A1  - Bargheer, Matias
T1  - Scaling up nanoplasmon catalysis
BT  - the role of heat dissipation
JF  - The journal of physical chemistry : C, Nanomaterials and interfaces
N2  - Nanoscale heating by optical excitation of plasmonic nanoparticles offers a new perspective of controlling chemical reactions, where heat is not spatially uniform as in conventional macroscopic heating but strong temperature gradients exist around microscopic hot spots. In nanoplasmonics, metal particles act as a nanosource of light, heat, and energetic electrons driven by resonant excitation of their localized surface plasmon resonance. As an example of the coupling reaction of 4-nitrothiophenol into 4,4′-dimercaptoazobenzene, we show that besides the nanoscopic heat distribution at hot spots, the microscopic distribution of heat dictated by the spot size of the light focus also plays a crucial role in the design of plasmonic nanoreactors. Small sizes of laser spots enable high intensities to drive plasmon-assisted catalysis. This facilitates the observation of such reactions by surface-enhanced Raman scattering, but it challenges attempts to scale nanoplasmonic chemistry up to large areas, where the excess heat must be dissipated by one-dimensional heat transport.
KW  - Gold
KW  - Raman spectroscopy
KW  - Silicon
KW  - Irradiation
KW  - Lasers
Y1  - 2019
U6  - https://doi.org/10.1021/acs.jpcc.8b12574
SN  - 1932-7447
VL  - 123
IS  - 14
SP  - 9352
EP  - 9357
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Zeuschner, Steffen
A1  - Parpiiev, Tymur
A1  - Pezeril, Thomas
A1  - Hillion, Arnaud
A1  - Dumesnil, Karine
A1  - Anane, Abdelmadjid
A1  - Pudell, Jan-Etienne
A1  - Willig, Lisa
A1  - Rössle, Matthias
A1  - Herzog, Marc
A1  - von Reppert, Alexander
A1  - Bargheer, Matias
T1  - Tracking picosecond strain pulses in heterostructures that exhibit giant magnetostriction
JF  - Structural Dynamics
N2  - We combine ultrafast X-ray diffraction (UXRD) and time-resolved Magneto-Optical Kerr Effect (MOKE) measurements to monitor the strain pulses in laser-excited TbFe2/Nb heterostructures. Spatial separation of the Nb detection layer from the laser excitation region allows for a background-free characterization of the laser-generated strain pulses. We clearly observe symmetric bipolar strain pulses if the excited TbFe2 surface terminates the sample and a decomposition of the strain wavepacket into an asymmetric bipolar and a unipolar pulse, if a SiO2 glass capping layer covers the excited TbFe2 layer. The inverse magnetostriction of the temporally separated unipolar strain pulses in this sample leads to a MOKE signal that linearly depends on the strain pulse amplitude measured through UXRD. Linear chain model simulations accurately predict the timing and shape of UXRD and MOKE signals that are caused by the strain reflections from multiple interfaces in the heterostructure.
KW  - Heterostructures
KW  - Magnetooptical effects
KW  - Metal oxides
KW  - Crystal lattices
KW  - Transition metals
KW  - Magnetism
KW  - Ultrafast X-ray diffraction
KW  - Lasers
KW  - Bragg peak
KW  - Phonons
Y1  - 2019
U6  - https://doi.org/10.1063/1.5084140
SN  - 2329-7778
VL  - 6
IS  - 2
PB  - AIP Publishing LLC
CY  - Melville, NY
ER  - 
TY  - GEN
A1  - Zeuschner, Steffen
A1  - Parpiiev, Tymur
A1  - Pezeril, Thomas
A1  - Hillion, Arnaud
A1  - Dumesnil, Karine
A1  - Anane, Abdelmadjid
A1  - Pudell, Jan-Etienne
A1  - Willig, Lisa
A1  - Rössle, Matthias
A1  - Herzog, Marc
A1  - von Reppert, Alexander
A1  - Bargheer, Matias
T1  - Tracking picosecond strain pulses in heterostructures that exhibit giant magnetostriction
T2  - Postprints der Universität Potsdam : Mathematisch-naturwissenschaftliche Reihe
N2  - We combine ultrafast X-ray diffraction (UXRD) and time-resolved Magneto-Optical Kerr Effect (MOKE) measurements to monitor the strain pulses in laser-excited TbFe2/Nb heterostructures. Spatial separation of the Nb detection layer from the laser excitation region allows for a background-free characterization of the laser-generated strain pulses. We clearly observe symmetric bipolar strain pulses if the excited TbFe2 surface terminates the sample and a decomposition of the strain wavepacket into an asymmetric bipolar and a unipolar pulse, if a SiO2 glass capping layer covers the excited TbFe2 layer. The inverse magnetostriction of the temporally separated unipolar strain pulses in this sample leads to a MOKE signal that linearly depends on the strain pulse amplitude measured through UXRD. Linear chain model simulations accurately predict the timing and shape of UXRD and MOKE signals that are caused by the strain reflections from multiple interfaces in the heterostructure.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 706 
KW  - Heterostructures
KW  - Magnetooptical effects
KW  - Metal oxides
KW  - Crystal lattices
KW  - Transition metals
KW  - Magnetism
KW  - Ultrafast X-ray diffraction
KW  - Lasers
KW  - Bragg peak
KW  - Phonons
Y1  - 2019
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-428457
SN  - 1866-8372
IS  - 706
ER  -