TY  - JOUR
A1  - Nacci, Christophe
A1  - Foelsch, Stefan
A1  - Zenichowski, Karl
A1  - Dokic, Jadranka
A1  - Klamroth, Tillmann
A1  - Saalfrank, Peter
T1  - Current versus temperature-induced switching in a single-molecule tunnel junction : 1,5 cyclooctadiene on Si(001)
N2  - The biconformational switching of single cyclooctadiene molecules chemisorbed on a Si(001) surface was explored by quantum chemical and quantum dynamical calculations and low-temperature scanning tunneling microscopy experiments. The calculations rationalize the experimentally observed switching driven by inelastic electron tunneling (IET) at 5 K. At higher temperatures, they predict a controllable crossover behavior between IET-driven and thermally activated switching, which is fully confirmed by experiment.
Y1  - 2009
UR  - http://pubs.acs.org/journal/nalefd
U6  - https://doi.org/10.1021/Nl901419g
SN  - 1530-6984
ER  -