TY  - JOUR
A1  - Mazurek-Budzyńska, Magdalena
A1  - Behl, Marc
A1  - Neumann, Richard
A1  - Lendlein, Andreas
T1  - 4D-actuators by 3D-printing combined with water-based curing
JF  - Materials today. Communications
N2  - The shape and the actuation capability of state of the art robotic devices typically relies on multimaterial systems from a combination of geometry determining materials and actuation components. Here, we present multifunctional 4D-actuators processable by 3D-printing, in which the actuator functionality is integrated into the shaped body. The materials are based on crosslinked poly(carbonate-urea-urethane) networks (PCUU), synthesized in an integrated process, applying reactive extrusion and subsequent water-based curing. Actuation capability could be added to the PCUU, prepared from aliphatic oligocarbonate diol, isophorone diisocyanate (IPDI) and water, in a thermomechanical programming process. When programmed with a strain of epsilon(prog) = 1400% the PCUU networks exhibited actuation apparent by reversible elongation epsilon'(rev) of up to 22%. In a gripper a reversible bending epsilon'(rev)((be)(nd)()) in the range of 37-60% was achieved when the actuation temperature (T-high) was varied between 45 degrees C and 49 degrees C. The integration of actuation and shape formation could be impressively demonstrated in two PCUU-based reversible fastening systems, which were able to hold weights of up to 1.1 kg. In this way, the multifunctional materials are interesting candidate materials for robotic applications where a freedom in shape design and actuation is required as well as for sustainable fastening systems.
KW  - 4D-actuation
KW  - 3D-printing
KW  - Ink
KW  - Gripper
KW  - Fastener
Y1  - 2022
U6  - https://doi.org/10.1016/j.mtcomm.2021.102966
SN  - 2352-4928
VL  - 30
PB  - Elsevier
CY  - Amsterdam
ER  -