TY - THES A1 - Alahverdjieva, Veneta T1 - Experimental study of mixed protein/surfactant systems at the aqueous solution/air interface Y1 - 2007 CY - Potsdam ER - TY - JOUR A1 - Dosche, Carsten A1 - Mickler, Wulfhard A1 - Löhmannsröben, Hans-Gerd A1 - Agenet, Nicolas A1 - Vollhardt, K. Peter C. T1 - Photoinduced electron transfer in [N]phenylenes N2 - First studies of electron transfer in [N]phenylenes were performed in bimolecular quenching reactions of angular [3]- and triangular [4]phenylene with various electron acceptors. The relation between the quenching rate constants k(q) and the free energy change of the electron transfer (Delta G(CS)(0)) could be described by the Rehm- Weller equation. From the experimental results, a reorganization energy lambda of 0.7 eV was derived. Intramolecular electron transfer reactions were studied in an [N]phenylene bichomophore and a corresponding reference compound. Fluorescence lifetime and quantum yield of the bichromophor display a characteristic dependence on the solvent polarity, whereas the corresponding values of the reference compound remain constant. From the results, a nearly isoenergonic charge separation process can be determined. As the triplet quantum yield is nearly independent of the polarity, charge recombination leads to the population of the triplet state. Y1 - 2007 UR - http://www.sciencedirect.com/science/journal/10106030 U6 - https://doi.org/10.1016/j.jphotochem.2006.12.038 SN - 1010-6030 ER - TY - THES A1 - Entrialgo Castano, Maria T1 - Hydrolytic degradation of aliphatic polyester: molecular modeling and quantum mechanical investigations Y1 - 2007 CY - Potsdam ER - TY - THES A1 - Frankovitch, Christine Marie T1 - Optical methods for monitoring biological parameters of phototropic microorganisms during cultivation Y1 - 2007 CY - Potsdam ER - TY - JOUR A1 - Haebel, Sophie A1 - Bahrke, Sven A1 - Peter, Martin G. T1 - Quantitative sequencing of complex mixtures of heterochitooligosaccharides by vMALDI-linear ion trap mass spectrometry N2 - Heterochitooligosaccharides possess interesting biol. properties. Isobaric mixts. of such linear heterochitooligosaccharides can be obtained by chem. or enzymic degrdn. of chitosan. However, the sepn. of such mixts. is a challenging anal. problem which is so far unresolved. It is shown that these isobaric mixts. can be sequenced and quantified simultaneously using std. derivatization and multistage tandem mass spectrometric techniques. A linear ion trap mass spectrometer equipped with a vacuum matrix-assisted laser desorption ionization (vMALDI) source is used to perform MS2 as well as MS3 expts. [on SciFinder (R)]. Y1 - 2007 UR - http://pubs.acs.org/loi/ancham U6 - https://doi.org/10.1021/Ac062254u SN - 0003-2700 ER - TY - THES A1 - Kaper, Helenea T1 - Structure control of nanoscaled inorganic matter by ionic liquids Y1 - 2007 CY - Potsdam ER - TY - JOUR A1 - Kleinpeter, Erich T1 - Syntheses and conformational analyses of mono- and trans-1,4-dialkoxy substituted cyclohexanes : the steric substituent/skeleton interactions N2 - Mono- and trans-1,4-dialkoxy substituted cyclohexanes (alkyl=Me, Et, i-Pr, t-Bu) were prepared using the solvomercuration-demercuration (SM-DM) procedure. The axialaxial and axial,axialequatorial, equatorial conformational equilibria of the products were studied by low temperature 1H and 13C NMR spectroscopy in CD2Cl2. The structures and relative energies of the participating conformers were calculated at both the B3LYP (6-311G*//6-311+G*) and MP2 (6-311+G*//6-311G*) levels of theory. In the case of DFT, good correlations of ;Gocalcd versus ;Goexptl were obtained. Both the structures and the energy differences of the conformers have been discussed with respect to established models of conformational analysis, viz. steric and hyperconjugative interactions. In addition, 1JH,C coupling constants were considered with respect to the hyperconjugation present. Y1 - 2007 UR - http://www.sciencedirect.com/science/journal/00404020 U6 - https://doi.org/10.1016/j.tet.2007.06.094 SN - 0040-4020 ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Klod, Sabrina A1 - Koch, Andreas T1 - Visualization of through space NMR shieldings of aromatic and anti-aromatic molecules and a simple means to compare and estimate aromaticity N2 - Through space NMR shieldings of aromatic (benzene, mono-substituted and annelated benzenes, ferrocene, [14]- and [18]-annulenes, phenylenes and tetra- to heptahelicene) and anti-aromatic molecules (cyclobutadiene and pentalene) were assessed by ab initio molecular-orbital calculations. Employing the nucleus-independent chemical shifts (NICS) concept, these through space NMR shieldings were visualized as iso-chemical-shielding surfaces (ICSSs) and can be applied quantitatively to determine the stereochemistry of proximal nuclei. In addition, the distances in Å at ICSS values of ±0.1 ppm in-plane and perpendicular-to-center of the aromatic ring system were employed as a simple means to compare and estimate qualitatively the aromaticity of the systems at hand. Y1 - 2007 UR - http://www.sciencedirect.com/science/journal/01661280 U6 - https://doi.org/10.1016/j.theochem.2007.02.049 SN - 0166-1280 ER - TY - BOOK A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Polyelectrolytes and nanoparticles T3 - Springer laboratory manuals in polymer science Y1 - 2007 SN - 3-540-46381-X PB - Springer-Verlag CY - Heidelberg ER - TY - THES A1 - Krause, Pascal T1 - Many-electron dynamics in molecules by means of time-dependent configuration interaction methods Y1 - 2007 CY - Potsdam ER -