TY - THES A1 - Luzi, Manja T1 - Kinetic studies of mixed gas hydrates Y1 - 2012 CY - Potsdam ER - TY - GEN A1 - Krehl, Stefan T1 - Entwicklung von Ruthenium-katalysierten Tandem-Reaktionssequenzen Y1 - 2012 CY - Potsdam ER - TY - THES A1 - Kupstat, Annette T1 - Förster resonance energy transfer (FRET)-based detection of molecular binding interactions - from fundamental research to application in life science Y1 - 2012 CY - Potsdam ER - TY - THES A1 - Schneider, Julia T1 - Characterisation of single and multibubble cavitation through analysis of molecular, atomic and ionic line emissions Y1 - 2012 CY - Potsdam ER - TY - THES A1 - Pick, Charlotte Hildegard T1 - Die Photo-Dehydro-Diels-Alder-Reaktion als potentielle Methode zur Ligandendarstellung: Untersuchungen zur atropselektiven Synthese von Biarylen und Synthese von Naphthylpryridinen Y1 - 2012 SN - 978-3-8439-0337-0 PB - Dr. Hut CY - München ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Stojanovic, Milovan A1 - Markovic, Rade A1 - Baranac-Stojanovic, Marija T1 - Synthesis of thiazolidine-fused heterocycles via exo-mode cyclizations of vinylogous N-acyliminium ions N2 - Syntheses of thiazolidine-fused heterocycles via exo-mode cyclizations of vinylogous N-acyliminium ions incorporating heteroatom-based nucleophiles have been examined and discussed. The formation of (5,6)-membered systems was feasible with all nucleophiles tried (O, S and N), while the closing of the five-membered ring was restricted to O- and S-nucleophiles. The closure of a four-membered ring failed. Instead, the bicyclic (5,6)-membered acetal derivative and the tricyclic system with an eight-membered central ring were obtained from the substrates containing O and S nucleophilic moieties, respectively. The reaction outcome and stereochemistry are rationalized using quantum chemical calculations at B3LYP/6-31G(d) level. The exclusive cis-stereoselectivity in the formation of (5,6)- and (5,5)-membered systems results from thermodynamic control, whereas the formation of the eight-membered ring was kinetically controlled. Y1 - 2012 SN - 1477-0520 ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Neuvonen, Kari A1 - Neuvonen, Helmi A1 - Koch, Andreas T1 - Taft equation in the light of NBO computations : Introduction of a novel polar computational substituent constant scale for alkyl groups Y1 - 2012 SN - 2210-271X ER -