TY  - JOUR
A1  - Mondal, Suvendu Sekhar
A1  - Marquardt, Dorothea
A1  - Janiak, Christoph
A1  - Holdt, Hans-Jürgen
T1  - Use of a 4,5-dicyanoimidazolate anion based ionic liquid for the synthesis of iron and silver nanoparticles
JF  - Dalton transactions : an international journal of inorganic chemistry
N2  - Sixteen new ionic liquids (ILs) with tetraethylammonium, 1-butyl-3-methylimidazolium, 3-methyl-1-octylimidazolium and tetrabutylphosphonium cations paired with 2-substituted 4,5-dicyanoimidazolate anions (substituent at C2 = methyl, trifluoromethyl, pentafluoroethyl, N,N′-dimethyl amino and nitro) have been synthesized and characterized by using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA). The effects of cation and anion type and structure of the resulting ILs, including several room temperature ionic liquids (RTILs), are reflected in the crystallization, melting points and thermal decomposition of the ILs. ILs exhibited large liquid and crystallization ranges and formed glasses on cooling with glass transition temperatures in the range of −22 to −71 °C. We selected one of the newly designed ILs due to its bigger size, compared to the common conventional IL anion and high electron-withdrawing nitrile group leads to an overall stabilization anion that may stabilize the metal nanoparticles. Stable and better separated iron and silver nanoparticles are obtained by the decomposition of corresponding Fe2(CO)9 and AgPF6, respectively, under N2-atmosphere in newly designed nitrile functionalized 4,5-dicyanoimidazolate anion based IL. Very small and uniform size for Fe-nanoparticles of about 1.8 ± 0.6 nm were achieved without any additional stabilizers or capping molecules. Comparatively bigger size of Ag-nanoparticles was obtained through the reduction of AgPF6 by hydrogen gas. Additionally, the AgPF6 precursor was decomposed under microwave irradiation (MWI), fabricating nut-in-shell-like, that is, core-separated-from-shell Ag-nano-structures.
Y1  - 2016
U6  - https://doi.org/10.1039/C6DT00225K
SN  - 1477-9226
IS  - 45
SP  - 5476
EP  - 5483
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - JOUR
A1  - Angelow, Jürgen
T1  - Verdun 1916
BT  - Ergebnis und Mythos
JF  - WeltTrends : das außenpolitische Journal
Y1  - 2016
VL  - 2016
IS  - 113
SP  - 50
EP  - 51
PB  - WeltTrends
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Kleger, Heinz
T1  - Mehrfachkrise und Populismus
JF  - WeltTrends : das außenpolitische Journal
Y1  - 2016
VL  - 24
IS  - 113
SP  - 42
EP  - 44
PB  - WeltTrends
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Klinnert, Anne
T1  - Von Vater Staat zu Mutter Merkel?
JF  - WeltTrends : das außenpolitische Journal
Y1  - 2016
SP  - 64
EP  - 66
PB  - WeltTrends
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Wehinger, Brunhilde
T1  - Nachwort : Der Kriminalroman im Spannungsfeld von (Schauer-)Romantik und Aufklärung
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86378
SN  - 978-3-86956-350-3
SP  - 161
EP  - 165
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Brink, Paula-Sophie
T1  - Verspielt
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86356
SN  - 978-3-86956-350-3
SP  - 149
EP  - 159
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Thormann, Martin
T1  - Der Florist
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86347
SN  - 978-3-86956-350-3
SP  - 113
EP  - 147
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Börnicke, Stefanie
A1  - Weimar, Friederike
T1  - Zurück am Neuen Palais
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86321
SN  - 978-3-86956-350-3
SP  - 93
EP  - 111
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Weilandt, Simone
T1  - Der Wunderbaum
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86316
SN  - 978-3-86956-350-3
SP  - 75
EP  - 92
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Börnicke, Stefanie
A1  - Weimar, Friederike
T1  - Kern der Dinge
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86299
SN  - 978-3-86956-350-3
SP  - 35
EP  - 73
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Dewart, Steven
T1  - Waage und Schwert
JF  - Spurensuche am Neuen Palais : Sechs mörderische Geschichten
Y1  - 2016
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-86282
SN  - 978-3-86956-350-3
SP  - 7
EP  - 34
PB  - Universitätsverlag Potsdam
CY  - Potsdam
ER  -