TY - GEN A1 - Hoehnel, Desiree A1 - Reimold, W. U. A1 - Mohr-Westheide, Tanja A1 - Hofmann, Axel A1 - Altenberger, Uwe T1 - PETROGRAPHY OF ARCHEAN SPHERULE LAYERS FROM THE CT3 DRILL CORE, BARBERTON GREENSTONE BELT, SOUTH AFRICA T2 - Scientific reports Y1 - 2016 SN - 1086-9379 SN - 1945-5100 VL - 51 SP - A333 EP - A333 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Fritz, Joerg A1 - Tagle, Roald A1 - Ashworth, Luisa A1 - Schmitt, Ralf Thomas A1 - Hofmann, Axel A1 - Luais, Beatrice A1 - Harris, Phillip D. A1 - Hoehnel, Desiree A1 - Ă–zdemir, Seda A1 - Mohr-Westheide, Tanja A1 - Koeberl, Christian T1 - Nondestructive spectroscopic and petrochemical investigations of Paleoarchean spherule layers from the ICDP drill core BARB5, Barberton Mountain Land, South Africa JF - Quaestiones geographicae N2 - A Paleoarchean impact spherule-bearing interval of the 763 m long International Continental Scientific Drilling Program (ICDP) drill core BARB5 from the lower Mapepe Formation of the Fig Tree Group, Barberton Mountain Land (South Africa) was investigated using nondestructive analytical techniques. The results of visual observation, infrared (IR) spectroscopic imaging, and micro-X-ray fluorescence (lXRF) of drill cores are presented. Petrographic and sedimentary features, as well as major and trace element compositions of lithologies from the micrometer to kilometer-scale, assisted in the localization and characterization of eight spherule-bearing intervals between 512.6 and 510.5 m depth. The spherule layers occur in a strongly deformed section between 517 and 503 m, and the rocks in the core above and below are clearly less disturbed. The lXRF element maps show that spherule layers have similar petrographic and geochemical characteristics but differences in (1) sorting of two types of spherules and (2) occurrence of primary minerals (Ni-Cr spinel and zircon). We favor a single impact scenario followed by postimpact reworking, and subsequent alteration. The spherule layers are Al2O3-rich and can be distinguished from the Al2O3-poor marine sediments by distinct Al-OH absorption features in the short wave infrared (SWIR) region of the electromagnetic spectrum. Infrared images can cover tens to hundreds of square meters of lithologies and, thus, may be used to search for Al-OH-rich spherule layers in Al2O3-poor sediments, such as Eoarchean metasediments, where the textural characteristics of the spherule layers are obscured by metamorphism. Y1 - 2016 U6 - https://doi.org/10.1111/maps.12736 SN - 1086-9379 SN - 1945-5100 VL - 51 SP - 2441 EP - 2458 PB - Wiley-Blackwell CY - Hoboken ER -