TY  - JOUR
A1  - Kraus, Florian
A1  - Aschenbrenner, Jürgen C.
A1  - Klamroth, Tillmann
A1  - Korber, Nikolaus
T1  - Hydrogen polyphosphides P3H23- and P3H32- : synthesis and crystal structure of K3(P3H2)·2.3NH3, Rb3(P3H2)·NH3, [Rb(18-crown-6)]2(P3H3)·7.5NH3, and [Cs(18-crown-6)]2(P3H3)·7NH3
N2  - The incongruous solvation of polyphosphides and phosphanes or the direct reduction of white phosphorus in liquid ammonia leads to the hydrogen polyphosphides catena-dihydrogen triphosphide, P3H23-, and catena-trihydrogen triphosphide, P3H32-, in the crystalline compounds K-3(P3H2)center dot 2.3NH(3) (1), Rb-3(P3H2)center dot NH3 (2), [Rb(18-crown-6)](2)(P3H3)center dot 7.5NH(3) (3), and [Cs(18-crown-6)](2)(P3H3)center dot 7NH(3) (4).
Y1  - 2009
UR  - http://pubs.acs.org/journal/inocaj
U6  - https://doi.org/10.1021/Ic8014546
SN  - 0020-1669
ER  -