TY  - JOUR
A1  - Behl, Marc
A1  - Balk, Maria
A1  - Lützow, Karola
A1  - Lendlein, Andreas
T1  - Impact of block sequence on the phase morphology of multiblock copolymers obtained by high-throughput robotic synthesis
JF  - European polymer journal : EPJ
N2  - The chemical nature, the number length of integrated building blocks, as well as their sequence structure impact the phase morphology of multiblock copolymers (MBC) consisting of two non-miscible block types. We hypothesized that a strictly alternating sequence should favour phase segregation and in this way the elastic properties. A library of well-defined MBCs composed of two different hydrophobic, semi-crystalline blocks providing domains with well-separated melting temperatures (T(m)s) were synthesized from the same type of precursor building blocks as strictly alternating (MBCsalt) or random (MBCsran) MBCs and compared. Three different series of MBCsalt or MBCsran were synthesized by high-throughput synthesis by coupling oligo(e-caprolactone) (OCL) of different molecular weights (2, 4, and 8 kDa) with oligotetrahydrofuran (OTHF, 2.9 kDa) via Steglich esterification in which the molar ratio of the reaction partners was slightly adjusted. Maximum of weight average molecular weight (M-w) were 65,000 g center dot mol(-1), 165,000 g center dot mol(-1), and 168,000 g center dot mol(-1) for MBCsalt and 80,500 g center dot mol(-1), 100,000 g center dot mol(-1), and 147,600 g center dot mol(-1) for MBCsran. When Mw increased, a decrease of both Tms associated to the melting of the OCL and OTHF domains was observed for all MBCs. T-m (OTHF) of MBCsran was always higher than Tm (OTHF) of MBCsalt, which was attributed to a better phase segregation. In addition, the elongation at break of MBCsalt was almost half as high when compared to MBCsran. In this way this study elucidates role of the block length and sequence structure in MBCs and enables a quantitative discussion of the structure-function relationship when two semi-crystalline block segments are utilized for the design of block copolymers.
KW  - Multiblock copolymers
KW  - Sequence structure
KW  - Phase morphology
KW  - Polymer
KW  - library
KW  - Robotic synthesis
KW  - High-throughput
Y1  - 2021
U6  - https://doi.org/10.1016/j.eurpolymj.2020.110207
SN  - 0014-3057
SN  - 1873-1945
VL  - 143
PB  - Elsevier
CY  - Oxford
ER  -