TY  - JOUR
A1  - Bastian, Philipp U.
A1  - Robel, Nathalie
A1  - Schmidt, Peter
A1  - Schrumpf, Tim
A1  - Günter, Christina
A1  - Roddatis, Vladimir
A1  - Kumke, Michael U.
T1  - Resonance energy transfer to track the motion of lanthanide ions
BT  - what drives the intermixing in core-shell upconverting nanoparticles?
JF  - Biosensors : open access journal
N2  - The imagination of clearly separated core-shell structures is already outdated by the fact, that the nanoparticle core-shell structures remain in terms of efficiency behind their respective bulk material due to intermixing between core and shell dopant ions. In order to optimize the photoluminescence of core-shell UCNP the intermixing should be as small as possible and therefore, key parameters of this process need to be identified. In the present work the Ln(III) ion migration in the host lattices NaYF4 and NaGdF4 was monitored. These investigations have been performed by laser spectroscopy with help of lanthanide resonance energy transfer (LRET) between Eu(III) as donor and Pr(III) or Nd(III) as acceptor. The LRET is evaluated based on the Forster theory. The findings corroborate the literature and point out the migration of ions in the host lattices. Based on the introduced LRET model, the acceptor concentration in the surrounding of one donor depends clearly on the design of the applied core-shell-shell nanoparticles. In general, thinner intermediate insulating shells lead to higher acceptor concentration, stronger quenching of the Eu(III) donor and subsequently stronger sensitization of the Pr(III) or the Nd(III) acceptors. The choice of the host lattice as well as of the synthesis temperature are parameters to be considered for the intermixing process.
KW  - upconversion nanoparticles
KW  - lanthanoid migration
KW  - lanthanides
KW  - core-shell
KW  - energy transfer
Y1  - 2021
U6  - https://doi.org/10.3390/bios11120515
SN  - 2079-6374
VL  - 11
IS  - 12
PB  - MDPI
CY  - Basel
ER  -