TY - JOUR A1 - Zuhr, Alexandra M. A1 - Dolman, Andrew M. A1 - Ho, Sze Ling A1 - Groeneveld, Jeroen A1 - Loewemark, Ludvig A1 - Grotheer, Hendrik A1 - Su, Chih-Chieh A1 - Laepple, Thomas T1 - Age-heterogeneity in marine sediments revealed by three-dimensional high-resolution radiocarbon measurements JF - Frontiers in Earth Science N2 - Marine sedimentary archives are routinely used to reconstruct past environmental changes. In many cases, bioturbation and sedimentary mixing affect the proxy time-series and the age-depth relationship. While idealized models of bioturbation exist, they usually assume homogeneous mixing, thus that a single sample is representative for the sediment layer it is sampled from. However, it is largely unknown to which extent this assumption holds for sediments used for paleoclimate reconstructions. To shed light on 1) the age-depth relationship and its full uncertainty, 2) the magnitude of mixing processes affecting the downcore proxy variations, and 3) the representativity of the discrete sample for the sediment layer, we designed and performed a case study on South China Sea sediment material which was collected using a box corer and which covers the last glacial cycle. Using the radiocarbon content of foraminiferal tests as a tracer of time, we characterize the spatial age-heterogeneity of sediments in a three-dimensional setup. In total, 118 radiocarbon measurements were performed on defined small- and large-volume bulk samples ( similar to 200 specimens each) to investigate the horizontal heterogeneity of the sediment. Additionally, replicated measurements on small numbers of specimens (10 x 5 specimens) were performed to assess the heterogeneity within a sample volume. Visual assessment of X-ray images and a quantitative assessment of the mixing strength show typical mixing from bioturbation corresponding to around 10 cm mixing depth. Notably, our 3D radiocarbon distribution reveals that the horizontal heterogeneity (up to 1,250 years), contributing to the age uncertainty, is several times larger than the typically assumed radiocarbon based age-model error (single errors up to 250 years). Furthermore, the assumption of a perfectly bioturbated layer with no mixing underneath is not met. Our analysis further demonstrates that the age-heterogeneity might be a function of sample size; smaller samples might contain single features from the incomplete mixing and are thus less representative than larger samples. We provide suggestions for future studies, optimal sampling strategies for quantitative paleoclimate reconstructions and realistic uncertainty in age models, as well as discuss possible implications for the interpretation of paleoclimate records. KW - paleoceanography KW - radiocarbon KW - age-heterogeneity KW - marine sediments KW - planktonic foraminifera KW - bioturbation KW - agemodeling KW - South China Sea Y1 - 2022 U6 - https://doi.org/10.3389/feart.2022.871902 SN - 2296-6463 VL - 10 PB - Frontiers Media CY - Lausanne ER - TY - JOUR A1 - Zhu, Chuanbin A1 - Cotton, Fabrice A1 - Kwak, Dong-Youp A1 - Ji, Kun A1 - Kawase, Hiroshi A1 - Pilz, Marco T1 - Within-site variability in earthquake site response JF - Geophysical journal international N2 - The within-site variability in site response is the randomness in site response at a given site from different earthquakes and is treated as aleatory variability in current seismic hazard/risk analyses. In this study, we investigate the single-station variability in linear site response at K-NET and KiK-net stations in Japan using a large number of earthquake recordings. We found that the standard deviation of the horizontal-to-vertical Fourier spectral ratio at individual sites, that is single-station horizontal-to-vertical spectral ratio (HVSR) sigma sigma(HV,s), approximates the within-site variability in site response quantified using surface-to-borehole spectral ratios (for oscillator frequencies higher than the site fundamental frequency) or empirical ground-motion models. Based on this finding, we then utilize the single-station HVSR sigma as a convenient tool to study the site-response variability at 697 KiK-net and 1169 K-NET sites. Our results show that at certain frequencies, stiff, rough and shallow sites, as well as small and local events tend to have a higher sigma(HV,s). However, when being averaged over different sites, the single-station HVSR sigma, that is sigma(HV), increases gradually with decreasing frequency. In the frequency range of 0.25-25 Hz, sigma(HV) is centred at 0.23-0.43 in ln scales (a linear scale factor of 1.26-1.54) with one standard deviation of less than 0.1. sigma(HV) is quite stable across different tectonic regions, and we present a constant, as well as earthquake magnitude- and distance-dependent sigma(HV) models. KW - earthquake ground motions KW - earthquake hazards KW - site effects Y1 - 2021 U6 - https://doi.org/10.1093/gji/ggab481 SN - 0956-540X SN - 1365-246X VL - 229 IS - 2 SP - 1268 EP - 1281 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Simon, François-Xavier A1 - Papadopoulos, Nikos A1 - Guillemoteau, Julien A1 - Oikonomou, Dimitris A1 - Simirdanis, Kleanthis T1 - Multi-frequency loop electromagnetic system measurement on shallow offshore archaeological site of Oulos JF - ArcheoSciences : revue d'archéométrie / Groupe des Méthodes Pluridisciplinaires Contribuant à l'Archéologie (GMPCA) KW - hallow offshore KW - multi-frequency KW - electromagnetic KW - modelling KW - case study Y1 - 2021 U6 - https://doi.org/10.4000/archeosciences.9690 SN - 1960-1360 SN - 2104-3728 VL - 45 IS - 1 SP - 215 EP - 218 PB - Presses Universitaires de Rennes CY - Rennes ER - TY - JOUR A1 - Dämpfling, Helge L. C. A1 - Mielke, Christian A1 - Koellner, Nicole A1 - Lorenz, Melanie A1 - Rogass, Christian A1 - Altenberger, Uwe A1 - Harlov, Daniel E. A1 - Knoper, Michael T1 - Automatic element and mineral detection in thin sections using hyperspectral transmittance imaging microscopy (HyperTIM) JF - European journal of mineralogy N2 - In this study we present a novel method for the automatic detection of minerals and elements using hyperspectral transmittance imaging microscopy measurements of complete thin sections (HyperTIM). This is accomplished by using a hyperspectral camera system that operates in the visible and near-infrared (VNIR) range with a specifically designed sample holder, scanning setup, and a microscope lens. We utilize this method on a monazite ore thin section from Steenkampskraal (South Africa), which we analyzed for the rare earth element (REE)-bearing mineral monazite ((Ce,Nd,La)PO4), with high concentrations of Nd. The transmittance analyses with the hyperspectral VNIR camera can be used to identify REE minerals and Nd in thin sections. We propose a three-point band depth index, the Nd feature depth index (NdFD), and its related product the Nd band depth index (NdBDI), which enables automatic mineral detection and classification for the Nd-bearing monazites in thin sections. In combination with the average concentration of the relative Nd content, it permits a destruction-free, total concentration calculation for Nd across the entire thin section. Y1 - 2022 U6 - https://doi.org/10.5194/ejm-34-275-2022 SN - 0935-1221 SN - 1617-4011 VL - 34 IS - 3 SP - 275 EP - 284 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Barbosa, Luis Romero A. A1 - Coelho, Victor Hugo R. A1 - Gusmao, Ana Claudia V. L. F. A1 - Fernandes, Lucila A. E. A1 - da Silva, Bernardo B. A1 - Galvao, Carlos de O. A1 - Caicedo, Nelson O. L. A1 - da Paz, Adriano R. A1 - Xuan, Yunqing A1 - Bertrand, Guillaume F. A1 - Melo, Davi de C. D. A1 - Montenegro, Suzana M. G. L. A1 - Oswald, Sascha E. A1 - Almeida, Cristiano das N. T1 - A satellite-based approach to estimating spatially distributed groundwater recharge rates in a tropical wet sedimentary region despite cloudy conditions JF - Journal of hydrology N2 - Groundwater recharge (GWR) is one of the most challenging water fluxes to estimate, as it relies on observed data that are often limited in many developing countries. This study developed an innovative water budget method using satellite products for estimating the spatially distributed GWR at monthly and annual scales in tropical wet sedimentary regions despite cloudy conditions. The distinctive features proposed in this study include the capacity to address 1) evapotranspiration estimations in tropical wet regions frequently overlaid by substantial cloud cover; and 2) seasonal root-zone water storage estimations in sedimentary regions prone to monthly variations. The method also utilises satellite-based information of the precipitation and surface runoff. The GWR was estimated and validated for the hydrologically contrasting years 2016 and 2017 over a tropical wet sedimentary region located in North-eastern Brazil, which has substantial potential for groundwater abstraction. This study showed that applying a cloud-cleaning procedure based on monthly compositions of biophysical data enables the production of a reasonable proxy for evapotranspiration able to estimate groundwater by the water budget method. The resulting GWR rates were 219 (2016) and 302 (2017) mm yr(-1), showing good correlations (CC = 0.68 to 0.83) and slight underestimations (PBIAS =-13 to-9%) when compared with the referenced estimates obtained by the water table fluctuation method for 23 monitoring wells. Sensitivity analysis shows that water storage changes account for +19% to-22% of our monthly evaluation. The satellite-based approach consistently demonstrated that the consideration of cloud-cleaned evapotranspiration and root-zone soil water storage changes are essential for a proper estimation of spatially distributed GWR in tropical wet sedimentary regions because of their weather seasonality and cloudy conditions. KW - remote sensing KW - water balance KW - groundwater recharge KW - water table KW - fluctuation KW - tropical climate KW - sedimentary aquifer Y1 - 2022 U6 - https://doi.org/10.1016/j.jhydrol.2022.127503 SN - 0022-1694 SN - 1879-2707 VL - 607 PB - Elsevier CY - Amsterdam ER - TY - CHAP A1 - Cárdenas, Aura A1 - Schernthanner, Harald ED - Jacob-Lopes, Eduardo ED - Queiroz Zepka, Leila ED - Costa Deprá, Mariany T1 - The role of livestock wastes in clean energy BT - a mapping in Germany’s potential installations T2 - Handbook of waste biorefinery N2 - Agricultural production worldwide has been increasing in the last decades at a very fast pace and with it the waste generation. Livestock activities are one of the largest producers of residues in the agricultural sector and contribute greatly to climate change. The present chapter gives an introduction and an in-depth analysis of the waste management of livestock for the conversion in a circular agriculture and economy based on research and experience in the sector conducted in the last decades. The conversion of animal waste into energy generation is an opportunity for farmers to obtain additional economic benefits, while contributing to the environment by preventing the release of GHGs into the atmosphere. The use of animal waste for energy generation through anaerobic digestion is a progressive technique and is being widely accepted in Europe, where Germany is the leading country in the use of biogas plants for energy production among others in the European Union. Economically speaking, the livestock industry faces the challenge of converting its production into a clean and more profitable production. The goal of this chapter is to analyze the economic benefit as well as the environmental contribution and future challenges of the use of livestock waste in the biorefineries sector from different perspectives, based on an intensive literature review. This review is accompanied by a geospatial analysis component, mapping biogas reactor hotspots and clusters in Germany, by means of methods of spatial statistics as analysis methods as kernel density estimations (KDE) and K-means clustering, based on volunteer geographic data. The applied methods easily can be transferred to other regions and allow a quick macroscopic overview over existing biogas reactors; furthermore, an identification of cluster and hotspots with a high biogas potential, that in a subsequent step can be analyzed in depth in larger scales. Y1 - 2022 SN - 978-3-031-06561-3 U6 - https://doi.org/10.1007/978-3-031-06562-0_12 SP - 337 EP - 343 PB - Springer CY - Cham ER - TY - JOUR A1 - Ben Dor, Yoav A1 - Flax, Tomer A1 - Levitan, Itamar A1 - Enzel, Yehouda A1 - Brauer, Achim A1 - Erel, Yigal T1 - The paleohydrological implications of aragonite precipitation under contrasting climates in the endorheic Dead Sea and its precursors revealed by experimental investigations JF - Chemical geology : official journal of the European Association for Geochemistry N2 - Carbonate minerals are common in both marine and lacustrine records, and are frequently used for paleoenvironmental reconstructions. The sedimentary sequence of the endorheic Dead Sea and its precursors contain aragonite laminae that provide a detailed sedimentary archive of climatic, hydrologic, limnologic and environmental conditions since the Pleistocene. However, the interpretation of these archives requires a detailed understanding of the constraints and mechanisms affecting CaCO3 precipitation, which are still debated. The implications of aragonite precipitation in the Dead Sea and in its late Pleistocene predecessor (Lake Lisan) were investigated in this study by mixing natural and synthetic brines with a synthetic bicarbonate solution that mimics flash-floods composition, with and without the addition of extracellular polymeric substances (EPS). Aragonite precipitation was monitored, and precipitation rates and carbonate yields were calculated and are discussed with respect to modern aquatic environments. The experimental insights on aragonite precipitation are then integrated with microfacies analyses in order to reconstruct and constrain prevailing limnogeological processes and their hydroclimatic drivers under low (interglacial) and high (glacial) lake level stands. Aragonite precipitation took place within days to several weeks after the mixing of the brines with a synthetic bicarbonate solution. Incubation time was proportional to bicarbonate concentration, and precipitation rates were partially influenced by ionic strength. Additionally, extracellular polymeric substances inhibited aragonite precipitation for several months. As for the lake's water budget, our calculations suggest that the precipitation of a typical aragonite lamina (0.5 mm thick) during high lake stand requires unreasonable freshwater inflow from either surface or subsurface sources. This discrepancy can be resolved by considering one or a combination of the following scenarios; (1) discontinuous aragonite deposition over parts of the lake floor; (2) supply of additional carbonate flux (or fluxes) to the lake from aeolian dust and the remobilization and dissolution of dust deposits at the watershed; (3) carbonate production via oxidation of organic carbon by sulfate-reducing bacteria. Altogether, it is suggested that aragonite laminae thickness cannot be directly interpreted for quantitatively reconstructing the hydrological balance for the entire lake, they may still prove valuable for identifying inherent hydroclimatic periodicities at a single site. KW - Dead Sea KW - Lake Lisan KW - Aragonite KW - Varves KW - Paleolimnology KW - Paleohydrology KW - Dead Sea deep drilling project KW - EPS KW - Extracellular polymeric substances KW - Levant climate KW - Eastern Mediterranean KW - Paleoclimate KW - Lacustrine carbonate Y1 - 2021 U6 - https://doi.org/10.1016/j.chemgeo.2021.120261 SN - 0009-2541 SN - 1872-6836 VL - 576 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Sarrazin, Fanny J. A1 - Kumar, Rohini A1 - Basu, Nandita B. A1 - Musolff, Andreas A1 - Weber, Michael A1 - Van Meter, Kimberly J. A1 - Attinger, Sabine T1 - Characterizing catchment-scale nitrogen legacies and constraining their uncertainties JF - Water resources research N2 - Improving nitrogen (N) status in European water bodies is a pressing issue. N levels depend not only on current but also past N inputs to the landscape, that have accumulated through time in legacy stores (e.g., soil, groundwater). Catchment-scale N models, that are commonly used to investigate in-stream N levels, rarely examine the magnitude and dynamics of legacy components. This study aims to gain a better understanding of the long-term fate of the N inputs and its uncertainties, using a legacy-driven N model (ELEMeNT) in Germany's largest national river basin (Weser; 38,450 km(2)) over the period 1960-2015. We estimate the nine model parameters based on a progressive constraining strategy, to assess the value of different observational data sets. We demonstrate that beyond in-stream N loading, soil N content and in-stream N concentration allow to reduce the equifinality in model parameterizations. We find that more than 50% of the N surplus denitrifies (1480-2210 kg ha(-1)) and the stream export amounts to around 18% (410-640 kg ha(-1)), leaving behind as much as around 230-780 kg ha(-1) of N in the (soil) source zone and 10-105 kg ha(-1) in the subsurface. A sensitivity analysis reveals the importance of different factors affecting the residual uncertainties in simulated N legacies, namely hydrologic travel time, denitrification rates, a coefficient characterizing the protection of organic N in source zone and N surplus input. Our study calls for proper consideration of uncertainties in N legacy characterization, and discusses possible avenues to further reduce the equifinality in water quality modeling. KW - nitrogen legacies KW - water quality modeling KW - equifinality KW - parameter KW - estimation KW - sensitivity analysis Y1 - 2022 U6 - https://doi.org/10.1029/2021WR031587 SN - 0043-1397 SN - 1944-7973 VL - 58 IS - 4 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Schildgen, Taylor F. A1 - van der Beek, Peter A. A1 - D'Arcy, Mitch A1 - Roda-Boluda, Duna N. A1 - Orr, Elizabeth N. A1 - Wittmann, Hella T1 - Quantifying drainage-divide migration from orographic rainfall over geologic timescales BT - Sierra de Aconquija, southern Central Andes JF - Earth & planetary science letters N2 - Drainage-divide migration, controlled by rock-uplift and rainfall patterns, may play a major role in the geomorphic evolution of mountain ranges. However, divide-migration rates over geologic timescales have only been estimated by theoretical studies and remain empirically poorly constrained. Geomorphological evidence suggests that the Sierra de Aconquija, on the eastern side of the southern Central Andes, northwest Argentina, is undergoing active westward drainage-divide migration. The mountain range has been subjected to steep rock trajectories and pronounced orographic rainfall for the last several million years, presenting an ideal setting for using low-temperature thermochronometric data to explore its topographic evolution. We perform three-dimensional thermal-kinematic modeling of previously published thermochronometric data spanning the windward and leeward sides of the range to explore the most likely structural and topographic evolution of the range. We find that the data can be explained by scenarios involving drainage-divide migration alone, or by scenarios that also involve changes in the structures that have accommodated deformation through time. By combining new Be-10-derived catchment-average denudation rates with geomorphic constraints on probable fault activity, we conclude that the evolution of the range was likely dominated by west-vergent faulting on a high-angle reverse fault underlying the range, together with westward drainage-divide migration at a rate of several km per million years. Our findings place new constraints on the magnitudes and rates of drainage-divide migration in real landscapes, quantify the effects of orographic rainfall and erosion on the topographic evolution of a mountain range, and highlight the importance of considering drainage-divide migration when interpreting thermochronometer age patterns. KW - drainage-divide migration KW - landscape evolution KW - orographic rainfall KW - thermochronology KW - cosmogenic nuclides KW - Central Andes Y1 - 2022 U6 - https://doi.org/10.1016/j.epsl.2021.117345 SN - 0012-821X SN - 1385-013X VL - 579 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Nwosu, Ebuka Canisius A1 - Roeser, Patricia Angelika A1 - Yang, Sizhong A1 - Ganzert, Lars A1 - Dellwig, Olaf A1 - Pinkerneil, Sylvia A1 - Brauer, Achim A1 - Dittmann, Elke A1 - Wagner, Dirk A1 - Liebner, Susanne T1 - From water into sediment-tracing freshwater cyanobacteria via DNA analyses JF - Microorganisms : open access journal N2 - Sedimentary ancient DNA-based studies have been used to probe centuries of climate and environmental changes and how they affected cyanobacterial assemblages in temperate lakes. Due to cyanobacteria containing potential bloom-forming and toxin-producing taxa, their approximate reconstruction from sediments is crucial, especially in lakes lacking long-term monitoring data. To extend the resolution of sediment record interpretation, we used high-throughput sequencing, amplicon sequence variant (ASV) analysis, and quantitative PCR to compare pelagic cyanobacterial composition to that in sediment traps (collected monthly) and surface sediments in Lake Tiefer See. Cyanobacterial composition, species richness, and evenness was not significantly different among the pelagic depths, sediment traps and surface sediments (p > 0.05), indicating that the cyanobacteria in the sediments reflected the cyanobacterial assemblage in the water column. However, total cyanobacterial abundances (qPCR) decreased from the metalimnion down the water column. The aggregate-forming (Aphanizomenon) and colony-forming taxa (Snowella) showed pronounced sedimentation. In contrast, Planktothrix was only very poorly represented in sediment traps (meta- and hypolimnion) and surface sediments, despite its highest relative abundance at the thermocline (10 m water depth) during periods of lake stratification (May-October). We conclude that this skewed representation in taxonomic abundances reflects taphonomic processes, which should be considered in future DNA-based paleolimnological investigations. KW - Aphanizomenon KW - Planktothrix KW - Snowella KW - cyanobacteria sedimentation KW - lake monitoring KW - sedimentary ancient DNA KW - sediment traps KW - environmental reconstruction Y1 - 2021 U6 - https://doi.org/10.3390/microorganisms9081778 SN - 2076-2607 VL - 9 IS - 8 PB - MDPI CY - Basel ER -