TY - JOUR A1 - Steinmetz, Matthias T1 - Die Vermessung des Universums JF - Vision als Aufgabe : das Leibniz-Universum im 21. Jahrhundert Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b4-opus4-25899 SN - 978-3-939818-67-0 SP - 197 EP - 210 PB - Berlin-Brandenburgische Akademie der Wissenschaften CY - Berlin ER - TY - JOUR A1 - Reindl, Nicole A1 - Rauch, Thomas A1 - Miller Bertolami, Marcelo Miguel A1 - Todt, Helge Tobias A1 - Werner, K. T1 - Breaking news from the HST BT - the central star of the Stingray Nebula is now returning towards the AGB JF - Monthly notices of the Royal Astronomical Society N2 - SAO 244567 is a rare example of a star that allows us to witness stellar evolution in real time. Between 1971 and 1990, it changed from a B-type star into the hot central star of the Stingray Nebula. This observed rapid heating has been a mystery for decades, since it is in strong contradiction with the low mass of the star and canonical post-asymptotic giant branch (AGB) evolution. We speculated that SAO 244567 might have suffered from a late thermal pulse (LTP) and obtained new observations with Hubble Space Telescope (HST)/COS to follow the evolution of the surface properties of SAO 244567 and to verify the LTP hypothesis. Our non-LTE spectral analysis reveals that the star cooled significantly since 2002 and that its envelope is now expanding. Therefore, we conclude that SAO 244567 is currently on its way back towards the AGB, which strongly supports the LTP hypothesis. A comparison with state-of-the-art LTP evolutionary calculations shows that these models cannot fully reproduce the evolution of all surface parameters simultaneously, pointing out possible shortcomings of stellar evolution models. Thereby, SAO 244567 keeps on challenging stellar evolution theory and we highly encourage further investigations. KW - stars: AGB and post-AGB KW - stars: atmospheres KW - stars: evolution Y1 - 2016 U6 - https://doi.org/10.1093/mnrasl/slw175 SN - 0035-8711 SN - 1365-2966 VL - 464 SP - L51 EP - L55 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Zehbe, Rolf A1 - Zaslansky, Paul A1 - Mochales, Carolina A1 - Mueller, Wolf-Dieter A1 - Fleck, Claudia T1 - Synchrotron micro tomographic evaluation of multilayered zirconia ceramics-Volumetric effects after indentation JF - Journal of the European Ceramic Society N2 - Electrophoretic deposition was used to produce zirconia specimen consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia. In this configuration, the tetragonal stabilized zirconia layers can undergo transformation toughening upon mechanical induced stresses, while the cubic stabilized layers can act as confining element. To understand the volumetric changes due to transformation toughening in these layered materials after indentation, we used an advanced synchrotron-based X-ray mu CT setup and compared the results with surface sensitive methods like Raman spectroscopy, AFM and white light interferometry. The high spatial resolution and the adapted beam energy between the absorption edges of zirconia and yttria allowed discriminating between individual layers due to differences in their yttria content. Furthermore we were able to identify single indents and link volume changes to different physical effects in the different stabilized zirconia parts and visualize the three dimensional volume around only few micrometre sized indents. (C) 2015 Elsevier Ltd. All rights reserved. KW - Yttria stabilized zirconia multilayers KW - X-ray mu CT KW - Electrophoretic deposition KW - Transformation toughening Y1 - 2016 U6 - https://doi.org/10.1016/j.jeurceramsoc.2015.09.015 SN - 0955-2219 SN - 1873-619X VL - 36 SP - 171 EP - 177 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Zehbe, Rolf A1 - Mochales, Carolina A1 - Radzik, Daniela A1 - Mueller, Wolf-Dieter A1 - Fleck, Claudia T1 - Electrophoretic deposition of multilayered (cubic and tetragonal stabilized) zirconia ceramics for adapted crack deflection JF - Journal of the European Ceramic Society N2 - The electrophoretic deposition process was used to produce multi-layered ceramics consisting of alternating layers of fully stabilized cubic zirconia and partially stabilized tetragonal zirconia to make use of their different mechanical behaviour, investigating the possibility to deflect advancing cracks at the interfaces of the different layers. This crack deflection is apparently impacted by a toughening mechanism only found in the tetragonal stabilized zirconia polymorph and is characterized by the stress induced transformation of the metastable tetragonal phase into the monoclinic one, which is accompanied by a volume increase resulting in a closing mechanism for advancing cracks. While improving the electrophoretic deposition process, we investigated the transformation toughening mechanism at the layer interfaces and their effect on crack propagation. Investigations involved a combination of different imaging methods, including light microscopy, white light interferometry, atomic force microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and Raman spectroscopy. (C) 2015 Elsevier Ltd. All rights reserved. KW - Electrophoretic deposition KW - Yttria stabilized zirconia KW - Transformation toughening KW - Multilayer KW - Crack deflection Y1 - 2016 U6 - https://doi.org/10.1016/j.jeurceramsoc.2015.08.022 SN - 0955-2219 SN - 1873-619X VL - 36 SP - 357 EP - 364 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Mengel, Matthias A1 - Feldmann, Johannes A1 - Levermann, Anders T1 - Linear sea-level response to abrupt ocean warming of major West Antarctic ice basin JF - Nature climate change N2 - Antarctica’s contribution to global sea-level rise has recently been increasing1. Whether its ice discharge will become unstable and decouple from anthropogenic forcing2,3,4 or increase linearly with the warming of the surrounding ocean is of fundamental importance5. Under unabated greenhouse-gas emissions, ocean models indicate an abrupt intrusion of warm circumpolar deep water into the cavity below West Antarctica’s Filchner–Ronne ice shelf within the next two centuries6,7. The ice basin’s retrograde bed slope would allow for an unstable ice-sheet retreat8, but the buttressing of the large ice shelf and the narrow glacier troughs tend to inhibit such instability9,10,11. It is unclear whether future ice loss will be dominated by ice instability or anthropogenic forcing. Here we show in regional and continental-scale ice-sheet simulations, which are capable of resolving unstable grounding-line retreat, that the sea-level response of the Filchner–Ronne ice basin is not dominated by ice instability and follows the strength of the forcing quasi-linearly. We find that the ice loss reduces after each pulse of projected warm water intrusion. The long-term sea-level contribution is approximately proportional to the total shelf-ice melt. Although the local instabilities might dominate the ice loss for weak oceanic warming12, we find that the upper limit of ice discharge from the region is determined by the forcing and not by the marine ice-sheet instability. Y1 - 2016 U6 - https://doi.org/10.1038/NCLIMATE2808 SN - 1758-678X SN - 1758-6798 VL - 6 SP - 71 EP - + PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Baushev, Anton N. T1 - Can the dark matter annihilation signal be significantly boosted by substructures? JF - Journal of cosmology and astroparticle physics N2 - A very general cosmological consideration suggests that, along with galactic dark matter halos, much smaller dark matter structures may exist. These structures are usually called `clumps', and their mass extends to 10−6 M ⊙ or even lower. The clumps should give the main contribution into the signal of dark matter annihilation, provided that they have survived until the present time. Recent observations favor a cored profile for low-mass astrophysical halos. We consider cored clumps and show that they are significantly less firm than the standard NFW ones. In contrast to the standard scenario, the cored clumps should have been completely destroyed inside ~ 20 kpc from the Milky Way center. The dwarf spheroidals should not contain any dark matter clumps. On the other hand, even under the most pessimistic assumption about the clump structure, the clumps should have survived in the Milky Way at a distance exceeding 50 kpc from the center, as well as in low-density cosmic structures. There they significantly boost the dark matter annihilation. We show that at least 70% of the clumps endured the primordial structure formation should still exist untouched in the present-day Universe. KW - dark matter theory KW - particle physics - cosmology connection KW - supersymmetry and cosmology KW - cosmic ray theory Y1 - 2016 U6 - https://doi.org/10.1088/1475-7516/2016/01/018 SN - 1475-7516 VL - 30 SP - 12 EP - 18 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Kuznetsov, Alexander P. A1 - Turukina, Ludmila V. A1 - Chernyshov, Nikolai Yu A1 - Sedova, Yuliya V. T1 - Oscillations and Synchronization in a System of Three Reactively Coupled Oscillators JF - International journal of bifurcation and chaos : in applied sciences and engineering N2 - We consider a system of three interacting van der Pol oscillators with reactive coupling. Phase equations are derived, using proper order of expansion over the coupling parameter. The dynamics of the system is studied by means of the bifurcation analysis and with the method of Lyapunov exponent charts. Essential and physically meaningful features of the reactive coupling are discussed. KW - Synchronization KW - quasi-periodic oscillation KW - bifurcation KW - chaos Y1 - 2016 U6 - https://doi.org/10.1142/S0218127416500103 SN - 0218-1274 SN - 1793-6551 VL - 26 SP - 31 EP - 39 PB - World Scientific CY - Singapore ER - TY - JOUR A1 - Yadavalli, Nataraja Sekhar A1 - Loebner, Sarah A1 - Papke, Thomas A1 - Sava, Elena A1 - Hurduc, Nicolae A1 - Santer, Svetlana T1 - A comparative study of photoinduced deformation in azobenzene containing polymer films JF - Soft matter N2 - In this paper two groups supporting different views on the mechanism of light induced polymer deformation argue about the respective underlying theoretical conceptions, in order to bring this interesting debate to the attention of the scientific community. The group of Prof. Nicolae Hurduc supports the model claiming that the cyclic isomerization of azobenzenes may cause an athermal transition of the glassy azobenzene containing polymer into a fluid state, the so-called photo-fluidization concept. This concept is quite convenient for an intuitive understanding of the deformation process as an anisotropic flow of the polymer material. The group of Prof. Svetlana Santer supports the re-orientational model where the mass-transport of the polymer material accomplished during polymer deformation is stated to be generated by the light-induced re-orientation of the azobenzene side chains and as a consequence of the polymer backbone that in turn results in local mechanical stress, which is enough to irreversibly deform an azobenzene containing material even in the glassy state. For the debate we chose three polymers differing in the glass transition temperature, 32 degrees C, 87 degrees C and 95 degrees C, representing extreme cases of flexible and rigid materials. Polymer film deformation occurring during irradiation with different interference patterns is recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. We also demonstrated the unique behaviour of azobenzene containing polymeric films to switch the topography in situ and reversibly by changing the irradiation conditions. We discuss the results of reversible deformation of three polymers induced by irradiation with intensity (IIP) and polarization (PIP) interference patterns, and the light of homogeneous intensity in terms of two approaches: the re-orientational and the photo-fluidization concepts. Both agree in that the formation of opto-mechanically induced stresses is a necessary prerequisite for the process of deformation. Using this argument, the deformation process can be characterized either as a flow or mass transport. Y1 - 2016 U6 - https://doi.org/10.1039/c6sm00029k SN - 1744-683X SN - 1744-6848 VL - 12 SP - 2593 EP - 2603 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Teif, Vladimir B. A1 - Cherstvy, Andrey G. T1 - Chromatin and epigenetics: current biophysical views T2 - AIMS biophysics N2 - Recent advances in high-throughput sequencing experiments and their theoretical descriptions have determined fast dynamics of the "chromatin and epigenetics" field, with new concepts appearing at high rate. This field includes but is not limited to the study of DNA-protein-RNA interactions, chromatin packing properties at different scales, regulation of gene expression and protein trafficking in the cell nucleus, binding site search in the crowded chromatin environment and modulation of physical interactions by covalent chemical modifications of the binding partners. The current special issue does not pretend for the full coverage of the field, but it rather aims to capture its development and provide a snapshot of the most recent concepts and approaches. Eighteen open-access articles comprising this issue provide a delicate balance between current theoretical and experimental biophysical approaches to uncover chromatin structure and understand epigenetic regulation, allowing free flow of new ideas and preliminary results. KW - chromatin KW - epigenetics KW - linker histones KW - nucleosome KW - DNA-protein binding KW - histone modifications KW - remodelers KW - topologically associated domains KW - DNA methylation KW - DNA supercoiling Y1 - 2016 U6 - https://doi.org/10.3934/biophy.2016.1.88 SN - 2377-9098 VL - 3 SP - 88 EP - 98 PB - American Institute of Mathematical Sciences CY - Springfield ER - TY - JOUR A1 - Liebig, Ferenc A1 - Sarhan, Radwan Mohamed A1 - Prietzel, Claudia Christina A1 - Reinecke, Antje A1 - Koetz, Joachim T1 - "Green" gold nanotriangles: synthesis, purification by polyelectrolyte/micelle depletion flocculation and performance in surface-enhanced Raman scattering JF - RSC Advances N2 - The aim of this study was to develop a one-step synthesis of gold nanotriangles (NTs) in the presence of mixed phospholipid vesicles followed by a separation process to isolate purified NTs. Negatively charged vesicles containing AOT and phospholipids, in the absence and presence of additional reducing agents (polyampholytes, polyanions or low molecular weight compounds), were used as a template phase to form anisotropic gold nanoparticles. Upon addition of the gold chloride solution, the nucleation process is initiated and both types of particles, i.e., isotropic spherical and anisotropic gold nanotriangles, are formed simultaneously. As it was not possible to produce monodisperse nanotriangles with such a one-step procedure, the anisotropic nanoparticles needed to be separated from the spherical ones. Therefore, a new type of separation procedure using combined polyelectrolyte/micelle depletion flocculation was successfully applied. As a result of the different purification steps, a green colored aqueous dispersion was obtained containing highly purified, well-defined negatively charged flat nanocrystals with a platelet thickness of 10 nm and an edge length of about 175 nm. The NTs produce promising results in surface-enhanced Raman scattering. Y1 - 2016 U6 - https://doi.org/10.1039/c6ra04808k SN - 2046-2069 VL - 6 SP - 33561 EP - 33568 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Sandmann, Michael A1 - Garz, Andreas A1 - Menzel, Ralf T1 - Physiological response of two different Chlamydomonas reinhardtii strains to light-dark rhythms JF - Botany N2 - Cells of a cell-wall deficient line (cw15-type) of Chlamydomonas reinhardtii and of the corresponding wild type were grown during repetitive light-dark cycles. In a direct comparison, both lines showed approximately the same relative biomass increase during light phase but the cw-line produced significantly more, and smaller, daughter cells. Throughout the light period the average cellular starch content, the cellular chlorophyll content, the cellular rate of dark respiration, and the cellular rate of photosynthesis of the cw-line was lower. Despite this, several non-cell volume related parameters like the development of starch content per cell volume were clearly different over time between the strains. Additionally, the chlorophyll-based photosynthesis rates were 2-fold higher in the mutant than in the wild-type cells, and the ratio of chlorophyll a to chlorophyll b as well as the light-saturation index were also consistently higher in the mutant cells. Differences in the starch content were also confirmed by single cell analyses using a sensitive SHG-based microscopy approach. In summary, the cw15-type mutant deviates from its genetic background in the entire cell physiology. Both lines should be used in further studies in comparative systems biology with focus on the detailed relation between cell volume increase, photosynthesis, starch metabolism, and daughter cell productivity. KW - cell wall deficient mutant KW - diurnal rhythm KW - nonlinear microscopy KW - photosynthesis KW - single-cell analysis Y1 - 2016 U6 - https://doi.org/10.1139/cjb-2015-0144 SN - 1916-2790 SN - 1916-2804 VL - 94 SP - 53 EP - 64 PB - NRC Research Press CY - Ottawa ER - TY - JOUR A1 - Frieler, Katja A1 - Mengel, M. A1 - Levermann, Anders T1 - Delaying future sea-level rise by storing water in Antarctica JF - Earth system dynamics N2 - Even if greenhouse gas emissions were stopped today, sea level would continue to rise for centuries, with the long-term sea-level commitment of a 2 degrees C warmer world significantly exceeding 2 m. In view of the potential implications for coastal populations and ecosystems worldwide, we investigate, from an ice-dynamic perspective, the possibility of delaying sea-level rise by pumping ocean water onto the surface of the Antarctic ice sheet. We find that due to wave propagation ice is discharged much faster back into the ocean than would be expected from a pure advection with surface velocities. The delay time depends strongly on the distance from the coastline at which the additional mass is placed and less strongly on the rate of sea-level rise that is mitigated. A millennium-scale storage of at least 80% of the additional ice requires placing it at a distance of at least 700 km from the coastline. The pumping energy required to elevate the potential energy of ocean water to mitigate the currently observed 3 mmyr(-1) will exceed 7% of the current global primary energy supply. At the same time, the approach offers a comprehensive protection for entire coastlines particularly including regions that cannot be protected by dikes. Y1 - 2016 U6 - https://doi.org/10.5194/esd-7-203-2016 SN - 2190-4979 SN - 2190-4987 VL - 7 SP - 203 EP - 210 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Sandev, T. A1 - Iomin, Alexander A1 - Kantz, Holger A1 - Metzler, Ralf A1 - Chechkin, Aleksei V. T1 - Comb Model with Slow and Ultraslow Diffusion JF - Mathematical modelling of natural phenomena N2 - We consider a generalized diffusion equation in two dimensions for modeling diffusion on a comb-like structures. We analyze the probability distribution functions and we derive the mean squared displacement in x and y directions. Different forms of the memory kernels (Dirac delta, power-law, and distributed order) are considered. It is shown that anomalous diffusion may occur along both x and y directions. Ultraslow diffusion and some more general diffusive processes are observed as well. We give the corresponding continuous time random walk model for the considered two dimensional diffusion-like equation on a comb, and we derive the probability distribution functions which subordinate the process governed by this equation to the Wiener process. KW - comb-like model KW - anomalous diffusion KW - mean squared displacement KW - probability density function Y1 - 2016 U6 - https://doi.org/10.1051/mmnp/201611302 SN - 0973-5348 SN - 1760-6101 VL - 11 SP - 18 EP - 33 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Pavlenko, Elena S. A1 - Sander, Mathias A1 - Mitzscherling, S. A1 - Pudell, Jan-Etienne A1 - Zamponi, Flavio A1 - Roessle, M. A1 - Bojahr, Andre A1 - Bargheer, Matias T1 - Azobenzene - functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers JF - Nanoscale N2 - We introduce azobenzene-functionalized polyelectrolyte multilayers as efficient, inexpensive optoacoustic transducers for hyper-sound strain waves in the GHz range. By picosecond transient reflectivity measurements we study the creation of nanoscale strain waves, their reflection from interfaces, damping by scattering from nanoparticles and propagation in soft and hard adjacent materials like polymer layers, quartz and mica. The amplitude of the generated strain epsilon similar to 5 x 10(-4) is calibrated by ultrafast X-ray diffraction. Y1 - 2016 U6 - https://doi.org/10.1039/c6nr01448h SN - 2040-3364 SN - 2040-3372 VL - 8 SP - 13297 EP - 13302 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Holländer, Lars A1 - Kossack, Wilhelm A1 - Kollosche, Matthias A1 - Wirges, Werner A1 - Kremer, Friedrich A1 - Gerhard, Reimund T1 - Influence of the remanent polarisation on the liquid crystal alignment in composite films of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and a cyanobiphenyl-based liquid crystal JF - Liquid crystals : an international journal of science and technology N2 - Polymer-dispersed liquid crystals (PDLCs) of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and nematic 4-cyano-4ʹ-n-hexylbiphenyl (6CB) or 4-cyano-4ʹ-n-pentylbiphenyl (5CB) were prepared to study the effect of the remanent polarisation of the polymer on the liquid crystal alignment. We measured the macroscopic alignment of the liquid crystal molecules in the thickness direction by means of Infrared Transition-Moment Orientational Analysis. Electrical poling at 100 V/µm caused an increased order parameter up to 0.15. After subsequent annealing above the nematic-to-isotropic phase-transition temperature, the order parameter was reduced to 0.02. Nevertheless, the order parameter was still higher than for non-poled film indicating a slight orientation in thickness direction. Both values are lower than those expected from model calculations. In agreement with dielectric measurements, we attribute this result to the shielding effect of mobile charge carriers within the liquid crystal inclusions. KW - Polymer-dispersed liquid crystal KW - ferroelectric polymer KW - remanent polarisation KW - liquid crystal alignment Y1 - 2016 U6 - https://doi.org/10.1080/02678292.2016.1185174 SN - 0267-8292 SN - 1366-5855 VL - 43 SP - 1514 EP - 1521 PB - Editions Rodopi BV CY - Abingdon ER - TY - JOUR A1 - Münch, Thomas A1 - Kipfstuhl, Sepp A1 - Freitag, Johannes A1 - Meyer, Hanno A1 - Laepple, Thomas T1 - Regional climate signal vs. local noise: a two-dimensional view of water isotopes in Antarctic firn at Kohnen Station, Dronning Maud Land JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - In low-accumulation regions, the reliability of delta O-18-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing delta O-18 in two 50m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken. Y1 - 2016 U6 - https://doi.org/10.5194/cp-12-1565-2016 SN - 1814-9324 SN - 1814-9332 VL - 12 SP - 1565 EP - 1581 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Ghosh, Surya K. A1 - Cherstvy, Andrey G. A1 - Petrov, Eugene P. A1 - Metzler, Ralf T1 - Interactions of rod-like particles on responsive elastic sheets JF - Soft matter N2 - What are the physical laws of the mutual interactions of objects bound to cell membranes, such as various membrane proteins or elongated virus particles? To rationalise this, we here investigate by extensive computer simulations mutual interactions of rod-like particles adsorbed on the surface of responsive elastic two-dimensional sheets. Specifically, we quantify sheet deformations as a response to adhesion of such filamentous particles. We demonstrate that tip-to-tip contacts of rods are favoured for relatively soft sheets, while side-by-side contacts are preferred for stiffer elastic substrates. These attractive orientation-dependent substrate-mediated interactions between the rod-like particles on responsive sheets can drive their aggregation and self-assembly. The optimal orientation of the membrane-bound rods is established via responding to the elastic energy profiles created around the particles. We unveil the phase diagramme of attractive-repulsive rod-rod interactions in the plane of their separation and mutual orientation. Applications of our results to other systems featuring membrane-associated particles are also discussed. Y1 - 2016 U6 - https://doi.org/10.1039/c6sm01522k SN - 1744-683X SN - 1744-6848 VL - 12 SP - 7908 EP - 7919 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Yang, Jie A1 - Gühr, Markus A1 - Vecchione, Theodore A1 - Robinson, Matthew Scott A1 - Li, Renkai A1 - Hartmann, Nick A1 - Shen, Xiaozhe A1 - Coffee, Ryan A1 - Corbett, Jeff A1 - Fry, Alan A1 - Gaffney, Kelly A1 - Gorkhover, Tais A1 - Hast, Carsten A1 - Jobe, Keith A1 - Makasyuk, Igor A1 - Reid, Alexander A1 - Robinson, Joseph A1 - Vetter, Sharon A1 - Wang, Fenglin A1 - Weathersby, Stephen A1 - Yoneda, Charles A1 - Wang, Xijie A1 - Centurion, Martin T1 - Femtosecond gas phase electron diffraction with MeV electrons JF - Faraday discussions N2 - We present results on ultrafast gas electron diffraction (UGED) experiments with femtosecond resolution using the MeV electron gun at SLAC National Accelerator Laboratory. UGED is a promising method to investigate molecular dynamics in the gas phase because electron pulses can probe the structure with a high spatial resolution. Until recently, however, it was not possible for UGED to reach the relevant timescale for the motion of the nuclei during a molecular reaction. Using MeV electron pulses has allowed us to overcome the main challenges in reaching femtosecond resolution, namely delivering short electron pulses on a gas target, overcoming the effect of velocity mismatch between pump laser pulses and the probe electron pulses, and maintaining a low timing jitter. At electron kinetic energies above 3 MeV, the velocity mismatch between laser and electron pulses becomes negligible. The relativistic electrons are also less susceptible to temporal broadening due to the Coulomb force. One of the challenges of diffraction with relativistic electrons is that the small de Broglie wavelength results in very small diffraction angles. In this paper we describe the new setup and its characterization, including capturing static diffraction patterns of molecules in the gas phase, finding time-zero with sub-picosecond accuracy and first time-resolved diffraction experiments. The new device can achieve a temporal resolution of 100 fs root-mean-square, and sub-angstrom spatial resolution. The collimation of the beam is sufficient to measure the diffraction pattern, and the transverse coherence is on the order of 2 nm. Currently, the temporal resolution is limited both by the pulse duration of the electron pulse on target and by the timing jitter, while the spatial resolution is limited by the average electron beam current and the signal-to-noise ratio of the detection system. We also discuss plans for improving both the temporal resolution and the spatial resolution. Y1 - 2016 U6 - https://doi.org/10.1039/c6fd00071a SN - 1359-6640 SN - 1364-5498 VL - 194 SP - 563 EP - 581 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Ghosh, Surya K. A1 - Cherstvy, Andrey G. A1 - Grebenkov, Denis S. A1 - Metzler, Ralf T1 - Anomalous, non-Gaussian tracer diffusion in crowded two-dimensional environments JF - NEW JOURNAL OF PHYSICS N2 - A topic of intense current investigation pursues the question of how the highly crowded environment of biological cells affects the dynamic properties of passively diffusing particles. Motivated by recent experiments we report results of extensive simulations of the motion of a finite sized tracer particle in a heterogeneously crowded environment made up of quenched distributions of monodisperse crowders of varying sizes in finite circular two-dimensional domains. For given spatial distributions of monodisperse crowders we demonstrate how anomalous diffusion with strongly non-Gaussian features arises in this model system. We investigate both biologically relevant situations of particles released either at the surface of an inner domain or at the outer boundary, exhibiting distinctly different features of the observed anomalous diffusion for heterogeneous distributions of crowders. Specifically we reveal an asymmetric spreading of tracers even at moderate crowding. In addition to the mean squared displacement (MSD) and local diffusion exponent we investigate the magnitude and the amplitude scatter of the time averaged MSD of individual tracer trajectories, the non-Gaussianity parameter, and the van Hove correlation function. We also quantify how the average tracer diffusivity varies with the position in the domain with a heterogeneous radial distribution of crowders and examine the behaviour of the survival probability and the dynamics of the tracer survival probability. Inter alia, the systems we investigate are related to the passive transport of lipid molecules and proteins in two-dimensional crowded membranes or the motion in colloidal solutions or emulsions in effectively two-dimensional geometries, as well as inside supercrowded, surface adhered cells. KW - anomalous diffusion KW - crowded fluids KW - stochastic processes Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/1/013027 SN - 1367-2630 VL - 18 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Ganopolski, A. A1 - Winkelmann, Ricarda A1 - Schellnhuber, Hans Joachim T1 - Critical insolation-CO2 relation for diagnosing past and future glacial inception JF - Nature : the international weekly journal of science N2 - The past rapid growth of Northern Hemisphere continental ice sheets, which terminated warm and stable climate periods, is generally attributed to reduced summer insolation in boreal latitudes(1-3). Yet such summer insolation is near to its minimum at present(4), and there are no signs of a new ice age(5). This challenges our understanding of the mechanisms driving glacial cycles and our ability to predict the next glacial inception(6). Here we propose a critical functional relationship between boreal summer insolation and global carbon dioxide (CO2) concentration, which explains the beginning of the past eight glacial cycles and might anticipate future periods of glacial inception. Using an ensemble of simulations generated by an Earth system model of intermediate complexity constrained by palaeoclimatic data, we suggest that glacial inception was narrowly missed before the beginning of the Industrial Revolution. The missed inception can be accounted for by the combined effect of relatively high late-Holocene CO2 concentrations and the low orbital eccentricity of the Earth(7). Additionally, our analysis suggests that even in the absence of human perturbations no substantial build-up of ice sheets would occur within the next several thousand years and that the current interglacial would probably last for another 50,000 years. However, moderate anthropogenic cumulative CO2 emissions of 1,000 to 1,500 gigatonnes of carbon will postpone the next glacial inception by at least 100,000 years(8,9). Our simulations demonstrate that under natural conditions alone the Earth system would be expected to remain in the present delicately balanced interglacial climate state, steering clear of both large-scale glaciation of the Northern Hemisphere and its complete deglaciation, for an unusually long time. Y1 - 2016 U6 - https://doi.org/10.1038/nature16494 SN - 0028-0836 SN - 1476-4687 VL - 529 SP - 200 EP - U159 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Archambault, S. A1 - Archer, A. A1 - Aune, T. A1 - Barnacka, Anna A1 - Benbow, W. A1 - Bird, R. A1 - Buchovecky, M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cardenzana, J. V. A1 - Cerruti, M. A1 - Chen, Xuhui A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Connolly, M. P. A1 - Cui, W. A1 - Dickinson, H. J. A1 - Dumm, J. A1 - Eisch, J. D. A1 - Falcone, A. A1 - Feng, Q. A1 - Finley, J. P. A1 - Fleischhack, H. A1 - Flinders, A. A1 - Fortin, P. A1 - Fortson, L. A1 - Furniss, A. A1 - Gillanders, G. H. A1 - Griffin, S. A1 - Grube, J. A1 - Gyuk, G. A1 - Huetten, M. A1 - Hakansson, Nils A1 - Hanna, D. A1 - Holder, J. A1 - Humensky, T. B. A1 - Johnson, C. A. A1 - Kaaret, P. A1 - Kar, P. A1 - Kelley-Hoskins, N. A1 - Kertzman, M. A1 - Khassen, Y. A1 - Kieda, D. A1 - Krause, M. A1 - Krennrich, F. A1 - Kumar, S. A1 - Lang, M. J. A1 - Maier, G. A1 - McArthur, S. A1 - McCann, A. A1 - Meagher, K. A1 - Millis, J. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nieto, D. A1 - Ong, R. A. A1 - Otte, A. N. A1 - Pandel, D. A1 - Park, N. A1 - Pelassa, V. A1 - Pohl, Martin A1 - Popkow, A. A1 - Pueschel, Elisa A1 - Quinn, J. A1 - Ragan, K. A1 - Reynolds, P. T. A1 - Richards, G. T. A1 - Roache, E. A1 - Rousselle, J. A1 - Rulten, C. A1 - Santander, M. A1 - Sembroski, G. H. A1 - Shahinyan, K. A1 - Smith, A. W. A1 - Staszak, D. A1 - Telezhinsky, Igor O. A1 - Tucci, J. V. A1 - Tyler, J. A1 - Vincent, S. A1 - Wakely, S. P. A1 - Weiner, O. M. A1 - Weinstein, A. A1 - Wilhelm, Alina A1 - Williams, D. A. A1 - Zitzer, B. T1 - EXCEPTIONALLY BRIGHT TEV FLARES FROM THE BINARY LS I+61 degrees 303 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - The TeV binary system LS I +61 degrees 303 is known for its regular, non-thermal emission pattern that traces the orbital period of the compact object in its 26.5 day orbit around its B0 Ve star companion. The system typically presents elevated TeV emission around apastron passage with flux levels between 5% and 15% of the steady flux from the Crab Nebula (> 300 GeV). In this article, VERITAS observations of LS I + 61 degrees. 303 taken in late 2014 are presented, during which bright TeV flares around apastron at flux levels peaking above 30% of the Crab Nebula flux were detected. This is the brightest such activity from this source ever seen in the TeV regime. The strong outbursts have rise and fall times of less than a day. The short timescale of the flares, in conjunction with the observation of 10 TeV photons from LS I + 61 degrees 303 during the flares, provides constraints on the properties of the accelerator in the source. KW - binaries: general KW - gamma-rays: general KW - stars: individual (LS I+61 degrees 303, VER J0240+612) KW - X-rays: binaries Y1 - 2016 U6 - https://doi.org/10.3847/2041-8205/817/1/L7 SN - 2041-8205 SN - 2041-8213 VL - 817 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Leonhardt, Helmar A1 - Gerhardt, Matthias A1 - Hoeppner, Nadine A1 - Krüger, Kirsten A1 - Tarantola, Marco A1 - Beta, Carsten T1 - Cell-substrate impedance fluctuations of single amoeboid cells encode cell-shape and adhesion dynamics JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We show systematic electrical impedance measurements of single motile cells on microelectrodes. Wild-type cells and mutant strains were studied that differ in their cell-substrate adhesion strength. We recorded the projected cell area by time-lapse microscopy and observed irregular oscillations of the cell shape. These oscillations were correlated with long-term variations in the impedance signal. Superposed to these long-term trends, we observed fluctuations in the impedance signal. Their magnitude clearly correlated with the adhesion strength, suggesting that strongly adherent cells display more dynamic cell-substrate interactions. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.93.012414 SN - 2470-0045 SN - 2470-0053 VL - 93 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schreck, Simon A1 - Pietzsch, Annette A1 - Kennedy, Brian A1 - Sathe, Conny A1 - Miedema, Piter S. A1 - Techert, Simone A1 - Strocov, Vladimir N. A1 - Schmitt, Thorsten A1 - Hennies, Franz A1 - Rubensson, Jan-Erik A1 - Föhlisch, Alexander T1 - Ground state potential energy surfaces around selected atoms from resonant inelastic x-ray scattering JF - Scientific reports N2 - Thermally driven chemistry as well as materials’ functionality are determined by the potential energy surface of a systems electronic ground state. This makes the potential energy surface a central and powerful concept in physics, chemistry and materials science. However, direct experimental access to the potential energy surface locally around atomic centers and to its long-range structure are lacking. Here we demonstrate how sub-natural linewidth resonant inelastic soft x-ray scattering at vibrational resolution is utilized to determine ground state potential energy surfaces locally and detect long-range changes of the potentials that are driven by local modifications. We show how the general concept is applicable not only to small isolated molecules such as O2 but also to strongly interacting systems such as the hydrogen bond network in liquid water. The weak perturbation to the potential energy surface through hydrogen bonding is observed as a trend towards softening of the ground state potential around the coordinating atom. The instrumental developments in high resolution resonant inelastic soft x-ray scattering are currently accelerating and will enable broad application of the presented approach. With this multidimensional potential energy surfaces that characterize collective phenomena such as (bio)molecular function or high-temperature superconductivity will become accessible in near future. Y1 - 2016 U6 - https://doi.org/10.1038/srep20054 SN - 2045-2322 VL - 6 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Rätzel, Dennis A1 - Wilkens, Martin A1 - Menzel, Ralf T1 - Gravitational properties of light-the gravitational field of a laser pulse JF - NEW JOURNAL OF PHYSICS N2 - The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources. KW - gravity KW - general relativity KW - laser pulses KW - electromagnetic radiation KW - linearized gravity KW - pp-wave solutions Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/2/023009 SN - 1367-2630 VL - 18 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Kappel, David A1 - Arnold, Gabriele A1 - Haus, Rainer T1 - Multi-spectrum retrieval of Venus IR surface emissivity maps from VIRTIS/VEX nightside measurements at Themis Regio JF - Icarus : international journal of solar system studies N2 - Renormalized emissivity maps of Themis Regio at the three surface windows are determined from 64 measurement repetitions. Retrieval errors are estimated by a statistical evaluation of maps derived from various disjoint selections of spectra and using different assumptions on the interfering parameters. Double standard deviation errors for the three surface windows amount to 3%, 8%, and 4%, respectively, allowing geologic interpretation. A comparison to results from an earlier error analysis based on synthetic spectra shows that unconsidered time variations of interfering atmospheric parameters are a major error source. Spatial variations of the 1.02 mu m surface emissivity of 20% that correspond to the difference between unweathered granitic and basaltic rocks would be easily detectable, but such variations are ruled out for the studied target area. Emissivity anomalies of up to 8% are detected at both 1.02 and 1.18 mu m. At present sensitivity, no anomalies are identified at 1.10 mu m, but anomalies exceeding the determined error level can be excluded. With single standard deviation significance, all three maps show interesting spatial emissivity variations. (C) 2015 Elsevier Inc. All rights reserved. KW - Venus, surface KW - Infrared observations KW - Radiative transfer Y1 - 2016 U6 - https://doi.org/10.1016/j.icarus.2015.10.014 SN - 0019-1035 SN - 1090-2643 VL - 265 SP - 42 EP - 62 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Ge, J. X. A1 - He, J. H. A1 - Yan, Huirong T1 - Effects of turbulent dust grain motion to interstellar chemistry JF - Monthly notices of the Royal Astronomical Society N2 - Theoretical studies have revealed that dust grains are usually moving fast through the turbulent interstellar gas, which could have significant effects upon interstellar chemistry by modifying grain accretion. This effect is investigated in this work on the basis of numerical gas-grain chemical modelling. Major features of the grain motion effect in the typical environment of dark clouds (DC) can be summarized as follows: (1) decrease of gas-phase (both neutral and ionic) abundances and increase of surface abundances by up to 2-3 orders of magnitude; (2) shifts of the existing chemical jumps to earlier evolution ages for gas-phase species and to later ages for surface species by factors of about 10; (3) a few exceptional cases in which some species turn out to be insensitive to this effect and some other species can show opposite behaviours too. These effects usually begin to emerge from a typical DC model age of about 10(5) yr. The grain motion in a typical cold neutral medium (CNM) can help overcome the Coulomb repulsive barrier to enable effective accretion of cations on to positively charged grains. As a result, the grain motion greatly enhances the abundances of some gas-phase and surface species by factors up to 2-6 or more orders of magnitude in the CNM model. The grain motion effect in a typical molecular cloud (MC) is intermediate between that of the DC and CNM models, but with weaker strength. The grain motion is found to be important to consider in chemical simulations of typical interstellar medium. KW - astrochemistry KW - turbulence KW - ISM: abundances KW - ISM: clouds KW - dust, extinction KW - ISM: molecules Y1 - 2016 U6 - https://doi.org/10.1093/mnras/stv2560 SN - 0035-8711 SN - 1365-2966 VL - 455 SP - 3570 EP - 3587 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Puhlmann, Dirk A1 - Henkel, Carsten A1 - Heuer, Axel A1 - Pieplow, Gregor A1 - Menzel, Ralf T1 - Characterization of a remote optical element with bi-photons JF - Physica scripta : an international journal for experimental and theoretical physics N2 - We present a simple setup that exploits the interference of entangled photon pairs. 'Signal' photons are sent through a Mach–Zehnder-like interferometer, while 'idlers' are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger–Yelin–Englert inequality between contrast and predictability. KW - quantum optics KW - quantum eraser KW - entanglement KW - bi-photons Y1 - 2016 U6 - https://doi.org/10.1088/0031-8949/91/2/023006 SN - 0031-8949 SN - 1402-4896 VL - 91 SP - 113 EP - 114 PB - IOP Publ. Ltd. CY - Bristol ER - TY - GEN A1 - Metzler, Ralf T1 - PROTEIN PHYSICS Forever ageing T2 - Nature physics N2 - Single-molecule techniques have long given us insight into the motion and interactions of individual molecules. But simulations now show that the dynamics inside single proteins is not as simple as we thought — and that proteins are forever changing. Y1 - 2016 U6 - https://doi.org/10.1038/nphys3585 SN - 1745-2473 SN - 1745-2481 VL - 12 SP - 113 EP - 114 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Sandin, C. A1 - Steffen, M. A1 - Schoenberner, D. A1 - Rühling, Ute T1 - Hot bubbles of planetary nebulae with hydrogen-deficient winds I. Heat conduction in a chemically stratified plasma JF - Frontiers in psychology N2 - Heat conduction has been found a plausible solution to explain discrepancies between expected and measured temperatures in hot bubbles of planetary nebulae (PNe). While the heat conduction process depends on the chemical composition, to date it has been exclusively studied for pure hydrogen plasmas in PNe. A smaller population of PNe show hydrogen-deficient and helium-and carbon-enriched surfaces surrounded by bubbles of the same composition; considerable differences are expected in physical properties of these objects in comparison to the pure hydrogen case. The aim of this study is to explore how a chemistry-dependent formulation of the heat conduction affects physical properties and how it affects the X-ray emission from PN bubbles of hydrogen-deficient stars. We extend the description of heat conduction in our radiation hydrodynamics code to work with any chemical composition. We then compare the bubble-formation process with a representative PN model using both the new and the old descriptions. We also compare differences in the resulting X-ray temperature and luminosity observables of the two descriptions. The improved equations show that the heat conduction in our representative model of a hydrogen-deficient PN is nearly as efficient with the chemistry-dependent description; a lower value on the diffusion coefficient is compensated by a slightly steeper temperature gradient. The bubble becomes somewhat hotter with the improved equations, but differences are otherwise minute. The observable properties of the bubble in terms of the X-ray temperature and luminosity are seemingly unaffected. KW - conduction KW - hydrodynamics KW - planetary nebulae: general KW - stars: AGB and post-AGB KW - stars: Wolf-Rayet KW - X-rays: stars Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527357 SN - 1432-0746 VL - 586 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Cioni, Maria-Rosa L. A1 - Bekki, Kenji A1 - Girardi, Leo A1 - de Grijs, Richard A1 - Irwin, Mike J. A1 - Ivanov, Valentin D. A1 - Marconi, Marcella A1 - Oliveira, Joana M. A1 - Piatti, Andres E. A1 - Ripepi, Vincenzo A1 - van Loon, Jacco Th. T1 - XVII. Proper motions of the Small Magellanic Cloud and the Milky Way globular cluster 47 Tucanae JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - Aims. In this study we use multi-epoch near-infrared observations from the VISTA survey of the Magellanic Cloud system (VMC) to measure the proper motions of different stellar populations in a tile of 1.5 deg2 in size in the direction of the Galactic globular cluster 47 Tuc. We obtain the proper motion of the cluster itself, of the Small Magellanic Cloud (SMC), and of the field Milky Way stars. Methods. Stars of the three main stellar components are selected according to their spatial distributions and their distributions in colour−magnitude diagrams. Their average coordinate displacement is computed from the difference between multiple Ks-band observations for stars as faint as Ks = 19 mag. Proper motions are derived from the slope of the best-fitting line among ten VMC epochs over a time baseline of ~1 yr. Background galaxies are used to calibrate the absolute astrometric reference frame. Results. The resulting absolute proper motion of 47 Tuc is (μαcos(δ), μδ) = (+7.26 ± 0.03, −1.25 ± 0.03) mas yr-1. This measurement refers to about 35 000 sources distributed between 10′ and 60′ from the cluster centre. For the SMC we obtain (μαcos(δ), μδ) = (+1.16 ± 0.07, −0.81 ± 0.07) mas yr-1 from about 5250 red clump and red giant branch stars. The absolute proper motion of the Milky Way population in the line of sight (l = 305.9, b = −44.9) of this VISTA tile is (μαcos(δ), μδ) = (+10.22 ± 0.14, −1.27 ± 0.12) mas yr-1 and has been calculated from about 4000 sources. Systematic uncertainties associated with the astrometric reference system are 0.18 mas yr-1. Thanks to the proper motion we detect 47 Tuc stars beyond its tidal radius. KW - proper motions KW - surveys KW - Magellanic Clouds KW - globular clusters: individual: 47 Tucanae Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527004 SN - 1432-0746 VL - 586 SP - 67 EP - 75 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Kumph, Muir A1 - Henkel, Carsten A1 - Rabl, Peter A1 - Brownnutt, Michael A1 - Blatt, Rainer T1 - Electric-field noise above a thin dielectric layer on metal electrodes JF - NEW JOURNAL OF PHYSICS N2 - The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps. KW - ion trap KW - electric field noise KW - fluctuation dissipation Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/2/023020 SN - 1367-2630 VL - 18 SP - 1125 EP - 1136 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Godec, Aljaz A1 - Metzler, Ralf T1 - First passage time distribution in heterogeneity controlled kinetics: going beyond the mean first passage time JF - Scientific reports N2 - The first passage is a generic concept for quantifying when a random quantity such as the position of a diffusing molecule or the value of a stock crosses a preset threshold (target) for the first time. The last decade saw an enlightening series of new results focusing mostly on the so-called mean and global first passage time (MFPT and GFPT, respectively) of such processes. Here we push the understanding of first passage processes one step further. For a simple heterogeneous system we derive rigorously the complete distribution of first passage times (FPTs). Our results demonstrate that the typical FPT significantly differs from the MFPT, which corresponds to the long time behaviour of the FPT distribution. Conversely, the short time behaviour is shown to correspond to trajectories connecting directly from the initial value to the target. Remarkably, we reveal a previously overlooked third characteristic time scale of the first passage dynamics mirroring brief excursion away from the target. Y1 - 2016 U6 - https://doi.org/10.1038/srep20349 SN - 2045-2322 VL - 6 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Zaks, Michael A. A1 - Tomov, Petar T1 - Onset of time dependence in ensembles of excitable elements with global repulsive coupling JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider the effect of global repulsive coupling on an ensemble of identical excitable elements. An increase of the coupling strength destabilizes the synchronous equilibrium and replaces it with many attracting oscillatory states, created in the transcritical heteroclinic bifurcation. The period of oscillations is inversely proportional to the distance from the critical parameter value. If the elements interact with the global field via the first Fourier harmonics of their phases, the stable equilibrium is in one step replaced by the attracting continuum of periodic motions. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.93.020201 SN - 2470-0045 SN - 2470-0053 VL - 93 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Sebek, Michael A1 - Tönjes, Ralf A1 - Kiss, Istvan Z. T1 - Complex Rotating Waves and Long Transients in a Ring Network of Electrochemical Oscillators with Sparse Random Cross-Connections JF - Physical review letters N2 - We perform experiments and phase model simulations with a ring network of oscillatory electrochemical reactions to explore the effect of random connections and nonisochronicity of the interactions on the pattern formation. A few additional links facilitate the emergence of the fully synchronized state. With larger nonisochronicity, complex rotating waves or persistent irregular phase dynamics can derail the convergence to global synchronization. The observed long transients of irregular phase dynamics exemplify the possibility of a sudden onset of hypersynchronous behavior without any external stimulus or network reorganization. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevLett.116.068701 SN - 0031-9007 SN - 1079-7114 VL - 116 SP - 3001 EP - 3009 PB - American Physical Society CY - College Park ER - TY - GEN A1 - Battiston, Stefano A1 - Farmer, J. Doyne A1 - Flache, Andreas A1 - Garlaschelli, Diego A1 - Haldane, Andrew G. A1 - Heesterbeek, Hans A1 - Hommes, Cars A1 - Jaeger, Carlo A1 - May, Robert A1 - Scheffer, Marten T1 - COMPLEX SYSTEMS Complexity theory and financial regulation T2 - Science N2 - Traditional economic theory could not explain, much less predict, the near collapse of the financial system and its long-lasting effects on the global economy. Since the 2008 crisis, there has been increasing interest in using ideas from complexity theory to make sense of economic and financial markets. Concepts, such as tipping points, networks, contagion, feedback, and resilience have entered the financial and regulatory lexicon, but actual use of complexity models and results remains at an early stage. Recent insights and techniques offer potential for better monitoring and management of highly interconnected economic and financial systems and, thus, may help anticipate and manage future crises. Y1 - 2016 U6 - https://doi.org/10.1126/science.aad0299 SN - 0036-8075 SN - 1095-9203 VL - 351 SP - 818 EP - 819 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Abeysekara, A. U. A1 - Archambault, S. A1 - Archer, A. A1 - Benbow, W. A1 - Bird, R. A1 - Buchovecky, M. A1 - Buckley, J. H. A1 - Byrum, K. A1 - Cardenzana, J. V. A1 - Cerruti, M. A1 - Chen, Xuhui A1 - Christiansen, J. L. A1 - Ciupik, L. A1 - Cui, W. A1 - Dickinson, H. J. A1 - Eisch, J. D. A1 - Errando, M. A1 - Falcone, A. A1 - Fegan, D. J. A1 - Feng, Q. A1 - Finley, J. P. A1 - Fleischhack, H. A1 - Fortin, P. A1 - Fortson, L. A1 - Furniss, A. A1 - Gillanders, G. H. A1 - Griffin, S. A1 - Grube, J. A1 - Gyuk, G. A1 - Huetten, M. A1 - Hakansson, Nils A1 - Hanna, D. A1 - Holder, J. A1 - Humensky, T. B. A1 - Johnson, C. A. A1 - Kaaret, P. A1 - Kar, P. A1 - Kelley-Hoskins, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krause, M. A1 - Krennrich, F. A1 - Kumar, S. A1 - Lang, M. J. A1 - Lin, T. T. Y. A1 - Maier, G. A1 - McArthur, S. A1 - McCann, A. A1 - Meagher, K. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nieto, D. A1 - Ong, R. A. A1 - Otte, A. N. A1 - Park, N. A1 - Perkins, J. S. A1 - Petrashyk, A. A1 - Pohl, Martin A1 - Popkow, A. A1 - Pueschel, Elisa A1 - Quinn, J. A1 - Ragan, K. A1 - Ratliff, G. A1 - Reynolds, P. T. A1 - Richards, G. T. A1 - Roache, E. A1 - Santander, M. A1 - Sembroski, G. H. A1 - Shahinyan, K. A1 - Staszak, D. A1 - Telezhinsky, Igor O. A1 - Tucci, J. V. A1 - Tyler, J. A1 - Vincent, S. A1 - Wakely, S. P. A1 - Weiner, O. M. A1 - Weinstein, A. A1 - Williams, D. A. A1 - Zitzer, B. T1 - A SEARCH FOR BRIEF OPTICAL FLASHES ASSOCIATED WITH THE SETI TARGET KIC 8462852 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - The F-type star KIC. 8462852 has recently been identified as an exceptional target for search for extraterrestrial intelligence (SETI) observations. We describe an analysis methodology for optical SETI, which we have used to analyze nine hours of serendipitous archival observations of KIC. 8462852 made with the VERITAS gamma-ray observatory between 2009 and 2015. No evidence of pulsed optical beacons, above a pulse intensity at the Earth of approximately 1 photon m(-2), is found. We also discuss the potential use of imaging atmospheric Cherenkov telescope arrays in searching for extremely short duration optical transients in general. KW - astrobiology KW - extraterrestrial intelligence KW - methods: observational KW - stars: individual ( KIC 8462852) KW - techniques: photometric Y1 - 2016 U6 - https://doi.org/10.3847/2041-8205/818/2/L33 SN - 2041-8205 SN - 2041-8213 VL - 818 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Liu, Rui A1 - Kliem, Bernhard A1 - Titov, Viacheslav S. A1 - Chen, Jun A1 - Wang, Yuming A1 - Wang, Haimin A1 - Liu, Chang A1 - Xu, Yan A1 - Wiegelmann, Thomas T1 - STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10–12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number ${{ \mathcal T }}_{w}$ for each individual field line. The MFR is moderately twisted ($| {{ \mathcal T }}_{w}| \lt 2$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum $| {{ \mathcal T }}_{w}| $ is a reliable proxy of the rope axis, and that the MFR's peak $| {{ \mathcal T }}_{w}| $ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in $| {{ \mathcal T }}_{w}| $ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that ${{ \mathcal T }}_{w}$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares. KW - coronal mass ejections (CMEs) KW - Sun: corona KW - Sun: filaments, pominences KW - Sun: flares KW - Sun: magnetic fields Y1 - 2016 U6 - https://doi.org/10.3847/0004-637X/818/2/148 SN - 0004-637X SN - 1538-4357 VL - 818 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Shi, Wenqin A1 - Eijt, Stephan W. H. A1 - Sandeep, Chandramathi Sukumaran Suchand A1 - Siebbeles, Laurens D. A. A1 - Houtepen, Arjan J. A1 - Kinge, Sachin A1 - Bruck, Ekkes A1 - Barbiellini, Bernardo A1 - Bansil, Arun T1 - Ligand-surface interactions and surface oxidation of colloidal PbSe quantum dots revealed by thin-film positron annihilation methods JF - Applied physics letters N2 - Positron Two Dimensional Angular Correlation of Annihilation Radiation (2D-ACAR) measurements reveal modifications of the electronic structure and composition at the surfaces of PbSe quantum dots (QDs), deposited as thin films, produced by various ligands containing either oxygen or nitrogen atoms. In particular, the 2D--ACAR measurements on thin films of colloidal PbSe QDs capped with oleic acid ligands yield an increased intensity in the electron momentum density (EMD) at high momenta compared to PbSe quantum dots capped with oleylamine. Moreover, the EMD of PbSe QDs is strongly affected by the small ethylenediamine ligands, since these molecules lead to small distances between QDs and favor neck formation between near neighbor QDs, inducing electronic coupling between neighboring QDs. The high sensitivity to the presence of oxygen atoms at the surface can be also exploited to monitor the surface oxidation of PbSe QDs upon exposure to air. Our study clearly demonstrates that positron annihilation spectroscopy applied to thin films can probe surface transformations of colloidal semiconductor QDs embedded in functional layers. (C) 2016 AIP Publishing LLC. Y1 - 2016 U6 - https://doi.org/10.1063/1.4942609 SN - 0003-6951 SN - 1077-3118 VL - 108 SP - 213 EP - 230 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Lenske, Gerlinde A1 - Wagner, Wolfgang A1 - Wirth, Joachim A1 - Thillmann, Hubertina A1 - Cauet, Eva A1 - Liepertz, Sven A1 - Leutner, Detlev T1 - The importance of pedagogical knowledge for classroom management and for and for students’ achievement JF - Zeitschrift für Erziehungswissenschaft N2 - Im Rahmen der vorliegenden Studie wurde untersucht, ob das pädagogisch-psychologische Wissen von Lehrkräften die prozessuale Qualität des Physikunterrichts mit Blick auf die Klassenführung und den Lernzuwachs der Schülerinnen und Schüler beeinflusst. Das pädagogisch-psychologische Professionswissen, konzeptualisiert als ein fächerübergreifendes, handlungsleitendes Wissen über Strategien und Mittel zur Unterrichtsgestaltung, wurde über einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualität wurde die Klassenführung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Schülerinnen und Schüler wurde über standardisierte Fachwissenstests im Prä-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkräfte und deren Schülerinnen und Schüler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das pädagogisch-psychologische Professionswissen über die Klassenführung vermittelt den Lernzuwachs der Schüler und Schülerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students’ learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers’ pedagogical knowledge, mediated by their classroom management, has a positive effect on their students’ learning achievement. KW - Classroom management KW - Instructional quality KW - Mediation-model KW - Pedagogical professional knowledge KW - Professional knowledge Y1 - 2016 U6 - https://doi.org/10.1007/s11618-015-0659-x SN - 1434-663X SN - 1862-5215 VL - 19 SP - 211 EP - 233 PB - Springer CY - Wiesbaden ER - TY - JOUR A1 - Reinhardt, Matthias A1 - Koc, Azize A1 - Leitenberger, Wolfram A1 - Gaal, Peter A1 - Bargheer, Matias T1 - Optimized spatial overlap in optical pump-X-ray probe experiments with high repetition rate using laser-induced surface distortions JF - Journal of synchrotron radiation N2 - Ultrafast X-ray diffraction experiments require careful adjustment of the spatial overlap between the optical excitation and the X-ray probe pulse. This is especially challenging at high laser repetition rates. Sample distortions caused by the large heat load on the sample and the relatively low optical energy per pulse lead to only tiny signal changes. In consequence, this results in small footprints of the optical excitation on the sample, which turns the adjustment of the overlap difficult. Here a method for reliable overlap adjustment based on reciprocal space mapping of a laser excited thin film is presented. KW - ultrafast X-ray diffraction KW - nanostructures KW - surface deformation KW - heat diffusion KW - optical pump Y1 - 2016 U6 - https://doi.org/10.1107/S1600577515024443 SN - 1600-5775 VL - 23 SP - 474 EP - 479 PB - International Union of Crystallography CY - Chester ER - TY - JOUR A1 - Eckert, Sebastian A1 - Miedema, P. S. A1 - Quevedo, W. A1 - Fondell, Mattis A1 - Beye, Martin A1 - Pietzsch, Annette A1 - Ross, M. A1 - Khalil, M. A1 - Föhlisch, Alexander T1 - Molecular structures and protonation state of 2-Mercaptopyridine in aqueous solution JF - Chemical physics letters N2 - The speciation of 2-Mercaptopyridine in aqueous solution has been investigated with nitrogen 1s Near Edge X-ray Absorption Fine Structure spectroscopy and time dependent Density Functional Theory. The prevalence of distinct species as a function of the solvent basicity is established. No indications of dimerization towards high concentrations are found. The determination of different molecular structures of 2-Mercaptopyridine in aqueous solution is put into the context of proton-transfer in keto-enol and thione-thiol tautomerisms. (C) 2016 The Authors. Published by Elsevier B.V. Y1 - 2016 U6 - https://doi.org/10.1016/j.cplett.2016.01.050 SN - 0009-2614 SN - 1873-4448 VL - 647 SP - 103 EP - 106 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Wenz, Leonie A1 - Kalkuhl, Matthias A1 - Steckel, Jan Christoph A1 - Creutzig, Felix T1 - Teleconnected food supply shocks JF - Environmental research letters N2 - The 2008-2010 food crisis might have been a harbinger of fundamental climate-induced food crises with geopolitical implications. Heat-wave-induced yield losses in Russia and resulting export restrictions led to increases in market prices for wheat across the Middle East, likely contributing to the Arab Spring. With ongoing climate change, temperatures and temperature variability will rise, leading to higher uncertainty in yields for major nutritional crops. Here we investigate which countries are most vulnerable to teleconnected supply-shocks, i.e. where diets strongly rely on the import of wheat, maize, or rice, and where a large share of the population is living in poverty. We find that the Middle East is most sensitive to teleconnected supply shocks in wheat, Central America to supply shocks in maize, and Western Africa to supply shocks in rice. Weighing with poverty levels, Sub-Saharan Africa is most affected. Altogether, a simultaneous 10% reduction in exports of wheat, rice, and maize would reduce caloric intake of 55 million people living in poverty by about 5%. Export bans in major producing regions would put up to 200 million people below the poverty line at risk, 90% of which live in Sub-Saharan Africa. Our results suggest that a region-specific combination of national increases in agricultural productivity and diversification of trade partners and diets can effectively decrease future food security risks. KW - food security KW - trade shocks KW - vulnerability KW - climate change KW - teleconnections Y1 - 2016 U6 - https://doi.org/10.1088/1748-9326/11/3/035007 SN - 1748-9326 VL - 11 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Wisotzki, Lutz A1 - Bacon, Roland A1 - Blaizot, J. A1 - Brinchmann, Jarle A1 - Herenz, Edmund Christian A1 - Schaye, Joop A1 - Bouche, Nicolas A1 - Cantalupo, Sebastiano A1 - Contini, Thierry A1 - Carollo, C. M. A1 - Caruana, Joseph A1 - Courbot, J. -B. A1 - Emsellem, E. A1 - Kamann, S. A1 - Kerutt, Josephine Victoria A1 - Leclercq, F. A1 - Lilly, S. J. A1 - Patricio, V. A1 - Sandin, C. A1 - Steinmetz, Matthias A1 - Straka, Lorrie A. A1 - Urrutia, Tanya A1 - Verhamme, A. A1 - Weilbacher, Peter Michael A1 - Wendt, Martin T1 - Extended Lyman alpha haloes around individual high-redshift galaxies revealed by MUSE JF - Science N2 - We report the detection of extended Ly alpha emission around individual star-forming galaxies at redshifts z = 3-6 in an ultradeep exposure of the Hubble Deep Field South obtained with MUSE on the ESO-VLT. The data reach a limiting surface brightness (1 sigma) of similar to 1 x 10(-19) erg s(-1) cm(-2) arcsec(-2) in azimuthally averaged radial profiles, an order of magnitude improvement over previous narrowband imaging. Our sample consists of 26 spectroscopically confirmed Ly alpha-emitting, but mostly continuum-faint (m(AB) greater than or similar to 27) galaxies. In most objects the Ly alpha emission is considerably more extended than the UV continuum light. While five of the faintest galaxies in the sample show no significantly detected Ly alpha haloes, the derived upper limits suggest that this is due to insufficient S/N. Ly alpha haloes therefore appear to be ubiquitous even for low-mass (similar to 10(8)-10(9) M-circle dot) star-forming galaxies at z > 3. We decompose the Ly alpha emission of each object into a compact component tracing the UV continuum and an extended halo component, and infer sizes and luminosities of the haloes. The extended Ly alpha emission approximately follows an exponential surface brightness distribution with a scale length of a few kpc. While these haloes are thus quite modest in terms of their absolute sizes, they are larger by a factor of 5-15 than the corresponding rest-frame UV continuum sources as seen by HST. They are also much more extended, by a factor similar to 5, than Ly alpha haloes around low-redshift star-forming galaxies. Between similar to 40% and greater than or similar to 90% of the observed Ly alpha flux comes from the extended halo component, with no obvious correlation of this fraction with either the absolute or the relative size of the Ly alpha halo. Our observations provide direct insights into the spatial distribution of at least partly neutral gas residing in the circumgalactic medium of low to intermediate mass galaxies at z > 3. KW - galaxies: high-redshift KW - galaxies: evolution KW - galaxies: formation KW - cosmology: observations KW - intergalactic medium Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527384 SN - 1432-0746 VL - 587 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Przybilla, Norbert A1 - Fossati, Luca A1 - Hubrig, Swetlana A1 - Nieva, M. -F. A1 - Jaervinen, S. P. A1 - Castro, Norberto A1 - Schoeller, M. A1 - Ilyin, Ilya A1 - Butler, Keith A1 - Schneider, F. R. N. A1 - Oskinova, Lida A1 - Morel, T. A1 - Langer, N. A1 - de Koter, A. T1 - B fields in OB stars (BOB): Detection of a magnetic field in the He-strong star CPD-57 degrees 3509 JF - Organic letters N2 - Methods. Spectropolarimetric observations with FORS2 and HARPSpol are analysed using two independent approaches to quantify the magnetic field strength. A high-S/N FLAMES/GIRAFFE spectrum is analysed using a hybrid non-LTE model atmosphere technique. Comparison with stellar evolution models constrains the fundamental parameters of the star. Results. We obtain a firm detection of a surface averaged longitudinal magnetic field with a maximum amplitude of about 1 kG. Assuming a dipolar configuration of the magnetic field, this implies a dipolar field strength larger than 3.3 kG. Moreover, the large amplitude and fast variation (within about 1 day) of the longitudinal magnetic field implies that CPD-57 degrees 3509 is spinning very fast despite its apparently slow projected rotational velocity. The star should be able to support a centrifugal magnetosphere, yet the spectrum shows no sign of magnetically confined material; in particular, emission in H alpha is not observed. Apparently, the wind is either not strong enough for enough material to accumulate in the magnetosphere to become observable or, alternatively, some leakage process leads to loss of material from the magnetosphere. The quantitative spectroscopic analysis of the star yields an effective temperature and a logarithmic surface gravity of 23 750 +/- 250 K and 4.05 +/- 0.10, respectively, and a surface helium fraction of 0.28 +/- 0.02 by number. The surface abundances of C, N, O, Ne, S, and Ar are compatible with the cosmic abundance standard, whereas Mg, Al, Si, and Fe are depleted by about a factor of 2. This abundance pattern can be understood as the consequence of a fractionated stellar wind. CPD-57 degrees 3509 is one of the most evolved He-strong stars known with an independent age constraint due to its cluster membership. KW - stars: abundances KW - stars: atmospheres KW - stars: evolution KW - stars: magnetic field KW - stars: individual: CPD-57 degrees 3509 KW - stars: massive Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527646 SN - 1432-0746 VL - 587 PB - EDP Sciences CY - Les Ulis ER - TY - GEN A1 - Barniske, Andreas A1 - Oskinova, Lida A1 - Hamann, Wolf-Rainer T1 - Two extremely luminous WN stars in the Galactic center with circumstellar emission from dust and gas (vol 486, pg 971, 2008) T2 - Physical chemistry, chemical physics : a journal of European Chemical Societies KW - stars: Wolf-Rayet KW - HII regions KW - Galaxy: center KW - stars: individual: WR 102ka KW - stars: individual: WR 102c KW - errata, addenda Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/200809568e SN - 1432-0746 VL - 587 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Kuznetsov, Sergey P. T1 - Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism JF - Technical Physics N2 - Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared. Y1 - 2016 U6 - https://doi.org/10.1134/S1063784216030129 SN - 1063-7842 SN - 1090-6525 VL - 61 SP - 436 EP - 445 PB - Pleiades Publ. CY - New York ER - TY - JOUR A1 - Zehbe, Kerstin A1 - Kollosche, Matthias A1 - Lardong, Sebastian A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Taubert, Andreas T1 - Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties JF - International journal of molecular sciences N2 - Ionogels (IGs) based on poly(methyl methacrylate) (PMMA) and the metal-containing ionic liquids (ILs) bis-1-butyl-3-methlimidazolium tetrachloridocuprate(II), tetrachloride cobaltate(II), and tetrachlorido manganate(II) have been synthesized and their mechanical and electrical properties have been correlated with their microstructure. Unlike many previous examples, the current IGs show a decreasing stability in stress-strain experiments on increasing IL fractions. The conductivities of the current IGs are lower than those observed in similar examples in the literature. Both effects are caused by a two-phase structure with micrometer-sized IL-rich domains homogeneously dispersed an IL-deficient continuous PMMA phase. This study demonstrates that the IL-polymer miscibility and the morphology of the IGs are key parameters to control the (macroscopic) properties of IGs. KW - microstructure KW - ionogels KW - ionic liquids KW - phase separation KW - mechanical properties KW - ionic conductivity Y1 - 2016 U6 - https://doi.org/10.3390/ijms17030391 SN - 1422-0067 VL - 17 PB - MDPI CY - Basel ER - TY - JOUR A1 - Bolotov, M. I. A1 - Osipov, Grigory V. A1 - Pikovskij, Arkadij T1 - Marginal chimera state at cross-frequency locking of pulse-coupled neural networks JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider two coupled populations of leaky integrate-and-fire neurons. Depending on the coupling strength, mean fields generated by these populations can have incommensurate frequencies or become frequency locked. In the observed 2:1 locking state of the mean fields, individual neurons in one population are asynchronous with the mean fields, while in another population they have the same frequency as the mean field. These synchronous neurons form a chimera state, where part of them build a fully synchronized cluster, while other remain scattered. We explain this chimera as a marginal one, caused by a self-organized neutral dynamics of the effective circle map. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.93.032202 SN - 2470-0045 SN - 2470-0053 VL - 93 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Goychuk, Igor T1 - Molecular machines operating on the nanoscale: from classical to quantum JF - Beilstein journal of nanotechnology N2 - The main physical features and operating principles of isothermal nanomachines in the microworld, common to both classical and quantum machines, are reviewed. Special attention is paid to the dual, constructive role of dissipation and thermal fluctuations, the fluctuation-dissipation theorem, heat losses and free energy transduction, thermodynamic efficiency, and thermodynamic efficiency at maximum power. Several basic models are considered and discussed to highlight generic physical features. This work examines some common fallacies that continue to plague the literature. In particular, the erroneous beliefs that one should minimize friction and lower the temperature for high performance of Brownian machines, and that the thermodynamic efficiency at maximum power cannot exceed one-half are discussed. The emerging topic of anomalous molecular motors operating subdiffusively but very efficiently in the viscoelastic environment of living cells is also discussed. KW - anomalous dynamics with memory KW - Brownian nanomachines KW - nanoscale friction and thermal noise KW - quantum effects KW - thermodynamic efficiency Y1 - 2016 U6 - https://doi.org/10.3762/bjnano.7.31 SN - 2190-4286 VL - 7 SP - 328 EP - 350 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften CY - Frankfurt, Main ER - TY - JOUR A1 - Paulke, Andreas A1 - Stranks, Samuel D. A1 - Kniepert, Juliane A1 - Kurpiers, Jona A1 - Wolff, Christian Michael A1 - Schön, Natalie A1 - Snaith, Henry J. A1 - Brenner, Thomas J. K. A1 - Neher, Dieter T1 - Charge carrier recombination dynamics in perovskite and polymer solar cells JF - Applied physics letters N2 - Time-delayed collection field experiments are applied to planar organometal halide perovskite (CH3NH3PbI3) based solar cells to investigate charge carrier recombination in a fully working solar cell at the nanosecond to microsecond time scale. Recombination of mobile (extractable) charges is shown to follow second-order recombination dynamics for all fluences and time scales tested. Most importantly, the bimolecular recombination coefficient is found to be time-dependent, with an initial value of ca. 10(-9) cm(3)/s and a progressive reduction within the first tens of nanoseconds. Comparison to the prototypical organic bulk heterojunction device PTB7:PC71BM yields important differences with regard to the mechanism and time scale of free carrier recombination. (C) 2016 AIP Publishing LLC. Y1 - 2016 U6 - https://doi.org/10.1063/1.4944044 SN - 0003-6951 SN - 1077-3118 VL - 108 SP - 252 EP - 262 PB - American Institute of Physics CY - Melville ER -