TY - JOUR A1 - Kampa, Nele A1 - Kunter, Mareike A1 - Maaz, Kai A1 - Baumert, Jürgen T1 - The social background of maths teachers in Germany its connection with professional occupation and job-related convictions among teachers at secondary schools JF - Zeitschrift für Pädagogik N2 - The present article analyzes the socio-economic background of maths teachers in Germany and its relation to career-related decisions and job-related convictions. These analyzes is based on data collected through questionnaires answered by 1126 maths teachers working at a sample of secondary schools representative of Germany. Following Bourdieu's theory, the authors examine whether the economic and cultural conditions prevailing in the teachers' families of origin are related to their decision to pursue this specific professional career or to their job-related convictions. Furthermore, it is analyzed in how far teachers, in their everyday work in the classroom, meet students from groups of origin foreign to the teachers themselves. The results show that the teachers, socio-economic background has no systematic relation to either their career-related decisions or their job-related convictions. Y1 - 2011 SN - 0044-3247 VL - 57 IS - 1 SP - 70 EP - 92 PB - Beltz CY - Weinheim ER - TY - JOUR A1 - Wessig, Pablo A1 - Möllnitz, Kristian A1 - Kelling, Alexandra A1 - Schilde, Uwe T1 - Crystal structure of 1r,2c,3c,4t,5t,6t-1,2,3,4,5,6-hexakis-trimethylsilanyloxy-cyclohexane, C24H60O6Si6 JF - Zeitschrift für Kristallographie : international journal for structural, physical and chemical aspects of crystalline materials ; New crystal structures N2 - C24H60O6Si6, triclinic, P (1) over bar (no. 2), a = 11.307(2) angstrom, b = 12.159(2) angstrom, = 16.576(2) angstrom, alpha = 109.47(1)degrees, beta = 94.64(1)degrees, gamma = 111.65(1)degrees, V = 1942.3 angstrom(3), Z = 2, R-gt(F) = 0.043, wR(ref)(F-2) = 0.118, T = 210 K. Y1 - 2011 U6 - https://doi.org/10.1524/ncrs.2011.0105 SN - 1433-7266 VL - 226 IS - 2 SP - 228 EP - 230 PB - De Gruyter Oldenbourg CY - München ER - TY - JOUR A1 - Kahlert, Daniela A1 - Brand, Ralf T1 - Questionnaires for assessing physical activity different response scale categories influence responses concerning health- and sport-related cognitions JF - Zeitschrift für Gesundheitspsychologie N2 - The present study examines whether the use of different frequency scales in questionnaires about physical activity influences respondents' own estimation of their activity, as well as subsequent measurements of health- und sport-related cognitions and evaluations. Using a randomized research design we recruited a sample of 118 participants. One group received a high frequency scale for assessing their exercise frequency with the response categories "never", "less often", "once a month", "once a week", or "most days." The other group answered with a medium frequency scale with the alternatives "never", "less often", " once every few months", "once a month", and " once a week or more often." As dependent variables all participants judged the subjective importance of physical activity and their health-related quality of life (WHO-QOL-bref). Results indicate the expected response errors, owing to the fact that using a high-frequency scale produces higher levels of self-reported physical activity (Cramer's V = .30). Corresponding to this the subjective importance of physical activity increased (d = .37) and the health-related quality of life was judged to be better (d = .36). Such artefacts might be eliminated by using standardized formulations such as "I exercise... times per week/month for... minutes." KW - physical activity KW - measurement KW - health-related cognition KW - response error Y1 - 2011 U6 - https://doi.org/10.1026/0943-8149/a000044 SN - 0943-8149 VL - 19 IS - 2 SP - 96 EP - 100 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Kürbis, Holger T1 - Peace of the Pyrenees 1659 history, response, reception history JF - Deutsche Zeitschrift für Geschichtswissenschaft Y1 - 2011 SN - 0044-2828 VL - 59 IS - 12 SP - 1074 EP - 1075 PB - Metropol-Verl. CY - Berlin ER - TY - JOUR A1 - Botsch, Gideon T1 - Elections in Europe a data Handbook JF - Deutsche Zeitschrift für Geschichtswissenschaft Y1 - 2011 SN - 0044-2828 VL - 59 IS - 10 SP - 869 EP - 871 PB - Metropol-Verl. CY - Berlin ER - TY - JOUR A1 - Botsch, Gideon T1 - Nazi criminals and citizens of the federal Republic the example of Dr. Gerhard Klopfer JF - Deutsche Zeitschrift für Geschichtswissenschaft Y1 - 2011 SN - 0044-2828 VL - 59 IS - 4 SP - 389 EP - 390 PB - Metropol-Verl. CY - Berlin ER - TY - JOUR A1 - Botsch, Gideon T1 - Perpetrators - Helper- Free Riders Nazi loaded from the Eastern Swabian JF - Deutsche Zeitschrift für Geschichtswissenschaft Y1 - 2011 SN - 0044-2828 VL - 59 IS - 4 SP - 389 EP - 390 PB - Metropol-Verl. CY - Berlin ER - TY - JOUR A1 - Krüger, Brigitte T1 - Dialogue with strangers memories of the 'European East' in the lyrics of Johannes Bobrowski JF - Zeitschrift für Germanistik Y1 - 2011 SN - 0323-7982 VL - 21 IS - 2 SP - 413 EP - 415 PB - Lang CY - Bern ER - TY - JOUR A1 - Zacke, Birgit T1 - Rhythm of the images narrative strategies in text and image products of the eleventh and thirteenth century JF - Zeitschrift für Germanistik Y1 - 2011 SN - 0323-7982 VL - 21 IS - 1 SP - 175 EP - 176 PB - Lang CY - Bern ER - TY - GEN A1 - Stockhorst, Stefanie T1 - Friedrich Nicolai (1733-1811). - on the two hundreth Anniversary of the Berlin Enlightenment writer and bookseller has works published T2 - Zeitschrift für Germanistik Y1 - 2011 SN - 0323-7982 VL - 21 IS - 1 SP - 153 EP - 159 PB - Lang CY - Bern ER - TY - JOUR A1 - Stockhorst, Stefanie T1 - Signals from the past forms and functions of the traditional behavior in Thomas Kling's essay JF - Zeitschrift für Germanistik Y1 - 2011 U6 - https://doi.org/10.3726/92132_114 SN - 0323-7982 VL - 21 IS - 1 SP - 114 EP - 130 PB - Lang CY - Bern ER - TY - JOUR A1 - Krahé, Barbara T1 - Pornography use, sexual scripts, and sexual aggression in adolescence JF - Zeitschrift für Entwicklungspsychologie und pädagogische Psychologie N2 - The link between pornography use, normative acceptance of sexual aggression, and the presence of risk factors of sexual aggression in sexual scripts for consensual sexual interactions was studied in a sample of 197 adolescents in Germany. Risk factors included sex after only a short acquaintanceship, alcohol and drug use in sexual interactions, and ambiguous communication of sexual intentions. In addition to a measure of overall pornography use, exposure to portrayals of consensual sex, coerced sex and degrading sex was measured. Almost all participants had seen pornografic material at least once, just under half had seen depictions of coerced sex. Significant correlations were found between all measures of pornography use and the presence of risk factors of sexual aggression in consensual sexual scripts. Violent pornography usage showed a positive correlation with the normative acceptance of sexual aggression that was partly accounted for by sexual scripts. The findings are discussed with regard to the significance of pornografic media contents in the process of adolescents' sexual socialization. KW - pornography KW - violent pornography KW - sexual scripts KW - adolescent sexuality Y1 - 2011 U6 - https://doi.org/10.1026/0049-8637/a000044 SN - 0049-8637 VL - 43 IS - 3 SP - 133 EP - 141 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Priewe, Marc T1 - Prospero's America: John Winthrop, Jr., Alchemy, and the Creation of New England Culture, 1606-1676 JF - Zeitschrift für Anglistik und Amerikanistik : a quarterly of language, literature and cultur Y1 - 2011 SN - 0044-2305 VL - 59 IS - 2 SP - 199 EP - 200 PB - Königshausen & Neumann CY - Würzburg ER - TY - JOUR A1 - Stecker, Christian T1 - Linking citizens and parties how electoral systems matter for political representation JF - West European politics Y1 - 2011 U6 - https://doi.org/10.1080/01402382.2011.616673 SN - 0140-2382 VL - 34 IS - 6 SP - 1316 EP - 1317 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Spies, Dennis A1 - Franzmann, Simon T. T1 - A two-dimensional approach to the political opportunity structure of extreme right parties in Western Europe JF - West European politics N2 - Previous studies on the electoral fortunes of extreme right parties (ERPs) have pointed to the importance of variables of party competition for the success - or failure - of ERPs. These studies vary greatly when it comes to describing the political opportunity structure of the extreme right. Apart from their methodological differences, existing studies differ especially with regard to the assumed underlying dimension of party competition. This article tests the impact of three frequently discussed variables in the political opportunity structure of ERPs (mainstream party convergence, position of the established right and party system polarisation) on the vote share of ERPs in Western Europe. In addition to examining previous studies in this field, it focuses on the interplay between the economic and the cultural dimensions as part of the political opportunity structure. The authors show that a decrease in polarisation with regard to economic questions is accompanied by a growing salience of ERPs' core issues, leading in the end to an increase in ERPs' vote share. Y1 - 2011 U6 - https://doi.org/10.1080/01402382.2011.591096 SN - 0140-2382 VL - 34 IS - 5 SP - 1044 EP - 1069 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Akal, Cuneyt A1 - Koralay, O. Ersin A1 - Candan, Osman A1 - Oberhänsli, Roland A1 - Chen, Fukun T1 - Geodynamic significance of the early triassic karaburun granitoid (Western Turkey) for the opening history of Neo-Tethys JF - Turkish journal of earth sciences = Türk yerbilimleri dergisi N2 - The Karaburun Peninsula, which is considered part of the Anatolide-Tauride Block of Turkey, contains clastic and carbonate sequences deposited on the northern margin of Gondwana. The Palaeozoic clastic sequence, which is intruded by the Early Triassic granitoid and tectonically overlies a Mesozoic melange sequence, can be divided into three subunits: a lower clastic subunit consisting of a sandstone-shale alternation, an upper clastic subunit consisting of black chert-bearing shales, sandstone and conglomerate, and a Permo-Carboniferous carbonate subunit. The lower Triassic Karaburun I-type granitoid has a high initial Sr-87/Sr-86 ratio (0.709021-0.709168), and low Nd-143/Nd-144 ratio (0.512004-0.512023) and epsilon Nd (-5.34 to -5.70) isotopic values. Geochronological data indicate a crystallization (intrusion) age of 247.1 +/- 2.0 Ma (Scythian). Geochemically, the acidic magmatism reflects a subduction-related continental-arc basin tectonic setting, which can be linked to the opening of the northern branch of Neo-Tethys as a continental back-arc rifting basin on the northern margin of Gondwana. This can be related to the closure through southward subduction of the Palaeotethys Ocean beneath Gondwana. KW - Karaburun KW - Neo-Tethys KW - Palaeo-Tethys KW - diorite KW - Triassic KW - magmatism Y1 - 2011 U6 - https://doi.org/10.3906/yer-1008-1 SN - 1300-0985 VL - 20 IS - 3 SP - 255 EP - 271 PB - Tübitak CY - Ankara ER - TY - JOUR A1 - David Coy, Ericsson A1 - Enrique Cuca, Luis A1 - Sefkow, Michael T1 - Pd-NHC catalyzed biaryl coupling by direct C-H Activation-A Novel strategy for the synthesis of dibenzocyclooctane lignans JF - Synthetic communications : an international journal for rapid communication of synthetic organic chemistry N2 - Cross-coupling reactions, such as Buchwald-Hartwig arylamination and direct intramolecular biaryl coupling by C-H activation, were carried out using various Palladium-N-heterocyclic carbenes (Pd-NHC) as catalysts. The yields were good to excellent. The latter strategy was adopted to transform two dibenzylbutane lignans, isolated from the leaves of Ocotea macrophylla (Lauraceae), into the corresponding dibenzocyclooctane lignans in good overall yields. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file. KW - Cross-coupling reactions KW - dibenzylbutane KW - dibenzocyclooctane KW - lignans KW - N-heterocyclic carbenes (NHC) Y1 - 2011 U6 - https://doi.org/10.1080/00397910903531755 SN - 0039-7911 VL - 41 IS - 1 SP - 41 EP - 51 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Feher, Kristen A1 - Whelan, James A1 - Müller, Samuel T1 - Assessing modularity using a random matrix theory approach JF - Statistical applications in genetics and molecular biology N2 - Random matrix theory (RMT) is well suited to describing the emergent properties of systems with complex interactions amongst their constituents through their eigenvalue spectrums. Some RMT results are applied to the problem of clustering high dimensional biological data with complex dependence structure amongst the variables. It will be shown that a gene relevance or correlation network can be constructed by choosing a correlation threshold in a principled way, such that it corresponds to a block diagonal structure in the correlation matrix, if such a structure exists. The structure is then found using community detection algorithms, but with parameter choice guided by RMT predictions. The resulting clustering is compared to a variety of hierarchical clustering outputs and is found to the most generalised result, in that it captures all the features found by the other considered methods. KW - random matrix theory KW - clustering KW - modularity Y1 - 2011 U6 - https://doi.org/10.2202/1544-6115.1667 SN - 2194-6302 SN - 1544-6115 VL - 10 IS - 1 PB - De Gruyter CY - Berlin ER - TY - JOUR A1 - Bressel, Katharina A1 - Prevost, Sylvain A1 - Appavou, Marie-Sousai A1 - Tiersch, Brigitte A1 - Koetz, Joachim A1 - Gradzielski, Michael T1 - Phase behaviour and structure of zwitanionic mixtures of perfluorocarboxylates and tetradecyldimethylamine oxide-dependence on chain length of the perfluoro surfactant JF - Soft matter N2 - Phase behaviour and the mesoscopic structure of zwitanionic surfactant mixtures based on the zwitterionic tetradecyldimethylamine oxide (TDMAO) and anionic lithium perfluoroalkyl carboxylates have been investigated for various chain lengths of the perfluoro surfactant with an emphasis on spontaneously forming vesicles. These mixtures were studied at a constant total concentration of 50 mM and characterised by means of dynamic light scattering (DLS), electric conductivity, small-angle neutron scattering (SANS), viscosity, and cryo-scanning electron microscopy (Cryo-SEM). No vesicles are formed for relatively short perfluoro surfactants. The extension of the vesicle phase becomes substantially larger with increasing chain length of the perfluoro surfactant, while at the same time the size of these vesicles increases. Head group interactions in these systems play a central role in the ability to form vesicles, as already protonating 10 mol% of the TDMAO largely enhances the propensity for vesicle formation. The range of vesicle formation in the phase diagram is not only substantially enlarged but also extends to shorter perfluoro surfactants, where without protonation no vesicles would be formed. The size and polydispersity of the vesicles are related to the chain length of the perfluoro surfactant, the vesicles becoming smaller and more monodisperse with increasing perfluoro surfactant chain length. The ability of the mixed systems to form well-defined unilamellar vesicles accordingly can be controlled by the length of the alkyl chain of the perfluorinated surfactant and depends strongly on the charge conditions, which can be tuned easily by pH-variation. Y1 - 2011 U6 - https://doi.org/10.1039/c1sm05618b SN - 1744-683X VL - 7 IS - 23 SP - 11232 EP - 11242 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Sangoro, J. R. A1 - Iacob, C. A1 - Naumov, S. A1 - Valiullin, R. A1 - Rexhausen, Hans A1 - Hunger, J. A1 - Buchner, R. A1 - Strehmel, Veronika A1 - Kaerger, J. A1 - Kremer, F. T1 - Diffusion in ionic liquids the interplay between molecular structure and dynamics JF - Soft matter N2 - Diffusion in a series of ionic liquids is investigated by a combination of Broadband Dielectric Spectroscopy (BDS) and Pulsed Field Gradient Nuclear Magnetic Resonance (PFG NMR). It is demonstrated that the mean jump lengths increase with the molecular volumes determined from quantum-chemical calculations. This provides a direct means-via Einstein-Smoluchowski relation-to determine the diffusion coefficient by BDS over more than 8 decades unambiguously and in quantitative agreement with PFG NMR measurements. New possibilities in the study of charge transport and dynamic glass transition in ionic liquids are thus opened. Y1 - 2011 U6 - https://doi.org/10.1039/c0sm01404d SN - 1744-683X VL - 7 IS - 5 SP - 1678 EP - 1681 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Weiss, Jan A1 - Böttcher, Christoph A1 - Laschewsky, André T1 - Self-assembly of double thermoresponsive block copolymers end-capped with complementary trimethylsilyl groups JF - Soft matter N2 - A set of double thermoresponsive diblock copolymers poly(N-n-propylacrylamide)-block-poly(N-ethylacrylamide) (PNPAM-b-PNEAM) was synthesised by sequential reversible addition-fragmentation chain transfer (RAFT) polymerisations. Using a twofold trimethylsilyl (TMS)-labeled RAFT-agent, the relative size of the two blocks was varied. While soluble as unimers below 15 degrees C, all copolymers exhibited thermally induced two-step self-assembly in water, due to distinct lower critical solution temperature (LCST) phase transitions of PNPAM (around 20 degrees C) and PNEAM (around 70 degrees C). Their temperature-dependent self-organisation in dilute aqueous solution was studied by turbidimetry, dynamic light scattering, transmission electron microscopy, and (1)H NMR spectroscopy. The copolymers show distinct, two-step self-organisation behaviour with respect to transition temperatures, aggregate type and size, which can be correlated to the relative lengths of the low and high LCST blocks. For polymers having short blocks with low LCST, the first thermal transition induces the formation of individual micelles. Further heating above the second thermal transition results reversibly either in a shrink of the micelle size or in aggregation of the micelles, with hydrodynamic diameters below 250 nm. In contrast in the case of polymers having a long block with low LCST, the first thermal transition already leads to clusters of micelles, while the second thermal transition makes the clusters shrink. Noteworthy, the twofold TMS-labeled end groups report not only on the molar masses of the polymers, but can simultaneously serve as NMR-probes for the self-assembly process. The signal of the TMS-aryl end group displays a reversible temperature dependent, two-step splitting that is indicative of the self-organisation of the block copolymers. Y1 - 2011 U6 - https://doi.org/10.1039/c0sm00531b SN - 1744-683X VL - 7 IS - 2 SP - 483 EP - 492 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Stoyanov, Hristiyan A1 - Kollosche, Matthias A1 - Risse, Sebastian A1 - McCarthy, Denis N. A1 - Kofod, Guggi T1 - Elastic block copolymer nanocomposites with controlled interfacial interactions for artificial muscles with direct voltage control JF - Soft matter N2 - Soft, physically crosslinking, block copolymer elastomers were filled with surface-treated nanoparticles, in order to evaluate the possibility for improvement of their properties when used as soft dielectric actuators. The nanoparticles led to improvements in dielectric properties, however they also reinforced the elastomer matrix. Comparing dielectric spectra of composites with untreated and surface-treated particles showed a measurable influence of the surface on the dielectric loss behaviour for high filler amounts, strongly indicating an improved host-guest interaction for the surface-treated particles. Breakdown strength was measured using a test bench and was found to be in good agreement with the results from the actuation measurements. Actuation responses predicted by a model for prestrained actuators agreed well with measurements up to a filler amount of 20%(vol). Strong improvements in actuation behaviour were observed, with an optimum near 15%(vol) nanoparticles, corresponding to a reduction in electrical field of 27% for identical actuation strains. The use of physically crosslinking elastomer ensured the mechanical properties of the matrix elastomer were unchanged by nanoparticles effecting the crosslinking reaction, contrary to similar experiments performed with chemically crosslinking elastomers. This allows for a firm conclusion about the positive effects of surface-treated nanoparticles on actuation behavior. Y1 - 2011 U6 - https://doi.org/10.1039/c0sm00715c SN - 1744-683X SN - 1744-6848 VL - 7 IS - 1 SP - 194 EP - 202 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Sorge, Arndt T1 - Too big to fail the inside story of how wall street and washington fought to save the financial system from crisis-and themselves JF - Socio-economic review KW - financial crisis KW - financial institutions KW - financial markets KW - capitalism KW - globalization Y1 - 2011 SN - 1475-1461 VL - 9 IS - 1 SP - 169 EP - 186 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Sorge, Arndt T1 - This time is different eight centuries of financial folly JF - Socio-economic review KW - financial crisis KW - financial institutions KW - financial markets KW - capitalism KW - globalization Y1 - 2011 SN - 1475-1461 VL - 9 IS - 1 SP - 169 EP - 186 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Sorge, Arndt T1 - How markets fail the logic of economic calamities JF - Socio-economic review KW - financial crisis KW - financial institutions KW - financial markets KW - capitalism KW - globalization Y1 - 2011 SN - 1475-1461 VL - 9 IS - 1 SP - 169 EP - 186 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Sorge, Arndt T1 - A failure of capitalism the crisis of '08 and the descent into depression JF - Socio-economic review KW - financial crisis KW - financial institutions KW - financial markets KW - capitalism KW - globalization Y1 - 2011 SN - 1475-1461 VL - 9 IS - 1 SP - 169 EP - 186 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Dimitrova, Ilinka A1 - Koppitz, Jörg T1 - On the maximal regular subsemigroups of ideals of order-preserving or order-reversing transformations JF - Semigroup forum N2 - We characterize the maximal regular subsemigroups of the ideals of the semigroup of all order-preserving transformations as well as of the semigroup of all order-preserving or order-reversing transformations on a finite ordered set. KW - Transformation semigroups KW - Regular semigroups KW - Order-preserving transformations KW - Order-reversing transformations KW - Maximal subsemigroups Y1 - 2011 U6 - https://doi.org/10.1007/s00233-010-9272-8 SN - 0037-1912 VL - 82 IS - 1 SP - 172 EP - 180 PB - Springer CY - New York ER - TY - JOUR A1 - Kita-Tokarczyk, Katarzyna A1 - Junginger, Mathias A1 - Belegrinou, Serena A1 - Taubert, Andreas ED - Muller, AHE ED - Borisov, O T1 - Amphiphilic polymers at interfaces JF - Advances in polymer science JF - Advances in Polymer Science N2 - Self-assembly phenomena in block copolymer systems are attracting considerable interest from the scientific community and industry alike. Particularly interesting is the behavior of amphiphilic copolymers, which can self-organize into nanoscale-sized objects such as micelles, vesicles, or tubes in solution, and which form well-defined assemblies at interfaces such as air-liquid, air-solid, or liquid-solid. Depending on the polymer chemistry and architecture, various types of organization at interfaces can be expected, and further exploited for applications in nanotechnology, electronics, and biomedical sciences. In this article, we discuss the formation and characterization of Langmuir monolayers from various amphiphilic block copolymers, including chargeable and thus pH-responsivematerials. Solid-supported polymer films are reviewed in the context of alteration of surface properties by ultrathin polymer layers and the possibilities for application in tissue engineering, sensors and biomaterials. Finally, we focus on how organic and polymer monolayers influence the growth of inorganic materials. This is a truly biomimetic approach since Nature uses soft interfaces to control the nucleation, growth, and morphology of biominerals such as calcium phosphate, calcium carbonate, and silica. KW - Amphiphilic polymers KW - Langmuir monolayers KW - Polymers on surfaces KW - Bio-inspired mineralization Y1 - 2011 SN - 978-3-642-22297-9 U6 - https://doi.org/10.1007/12_2010_58 SN - 0065-3195 VL - 242 IS - 1 SP - 151 EP - 201 PB - Springer CY - Berlin ER - TY - JOUR A1 - Antoniou, Stella A1 - Pashalidis, I. A1 - Gessner, Andre A1 - Kumke, Michael Uwe T1 - The effect of humic acid on the formation and solubility of secondary solid phases (Nd(OH)CO3 and Sm(OH)CO3) JF - Radiochimica acta : international journal for chemical aspects of nuclear science and technology N2 - The formation of secondary Ln(III) solid phases (e.g. Nd(OH)CO3 and Sm(OH)CO3) has been studied as a function of the humic acid (HA) concentration in 0.1 M NaClO4 aqueous solution and their solubility has been investigated in the neutral pH range (6.5-8) under normal atmospheric conditions. Nd(III) and Sm(III) were selected as analogues for trivalent lanthanide and actinide ions. The solid phases under investigation have been prepared by alkaline precipitation and characterized by TGA, ATR-FTIR, XRD, TRLFS, DR-UV-Vis and Raman spectroscopy, and solubility measurements. The spectroscopic data obtained indicate that Nd(OH)CO3 and Sm(OH)CO3 are stable and remain the solubility limiting solid phases even in the presence of increased HA concentration (0.5 g/L) in solution. Upon base addition in the Ln(III)-HA system decomplexation of the previously formed Ln(III)-humate complexes and precipitation of two distinct phases occurs, the inorganic (Ln(OH)CO3) and the organic phase (HA), which is adsorbed on the particle surface of the former. Nevertheless, HA affects the particle size of the solid phases. Increasing HA concentration results in decreasing crystallite size of the Nd(OH)CO3 and increasing crystallite size of the Sm(OH)CO3 solid phase, and affects inversely the solubility of the solid phases. However, this impact on the solid phase properties is expected to be of minor relevance regarding the chemical behavior and migration of trivalent lanthanides and actinides in the geosphere. KW - Lanthanide ions KW - Humic acid KW - Solid phase KW - Solubility KW - Raman KW - TRLFS KW - DR-UV-Vis Y1 - 2011 U6 - https://doi.org/10.1524/ract.2011.1812 SN - 0033-8230 VL - 99 IS - 4 SP - 217 EP - 223 PB - De Gruyter CY - Berlin ER - TY - JOUR A1 - Wischnewski, Juliane A1 - Mischke, Steffen A1 - Wang, Yongbo A1 - Herzschuh, Ulrike T1 - Reconstructing climate variability on the northeastern Tibetan Plateau since the last Lateglacial - a multi-proxy, dual-site approach comparing terrestrial and aquatic signals JF - Quaternary science reviews : the international multidisciplinary research and review journal N2 - A sediment core from a closed basin lake (Lake Kuhai) from the semi-arid northeastern Tibetan Plateau was analysed for its pollen record to infer Lateglacial and post glacial vegetation and climatic change. At Lake Kuhai five major vegetation and climate shifts could be identified: (1) a change from cold and dry to relatively warmer and more moist conditions at 14.8 cal ka BP: (2) a shift to conditions of higher effective moisture and a stepwise warmer climate at 13.6 cal ka BP; (3) a further shift with increased moisture but colder conditions at 7.0 cal ka BP; (4) a return to a significantly colder and drier phase at 6.3 cal ka BP; (5) and a change back to relatively moist conditions at 2.2 cal ka BP. To investigate the response of lake ecosystems to climatic changes, statistical comparisons were made between the lake Kuhai pollen record and a formerly published ostracod and sedimentary record from the same sediment core. Furthermore, the pollen and lacustrine proxies from lake Kuhai were compared to a previously published pollen and lacustrine record from the nearby Lake Koucha. Statistical comparisons were done using non-metric multidimensional scaling and Procrustes rotation. Differences between lacustrine and pollen responses within one site could be identified, suggesting that lacustrine proxies are partly influenced by in-lake or local catchment processes, whereas the terrestrial (pollen) proxy shows a regional climate signal. Furthermore, we found regional differences in proxy response between lake Kuhai and Lake Koucha. Both pollen records reacted in similar ways to major environmental changes, with minor differences in the timing and magnitude of these changes. The lacustrine records were very similar in their timing and magnitude of response to environmental changes; however, the nature of change was at times very distinct. To place the current study in the context of Holocene moisture evolution across the Tibetan Plateau, we applied a five-scale moisture index and average link clustering to all available continuous palaeo-climate records from the Tibetan Plateau to possibly find general patterns of moisture evolution on the Plateau. However, no common regional pattern of moisture evolution during the Holocene could be detected. We assign this to complex responses of different proxies to environmental and atmospheric changes in an already very heterogeneous mountain landscape where minor differences in elevation can cause strong variation in microenvironments. Y1 - 2011 U6 - https://doi.org/10.1016/j.quascirev.2010.10.001 SN - 0277-3791 VL - 30 IS - 1-2 SP - 82 EP - 97 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Parkinson, Jim A1 - Springer, Anne A1 - Prinz, Wolfgang T1 - Can you see me in the snow? - action simulation aids the detection of visually degraded human motion JF - The quarterly journal of experimental psychology N2 - Using a novel paradigm, we demonstrate that action simulation can directly facilitate ongoing perception of people's movements. Point-light actors (PLAs) representing common human motions were shown embedded in a visual noise reminiscent of "TV snow". At first, the PLAs were perceived clearly, then occluded from view for a short duration, during which it was hypothesized that a real-time action simulation was generated tracking the motion's course. The PLA then reappeared in motion at variable visibility against the noise, whilst detection thresholds for the reappearance were measured. In the crucial manipulation, the test motion was either temporally congruent with the motion as it would have continued during occlusion, and thus temporally matching the simulation, or temporally incongruent. Detection thresholds were lower for congruent than for incongruent reappearing motions, suggesting that reappearing motion that temporally matched the internal action simulation was more likely to be detected. KW - Biological motion KW - Action-perception KW - Real-time prediction KW - Point-light action Y1 - 2011 U6 - https://doi.org/10.1080/17470218.2011.594895 SN - 1747-0218 VL - 64 IS - 8 SP - 1463 EP - 1472 PB - Wiley CY - Hove ER - TY - JOUR A1 - Heister, Julian A1 - Würzner, Kay-Michael A1 - Bubenzer, Johannes A1 - Pohl, Edmund A1 - Hanneforth, Thomas A1 - Geyken, Alexander A1 - Kliegl, Reinhold T1 - dlexDB - A lexical database for the psychological and linguistic research JF - Psychologische Rundschau : offizielles Organ der Deutschen Gesellschaft für Psychologie N2 - The lexical database dlexDB supplies in form of an online database frequency-based norms of numerous process-related word properties for psychological and linguistic research. These values include well known variables such as printed frequency of word form and lemma as documented also in CELEX (Baayen, Piepenbrock und Gulikers, 1995). In addition, we compute new values like frequencies based on syllables, and morphemes as well as frequencies of character chains, and multiple word combinations. The statistics are based on the Kernkorpus des Digitalen Wrterbuchs der deutschen Sprache (DWDS) with over 100 million running words. We illustrate the validity of these norms with new results about fixation durations in sentence reading. KW - corpus linguistics KW - lexical database KW - dlex KW - dlexDB KW - CELEX KW - eve movement KW - reading KW - parafovea Y1 - 2011 U6 - https://doi.org/10.1026/0033-3042/a000029 SN - 0033-3042 SN - 2190-6238 VL - 62 IS - 1 SP - 10 EP - 20 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Rjosk, Camilla A1 - McElvany, Nele A1 - Anders, Yvonne A1 - Becker, Michael T1 - Teachers' diagnostic skills in estimating students' basic reading capacities JF - Psychologie in Erziehung und Unterricht : Zeitschrift für Forschung und Praxis N2 - The present study investigates diagnostic skills of German teachers in estimating basic reading capacities of sixth graders and the way they relate to achievement heterogeneity of the judged student group and to students' language background. The data were obtained from a sample of 39 German teachers and their classes in the context of the Berlin Longitudinal Reading Study. Judgements on different levels were analysed (achievement of sixth graders in general and of individual students). Diagnostic skills were investigated using different indicators: the personal judgement error and tendency and the accuracy in identifying achievement differences between individual students (rank component). The accuracy in estimating reading capacities of students with and without a different language background was investigated by means of achievement level matched pairs. The outcomes indicated, among others, an overestimation of students' general achievement level and on average an acceptable accuracy in identifying achievement differences between individual students. They showed equal difficulties in judging performances of students with and without a different language background. KW - Diagnostic skills KW - diagnostic competence KW - teacher judgement accuracy KW - basic reading capacities KW - language background Y1 - 2011 U6 - https://doi.org/10.2378/peu2011.art04d SN - 0342-183X VL - 58 IS - 2 SP - 92 EP - 105 PB - Reinhardt CY - München ER - TY - JOUR A1 - Lilie, Hauke A1 - Baer, Dorit A1 - Kettner, Karina A1 - Weininger, Ulrich A1 - Balbach, Jochen A1 - Naumann, Manfred A1 - Mueller, Eva-Christina A1 - Otto, Albrecht A1 - Gast, Klaus A1 - Golbik, Ralph A1 - Kriegel, Thomas T1 - Yeast hexokinase isoenzyme ScHxk2 stability of a two-domain protein with discontinuous domains JF - Protein engineering design & selection N2 - The hexokinase isoenzyme 2 of Saccharomyces cerevisiae (ScHxk2) represents an archetype of a two-domain protein with the active site located in a cleft between the two domains. Binding of the substrate glucose results in a rigid body movement of the two domains leading to a cleft closure of the active site. Both domains of this enzyme are composed of discontinuous peptide sequences. This structural feature is reflected in the stability and folding of the ScHxk2 protein. Structural transitions induced by urea treatment resulted in the population of a thermodynamically stable folding intermediate, which, however, does not correspond to a molecule with one domain folded and the other unfolded. As demonstrated by different spectroscopic techniques, both domains are structurally affected by the partial denaturation. The intermediate possesses only 40% of the native secondary structural content and a substantial increase in the Stokes radius as judged by circular dichroism and dynamic light scattering analyses. One-dimensional H-1 NMR data prove that all tryptophan residues are in a non-native environment in the intermediate, indicating substantial changes in the tertiary structure. Still, the intermediate possesses quite a high stability for a transition intermediate of about Delta G = -22 kJ mol(-1). KW - dynamic light scattering KW - NMR KW - ScHxk2 KW - stability KW - transition intermediate Y1 - 2011 U6 - https://doi.org/10.1093/protein/gzq098 SN - 1741-0126 VL - 24 IS - 1-2 SP - 79 EP - 87 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Esser, Günter A1 - Blank, Sarah T1 - Efficacy of psychotherapy with children and adolescents JF - Praxis der Kinderpsychologie und Kinderpsychiatrie : Ergebnisse aus Psychotherapie, Beratung und Psychiatrie N2 - Efficacy of Psychotherapy with Children and Adolescents Psychotherapeutic interventions require empirical as well as scientific assessment. Specifically, the proven efficacy of psychotherapy for children and adolescents is essential. Thus, studies examining treatment efficacy and meta-analyses are necessary to compare effect sizes of individual therapeutic interventions between treatment groups and waiting control groups. Assessment of 138 primary studies from 1993-2009 documented the efficacy of psychotherapy for children and adolescents. Furthermore, behavioural therapy outperformed non-behavioural interventions, as 90 % of behavioural interventions showed larger effect sizes compared to non-behavioural psychotherapy. Analysis of moderator variables demonstrated an improved treatment efficacy for individual therapy, inclusion of the family, treatment of internalised disorders, and in clinical samples. Stability of psychotherapeutic treatment effects over time was demonstrated. KW - psychotherapy KW - efficacy KW - child and adolescent psychotherapy KW - meta-analysis Y1 - 2011 SN - 0032-7034 VL - 60 IS - 8 SP - 626 EP - 638 PB - Vandenhoeck & Ruprecht CY - Göttingen ER - TY - JOUR A1 - Mohnke, Sebastian A1 - Warschburger, Petra T1 - Body dissatisfaction among female and male adolescents comparing prevalence, predictors, and consequences between the sexes JF - Praxis der Kinderpsychologie und Kinderpsychiatrie : Ergebnisse aus Psychotherapie, Beratung und Psychiatrie N2 - As part of the POPS study (Potsdam prevention of eating disorders) 300 adolescents aged between 10 and 13 years completed questionnaires measuring satisfaction with weight and muscles, body change strategies and disturbed eating behavior. More than half of the girls and a third of the boys are dissatisfied with their weight. Nearly 70% of the male participants were unhappy with their muscles. Both forms of body dissatisfaction are influenced by similar sociocultural and psychological factors. While weight dissatisfaction leads to weight reduction strategies and disturbed eating, muscle dissatisfaction results in muscle enhancement methods. Potential harmful consequences of excessive muscle building techniques are discussed. The data emphasize the need for a sex-specific investigation of body dissatisfaction and its consequences. Body image aspects relevant to boys should be added to intervention and prevention approaches. KW - body dissatisfaction KW - disturbed eating KW - muscle enhancement KW - prevention KW - adolescents Y1 - 2011 SN - 0032-7034 VL - 60 IS - 4 SP - 285 EP - 303 PB - Vandenhoeck & Ruprecht CY - Göttingen ER - TY - JOUR A1 - Kroeller, Katja A1 - Warschburger, Petra T1 - Problematic eating behavior in childhood do maternal feeding patterns play a role? JF - Praxis der Kinderpsychologie und Kinderpsychiatrie : Ergebnisse aus Psychotherapie, Beratung und Psychiatrie N2 - Past research indicates an association in adults and young people of emotional and contextual factors with a higher risk for the development of eating disorders or obesity. Few studies focus on problematic eating patterns in childhood, especially in association with parental feeding strategies. 482 mothers completed a questionnaire about eating behaviors and the weight status of their 1- to 10-year-old child as well as their own feeding strategies. A classification of the child's eating behavior (food responsiveness, emotional eating, external eating, eating time and meal structure) using hierarchical cluster analysis revealed a conspicuous eating pattern (10 %) showing above-average values in all eating behaviors. Controlling for weight and demographic variables mothers of children with conspicuous eating patterns were characterized by restrictive strategies and were less likely to encourage or facilitate their child to control his or her eating. Similar problematic eating patterns were also identified in early childhood. The association of maternal feeding strategies - beyond weight control issues - with conspicuous eating patterns in children might indicate a possibility of early prevention through parent training. KW - child's eating behavior KW - problematic eating behavior KW - maternal feeding behavior KW - obesity Y1 - 2011 SN - 0032-7034 VL - 60 IS - 4 SP - 253 EP - 269 PB - Vandenhoeck & Ruprecht CY - Göttingen ER - TY - INPR A1 - Warschburger, Petra A1 - Lehmkuhl, Ulrike T1 - Disturbed eating behavior and its consequences T2 - Praxis der Kinderpsychologie und Kinderpsychiatrie : Ergebnisse aus Psychotherapie, Beratung und Psychiatrie Y1 - 2011 SN - 0032-7034 VL - 60 IS - 4 SP - 249 EP - 252 PB - Vandenhoeck & Ruprecht CY - Göttingen ER - TY - JOUR A1 - Buller, Jens A1 - Laschewsky, André A1 - Lutz, Jean-Francois A1 - Wischerhoff, Erik T1 - Tuning the lower critical solution temperature of thermoresponsive polymers by biospecific recognition JF - Polymer Chemistry N2 - A thermosensitive statistical copolymer based on oligo(ethylene glycol) methacrylates incorporating biotin was synthesized by free radical copolymerisation. The influence of added avidin on its thermoresponsive behaviour was investigated. The specific binding of avidin to the biotinylated copolymers provoked a marked increase of the lower critical solution temperature. Y1 - 2011 U6 - https://doi.org/10.1039/c1py00001b SN - 1759-9954 VL - 2 IS - 7 SP - 1486 EP - 1489 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Zehm, Daniel A1 - Laschewsky, André A1 - Heunemann, Peggy A1 - Gradzielski, Michael A1 - Prevost, Sylvain A1 - Liang, Hua A1 - Rabe, Jürgen P. A1 - Lutz, Jean-Francois T1 - Synthesis and self-assembly of amphiphilic semi-brush and dual brush block copolymers in solution and on surfaces JF - Polymer Chemistry N2 - The combination of two techniques of controlled free radical polymerization, namely the reversible addition fragmentation chain transfer (RAFT) and the atom transfer radical polymerization (ATRP) techniques, together with the use of a macromonomer allowed the synthesis of symmetrical triblock copolymers, designed as amphiphilic dual brushes. One type of brush was made of poly(n-butyl acrylate) as soft hydrophobic block, i.e. characterized by a low glass transition temperature, while the other one was made of hydrophilic poly(ethylene glycol) (PEG). The new triblock polymers represent "giant surfactants" according to their molecular architecture. The hydrophobic and hydrophilic blocks microphase separate in the bulk. In aqueous solution, they aggregate into globular micellar aggregates, their size being determined by the length of the stretched polymer molecules. As determined by the combination of various scattering techniques for the dual brush copolymer, a rather compact structure is formed, which is dominated by the large hydrophobic poly(n-butyl acrylate) block. The aggregation number for the dual brush is about 10 times larger than for the "semi-brush" precursor copolymer, due to the packing requirements for the much bulkier hydrophobic core. On mica surfaces the triblock copolymers adsorb with worm-like backbones and stretched out side chains. Y1 - 2011 U6 - https://doi.org/10.1039/c0py00200c SN - 1759-9954 VL - 2 IS - 1 SP - 137 EP - 147 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Rohlfing, Anne-Katrin A1 - Miteva, Yana A1 - Moronetti, Lorenza A1 - He, Liping A1 - Lamitina, Todd T1 - The caenorhabditis elegans mucin-like protein OSM-8 negatively regulates osmosensitive physiology via the transmembrane protein PTR-23 JF - PLoS Genetics : a peer-reviewed, open-access journal N2 - The molecular mechanisms of animal cell osmoregulation are poorly understood. Genetic studies of osmoregulation in yeast have identified mucin-like proteins as critical regulators of osmosensitive signaling and gene expression. Whether mucins play similar roles in higher organisms is not known. Here, we show that mutations in the Caenorhabditis elegans mucin-like gene osm-8 specifically disrupt osmoregulatory physiological processes. In osm-8 mutants, normal physiological responses to hypertonic stress, such as the accumulation of organic osmolytes and activation of osmoresponsive gene expression, are constitutively activated. As a result, osm-8 mutants exhibit resistance to normally lethal levels of hypertonic stress and have an osmotic stress resistance (Osr) phenotype. To identify genes required for Osm-8 phenotypes, we performed a genome-wide RNAi osm-8 suppressor screen. After screening,18,000 gene knockdowns, we identified 27 suppressors that specifically affect the constitutive osmosensitive gene expression and Osr phenotypes of osm-8 mutants. We found that one suppressor, the transmembrane protein PTR-23, is co-expressed with osm-8 in the hypodermis and strongly suppresses several Osm-8 phenotypes, including the transcriptional activation of many osmosensitive mRNAs, constitutive glycerol accumulation, and osmotic stress resistance. Our studies are the first to show that an extracellular mucin-like protein plays an important role in animal osmoregulation in a manner that requires the activity of a novel transmembrane protein. Given that mucins and transmembrane proteins play similar roles in yeast osmoregulation, our findings suggest a possible evolutionarily conserved role for the mucin-plasma membrane interface in eukaryotic osmoregulation. Y1 - 2011 U6 - https://doi.org/10.1371/journal.pgen.1001267 SN - 1553-7390 VL - 7 IS - 1 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Pilz, Marco A1 - Parolai, Stefano A1 - Picozzi, Matteo A1 - Zschau, Jochen T1 - Evaluation of proxies for seismic site conditions in large urban areas the example of Santiago de Chile JF - Physics and chemistry of the earth N2 - Characterizing the local site response in large cities is an important step towards seismic hazard assessment. To this regard, single station seismic noise measurements were carried out at 146 sites in the northern part of Santiago de Chile. This extensive survey allowed the fundamental resonance frequency of the sedimentary cover, derived from horizontal-to-vertical (H/V) spectral ratios, to be mapped. By inverting the spectral ratios under the constraint of the thickness of the sedimentary cover, known from previous gravimetric measurements, local S-wave velocity profiles have been retrieved. After interpolation between the individual profiles, the resulting high resolution 3D S-wave velocity model allows the entire area, as well as deeper parts of the basin, to be represented in great detail. Since one lithology shows a great scatter in the velocity values only a very general correlation between S-wave velocity in the uppermost 30 m (v(s)(30)) and local geology is found. Local S-wave velocity profiles can serve as a key factor in seismic hazard assessment, since they allow an estimate of the amplification potential of the sedimentary cover. Mapping the intensity distribution of the 27 February 2010 Maule, Chile, event (Mw = 8.8) the results indicate that local amplification of the ground motion might partially explain the damage distribution and encourage the use of the low cost seismic noise techniques for the study of seismic site effects. KW - Ambient seismic noise KW - H/V ratio KW - Inversion KW - S-wave velocity KW - Site effects Y1 - 2011 U6 - https://doi.org/10.1016/j.pce.2011.01.007 SN - 1474-7065 VL - 36 IS - 16 SP - 1259 EP - 1266 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Utecht, Manuel Martin A1 - Klamroth, Tillmann A1 - Saalfrank, Peter T1 - Optical absorption and excitonic coupling in azobenzenes forming self-assembled monolayers a study based on density functional theory JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Based on the analysis of optical absorption spectra, it has recently been speculated that the excitonic coupling between individual azobenzene-functionalized alkanethiols arranged in a self-assembled monolayer (SAM) on a gold surface could be strong enough to hinder collective trans-cis isomerization-on top of steric hindrance [Gahl et al., J. Am. Chem. Soc., 2010, 132, 1831]. Using models of SAMs of increasing complexity (dimer, linear N-mers, and two-dimensionally arranged N-mers) and density functional theory on the (TD-) B3LYP/6-31G* level, we determine optical absorption spectra, the nature and magnitude of excitonic couplings, and the corresponding spectral shifts. It is found that at inter-monomer distances of about 20 angstrom and above, TD-B3LYP excitation frequencies (and signal intensities) can be well described by the frequently used point-dipole approximation. Further, calculated blue shifts in optical absorption spectra account for the experimental observations made for azobenzene/gold SAMs, and hint to the fact that they can indeed be responsible for reduced switching probability in densely packed self-assembled structures. Y1 - 2011 U6 - https://doi.org/10.1039/c1cp22793a SN - 1463-9076 VL - 13 IS - 48 SP - 21608 EP - 21614 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Koch, Andreas T1 - Chelatoaromaticity-existing: yes or no? An answer given by spatial magnetic properties (through space NMR shieldings-TSNMRS) JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - The spatial magnetic properties (through space NMR shieldings-TSNMRS) of metal complexes (with ligands such as acetylacetone, 3-hydroxy-pyran(4) one) and "metallobenzenes" have been calculated by the GIAO perturbation method and visualized as Iso-Chemical-Shielding Surfaces (ICSS) of various sizes and directions. The TSNMRS values, thus obtained, can be successfully employed to quantify and visualize partial aromaticity of the metallocyclic ring by comparison with the spatial magnetic properties of the corresponding non-complexed ligands in comparable structural and electronic situations, and benzene, respectively. Because anisotropy/ring current effects in H-1 NMR spectra proved to be the molecular response property of TSNMRS, the results obtained concerning partial "chelatoaromaticity" are experimentally ensured. Y1 - 2011 U6 - https://doi.org/10.1039/c1cp21942a SN - 1463-9076 SN - 1463-9084 VL - 13 IS - 46 SP - 20593 EP - 20601 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Tiseanu, Carmen A1 - Parvulescu, Vasile I. A1 - Boutonnet, Magali A1 - Cojocaru, Bogdan A1 - Primus, Philipp A. A1 - Teodorescu, Cristian M. A1 - Solans, Conchita A1 - Sanchez Dominguez, Margarita T1 - Surface versus volume effects in luminescent ceria nanocrystals synthesized by an oil-in-water microemulsion method JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Pure and europium (Eu3+) doped cerium dioxide (CeO2) nanocrystals have been synthesized by a novel oil-in-water microemulsion reaction method under soft conditions. In-situ X-ray diffraction and RAMAN spectroscopy, high-resolution transmission electron microscopy, UV/Vis diffuse-reflectance and Fourier transform infrared spectroscopy as well as time-resolved photoluminescence spectroscopy were used to characterize the nanaocrystals. The as-synthesized powders are nanocrystalline and have a narrow size distribution centered on 3 nm and high surface area of similar to 250 m(2) g(-1). Only a small fraction of the europium ions substitutes for the bulk, cubic Ce4+ sites in the europium-doped ceria nanocrystals. Upon calcination up to 1000 degrees C, a remarkable high surface area of similar to 120 m(2) g (-1) is preserved whereas an enrichment of the surface Ce4+ relative to Ce3+ ions and relative strong europium emission with a lifetime of similar to 1.8 ms and FWHM as narrow as 10 cm(-1) are measured. Under excitation into the UV and visible spectral range, the europium doped ceria nanocrystals display a variable emission spanning the orange-red wavelengths. The tunable emission is explained by the heterogeneous distribution of the europium dopants within the ceria nanocrystals coupled with the progressive diffusion of the europium ions from the surface to the inner ceria sites and the selective participation of the ceria host to the emission sensitization. Effects of the bulk-doping and impregnation with europium on the ceria host structure and optical properties are also discussed. Y1 - 2011 U6 - https://doi.org/10.1039/c1cp21135h SN - 1463-9076 VL - 13 IS - 38 SP - 17135 EP - 17145 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Thiel, Kerstin A1 - Klamroth, Tillmann A1 - Strauch, Peter A1 - Taubert, Andreas T1 - On the interaction of ascorbic acid and the tetrachlorocuprate ion [CuCl4](2-) in CuCl nanoplatelet formation from an ionic liquid precursor (ILP) JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - The formation of CuCl nanoplatelets from the ionic liquid precursor (ILP) butylpyridinium tetrachlorocuprate [C4Py](2)[CuCl4] using ascorbic acid as a reducing agent was investigated. In particular, electron paramagnetic resonance (EPR) spectroscopy was used to evaluate the interaction between ascorbic acid and the Cu(II) ion before reduction to Cu(I). EPR spectroscopy suggests that the [CuCl4](2-) ion in the neat IL is a distorted tetrahedron, consistent with DFT calculations. Addition of ascorbic acid leads to the removal of one chloride from the [CuCl4](2-) anion, as shown by DFT and the loss of symmetry by EPR. DFT furthermore suggests that the most stable adduct is formed when only one hydroxyl group of the ascorbic acid coordinates to the Cu(II) ion. Y1 - 2011 U6 - https://doi.org/10.1039/c1cp20648f SN - 1463-9076 VL - 13 IS - 30 SP - 13537 EP - 13543 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Filimon, Marlena A1 - Kopf, Ilona A1 - Schmidt, Dietrich A. A1 - Bruendermann, Erik A1 - Rühe, Jürgen A1 - Santer, Svetlana A1 - Havenith, Martina T1 - Local chemical composition of nanophase-separated polymer brushes JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Using scattering scanning nearfield infrared microscopy (s-SNIM), we have imaged the nanoscale phase separation of mixed polystyrene-poly(methyl methacrylate) (PS-PMMA) brushes and investigated changes in the top layer as a function of solvent exposure. We deduce that the top-layer of the mixed brushes is composed primarily of PMMA after exposure to acetone, while after exposure to toluene this changes to PS. Access to simultaneously measured topographic and chemical information allows direct correlation of the chemical morphology of the sample with topographic information. Our results demonstrate the potential of s-SNIM for chemical mapping based on distinct infrared absorption properties of polymers with a high spatial resolution of 80 nm x 80 nm. Y1 - 2011 U6 - https://doi.org/10.1039/c0cp02756a SN - 1463-9076 VL - 13 IS - 24 SP - 11620 EP - 11626 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Dodoo, S. A1 - Steitz, R. A1 - Laschewsky, André A1 - von Klitzing, Regine T1 - Effect of ionic strength and type of ions on the structure of water swollen polyelectrolyte multilayers JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - This study addresses the effect of ionic strength and type of ions on the structure and water content of polyelectrolyte multilayers. Polyelectrolyte multilayers of poly(sodium-4-styrene sulfonate) (PSS) and poly(diallyl dimethyl ammonium chloride) (PDADMAC) prepared at different NaF, NaCl and NaBr concentrations have been investigated by neutron reflectometry against vacuum, H2O and D2O. Both thickness and water content of the multilayers increase with increasing ionic strength and increasing ion size. Two types of water were identified, "void water" which fills the voids of the multilayers and does not contribute to swelling but to a change in scattering length density and "swelling water" which directly contributes to swelling of the multilayers. The amount of void water decreases with increasing salt concentration and anion radius while the amount of swelling water increases with salt concentration and anion radius. This is interpreted as a denser structure in the dry state and larger ability to swell in water (sponge) for multilayers prepared from high ionic strengths and/or salt solution of large anions. No exchange of hydration water or replacement of H by D was detected even after eight hours incubation time in water of opposing isotopic composition. Y1 - 2011 U6 - https://doi.org/10.1039/c0cp01357a SN - 1463-9076 VL - 13 IS - 21 SP - 10318 EP - 10325 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Füchsel, Gernot A1 - Klamroth, Tillmann A1 - Monturet, Serge A1 - Saalfrank, Peter T1 - Dissipative dynamics within the electronic friction approach the femtosecond laser desorption of H-2/D-2 from Ru(0001) JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - An electronic friction approach based on Langevin dynamics is used to describe the multidimensional (six-dimensional) dynamics of femtosecond laser induced desorption of H-2 and D-2 from a H(D)-covered Ru(0001) surface. The paper extends previous reduced-dimensional models, using a similar approach. In the present treatment forces and frictional coefficients are calculated from periodic density functional theory (DFT) and essentially parameter-free, while the action of femtosecond laser pulses on the metal surface is treated by using the two-temperature model. Our calculations shed light on the performance and validity of various adiabatic, non-adiabatic, and Arrhenius/Kramers type kinetic models to describe hot-electron mediated photoreactions at metal surfaces. The multidimensional frictional dynamics are able to reproduce and explain known experimental facts, such as strong isotope effects, scaling of properties with laser fluence, and non-equipartitioning of vibrational, rotational, and translational energies of desorbing species. Further, detailed predictions regarding translations are made, and the question for the controllability of photoreactions at surfaces with the help of vibrational preexcitation is addressed. Y1 - 2011 U6 - https://doi.org/10.1039/c0cp02086a SN - 1463-9076 VL - 13 IS - 19 SP - 8659 EP - 8670 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Bartlett, Nate C. -M. A1 - Jankunas, Justin A1 - Goswami, Tapas A1 - Zare, Richard N. A1 - Bouakline, Foudhil A1 - Althorpe, Stuart C. T1 - Differential cross sections for H + D-2 -> HD(v '=2, j '=0,3,6,9) + D at center-of-mass collision energies of 1.25, 1.61, and 1.97 eV JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - We have measured differential cross sections (DCSs) for the reaction H + D-2 -> HD- (v' = 2, j' = 0,3,6,9) + D at center-of-mass collision energies E-coll of 1.25, 1.61, and 1.97 eV using the photoloc technique. The DCSs show a strong dependence on the product rotational quantum number. For the HD(v' = 2, j' = 0) product, the DCS is bimodal but becomes oscillatory as the collision energy is increased. For the other product states, they are dominated by a single peak, which shifts from back to sideward scattering as j' increases, and they are in general less sensitive to changes in the collision energy. The experimental results are compared to quantum mechanical calculations and show good, but not fully quantitative agreement. Y1 - 2011 U6 - https://doi.org/10.1039/c0cp02460k SN - 1463-9076 VL - 13 IS - 18 SP - 8175 EP - 8179 PB - Royal Society of Chemistry CY - Cambridge ER -