TY  - JOUR
A1  - Schmidt, Bernd
A1  - Geissler, Diana
T1  - Olefin-Metathesis-Based Synthesis of Furans by an RCM/Deprotonation/Phosphorylation Sequence and Their Diels-Alder Reactions
JF  - European journal of organic chemistry
N2  - Butenolides, obtained by ring-closing metathesis (RCM) of acrylates, undergo quantitative deprotonation with amide bases. Trapping of the resulting anions with electrophiles, for example, chlorophosphates, give furans. Subsequent DielsAlder reaction and acid-catalysed rearrangement of the resulting oxabicyclonorbornadienes give substituted benzenes.
KW  - Lactones
KW  - Metathesis
KW  - Ruthenium
KW  - Oxygen heterocycles
KW  - Metalation
Y1  - 2011
U6  - https://doi.org/10.1002/ejoc.201101078
SN  - 1434-193X
IS  - 35
SP  - 7140
EP  - 7147
PB  - Wiley-VCH
CY  - Weinheim
ER  -