TY  - JOUR
A1  - Attenberger, Bianca
A1  - Moussa, Mehdi El Sayed
A1  - Brietzke, Thomas Martin
A1  - Vreshch, Volodimir
A1  - Holdt, Hans-Jürgen
A1  - Lescop, Christophe
A1  - Scheer, Manfred
T1  - Discrete Polymetallic Arrangements of Ag-I and Cu-I Ions Based on Multiple Bridging Phosphane Ligands and pi-pi Interactions
JF  - European journal of inorganic chemistry : a journal of ChemPubSoc Europe
N2  - A simple and straightforward approach to new polymetallic Ag-I and Cu-I supramolecules is presented. The reaction of N,P,N,P,N ligand 2 with Ag-I ions affords a trimetallic complex bearing a triangular Ag-3 core; metallophilic interactions are stabilized by ligands that display a multiple bridging coordination mode as 10-electron donors. Heteroleptic polymetallic Ag-I and Cu-I complexes based on ligand 2 and the 1,12-diazaperylene (dape) ligand are obtained by an alternative molecular organization of the polymetallic arrays compared to that in homoleptic complexes of ligand 2.
KW  - Heterocycles
KW  - N
KW  - P ligands
KW  - Pi interactions
KW  - Polyaromatic fragments
KW  - Supramolecular chemistry
Y1  - 2015
U6  - https://doi.org/10.1002/ejic.201500445
SN  - 1434-1948
SN  - 1099-0682
IS  - 18
SP  - 2934
EP  - 2938
PB  - Wiley-VCH
CY  - Weinheim
ER  -