TY  - JOUR
A1  - Lazareva, Nataliya F.
A1  - Albanov, Alexander I.
A1  - Shainyan, Bagrat A.
A1  - Kleinpeter, Erich
T1  - Synthesis and conformational properties of substituted 1,4,2-oxazasilinanes low temperature NMR study and quantum chemical calculations
JF  - Tetrahedron
N2  - A number of N-substituted 2,2-dimethyl-1,4,2-oxazasilinanes 1 were synthesized and studied by variable temperature dynamic H-1 and C-13 NMR spectroscopy, room temperature N-15 NMR spectroscopy and theoretical calculations at the DFT and MP2 levels of theory. Both the preferred conformers were assigned and the barrier to the ring inversion of the saturated six-membered ring determined. From 1 the corresponding methyl iodide salts were produced, their structure studied by X-ray analysis and found to be in excellent agreement with the results of the theoretical calculations.
KW  - 1,4,2-Oxazasilinanes
KW  - Conformational analysis
KW  - Dynamic NMR
KW  - X-ray analysis
KW  - Quantum chemical calculations
Y1  - 2012
U6  - https://doi.org/10.1016/j.tet.2011.11.077
SN  - 0040-4020
VL  - 68
IS  - 4
SP  - 1097
EP  - 1104
PB  - Elsevier
CY  - Oxford
ER  -