TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Peter, Martin G. T1 - Analysis of deacetylation deree in chitosans from various sources Y1 - 1998 ER - TY - JOUR A1 - Struszczyk, Marcin Henryk A1 - Loth, Fritz A1 - Köhler, L. A. A1 - Peter, Martin G. T1 - Characterization of chitosan Y1 - 1998 ER - TY - JOUR A1 - Berth, Gisela A1 - Dautzenberg, Herbert A1 - Peter, Martin G. T1 - Physico-chemical characterization of chitosans varying in degree of acetylation Y1 - 1998 SN - 0144-8617 ER - TY - JOUR A1 - Yenesew, Abiy A1 - Midiwo, Jacob O. A1 - Heydenreich, Matthias A1 - Peter, Martin G. T1 - Four isoflavanones from stem bark of erythrina sacleuxii Y1 - 1998 ER - TY - JOUR A1 - Yenesew, Abiy A1 - Midiwo, Jacob O. A1 - Meisner, M. A1 - Heydenreich, Matthias A1 - Peter, Martin G. T1 - Two prenylated flavanones from stem bark of erythrina burttii Y1 - 1998 ER - TY - JOUR A1 - Duvinage, Brigitte T1 - Baustoffe Y1 - 1998 ER - TY - JOUR A1 - Duvinage, Brigitte T1 - Begriffe : Begriffsbildung Y1 - 1998 ER - TY - JOUR A1 - Reiche, K. B. A1 - Starke, Ines A1 - Kleinpeter, Erich A1 - Holdt, Hans-Jürgen T1 - Host-guest complexation of imine-type meta-bridged bis(benzo crown ether)s with alkali cations in the gas phase under FAB conditions Y1 - 1998 ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Heydenreich, Matthias A1 - Woller, Jochen A1 - Wolf, Gunter A1 - Koch, Andreas A1 - Kempter, Gerhard A1 - Pihlaja, Kalevi T1 - Configuration and stereodynamics of exo/endoisomeric push-pull alkenes of pentadiene structure Y1 - 1998 ER - TY - JOUR A1 - Heydenreich, Matthias A1 - Koch, Andreas A1 - Ristau, Thomas A1 - Knoll, Susanne A1 - Heinicke, Jochen A1 - Sieler, Joachim A1 - Niemitz, Matthias A1 - Mühlstädt, Manfred A1 - Kleinpeter, Erich T1 - Conformational analysis of sulfur-containing heterocycles ; part I: synthesis and structural determination of diastereomerically pure 4,6-bis(phenoxymethyl)-1,2,5-trithiepanes Y1 - 1998 ER - TY - JOUR A1 - Hilfert, Liane A1 - Sarodnick, Gerhard A1 - Kempter, Gerhard A1 - Kleinpeter, Erich T1 - 1H, 13C and 15 N NMR study and molecular modelling of 2,3- disubstituted quinoxalines with sterically hinderered aromatic and heteroaromatic substituents Y1 - 1998 ER - TY - JOUR A1 - Kosmella, Sabine A1 - Koetz, Joachim A1 - Shirahama, K. A1 - Liu, J. T1 - The cooperative nature of complex formation in mixed polyelectrolyte-surfactant systems Y1 - 1998 ER - TY - JOUR A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Polyelectrolyte complex formation with chitosan Y1 - 1998 ER - TY - JOUR A1 - Streffer, Katrin A1 - Kaatz, Helvi A1 - Bauer, Christian G. A1 - Makower, Alexander A1 - Schulmeister, Thomas A1 - Scheller, Frieder W. A1 - Peter, Martin G. A1 - Wollenberger, Ursula T1 - Application of a sensitive catechol detector for determination of tyrosinase inhibitors Y1 - 1998 ER - TY - JOUR A1 - Mahapatra, Susanta A1 - Vetter, Reinhard A1 - Zuhrt, Christian A1 - Nguyen, Huu Tong A1 - Ritschel, Thomas A1 - Zülicke, Lutz T1 - Ground state potential energy surface, 3D time-dependent intramolecular dynamics and vibrational states of the N2H+ molecular ion Y1 - 1998 ER - TY - JOUR A1 - Beitz, Toralf A1 - Bechmann, Wolfgang A1 - Mitzner, Rolf T1 - Investigations of reactions of selected Azaarenes with radicals in water, 1. Hydroxyl and sulfate radicals Y1 - 1998 ER - TY - JOUR A1 - Schneider, Ingo A1 - Mross, A. A1 - Bechmann, Wolfgang T1 - Der Einfluss einer permanenten Mineralölkohlenwasserstoff-Kontamination auf Bodenmikroorganismen in der Döberitzer Heide Y1 - 1998 ER - TY - JOUR A1 - Benassi, Rois A1 - Bregulla, Antje A1 - Friedrich, Alwin A1 - Henning, Dietrich A1 - Heydenreich, Matthias A1 - Mickler, Wulfhard A1 - Kleinpeter, Erich A1 - Kempter, Gerhard A1 - Schilde, Uwe A1 - Taddei, F. T1 - NMR spectroscopic and theoretical structural study of 5-exo-methylene-substituted hydantoins Y1 - 1998 ER - TY - JOUR A1 - Cierpiszewski, Ryszard A1 - Rusinska-Roszak, D. A1 - Szymanowski, Jan A1 - Mickler, Wulfhard A1 - Uhlemann, Erhard T1 - Rate of coper extraction and structure of model ß-diketones and 4-acyl-5-pyrazolones Y1 - 1998 ER - TY - JOUR A1 - Kallies, Bernd A1 - Mitzner, Rolf T1 - Structural Properties of Protonated Acyl Derivatives as Studied by Quantum Mechanics N2 - Basicities of 16 acyl compounds including selected aldehydes, ketones, esters, amides and ureas in the gas phase and in water were calculated with the Becke3LYP/6-31G* method. Solvent effects were modeled using a polarizable electrostatic continuum representation of the solvent. The properties of the electron densities of protonated molecules were described by localized bond orbitals. Our results suggest that the carbonyl oxygen is the preferred site of protonation for all molecules studied. Calculated pKa values in water range from -12 for aldehydes to + 1.5 for ureas. They agree well with published experimental data. We found that a high basicity of acyl compounds at the carbonyl oxygen is coupled with a large amount of additional resonance stabilization at the carbonyl group. The protonation of the leaving group of eaters, amides and ureas is less preferred, but the basicity difference between C=O and -OR or -NR2 decreases from esters to ureas. Calculated pKa values for this site range from -18 for esters to + 3 for ureas. These values are often not accessible by experiment. The structure of carboxylic acid derivatives protonated at the leaving group is determined by prefragmentation of the molecules into an acylium ion or positively charged isocyanate and an alcohol or amine. (C) 1998 Elsevier Science B.V. Y1 - 1998 ER -