TY - JOUR A1 - Poghosyan, Armen H. A1 - Shahinyan, A. A. A1 - Koetz, Joachim T1 - Self-assembled monolayer formation of distorted cylindrical AOT micelles on gold surfaces JF - Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects N2 - Self-assembling features of sodium dioctyl sulfosuccinate (AOT) molecules and micelle adsorption on gold Au (111) surfaces have been examined using molecular dynamics simulation. We argue that AOT micelles display a strong adsorption on gold surfaces resulting in distorted cylindrical micelles attached to the (111) facets. The well protected Au(111) facets decorated by a dense packed elongated ellipsoidal AOT layer hinder the diffusion of the reactant to the (111) facets and could result in the preferential growth of ultra-thin gold nanoplatelets. KW - Surfactant micelles KW - Adsorption KW - Gold surface KW - Molecular dynamics Y1 - 2018 U6 - https://doi.org/10.1016/j.colsurfa.2018.02.067 SN - 0927-7757 SN - 1873-4359 VL - 546 SP - 20 EP - 27 PB - Elsevier CY - Amsterdam ER -