TY - JOUR A1 - Tsukamoto, Junko A1 - Haebel, Sophie A1 - Valenca, Gustavo P. A1 - Peter, Martin G. A1 - FRanco, Telma T. T1 - Enzymatic direct synthesis of acrylic acid esters of mono- and disaccharides N2 - Background: There is an increased need to replace materials derived from fossil sources by renewables. Sugar- cane derived carbohydrates are very abundant in Brazil and are the cheapest sugars available in the market, with more than 400 million tons of sugarcane processed in the year 2007. The objective of this work was to study the prepn. of sugar acrylates from free sugars and free acrylic acid, thus avoiding the previous prepn. of protected sugar derivs., such as glycosides, or activated acrylates, such as vinyl acrylate. Results: Lipase catalyzed esterification of three mono- and two disaccharides with acrylic acid, in the presence or absence of mol. sieves was investigated. The reactions were monitored by high-performance liq. chromatog. (HPLC) and the products were analyzed by matrix-assisted laser desorption ionization-time of flight (MALDI-TOF) mass spectrometry. The main products are mono- and diacrylates, while higher esters are formed as minor products. The highest conversion to sugar acrylates was obsd. for the D-glucose and D- fructose, followed by D-xylose and D-maltose. Mol. sieves had no pronounced effect on the conversion. Conclusions: A feasible method is described to produce and to characterize sugar acrylates, including those contg. more than two acrylate groups. The process for prodn. of these higher esters could potentially be optimized further to produce mols. for crosslinking in acrylate polymn. and other applications. The direct enzymic esterification of free carbohydrates with acrylic acid is unprecedented. [on SciFinder (R)]. Y1 - 2008 UR - http://www3.interscience.wiley.com/journal/117946200/grouphome/home.html SN - 0268-2575 ER - TY - JOUR A1 - López-Franco, Yolanda L. A1 - Calderón de la Barca, Ana M. A1 - Valdez, Miguel A. A1 - Peter, Martin G. A1 - Rinaudo, Marguerite A1 - Chambat, Gérard A1 - Goycoolea, Francisco M. T1 - Structural characterization of mesquite (Prosopis velutina) gum and its fractions N2 - Structural and physicochem. characteristics of mesquite gum (from Prosopis velutina) were investigated using FT- IR spectroscopic, mass spectrometric and chromatog. methods. Four fractions (F-I, F-IIa, F-IIb and F-III) were isolated by hydrophobic interaction chromatog. The samples were characterized and analyzed for their monosaccharide and oligomers compn. by high performance anion-exchange chromatog. with pulsed amperometric detection (HPAEC-PAD). L-Arabinose (L-Ara) and D-galactose (D-Gal) were found as the main carbohydrate constituent residues in the polysaccharides from mesquite gum and their ratio (L-Ara/D-Gal) varied within the range 2.54 to 3.06 among the various fractions. Small amts. of D- glucose (D-Glc), D-mannose (D-Man) and D-xylose (D-Xyl) were also detected, particularly in Fractions IIa, IIb and III. IR spectroscopy identified polysaccharides and protein in all the samples. Data from mass spectrometry (MALDI-TOF MS) was consistent with the idea that the structure corresponding to the periphereal chains of Fraction I is predominantly a chain of pentoses attached to uronic acid. [on SciFinder (R)]. Y1 - 2008 UR - http://www3.interscience.wiley.com/journal/77002860/home?CRETRY=1&SRETRY=0 U6 - https://doi.org/10.1002/mabi.200700285 SN - 1616-5187 ER - TY - JOUR A1 - Yenesew, Abiy A1 - Twinomuhwezi, Hannington A1 - Kiremire, Bernard T. A1 - Mbugua, Martin N. A1 - Gitu, Peter M. A1 - Heydenreich, Matthias A1 - Peter, Martin G. T1 - 8-Methoxyneorautenol and radical scavenging flavonoids from Erythrina abyssinica N2 - A new pterocarpan (named 8-methoxyneorautenol) was isolated from the acetone ext. of the root bark of Erythrina abyssinica. In addn., the known isoflavonoid derivs. eryvarin L, erycristagallin and shinpterocarpin were identified for the first time from the roots of this plant. The structures were detd. on the basis of spectroscopic evidence. The new compd. showed selective antimicrobial activity against Trichophyton mentagrophytes. The acetone ext. of the root bark of E. abyssinica showed radical scavenging activity towards 2,2-diphenyl-1-picrylhydrazyl radical (DPPH). The pterocarpenes, 3-hydroxy-9-methoxy-10-(3,3-dimethylallyl)pterocarpene and erycristagallin, were the most active constituents of the roots of this plant and showing dose-dependent activities similar to that of the std. quercetin. [on SciFinder (R)] Y1 - 2009 UR - http://www.ajol.info/journal_index.php?jid=120&ab=bcse SN - 1011-3924 ER - TY - JOUR A1 - Fettke, Anja A1 - Peikow, Dirk A1 - Peter, Martin G. A1 - Kleinpeter, Erich T1 - Synthesis and conformational analysis of glycomimetic analogs of thiochitobiose N2 - The synthesis of six analogs of N,N;-diacetylchitobiose is reported, including a novel transglycosylation reaction for the preparation of S-aryl thioglycosides. The conformations of the compounds were studied by a combination of NMR spectroscopy and molecular modeling, using force field calculations. In the case of the S-aryl thioglycosides with exclusively S-glycosidic linkages, dihedral angles of the disaccharidic S-glycosidic bonds, ;; and ;; and of the S-arylglycoside bonds, ; and ;, were found to be similar, whereas they were different in mixed glycosides and in a thiazoline derivative. An adequate correlation between the calculated H,H-distances of the local minima and the measured NOE contacts was achieved by applying population-weighted averages over participating conformers based on weighted relative energies. Y1 - 2009 UR - http://www.sciencedirect.com/science/journal/00404020 U6 - https://doi.org/10.1016/j.tet.2009.03.067 SN - 0040-4020 ER - TY - JOUR A1 - Menezes, Bruno M. A1 - Grigolon, Lisanne A1 - Todorovic, Zoran A1 - Peter, Martin G. A1 - Franco, Telma T. T1 - On the depolymerization of chitosan by papain : a re-assessment Y1 - 2009 ER - TY - JOUR A1 - Oliveira, Enio N. A1 - el Gueddari, Nour E. A1 - Moerschbacher, Bruno M. A1 - Peter, Martin G. A1 - Franco, Telma T. T1 - Growth of phytopathogenic fungi in the presence of partially acetylated chitooligosaccharides N2 - Four phytopathogenic fungi were cultivated up to six days in media contg. chitooligosaccharide mixts. differing in av. DP and F A. The three different mixts. were named Q3 (which contained oligosaccharides of DP2-DP10, with DP2-DP7 as main components), Q2 (which contained oligosaccharides of DP2-DP12, with DP2-DP10 as main components) and Q1 (which derived from Q2 and contained oligomers of DP5-DP8 with hexamer and a heptamer as the main components). The novel aspect of this work is the description of the effect of mixts. of oligosaccharides with different and known compn. on fungal growth rates. The growth rate of Alternaria alternata and Rhizopus stolonifer was initially inhibited by Q3 and Q2 at higher concns. Q1 had a growth stimulating effect on these two fungi. Growth of Botrytis cinerea was inhibited by Q3 and Q2, while Q1 had no effect on the growth of this fungus. Growth of Penicillium expansum was only slightly inhibited by higher concns. of sample Q3, while Q2 and Q1 had no effect. The inhibition of growth rates or their resistance toward chitooligosaccharides correlated with the absence or presence of chitinolytic enzymes in the culture media, resp. [on SciFinder (R)] Y1 - 2008 UR - http://www.springerlink.com/content/102966 SN - 0301-486X ER - TY - JOUR A1 - Bringmann, Gerhard A1 - Mutanyatta-Comar, Joan A1 - Maksimenka, Katja A1 - Wanjohi, John M. A1 - Heydenreich, Matthias A1 - Brun, Reto A1 - Müller, Werner E. G. A1 - Peter, Martin G. A1 - Midiwo, Jacob O. A1 - Yenesew, Abiy T1 - Joziknipholones A and B : the first dimeric phenylanthraquinones, from the roots of Bulbine frutescens N2 - From the roots of the African plant Bulbine frutescens (Asphodelaceae), two unprecedented novel dimeric phenylanthraquinones, named joziknipholones A and B, possessing axial and centrochirality, were isolated, together with six known compounds. Structural elucidation of the new metabolites was achieved by spectroscopic and chiroptical methods, by reductive cleavage of the central bond between the monomeric phenylanthraquinone and -anthrone portions with sodium dithionite, and by quantum chemical CD calculations. Based on the recently revised absolute axial configuration of the parent phenylanthraquinones, knipholone and knipholone anthrone, the new dimers were attributed to possess the P- configuration (i.e., with the acetyl portions below the anthraquinone plane) at both axes in the case of joziknipholone A, whereas in joziknipholone B, the knipholone part was found to be M-configured. Joziknipholones A and B are active against the chloroquine resistant strain K1 of the malaria pathogen, Plasmodium falciparum, and show moderate activity against murine leukemic lymphoma L5178y cells. Y1 - 2008 UR - http://www3.interscience.wiley.com/journal/26293/home?CRETRY=1&SRETRY=0 SN - 0947-6539 ER - TY - JOUR A1 - Rukunga, G. M. A1 - Muregi, F. W. A1 - Omar, S. A. A1 - Gathirwa, J. W. A1 - Muthaura, C. N. A1 - Peter, Martin G. T1 - Anti-plasmodial activity of the extracts and two sesquiterpenes from Cyperus articulatus N2 - Two sesquiterpenes, corymbolone and mustakone, isolated from the chloroform extract of the rhizomes of Cyperus articulatus, exhibited significant anti-plasmodial properties. Mustakone was approximately ten times more active than corymbolone against the sensitive strains of the Plasmodium falciparum. Y1 - 2008 SN - 0367-326X ER - TY - JOUR A1 - Issaree, Arisara A1 - Vijayakrishnan, Balakumar A1 - Abdelnur, Patricia V. A1 - Corilo, Yuri E. A1 - Riccio, Maria F. A1 - Sanvido, Gustavo B. A1 - Eberlin, Marcos N. A1 - Peter, Martin G. T1 - Mass spectrometry of aminoglucan oligosaccharides using electrospray ionization MS/MS and MS/MS/MS Y1 - 2009 ER - TY - JOUR A1 - Peter, Martin G. A1 - Ley, J. P. A1 - Petersen, Stefan A1 - Londershausen, M. A1 - Schumacher-Wandersleb, Michael H. M. G. A1 - Spindler, Klaus-Dieter A1 - Spindler-Barth, Margarethe A1 - Turberg, Andreas T1 - Synthesis of chitinase inhibitors Y1 - 1994 ER - TY - JOUR A1 - Krösche, Christian A1 - Crescenzi, Orlando A1 - Hoffbauer, Wilfried A1 - Jansen, Martin A1 - Napolitano, Alessandra A1 - Prota, Guiseppe A1 - Peter, Martin G. T1 - Synthesis of dopamines labelled with 13C in the alpha- or beta-side chain positions, and their application for structure studies on melanins by solid state NMR spectroscopy Y1 - 1994 ER - TY - JOUR A1 - Schumacher-Wandersleb, Michael H. M. G. A1 - Petersen, Stefan A1 - Peter, Martin G. T1 - Preparation of the N-Acetylglucosaminidase inhibitor 1-Acetamido-1,2,5-tride oxy-2,5-imino-D-glucitol from methyl a-D-Mannopyranoside Y1 - 1994 ER - TY - JOUR A1 - Peter, Martin G. A1 - Andersen, S. O. T1 - The molecular architecture of the insect exoskeleton Y1 - 1994 ER - TY - JOUR A1 - Ley, J. P. A1 - Peter, Martin G. T1 - Synthesis of N-(2-Acetamido-2-deoxy-ß-D-glucopyranosyl)- and of N-(N,N-Diacetylchitobiosyl)-amide of lhistidine Y1 - 1994 SN - 0039-7881 ER - TY - JOUR A1 - Schumacher-Wandersleb, Michael H. M. G. A1 - Peter, Martin G. T1 - Synthesis of chitobiosyl pyrrolidines Y1 - 1995 ER - TY - JOUR A1 - Peter, Martin G. A1 - Merz, A. T1 - Stereoselective benzylic deprotonation in the enzymatic rearrangement of N-acetyldopamine derived o-Quinone to the p-Quinone methide Y1 - 1995 SN - 0957-4166 ER - TY - JOUR A1 - Peter, Martin G. T1 - Chitin in den Startlöchern Y1 - 1995 SN - 0009-2959 ER - TY - JOUR A1 - Peter, Martin G. T1 - Chemistry and biochemistry of the insect exoskeleton Y1 - 1995 ER - TY - JOUR A1 - Peter, Martin G. T1 - Chemie i Biochemia Zewnetrznego Szkieletu Owadow : (Chemistry and biochemistry of the insect exoskeleton) Y1 - 1995 ER - TY - JOUR A1 - Peter, Martin G. T1 - The Bio-organic chemistry of melanogenesis Y1 - 1995 ER - TY - JOUR A1 - Abegaz, Berhanu M. A1 - Peter, Martin G. T1 - Emodine and emodinanthrone rhamnoside acetates from fruits of rhamnus prinoides Y1 - 1995 SN - 0031-9422 ER - TY - JOUR A1 - Peter, Martin G. T1 - Applications and environmental aspects of chitin and chitosan Y1 - 1995 SN - 0022-233X ER - TY - JOUR A1 - Buss, U. A1 - Varum, K. M. A1 - Peter, Martin G. A1 - Spindler-Barth, Margarethe T1 - ELISA for quantitation of chitin, chitosan and related compounds Y1 - 1996 ER - TY - JOUR A1 - Ley, J. P. A1 - Peter, Martin G. T1 - Synthesis of L-histidine and (-)-spinacine chitooligosyl amides Y1 - 1996 ER - TY - JOUR A1 - Krösche, Ch. A1 - Peter, Martin G. T1 - Detection of melanochromes by MALDI-TOF mass spectrometry Y1 - 1996 ER - TY - JOUR A1 - Andersen, S. O. A1 - Peter, Martin G. A1 - Roepstorff, Peter T1 - Cuticular sclerotization in insects Y1 - 1996 ER - TY - JOUR A1 - Londershausen, M. A1 - Turberg, Andreas A1 - Spindler-Barth, Margarethe A1 - Peter, Martin G. T1 - Screening Test for Insecticides Interfering with Cuticular Sclerotization Y1 - 1996 ER - TY - JOUR A1 - Londershausen, M. A1 - Turberg, Andreas A1 - Bieseler, Barbara A1 - Lennarz, M. A1 - Peter, Martin G. T1 - Characterization and Inhibitor Studies of Chitinases from Parasitic Blowfly (Lucilia cuprina), Tick (Boophilus micoplus), Intestinale Nematode (Haemonchus contortus), and a Bean (Phaseolus vulgaris) Y1 - 1996 ER - TY - JOUR A1 - Peter, Martin G. A1 - Miessner, Merle T1 - Primärstoffwechsel, Shikimat- und Phenylpropan-Gruppe, Vitamine, Coenzyme, Pflanzeninhaltsstoffe Y1 - 1997 ER - TY - JOUR A1 - Schanzenbach, Dirk A1 - Peter, Martin G. T1 - Chromatography of chito-oligosaccarides Y1 - 1997 ER - TY - JOUR A1 - Ley, J. P. A1 - Schweikart, F. A1 - Peter, Martin G. T1 - Chitinase inhibitors Y1 - 1997 ER - TY - JOUR A1 - Schanzenbach, Dirk A1 - Matern, Christa-Maria A1 - Peter, Martin G. T1 - Synthesis of glycosylamines and glycopeptides Y1 - 1997 ER - TY - JOUR A1 - Schanzenbach, Dirk A1 - Peter, Martin G. T1 - NMR spectroscopy of chito-oligosaccharides Y1 - 1997 ER - TY - JOUR A1 - Schanzenbach, Dirk A1 - Matern, Christa-Maria A1 - Peter, Martin G. T1 - Cleavage of chitin by means of sulfurice acid/acetc anhydride and isolation of peracetylated chito- oligosaccharides Y1 - 1997 ER - TY - JOUR A1 - Ratajska, M. A1 - Struszczyk, Marcin Henryk A1 - Boryniec, Stefan A1 - Peter, Martin G. A1 - Loth, Fritz T1 - The degree of acetylation of chitosan : optimization of the IR Method Y1 - 1997 ER - TY - JOUR A1 - Peter, Martin G. A1 - Wollenberger, Ursula T1 - Phenol-oxidizing enzymes : mechanisms and applications Y1 - 1997 ER - TY - JOUR A1 - Haebel, Sophie A1 - Peter-Katalinic, Jasna A1 - Peter, Martin G. T1 - Mass spectrometry of chitooligosaccharides Y1 - 1997 SN - 88-86889- 01-1 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Ratajska, M. A1 - Boryniec, Stefan A1 - Peter, Martin G. A1 - Loth, Fritz T1 - The determination of the degree of N-acetylation of chitosan Y1 - 1997 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Peter, Martin G. T1 - Analysis of deacetylation deree in chitosans from various sources Y1 - 1998 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Köhler, L. A. A1 - Peter, Martin G. T1 - Characterization of chitosan Y1 - 1998 ER - TY - JOUR A1 - Berth, Gisela A1 - Dautzenberg, Herbert A1 - Peter, Martin G. T1 - Physico-chemical characterization of chitosans varying in degree of acetylation Y1 - 1998 SN - 0144-8617 ER - TY - JOUR A1 - Yenesew, Abiy A1 - Midiwo, Jacob O. A1 - Heydenreich, Matthias A1 - Peter, Martin G. T1 - Four isoflavanones from stem bark of erythrina sacleuxii Y1 - 1998 ER - TY - JOUR A1 - Yenesew, Abiy A1 - Midiwo, Jacob O. A1 - Meisner, M. A1 - Heydenreich, Matthias A1 - Peter, Martin G. T1 - Two prenylated flavanones from stem bark of erythrina burttii Y1 - 1998 ER - TY - JOUR A1 - Streffer, Katrin A1 - Kaatz, Helvi A1 - Bauer, Christian G. A1 - Makower, Alexander A1 - Schulmeister, Thomas A1 - Scheller, Frieder W. A1 - Peter, Martin G. A1 - Wollenberger, Ursula T1 - Application of a sensitive catechol detector for determination of tyrosinase inhibitors Y1 - 1998 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Peter, Martin G. T1 - Calibration of methods for the determination of the degree of decatetylation of chitosan Y1 - 1998 ER - TY - JOUR A1 - Alarcon, Julio A1 - Alderete, Joel B. A1 - Peter, Martin G. A1 - Becerra, Juan J. A1 - Silva, M. T1 - Study on synthesis of 3 alpha,4 alpha-dihydroxy-dihydro-beta-agarofuran Y1 - 1998 ER - TY - JOUR A1 - Kamlage, Stefan A1 - Sefkow, Michael A1 - Peter, Martin G. T1 - Cross coupling of benzylic bromides and vinyl stannanes Y1 - 1999 ER - TY - JOUR A1 - Kaatz, Helvi A1 - Streffer, Katrin A1 - Wollenberger, Ursula A1 - Peter, Martin G. T1 - Inhibition of mushroom tyrosinase by kojic acid octanoates Y1 - 1999 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Peter, Martin G. T1 - Method of microcrystalline chitosan-protein films preparation Y1 - 1999 ER - TY - JOUR A1 - Rottmann, Antje A1 - Synstad, Bjoenar A1 - Thiele, G. A1 - Schanzenbach, Dirk A1 - Eijsink, Vincent G. H. A1 - Peter, Martin G. T1 - Approaches towards the design of new chitinase inhibitors Y1 - 1999 SN - 3-9806494-5-8 ER -