TY - JOUR A1 - Thon, Ingo A1 - Landwehr, Niels A1 - De Raedt, Luc T1 - Stochastic relational processes efficient inference and applications JF - Machine learning N2 - One of the goals of artificial intelligence is to develop agents that learn and act in complex environments. Realistic environments typically feature a variable number of objects, relations amongst them, and non-deterministic transition behavior. While standard probabilistic sequence models provide efficient inference and learning techniques for sequential data, they typically cannot fully capture the relational complexity. On the other hand, statistical relational learning techniques are often too inefficient to cope with complex sequential data. In this paper, we introduce a simple model that occupies an intermediate position in this expressiveness/efficiency trade-off. It is based on CP-logic (Causal Probabilistic Logic), an expressive probabilistic logic for modeling causality. However, by specializing CP-logic to represent a probability distribution over sequences of relational state descriptions and employing a Markov assumption, inference and learning become more tractable and effective. Specifically, we show how to solve part of the inference and learning problems directly at the first-order level, while transforming the remaining part into the problem of computing all satisfying assignments for a Boolean formula in a binary decision diagram. We experimentally validate that the resulting technique is able to handle probabilistic relational domains with a substantial number of objects and relations. KW - Statistical relational learning KW - Stochastic relational process KW - Markov processes KW - Time series KW - CP-Logic Y1 - 2011 U6 - https://doi.org/10.1007/s10994-010-5213-8 SN - 0885-6125 VL - 82 IS - 2 SP - 239 EP - 272 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Rabenalt, Thomas A1 - Goessel, Michael A1 - Leininger, Andreas T1 - Masking of X-Values by use of a hierarchically configurable register JF - Journal of electronic testing : theory and applications N2 - In this paper we consider masking of unknowns (X-values) for VLSI circuits. We present a new hierarchical method of X-masking which is a major improvement of the method proposed in [4], called WIDE1. By the method proposed, the number of observable scan cells is optimized and data volume for X-masking can be significantly reduced in comparison to WIDEL This is demonstrated for three industrial designs. In cases where all X-values have to be masked the novel approach is especially efficient. KW - Masking of X-values KW - Hierarchically configurable mask register Y1 - 2011 U6 - https://doi.org/10.1007/s10836-010-5179-2 SN - 0923-8174 VL - 27 IS - 1 SP - 31 EP - 41 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Zaupa, Alessandro A1 - Neffe, Axel T. A1 - Pierce, Benjamin F. A1 - Lendlein, Andreas A1 - Hofmann, Dieter T1 - A molecular dynamic analysis of gelatin as an amorphous material Prediction of mechanical properties of gelatin systems JF - The international journal of artificial organs N2 - Biomaterials are used in regenerative medicine for induced autoregeneration and tissue engineering. This is often challenging, however, due to difficulties in tailoring and controlling the respective material properties. Since functionalization is expected to offer better control, in this study gelatin chains were modified with physically interacting groups based on tyrosine with the aim of causing the formation of physical crosslinks. This method permits application-specific properties like swelling and better tailoring of mechanical properties. The design of the crosslink strategy was supported by molecular dynamic (MD) simulations of amorphous bulk models for gelatin and functionalized gelatins at different water contents (0.8 and 25 wt.-%). The results permitted predictions to be formulated about the expected crosslink density and its influence on equilibrium swelling behavior and on elastic material properties. The models of pure gelatin were used to validate the strategy by comparison between simulated and experimental data such as density, backbone conformation angle distribution, and X-ray scattering spectra. A key result of the simulations was the prediction that increasing the number of aromatic functions attached to the gelatin chain leads to an increase in the number of physical netpoints observed in the simulated bulk packing models. By comparison with the Flory-Rehner model, this suggested reduced equilibrium swelling of the functionalized materials in water, a prediction that was subsequently confirmed by our experimental work. The reduction and control of the equilibrium degree of swelling in water is a key criterion for the applicability of functionalized gelatins when used, for example, as matrices for induced autoregeneration of tissues. KW - Physical Network KW - Biopolymer material KW - Molecular modeling KW - Gelatin Y1 - 2011 U6 - https://doi.org/10.5301/IJAO.2010.6083 SN - 0391-3988 VL - 34 IS - 2 SP - 139 EP - 151 PB - Wichtig CY - Milano ER - TY - JOUR A1 - Reiche, Jürgen A1 - Kratz, Karl A1 - Hofmann, Dieter A1 - Lendlein, Andreas T1 - Current status of Langmuir monolayer degradation of polymeric biomaterials JF - The international journal of artificial organs N2 - Langmuir monolayer degradation (LMD) experiments with polymers possessing outstanding biomedical application potential yield information regarding the kinetics of their hydrolytic or enzymatic chain scission under well-defined and adjustable degradation conditions. A brief review is given of LMD investigations, including the author's own work on 2-dimensional (2D) polymer systems, providing chain scission data, which are not disturbed by simultaneously occurring transport phenomena, such as water penetration into the sample or transport of scission fragments out of the sample. A knowledge-based approach for the description and simulation of polymer hydrolytic and enzymatic degradation based on a combination of fast LMD experiments and computer simulation of the water penetration is briefly introduced. Finally, the advantages and disadvantages of this approach are discussed. KW - Monolayer KW - Hydrolytic degradation KW - Enzymatic degradation KW - Biomaterial KW - Degradable polymer Y1 - 2011 U6 - https://doi.org/10.5301/IJAO.2011.6401 SN - 0391-3988 VL - 34 IS - 2 SP - 123 EP - 128 PB - Wichtig CY - Milano ER - TY - JOUR A1 - Tran Thanh Tuan, A1 - Scherbaum, Frank A1 - Malischewsky, Peter G. T1 - On the relationship of peaks and troughs of the ellipticity (H/V) of Rayleigh waves and the transmission response of single layer over half-space models JF - Geophysical journal international N2 - One of the key challenges in the context of local site effect studies is the determination of frequencies where the shakeability of the ground is enhanced. In this context, the H/V technique has become increasingly popular and peak frequencies of H/V spectral ratio are sometimes interpreted as resonance frequencies of the transmission response. In the present study, assuming that Rayleigh surface wave is dominant in H/V spectral ratio, we analyse theoretically under which conditions this may be justified and when not. We focus on 'layer over half-space' models which, although seemingly simple, capture many aspects of local site effects in real sedimentary structures. Our starting point is the ellipticity of Rayleigh waves. We use the exact formula of the H/V-ratio presented by Malischewsky & Scherbaum (2004) to investigate the main characteristics of peak and trough frequencies. We present a simple formula illustrating if and where H/V-ratio curves have sharp peaks in dependence of model parameters. In addition, we have constructed a map, which demonstrates the relation between the H/V-peak frequency and the peak frequency of the transmission response in the domain of the layer's Poisson ratio and the impedance contrast. Finally, we have derived maps showing the relationship between the H/V-peak and trough frequency and key parameters of the model such as impedance contrast. These maps are seen as diagnostic tools, which can help to guide the interpretation of H/V spectral ratio diagrams in the context of site effect studies. KW - Site effects KW - Theoretical seismology KW - Wave propagation Y1 - 2011 U6 - https://doi.org/10.1111/j.1365-246X.2010.04863.x SN - 0956-540X VL - 184 IS - 2 SP - 793 EP - 800 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Fanselow, Gisbert A1 - Lenertova, Denisa T1 - Left peripheral focus mismatches between syntax and information structure JF - Natural language & linguistic theory N2 - In Czech, German, and many other languages, part of the semantic focus of the utterance can be moved to the left periphery of the clause. The main generalization is that only the leftmost accented part of the semantic focus can be moved. We propose that movement to the left periphery is generally triggered by an unspecific edge feature of C (Chomsky 2008) and its restrictions can be attributed to requirements of cyclic linearization, modifying the theory of cyclic linearization developed by Fox and Pesetsky (2005). The crucial assumption is that structural accent is a direct consequence of being linearized at merge, thus it is indirectly relevant for (locality restrictions on) movement. The absence of structural accent correlates with givenness. Given elements may later receive (topic or contrastive) accents, which accounts for fronting in multiple focus/contrastive topic constructions. Without any additional assumptions, the model can account for movement of pragmatically unmarked elements to the left periphery ('formal fronting', Frey 2005). Crucially, the analysis makes no reference at all to concepts of information structure in the syntax, in line with the claim of Chomsky (2008) that UG specifies no direct link between syntax and information structure. KW - Czech KW - German KW - Focus KW - Topic KW - Information structure KW - Intervention effects KW - Cyclic linearization KW - A-bar-movement KW - Prosody-syntax interface KW - Accentuation Y1 - 2011 U6 - https://doi.org/10.1007/s11049-010-9109-x SN - 0167-806X VL - 29 IS - 1 SP - 169 EP - 209 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Hoban, Matty J. A1 - Campbell, Earl T. A1 - Loukopoulos, Klearchos A1 - Browne, Dan E. T1 - Non-adaptive measurement-based quantum computation and multi-party Bell inequalities JF - New journal of physics : the open-access journal for physics N2 - Quantum correlations exhibit behaviour that cannot be resolved with a local hidden variable picture of the world. In quantum information, they are also used as resources for information processing tasks, such as measurement-based quantum computation (MQC). In MQC, universal quantum computation can be achieved via adaptive measurements on a suitable entangled resource state. In this paper, we look at a version of MQC in which we remove the adaptivity of measurements and aim to understand what computational abilities remain in the resource. We show that there are explicit connections between this model of computation and the question of non-classicality in quantum correlations. We demonstrate this by focusing on deterministic computation of Boolean functions, in which natural generalizations of the Greenberger-Horne-Zeilinger paradox emerge; we then explore probabilistic computation via, which multipartite Bell inequalities can be defined. We use this correspondence to define families of multi-party Bell inequalities, which we show to have a number of interesting contrasting properties. Y1 - 2011 U6 - https://doi.org/10.1088/1367-2630/13/2/023014 SN - 1367-2630 VL - 13 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Havelius, Kajsa G. V. A1 - Reschke, Stefan A1 - Horn, Sebastian A1 - Doerlng, Alexander A1 - Niks, Dimitri A1 - Hille, Russ A1 - Schulzke, Carola A1 - Leimkühler, Silke A1 - Haumann, Michael T1 - Structure of the molybdenum site in YedY, a sulfite oxidase homologue from escherichia coli JF - Inorganic chemistry N2 - YedY from Escherichia coil is a new member of the sulfite oxidase family of molybdenum cofactor (Moco)-containing oxidoreductases. We investigated the atomic structure of the molybdenum site in YedY by X-ray absorption spectroscopy, in comparison to human sulfite oxidase (hSO) and to a Mo(IV) model complex. The K-edge energy was indicative of Mo(V) in YedY, in agreement with X- and Q-band electron paramagnetic resonance results, whereas the hSO protein contained Mo(VI). In YedY and hSO, molybdenum is coordinated by two sulfur ligands from the molybdopterin ligand of the Moco, one thiolate sulfur of a cysteine (average Mo-S bond length of similar to 2.4 angstrom), and one (axial) oxo ligand (Mo=O, similar to 1.7 angstrom). hSO contained a second oxo group at Mo as expected, but in YedY, two species in about a 1:1 ratio were found at the active site, corresponding to an equatorial Mo-OH bond (similar to 2.1 angstrom) or possibly to a shorter M-O(-) bond. Yet another oxygen (or nitrogen) at a similar to 2.6 angstrom distance to Mo in YedY was identified, which could originate from a water molecule in the substrate binding cavity or from an amino acid residue close to the molybdenum site, i.e., Glu104, that is replaced by a glycine in hSO, or Asn45. The addition of the poor substrate dimethyl sulfoxide to YedY left the molybdenum coordination unchanged at high pH. In contrast, we found indications that the better substrate trimethylamine N-oxide and the substrate analogue acetone were bound at a similar to 2.6 angstrom distance to the molybdenum, presumably replacing the equatorial oxygen ligand. These findings were used to interpret the recent crystal structure of YedY and bear implications for its catalytic mechanism. Y1 - 2011 U6 - https://doi.org/10.1021/ic101291j SN - 0020-1669 VL - 50 IS - 3 SP - 741 EP - 748 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Giewekemeyer, K. A1 - Krueger, S. P. A1 - Kalbfleisch, S. A1 - Bartels, Meike A1 - Beta, Carsten A1 - Salditt, T. T1 - X-ray propagation microscopy of biological cells using waveguides as a quasipoint source JF - Physical review : A, Atomic, molecular, and optical physics N2 - We have used x-ray waveguides as highly confining optical elements for nanoscale imaging of unstained biological cells using the simple geometry of in-line holography. The well-known twin-image problem is effectively circumvented by a simple and fast iterative reconstruction. The algorithm which combines elements of the classical Gerchberg-Saxton scheme and the hybrid-input-output algorithm is optimized for phase-contrast samples, well-justified for imaging of cells at multi-keV photon energies. The experimental scheme allows for a quantitative phase reconstruction from a single holographic image without detailed knowledge of the complex illumination function incident on the sample, as demonstrated for freeze-dried cells of the eukaryotic amoeba Dictyostelium discoideum. The accessible resolution range is explored by simulations, indicating that resolutions on the order of 20 nm are within reach applying illumination times on the order of minutes at present synchrotron sources. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevA.83.023804 SN - 1050-2947 VL - 83 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Huber, Christian A1 - Klamroth, Tillmann T1 - Explicitly time-dependent coupled cluster singles doubles calculations of laser-driven many-electron dynamics JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - We report explicitly time-dependent coupled cluster singles doubles (TD-CCSD) calculations, which simulate the laser-driven correlated many-electron dynamics in molecular systems. Small molecules, i.e., HF, H(2)O, NH(3), and CH(4), are treated mostly with polarized valence double zeta basis sets. We determine the coupled cluster ground states by imaginary time propagation for these molecules. Excited state energies are obtained from the Fourier transform of the time-dependent dipole moment after an ultrashort, broadband laser excitation. The time-dependent expectation values are calculated from the complex cluster amplitudes using the corresponding configuration interaction singles doubles wave functions. Also resonant laser excitations of these excited states are simulated, in order to explore the limits for the numerical stability of our current TD-CCSD implementation, which uses time-independent molecular orbitals to form excited configurations. Y1 - 2011 U6 - https://doi.org/10.1063/1.3530807 SN - 0021-9606 VL - 134 IS - 5 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Xie, Zai-Lai A1 - Taubert, Andreas T1 - Thermomorphic behavior of the ionic liquids [C(4)mim][FeCl4] and [C(12)mim][FeCl4] JF - ChemPhysChem : a European journal of chemical physics and physical chemistry N2 - The iron-containing ionic liquids 1-butyl-3-methylimidazolium tetrachloroferrate(III) [C(4)mim][FeCl4] and 1-dodecyl-3-methylimidazolium tetrachloroferrate(III) [C(12)mim][FeCl4] exhibit a thermally induced demixing with water (thermomorphism). The phase separation temperature varies with IL weight fraction in water and can be tuned between 100 degrees C and room temperature. The reversible lower critical solution temperature (LCST) is only observed at IL weight fractions below ca. 35% in water. UV/Vis, IR, and Raman spectroscopy along with elemental analysis prove that the yellow-brown liquid phase recovered after phase separation is the starting IL [C(4)mim][FeCl4] and [C(12)mim][FeCl4], respectively. Photometry and ICP-OES show that about 40% of iron remains in the water phase upon phase separation. Although the process is thus not very efficient at the moment, the current approach is the first example of an LCST behavior of a metal-containing IL and therefore, although still inefficient, a prototype for catalyst removal or metal extraction. KW - imidazolium KW - ionic liquids KW - phase transitions KW - Raman spectroscopy KW - thermomorphism Y1 - 2011 U6 - https://doi.org/10.1002/cphc.201000808 SN - 1439-4235 VL - 12 IS - 2 SP - 364 EP - 368 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Berger, Alfons A1 - Schmid, Stefan M. A1 - Engi, Martin A1 - Bousquet, Romain A1 - Wiederkehr, Michael T1 - Mechanisms of mass and heat transport during Barrovian metamorphism: A discussion based on field evidence from the Central Alps (Switzerland/northern Italy) JF - Tectonics N2 - Tectonic and metamorphic data for the Central Alps (Switzerland/Italy) are used to discuss this classic example of a Barrovian metamorphic terrain, notably the evolution of its thermal structure in space and time. Available P-T-t data indicate variable contributions of advective and conductive heat transport during collision and subsequent cooling and exhumation. Some areas experienced a prolonged period of partial melting while other areas, at the same time, show but moderate heating. The Barrow-type metamorphic field gradient observed in the final orogen is the result of two distinct tectonic processes, with their related advective and conductive heat transport processes. The two tectonic processes are (1) accretion of material within a subduction channel related to decompression and emplacement of high-pressure units in the middle crust and (2) wedging and related nappe formation in the continental lower plate. The second process postdates the first one. Wedging and underthrusting of continental lower plate material produces heat input into lower crustal levels, and this process is responsible for predominantly conductive heat transport in the overlying units. The interacting processes lead to different maximum temperatures at different times, producing the final Barrovian metamorphic field gradient. The south experienced rapid cooling, whereas the north shows moderate cooling rates. This discrepancy principally reflects differences in the temperature distribution in the deeper crust prior to cooling. Differences in the local thermal gradient that prevailed before the cooling also determined the relationships between cooling rate and exhumation rate in the different areas. Citation: Berger, A., S. M. Schmid, M. Engi, R. Bousquet, and M. Wiederkehr (2011), Mechanisms of mass and heat transport during Barrovian metamorphism: A discussion based on field evidence from the Central Alps (Switzerland/northern Italy), Tectonics, 30, TC1007, doi:10.1029/2009TC002622. Y1 - 2011 U6 - https://doi.org/10.1029/2009TC002622 SN - 0278-7407 VL - 30 IS - 2 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Maerker, Michael A1 - Pelacani, Samanta A1 - Schroeder, Boris T1 - A functional entity approach to predict soil erosion processes in a small Plio-Pleistocene Mediterranean catchment in Northern Chianti, Italy JF - Geomorphology : an international journal on pure and applied geomorphology N2 - In this paper we evaluate different methods to predict soil erosion processes. We derived different layers of predictor variables for the study area in the Northern Chianti, Italy, describing the soil-lithologic complex, land use, and topographic characteristics. For a subcatchment of the Orme River, we mapped erosion processes by interpreting aerial photographs and field observations. These were classified as erosional response units (ERU), i.e. spatial areas of homogeneous erosion processes. The ERU were used as the response variable in the soil erosion modelling process. We applied two models i) bootstrap aggregation (Random Forest: RF), and ii) stochastic gradient boosting (TreeNet: TN) to predict the potential spatial distribution of erosion processes for the entire Orme River catchment. The models are statistically evaluated using training data and a set of performance parameters such as the area under the receiver operating characteristic curve (AUC), Cohen's Kappa, and pseudo R2. Variable importance and response curves provide further insight into controlling factors of erosion. Both models provided good performance in terms of classification and calibration; however, TN outperformed RF. Similar classes such as active and inactive landslides can be discriminated and well interpreted by considering response curves and relative variable importance. The spatial distribution of the predicted erosion susceptibilities generally follows topographic constraints and is similar for both models. Hence, the model-based delineation of ERU on the basis of soil and terrain information is a valuable tool in geomorphology; it provides insights into factors controlling erosion processes and may allow the extrapolation and prediction of erosion processes in unsurveyed areas. KW - Erosion processes KW - Boostrap aggregation KW - Stochastic gradient boosting KW - Spatially explicit prediction KW - Tuscany KW - Italy Y1 - 2011 U6 - https://doi.org/10.1016/j.geomorph.2010.10.022 SN - 0169-555X VL - 125 IS - 4 SP - 530 EP - 540 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Kreye, Oliver A1 - Toth, Tommy A1 - Meier, Michael A. R. T1 - Introducing multicomponent reactions to polymer science passerini reactions of renewable monomers JF - Journal of the American Chemical Society N2 - Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science. Y1 - 2011 U6 - https://doi.org/10.1021/ja1113003 SN - 0002-7863 VL - 133 IS - 6 SP - 1790 EP - 1792 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Hain, Mathis P. A1 - Sigman, Daniel M. A1 - Haug, Gerald H. T1 - Shortcomings of the isolated abyssal reservoir model for deglacial radiocarbon changes in the mid-depth Indo-Pacific Ocean JF - Geophysical research letters N2 - Severely negative Delta(14)C anomalies from the mid-depth Pacific and the Arabian Sea have been taken as support for the hypothesized deglacial release of a previously isolated, extremely (14)C-deplete deep ocean carbon reservoir. We report box model simulations that cast doubt on both the existence of the hypothesized deep reservoir and its ability to explain the mid-depth Delta(14)C anomalies. First, the degree of ice age isolation needed to substantially reduce the deep Delta(14)C of the deep reservoir causes anoxia and the trapping of alkalinity from CaCO(3) dissolution, the latter increasing atmospheric CO(2). Second, even with a completely (14)C-free deep reservoir, achieving the mid-depth Delta(14)C anomalies of observed duration requires ad hoc stifling of aspects of deep circulation to prevent rapid dissipation of the anomalous (14)C-free carbon to the rest of the ocean and the atmosphere. We suggest that the mid-depth anomalies do not record basin-scale Delta(14)C changes but are instead local phenomena. Y1 - 2011 U6 - https://doi.org/10.1029/2010GL046158 SN - 0094-8276 VL - 38 IS - 6 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Mulansky, Mario A1 - Ahnert, Karsten A1 - Pikovskij, Arkadij T1 - Scaling of energy spreading in strongly nonlinear disordered lattices JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - To characterize a destruction of Anderson localization by nonlinearity, we study the spreading behavior of initially localized states in disordered, strongly nonlinear lattices. Due to chaotic nonlinear interaction of localized linear or nonlinear modes, energy spreads nearly subdiffusively. Based on a phenomenological description by virtue of a nonlinear diffusion equation, we establish a one-parameter scaling relation between the velocity of spreading and the density, which is confirmed numerically. From this scaling it follows that for very low densities the spreading slows down compared to the pure power law. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevE.83.026205 SN - 1539-3755 VL - 83 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Pikovskij, Arkadij A1 - Fishman, Shmuel T1 - Scaling properties of weak chaos in nonlinear disordered lattices JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We study the discrete nonlinear Schrodinger equation with a random potential in one dimension. It is characterized by the length, the strength of the random potential, and the field density that determines the effect of nonlinearity. Following the time evolution of the field and calculating the largest Lyapunov exponent, the probability of the system to be regular is established numerically and found to be a scaling function of the parameters. This property is used to calculate the asymptotic properties of the system in regimes beyond our computational power. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevE.83.025201 SN - 1539-3755 SN - 1550-2376 VL - 83 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schmelzbach, C. A1 - Tronicke, Jens A1 - Dietrich, P. T1 - Three-dimensional hydrostratigraphic models from ground-penetrating radar and direct-push data JF - Journal of hydrology N2 - Three-dimensional models of hydraulic conductivity and porosity are essential to understand and simulate groundwater flow in heterogeneous geological environments. However, considering the inherent limitations of traditional hydrogeological field methods in terms of resolution, alternative field approaches are needed to establish such 3-D models with sufficient accuracy. In this study, we developed a workflow combining 3-D structural information extracted from ground penetrating radar (GPR) images with 1-D in situ physical-property estimates from direct-push (DP) logging to construct a 3-D hydrostratigraphic model. To illustrate this workflow, we collected an similar to 70 m x 90 m 100 MHz 3-D GPR data set over a shallow sedimentary aquifer system resolving six different GPR facies down to similar to 15 m depth. DP logs of the relative dielectric permittivity, the relative hydraulic conductivity, the cone resistance, the sleeve friction and the pore pressure provided crucial data (1) to establish a GPR velocity model for 3-D depth migration and to check the time-to-depth conversion of the GPR data, and (2) to construct a 3-D hydrostratigraphic model. This model was built by assigning porosity values, which were computed from the DP relative dielectric permittivity logs, and DP relative hydraulic conductivity estimates to the identified GPR facies. We conclude that the integration of 3-D GPR structural images and 1-D DP logs of target physical parameters provides an efficient way for detailed 3-D subsurface characterization as needed, for example, for groundwater flow simulations. KW - Ground-penetrating radar KW - Direct push KW - Hydrostratigraphic model KW - Three-dimensional KW - Aquifer KW - Saturated zone Y1 - 2011 U6 - https://doi.org/10.1016/j.jhydrol.2010.12.023 SN - 0022-1694 SN - 1879-2707 VL - 398 IS - 3-4 SP - 235 EP - 245 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Burleigh, J. Gordon A1 - Bansal, Mukul S. A1 - Eulenstein, Oliver A1 - Hartmann, Stefanie A1 - Wehe, Andre A1 - Vision, Todd J. T1 - Genome-Scale Phylogenetics inferring the plant tree of life from 18,896 gene trees JF - Systematic biology N2 - Phylogenetic analyses using genome-scale data sets must confront incongruence among gene trees, which in plants is exacerbated by frequent gene duplications and losses. Gene tree parsimony (GTP) is a phylogenetic optimization criterion in which a species tree that minimizes the number of gene duplications induced among a set of gene trees is selected. The run time performance of previous implementations has limited its use on large-scale data sets. We used new software that incorporates recent algorithmic advances to examine the performance of GTP on a plant data set consisting of 18,896 gene trees containing 510,922 protein sequences from 136 plant taxa (giving a combined alignment length of >2.9 million characters). The relationships inferred from the GTP analysis were largely consistent with previous large-scale studies of backbone plant phylogeny and resolved some controversial nodes. The placement of taxa that were present in few gene trees generally varied the most among GTP bootstrap replicates. Excluding these taxa either before or after the GTP analysis revealed high levels of phylogenetic support across plants. The analyses supported magnoliids sister to a eudicot + monocot clade and did not support the eurosid I and II clades. This study presents a nuclear genomic perspective on the broad-scale phylogenic relationships among plants, and it demonstrates that nuclear genes with a history of duplication and loss can be phylogenetically informative for resolving the plant tree of life. KW - Gene tree-species tree reconciliation KW - gene tree parsimony KW - plant phylogeny KW - phylogenomics Y1 - 2011 U6 - https://doi.org/10.1093/sysbio/syq072 SN - 1063-5157 VL - 60 IS - 2 SP - 117 EP - 125 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Scherler, Dirk A1 - Bookhagen, Bodo A1 - Strecker, Manfred T1 - Spatially variable response of Himalayan glaciers to climate change affected by debris cover JF - Nature geoscience N2 - Controversy about the current state and future evolution of Himalayan glaciers has been stirred up by erroneous statements in the fourth report by the Intergovernmental Panel on Climate Change(1,2). Variable retreat rates(3-6) and a paucity of glacial mass-balance data(7,8) make it difficult to develop a coherent picture of regional climate-change impacts in the region. Here, we report remotely-sensed frontal changes and surface velocities from glaciers in the greater Himalaya between 2000 and 2008 that provide evidence for strong spatial variations in glacier behaviour which are linked to topography and climate. More than 65% of the monsoon-influenced glaciers that we observed are retreating, but heavily debris-covered glaciers with stagnant low-gradient terminus regions typically have stable fronts. Debris-covered glaciers are common in the rugged central Himalaya, but they are almost absent in subdued landscapes on the Tibetan Plateau, where retreat rates are higher. In contrast, more than 50% of observed glaciers in the westerlies-influenced Karakoram region in the northwestern Himalaya are advancing or stable. Our study shows that there is no uniform response of Himalayan glaciers to climate change and highlights the importance of debris cover for understanding glacier retreat, an effect that has so far been neglected in predictions of future water availability(9,10) or global sea level(11). Y1 - 2011 U6 - https://doi.org/10.1038/NGEO1068 SN - 1752-0894 VL - 4 IS - 3 SP - 156 EP - 159 PB - Nature Publ. Group CY - New York ER - TY - JOUR A1 - Balazadeh, Salma A1 - Kwasniewski, Miroslaw A1 - Caldana, Camila A1 - Mehrnia, Mohammad A1 - Zanor, Maria Ines A1 - Xue, Gang-Ping A1 - Müller-Röber, Bernd T1 - ORS1, an H2O2-Responsive NAC Transcription Factor, Controls Senescence in Arabidopsis thaliana JF - Molecular plant N2 - We report here that ORS1, a previously uncharacterized member of the NAC transcription factor family, controls leaf senescence in Arabidopsis thaliana. Overexpression of ORS1 accelerates senescence in transgenic plants, whereas its inhibition delays it. Genes acting downstream of ORS1 were identified by global expression analysis using transgenic plants producing dexamethasone-inducible ORS1-GR fusion protein. Of the 42 up-regulated genes, 30 (similar to 70%) were previously shown to be up-regulated during age-dependent senescence. We also observed that 32 (similar to 76%) of the ORS1-dependent genes were induced by long-term (4 d), but not short-term (6 h) salinity stress (150 mM NaCl). Furthermore, expression of 16 and 24 genes, respectively, was induced after 1 and 5 h of treatment with hydrogen peroxide (H2O2), a reactive oxygen species known to accumulate during salinity stress. ORS1 itself was found to be rapidly and strongly induced by H2O2 treatment in both leaves and roots. Using in vitro binding site selection, we determined the preferred binding motif of ORS1 and found it to be present in half of the ORS1-dependent genes. ORS1 is a paralog of ORE1/ANAC092/AtNAC2, a previously reported regulator of leaf senescence. Phylogenetic footprinting revealed evolutionary conservation of the ORS1 and ORE1 promoter sequences in different Brassicaceae species, indicating strong positive selection acting on both genes. We conclude that ORS1, similarly to ORE1, triggers expression of senescence-associated genes through a regulatory network that may involve cross-talk with salt- and H2O2-dependent signaling pathways. KW - NAC transcription factor KW - leaf senescence KW - gene expression KW - gene regulatory network KW - hydrogen peroxide Y1 - 2011 U6 - https://doi.org/10.1093/mp/ssq080 SN - 1674-2052 VL - 4 IS - 2 SP - 346 EP - 360 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Konrad-Schmolke, Matthias A1 - O'Brien, Patrick J. A1 - Zack, Thomas T1 - Fluid Migration above a Subducted Slab-Constraints on Amount, Pathways and Major Element Mobility from Partially Overprinted Eclogite-facies Rocks (Sesia Zone, Western Alps) JF - Journal of petrology N2 - The Western Alpine Sesia-Lanzo Zone (SLZ) is a sliver of eclogite-facies continental crust exhumed from mantle depths in the hanging wall of a subducted oceanic slab. Eclogite-facies felsic and basic rocks sampled across the internal SLZ show different degrees of retrograde metamorphic overprint associated with fluid influx. The weakly deformed samples preserve relict eclogite-facies mineral assemblages that show partial fluid-induced compositional re-equilibration along grain boundaries, brittle fractures and other fluid pathways. Multiple fluid influx stages are indicated by replacement of primary omphacite by phengite, albitic plagioclase and epidote as well as partial re-equilibration and/or overgrowths in phengite and sodic amphibole, producing characteristic step-like compositional zoning patterns. The observed textures, together with the map-scale distribution of the samples, suggest open-system, pervasive and reactive fluid flux across large rock volumes above the subducted slab. Thermodynamic modelling indicates a minimum amount of fluid of 0 center dot 1-0 center dot 5 wt % interacting with the wall-rocks. Phase relations and reaction textures indicate mobility of K, Ca, Fe and Mg, whereas Al is relatively immobile in these medium-temperature-high-pressure fluids. Furthermore, the thermodynamic models show that recycling of previously fractionated material, such as in the cores of garnet porphyroblasts, largely controls the compositional re-equilibration of the exhumed rock body. KW - fluid migration KW - subduction KW - fluid-rock interaction KW - Sesia Zone Y1 - 2011 U6 - https://doi.org/10.1093/petrology/egq087 SN - 0022-3530 VL - 52 IS - 3 SP - 457 EP - 486 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Zude, Manuela A1 - Pflanz, Michael A1 - Spinelli, Lorenzo A1 - Dosche, Carsten A1 - Torricelli, Alessandro T1 - Non-destructive analysis of anthocyanins in cherries by means of Lambert-Beer and multivariate regression based on spectroscopy and scatter correction using time-resolved analysis JF - Journal of food engineering N2 - In high-value sweet cherry (Prunus avium), the red coloration - determined by the anthocyanins content - is correlated with the fruit ripeness stage and market value. Non-destructive spectroscopy has been introduced in practice and may be utilized as a tool to assess the fruit pigments in the supply chain processes. From the fruit spectrum in the visible (Vis) wavelength range, the pigment contents are analyzed separately at their specific absorbance wavelengths. A drawback of the method is the need for re-calibration due to varying optical properties of the fruit tissue. In order to correct for the scattering differences, most often the spectral intensity in the visible spectrum is normalized by wavelengths in the near infrared (NIR) range, or pre-processing methods are applied in multivariate calibrations. In the present study, the influence of the fruit scattering properties on the Vis/NIR fruit spectrum were corrected by the effective pathlength in the fruit tissue obtained from time-resolved readings of the distribution of time-of-flight (DTOF). Pigment analysis was carried out according to Lambert-Beer law, considering fruit spectral intensities, effective pathlength, and refractive index. Results were compared to commonly applied linear color and multivariate partial least squares (PLS) regression analysis. The approaches were validated on fruits at different ripeness stages, providing variation in the scattering coefficient and refractive index exceeding the calibration sample set. In the validation, the measuring uncertainty of non-destructively analyzing fruits with Vis/NIR spectra by means of PLS or Lambert-Beer in comparison with combined application of Vis/NIR spectroscopy and DTOF measurements showed a dramatic bias reduction as well as enhanced coefficients of determination when using both, the spectral intensities and apparent information on the scattering influence by means of DTOF readings. Corrections for the refractive index did not render improved results. KW - Cherry KW - DTOF KW - Effective pathlength KW - Fruit maturity KW - Lambert-Beer KW - NIR KW - Non-invasive KW - Pigments KW - PLS KW - Ripeness KW - Sensor fusion KW - Spectroscopy KW - Time-resolved spectroscopy KW - TIRF KW - Vis KW - Scattering Y1 - 2011 U6 - https://doi.org/10.1016/j.jfoodeng.2010.09.021 SN - 0260-8774 VL - 103 IS - 1 SP - 68 EP - 75 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - De Frenne, Pieter A1 - Baeten, Lander A1 - Graae, Bente J. A1 - Brunet, Jorg A1 - Wulf, Monika A1 - Orczewska, Anna A1 - Kolb, Annette A1 - Jansen, Ivy A1 - Jamoneau, Aurelien A1 - Jacquemyn, Hans A1 - Hermy, Martin A1 - Diekmann, Martin A1 - De Schrijver, An A1 - De Sanctis, Michele A1 - Decocq, Guillaume A1 - Cousins, Sara A. O. A1 - Verheyen, Kris T1 - Interregional variation in the floristic recovery of post-agricultural forests JF - The journal of ecology N2 - 1. Worldwide, the floristic composition of temperate forests bears the imprint of past land use for decades to centuries as forests regrow on agricultural land. Many species, however, display significant interregional variation in their ability to (re)colonize post-agricultural forests. This variation in colonization across regions and the underlying factors remain largely unexplored. 2. We compiled data on 90 species and 812 species x study combinations from 18 studies across Europe that determined species' distribution patterns in ancient (i.e. continuously forested since the first available land use maps) and post-agricultural forests. The recovery rate (RR) of species in each landscape was quantified as the log-response ratio of the percentage occurrence in post-agricultural over ancient forest and related to the species-specific life-history traits and local (soil characteristics and light availability) and regional factors (landscape properties as habitat availability, time available for colonization, and climate). 3. For the herb species, we demonstrate a strong (interactive) effect of species' life-history traits and forest habitat availability on the RR of post-agricultural forest. In graminoids, however, none of the investigated variables were significantly related to the RR. 4. The better colonizing species that mainly belonged to the short-lived herbs group showed the largest interregional variability. Their recovery significantly increased with the amount of forest habitat within the landscape, whereas, surprisingly, the time available for colonization, climate, soil characteristics and light availability had no effect. 5. Synthesis. By analysing 18 independent studies across Europe, we clearly showed for the first time on a continental scale that the recovery of short-lived forest herbs increased with the forest habitat availability in the landscape. Small perennial forest herbs, however, were generally unsuccessful in colonizing post-agricultural forest even in relatively densely forested landscapes. Hence, our results stress the need to avoid ancient forest clearance to preserve the typical woodland flora. KW - ancient forest KW - colonization capacity KW - forest herbs KW - functional traits KW - habitat fragmentation KW - habitat loss KW - life-history traits KW - meta-analysis KW - plant population and community dynamics KW - secondary succession Y1 - 2011 U6 - https://doi.org/10.1111/j.1365-2745.2010.01768.x SN - 0022-0477 VL - 99 IS - 2 SP - 600 EP - 609 PB - Wiley-Blackwell CY - Malden ER - TY - INPR A1 - Walz, Norbert A1 - Adrian, Rita A1 - Gilbert, John J. A1 - Monaghan, Michael T. A1 - Weithoff, Guntram A1 - Zimmermann-Timm, Heike T1 - Preface T2 - Hydrobiologia : acta hydrobiologica, hydrographica, limnologica et protistologica Y1 - 2011 U6 - https://doi.org/10.1007/s10750-010-0514-2 SN - 0018-8158 VL - 662 IS - 1 SP - 1 EP - 4 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Streich, Rita A1 - Becken, Michael T1 - Electromagnetic fields generated by finite-length wire sources: comparison with point dipole solutions JF - Geophysical prospecting N2 - In present-day land and marine controlled-source electromagnetic (CSEM) surveys, electromagnetic fields are commonly generated using wires that are hundreds of metres long. Nevertheless, simulations of CSEM data often approximate these sources as point dipoles. Although this is justified for sufficiently large source-receiver distances, many real surveys include frequencies and distances at which the dipole approximation is inaccurate. For 1D layered media, electromagnetic (EM) fields for point dipole sources can be computed using well-known quasi-analytical solutions and fields for sources of finite length can be synthesized by superposing point dipole fields. However, the calculation of numerous point dipole fields is computationally expensive, requiring a large number of numerical integral evaluations. We combine a more efficient representation of finite-length sources in terms of components related to the wire and its end points with very general expressions for EM fields in 1D layered media. We thus obtain a formulation that requires fewer numerical integrations than the superposition of dipole fields, permits source and receiver placement at any depth within the layer stack and can also easily be integrated into 3D modelling algorithms. Complex source geometries, such as wires bent due to surface obstructions, can be simulated by segmenting the wire and computing the responses for each segment separately. We first describe our finite-length wire expressions and then present 1D and 3D examples of EM fields due to finite-length sources for typical land and marine survey geometries and discuss differences to point dipole fields. KW - Electromagnetics KW - Mathematical formulation KW - Modelling KW - Numerical study Y1 - 2011 U6 - https://doi.org/10.1111/j.1365-2478.2010.00926.x SN - 0016-8025 VL - 59 IS - 2 SP - 361 EP - 374 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Schmidt, Bernd A1 - Staude, Lucia A1 - Kelling, Alexandra A1 - Schilde, Uwe T1 - A Cross-Metathesis-Conjugate addition route to enantiopure gamma-Butyrolactams and gamma-Lactones from a C-2-Symmetric Precursor JF - European journal of organic chemistry N2 - A protected derivative of (3R, 4R)-hexa-1,5-diene-3,4-diol, a conveniently accessible C-2-symmetric building block, undergoes single or double cross metathesis with methyl acryl-ate. The cross metathesis products are amenable to stereoselective conjugate addition reactions and can be converted into either gamma-butyrolactones or gamma-lactams. KW - Lactams KW - Lactones KW - Oxygen heterocycles KW - Metathesis KW - Desymmetrization Y1 - 2011 U6 - https://doi.org/10.1002/ejoc.201001528 SN - 1434-193X IS - 9 SP - 1721 EP - 1727 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Yarman, Aysu A1 - Nagel, Thomas A1 - Gajovic-Eichelmann, Nenad A1 - Fischer, Anna A1 - Wollenberger, Ursula A1 - Scheller, Frieder W. T1 - Bioelectrocatalysis by Microperoxidase-11 in a Multilayer Architecture of Chitosan Embedded Gold Nanoparticles JF - Electroanalysis : an international journal devoted to fundamental and practical aspects of electroanalysis N2 - We report on the redox behaviour of the microperoxidase-11 (MP-11) which has been electrostatically immobilized in a matrix of chitosan-embedded gold nanoparticles on the surface of a glassy carbon electrode. MP-11 contains a covalently bound heme c as the redox active group that exchanges electrons with the electrode via the gold nanoparticles. Electroactive surface concentration of MP-11 at high scan rate is between 350+/-50 pmol cm(-2), which reflects a multilayer process. The formal potential (E degrees') of MP-11 in the gold nanoparticles-chitosan film was estimated to be -(267.7+/-2.9) mV at pH 7.0. The heterogeneous electron transfer rate constant (k(s)) starts at 1.21 s(-1) and levels off at 6.45 s(-1) in the scan rate range from 0.1 to 2.0 V s(-1). Oxidation and reduction of MP-11 by hydrogen peroxide and superoxide, respectively have been coupled to the direct electron transfer of MP-11. KW - Microperoxidase KW - Direct electron transfer KW - Nanoparticles KW - Hydrogen peroxide KW - Superoxide KW - Bioelectrocatalysis Y1 - 2011 U6 - https://doi.org/10.1002/elan.201000535 SN - 1040-0397 VL - 23 IS - 3 SP - 611 EP - 618 PB - Wiley-Blackwell CY - Malden ER - TY - GEN A1 - Nathan, Ran A1 - Horvitz, Nir A1 - He, Yanping A1 - Kuparinen, Anna A1 - Schurr, Frank Martin A1 - Katul, Gabriel G. T1 - Spread of North American wind-dispersed trees in future environments T2 - Ecology letters N2 - P>Despite ample research, understanding plant spread and predicting their ability to track projected climate changes remain a formidable challenge to be confronted. We modelled the spread of North American wind-dispersed trees in current and future (c. 2060) conditions, accounting for variation in 10 key dispersal, demographic and environmental factors affecting population spread. Predicted spread rates vary substantially among 12 study species, primarily due to inter-specific variation in maturation age, fecundity and seed terminal velocity. Future spread is predicted to be faster if atmospheric CO2 enrichment would increase fecundity and advance maturation, irrespective of the projected changes in mean surface windspeed. Yet, for only a few species, predicted wind-driven spread will match future climate changes, conditioned on seed abscission occurring only in strong winds and environmental conditions favouring high survival of the farthest-dispersed seeds. Because such conditions are unlikely, North American wind-dispersed trees are expected to lag behind the projected climate range shift. KW - Climate change KW - demography KW - dispersal KW - fat-tailed dispersal kernels KW - forecasting KW - forests KW - invasion by extremes KW - long-distance dispersal KW - mechanistic models KW - plant migration KW - population spread KW - range expansion KW - survival KW - wind dispersal Y1 - 2011 U6 - https://doi.org/10.1111/j.1461-0248.2010.01573.x SN - 1461-023X VL - 14 IS - 3 SP - 211 EP - 219 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Neuvonen, Kari A1 - Neuvonen, Helmi A1 - Koch, Andreas A1 - Kleinpeter, Erich T1 - NBO analysis of polar and steric effect using the axial-equatorial equilibrium of cyclohexyl acetates as a probe JF - Computational and theoretical chemistry N2 - The proportion of the axial conformer increases in the ax reversible arrow eq equilibrium of cyclohexyl acetates (RCOOC(6)H(11), R reversible arrow Me, Et, iPr, tBu, CH(2)Cl, CHCl(2), CO(3). CH(2)Br, CHBr(2), CBr(3)) with the increasing size of the acyloxy substitution. The nature of this unexpected steric substituent effect, which is opposite to general stereochemical concepts, was studied by means of ab kiln MO method, accompanied by NBO and isodesmic calculations. NBO parameters seem to be good descriptors for quantitative prediction of the experimental Delta G degrees value of the title conformational equilibrium. The origin and propagation of the substituent effect of the polar substitutions (CH(2)Cl, CHCl(2), CCl(3), CH(2)Br, CHBr(2), CBr(3)) differ, however, from those of the pure alkyl (Me, Et, iPr, tBu) substitutions. The Delta G degrees value of the polar derivatives depends on the qC8 charges, on the occupation of the sigma(center dot)(C1-07) orbital and on the hyperconjugative pi(center dot)(c=O) -> sigma(center dot)(C10-X) and sigma(center dot)(C10-X) -> pi(center dot)(c=O) interactions. The substituent sensitivity of these NBC parameters for the two conformers differ to the effect that the ax reversible arrow eq equilibrium is shifted to the left side with increasing electron withdrawing character of the acyloxy group. The Delta G degrees values of the alkyl derivatives are interpreted in terms of the calculated dipole moments. The destabilization in the non-polar medium (the experimental Delta G degrees values used were measured in CD(2)Cl(2)) due to the enhanced dipolar character is more prominent in the case of the equatorial alkyl conformers. As the consequence, the ax reversible arrow eq equilibrium is shifted to the left despite the increasing size of the R group when going from Me to tBu substitution. KW - Substituent effects KW - Ab initio MO computations KW - Conformational equilibria KW - Cyclohexyl esters KW - NBO analysis Y1 - 2011 U6 - https://doi.org/10.1016/j.comptc.2010.12.033 SN - 2210-271X VL - 964 IS - 1-3 SP - 234 EP - 242 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Schleuning, Matthias A1 - Templin, Mathias A1 - Huaman, Vicky A1 - Vadillo, Giovana P. A1 - Becker, Thomas A1 - Durka, Walter A1 - Fischer, Markus A1 - Matthies, Diethart T1 - Effects of inbreeding, outbreeding, and supplemental pollen on the reproduction of a hummingbird-pollinated clonal amazonian herb JF - Biotropica : a publication of the Association for Tropical Biology N2 - Understory herbs are an essential part of tropical rain forests, but little is known about factors limiting their reproduction. Many of these herbs are clonal, patchily distributed, and produce large floral displays of nectar-rich 1-d flowers to attract hummingbird pollinators that may transport pollen over long distances. The aim of this study was to investigate the effects of clonality, cross-proximity, and patchy distribution on the reproduction of the hummingbird-pollinated Amazonian herb Heliconia metallica. We experimentally pollinated flowers within populations with self-pollen and with pollen of different diversity, crossed flowers between populations, and added supplemental pollen to ramets growing solitarily or in conspecific patches. Only flowers pollinated early in the morning produced seeds. Selfed flowers produced seeds, but seed number and mass were strongly reduced, suggesting partial sterility and inbreeding depression after selfing. Because of pollen competition, flowers produced more seeds after crosses with several than with single donor plants. Crosses between populations mostly resulted in lower seed production than those within populations, suggesting outbreeding depression. Ramets in patches produced fewer seeds than solitary ramets and were more pollen-limited, possibly due to geitonogamy and biparental inbreeding in patches. We conclude that high rates of geitonogamy due to clonality and pollen limitation due to the short receptivity of flowers and patchy distribution constrain the reproduction of this clonal herb. Even in unfragmented rain forests with highly mobile pollinators, outbreeding depression may be a widespread phenomenon in plant reproduction. KW - clonality KW - geitonogamy KW - Heliconiaceae KW - hummingbird pollination KW - Peru KW - pollen limitation KW - pollination experiment KW - rain forest understory Y1 - 2011 U6 - https://doi.org/10.1111/j.1744-7429.2010.00663.x SN - 0006-3606 VL - 43 IS - 2 SP - 183 EP - 191 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Kofod, Guggi A1 - Stoyanov, Hristiyan A1 - Gerhard, Reimund T1 - Multilayer coaxial fiber dielectric elastomers for actuation and sensing JF - Applied physics : A, Materials science & processing N2 - A simple dip-coating technique was employed to manufacture coaxial actuators with multiple layers of alternating dielectric and conducting layers. A thin rubber string was coated with an electrode-insulator-electrode structure, giving rise to a thin, fiber-like actuator with coaxial geometry. The process was repeated to achieve a compact multilayer actuator with up to three coaxial dielectric layers. Mechanical and electromechanical characterization of the actuators is presented, showing actuation strains up to 8% and proper voltage-thickness scaling behavior. Also presented is a capacitance vs. extension plot, demonstrating that these structures can be used for compact and accurate capacitive strain sensing. Y1 - 2011 U6 - https://doi.org/10.1007/s00339-010-6066-5 SN - 0947-8396 SN - 1432-0630 VL - 102 IS - 3 SP - 577 EP - 581 PB - Springer CY - New York ER - TY - JOUR A1 - Scheffler, Christiane T1 - The change of skeletal robustness of 6-12 years old children in Brandenburg (Germany) - Comparison of body composition 1999-2009 JF - Journal of biological and clinical anthropology : Anthropologischer Anzeiger ; Mitteilungsorgan der Gesellschaft für Anthropologie N2 - Overweight as a global problem is a challenge to the health systems today and in the future. Detailed information about the development of body composition in children can help to design preventive measures to stop this trend. In the present study 1397 German children aged 6-12 complete years were investigated with anthropometric methods (i.e. height, weight, BMI, skeleton robustness, and percentage of body fat) in 2008/09. The results were compared with a 10 years old identical study. Today, the investigated children are a little bit smaller and the range of BMI and percentage of body fat is increasing. The large decrease of the skeletal robustness especially in the 10(th) and 3(rd) percentile is important. Decrease of physical activity as the most important reason for shrinking skeletal robustness is discussed. KW - school children KW - body composition KW - skeletal robustness Y1 - 2011 U6 - https://doi.org/10.1127/0003-5548/2011/0095 SN - 0003-5548 VL - 68 IS - 2 SP - 153 EP - 165 PB - Schweizerbart CY - Stuttgart ER - TY - JOUR A1 - Wengenmayer, Christina A1 - Krikov, Maxim A1 - Mueller, Susanne A1 - Lucht, Kristin A1 - Villringer, Arno A1 - Hocher, Berthold A1 - Unger, Thomas A1 - Thoene-Reineke, Christa T1 - Novel therapy approach in primary stroke prevention simultaneous inhibition of endothelin converting enzyme and neutral endopeptidase in spontaneously hypertensive, stroke-prone rats improves survival JF - Neurological research : a journal of progress in neurosurgery and neurosciences N2 - Objectives: Stroke, frequently a consequence of hypertension, is one of the leading causes of death and neurological disabilities worldwide. In the ischemic brain, levels of endothelin-1, one of the most potent vasoconstrictors, are raised. Anti-inflammatory and neuroprotective effects of endothelin antagonists after stroke have been described in literature. Based on these findings, we investigated the protective effect of the endothelin converting enzyme/neutral endopeptidase blocker, SLV 338, in salt-loaded, stroke-prone, spontaneously hypertensive rats. Methods: Male, 8-week-old spontaneously hypertensive stroke-prone rats were put on a high salt diet and treated with either 30 mg/kg or 100 mg/kg SLV 338 or vehicle for 27 weeks. Blood pressure, neurological outcome, body weight, and mortality were investigated throughout treatment. In weeks 1 and 9, animals were housed in metabolic cages for collection of urinary and blood samples and assessment of salt water and food intake. In weeks 22 and 27, additional blood samples were taken. At the end of the study, all brains were analyzed using magnetic resonance imaging. Results: SLV 338 was well tolerated in all animals. Neurological outcome and infarct size were similar in all groups. Albuminuria was considerably delayed and the incidence of stroke significantly lowered in treated animals. In spontaneously hypertensive stroke-prone rats, treatment with SLV 338 significantly (P=0.01) improved survival in comparison to the vehicle treated group in a blood pressure-independent manner. Discussion: Our data in spontaneously hypertensive stroke-prone rats demonstrate that combined endothelin converting enzyme/neutral endopeptidase inhibition could offer a new therapeutic approach for primary stroke prevention and improvement of mortality. The mechanism seems to be blood pressure-independent. KW - Endothelin KW - Hypertension KW - Natriuretic peptides KW - Stroke Y1 - 2011 U6 - https://doi.org/10.1179/016164111X12881719352534 SN - 0161-6412 VL - 33 IS - 2 SP - 201 EP - 207 PB - Routledge, Taylor & Francis Group CY - Leeds ER - TY - JOUR A1 - Bordihn, Henning A1 - Holzer, Markus A1 - Kutrib, Martin T1 - Decidability of operation problems for TOL languages and subclasses JF - Information and computation N2 - We investigate the decidability of the operation problem for TOL languages and subclasses. Fix an operation on formal languages. Given languages from the family considered (OL languages, TOL languages, or their propagating variants), is the application of this operation to the given languages still a language that belongs to the same language family? Observe, that all the Lindenmayer language families in question are anti-AFLs, that is, they are not closed under homomorphisms, inverse homomorphisms, intersection with regular languages, union, concatenation, and Kleene closure. Besides these classical operations we also consider intersection and substitution, since the language families under consideration are not closed under these operations, too. We show that for all of the above mentioned language operations, except for the Kleene closure, the corresponding operation problems of OL and TOL languages and their propagating variants are not even semidecidable. The situation changes for unary OL languages. In this case we prove that the operation problems with respect to Kleene star, complementation, and intersection with regular sets are decidable. KW - L systems KW - Operation problem KW - Decidability KW - Unary languages Y1 - 2011 U6 - https://doi.org/10.1016/j.ic.2010.11.008 SN - 0890-5401 VL - 209 IS - 3 SP - 344 EP - 352 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Kuechly, Helga Ursula A1 - Mueller, Julia Sophie A1 - Reinfelder, Vanessa Luisa A1 - Wiedemann, Stephan A1 - Blaum, Niels T1 - Rodent-mediated dispersal of Acacia seeds in Kalahari savannah rangelands - implications for bush encroachment JF - African journal of ecology Y1 - 2011 U6 - https://doi.org/10.1111/j.1365-2028.2010.01230.x SN - 0141-6707 VL - 49 IS - 1 SP - 119 EP - 121 PB - Wiley-Blackwell CY - Malden ER - TY - GEN A1 - Patil, Kaustubh R. A1 - Haider, Peter A1 - Pope, Phillip B. A1 - Turnbaugh, Peter J. A1 - Morrison, Mark A1 - Scheffer, Tobias A1 - McHardy, Alice C. T1 - Taxonomic metagenome sequence assignment with structured output models T2 - Nature methods : techniques for life scientists and chemists Y1 - 2011 U6 - https://doi.org/10.1038/nmeth0311-191 SN - 1548-7091 VL - 8 IS - 3 SP - 191 EP - 192 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Toke, Nathan A. A1 - Arrowsmith, J. Ramon A1 - Rymer, Michael J. A1 - Landgraf, Angela A1 - Haddad, David E. A1 - Busch, Melanie A1 - Coyan, Joshua A1 - Hannah, Alexander T1 - Late Holocene slip rate of the San Andreas fault and its accommodation by creep and moderate-magnitude earthquakes at Parkfield, California JF - Geology N2 - Investigation of a right-laterally offset channel at the Miller's Field paleoseismic site yields a late Holocene slip rate of 26.2 +6.4/-4.3 mm/yr (1 sigma) for the main trace of the San Andreas fault at Parkfield, California. This is the first well-documented geologic slip rate between the Carrizo and creeping sections of the San Andreas fault. This rate is lower than Holocene measurements along the Carrizo Plain and rates implied by far-field geodetic measurements (similar to 35 mm/yr). However, the rate is consistent with historical slip rates, measured to the northwest, along the creeping section of the San Andreas fault (<30 mm/yr). The paleoseismic exposures at the Miller's Field site reveal a pervasive fabric of clay shear bands, oriented clockwise oblique to the San Andreas fault strike and extending into the uppermost stratigraphy. This fabric is consistent with dextral aseismic creep and observations of surface slip from the 28 September 2004 M6 Parkfield earthquake. Together, this slip rate and deformation fabric suggest that the historically observed San Andreas fault slip behavior along the Parkfield section has persisted for at least a millennium, and that significant slip is accommodated by structures in a zone beyond the main San Andreas fault trace. Y1 - 2011 U6 - https://doi.org/10.1130/G31498.1 SN - 0091-7613 VL - 39 IS - 3 SP - 243 EP - 246 PB - American Institute of Physics CY - Boulder ER - TY - JOUR A1 - Hajialioghli, Robab A1 - Moazzen, Mohssen A1 - Jahangiri, Ahmad A1 - Oberhänsli, Roland A1 - Mocek, Beate A1 - Altenberger, Uwe T1 - Petrogenesis and tectonic evolution of metaluminous sub-alkaline granitoids from the Takab Complex, NW Iran JF - Geological magazine N2 - The Takab complex is composed of a variety of metamorphic rocks including amphibolites, metapelites, mafic granulites, migmatites and meta-ultramafics, which are intruded by the granitoid. The granitoid magmatic activity occurred in relation to the subduction of the Neo-Tethys oceanic crust beneath the Iranian crust during Tertiary times. The granitoids are mainly granodiorite, quartz monzodiorite, monzonite and quartz diorite. Chemically, the magmatic rocks are characterized by ASI < 1.04, AI < 0.87 and high contents of CaO (up to similar to 14.5 wt %), which are consistent with the I-type magmatic series. Low FeO(t)/(FeO(t)+MgO) values (< 0.75) as well as low Nb, Y and K(2)O contents of the investigated rocks resemble the calc-alkaline series. Low SiO(2), K(2)O/Na(2)O and Al(2)O(3) accompanied by high CaO and FeO contents indicate melting of metabasites as an appropriate source for the intrusions. Negative Ti and Nb anomalies verify a metaluminous crustal origin for the protoliths of the investigated igneous rocks. These are comparable with compositions of the associated mafic migmatites, in the Takab metamorphic complex, which originated from the partial melting of amphibolites. Therefore, crustal melting and a collision-related origin for the Takab calc-alkaline intrusions are proposed here on the basis of mineralogy and geochemical characteristics. The P-T evolution during magmatic crystallization and subsolidus cooling stages is determined by the study of mineral chemistry of the granodiorite and the quartz diorite. Magmatic crystallization pressure and temperature for the quartz-diorite and the granodiorite are estimated to be P similar to 7.8 +/- 2.5 kbar, T similar to 760 +/- 75 degrees C and P similar to 5 +/- 1 kbar, T similar to 700 degrees C, respectively. Subsolidus conditions are consistent with temperatures of similar to 620 degrees C and similar to 600 degrees C, and pressures of similar to 5 kbar and similar to 3.5 kbar for the quartz-diorite and the granodiorite, respectively. KW - granitoids KW - partial melting KW - Neo-Tethys KW - Takab KW - NW Iran Y1 - 2011 U6 - https://doi.org/10.1017/S0016756810000683 SN - 0016-7568 VL - 148 IS - 2 SP - 250 EP - 268 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Malic, E. A1 - Weber, C. A1 - Richter, M. A1 - Atalla, V. A1 - Klamroth, Tillmann A1 - Saalfrank, Peter A1 - Reich, Sebastian A1 - Knorr, A. T1 - Microscopic model of the optical absorption of carbon nanotubes functionalized with molecular spiropyran photoswitches JF - Physical review letters N2 - The adsorption of molecules to the surface of carbon nanostructures opens a new field of hybrid systems with distinct and controllable properties. We present a microscopic study of the optical absorption in carbon nanotubes functionalized with molecular spiropyran photoswitches. The switching process induces a change in the dipole moment leading to a significant coupling to the charge carriers in the nanotube. As a result, the absorption spectra of functionalized tubes reveal a considerable redshift of transition energies depending on the switching state of the spiropyran molecule. Our results suggest that carbon nanotubes are excellent substrates for the optical readout of spiropyran-based molecular switches. The gained insights can be applied to other noncovalently functionalized one-dimensional nanostructures in an externally induced dipole field. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevLett.106.097401 SN - 0031-9007 VL - 106 IS - 9 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schildroth, Janice A1 - Rettig-Zimmermann, Juliane A1 - Kalk, Philipp A1 - Steege, Andreas A1 - Faehling, Michael A1 - Sendeski, Mauricio A1 - Paliege, Alexander A1 - Lai, En Yin A1 - Bachmann, Sebastian A1 - Persson, Pontus B. A1 - Hocher, Berthold A1 - Patzak, Andreas T1 - Endothelin type A and B receptors in the control of afferent and efferent arterioles in mice JF - Nephrology, dialysis, transplantation N2 - Background. Endothelin 1 contributes to renal blood flow control and pathogenesis of kidney diseases. The differential effects, however, of endothelin 1 (ET-1) on afferent (AA) and efferent arterioles (EA) remain to be established. Methods. We investigated endothelin type A and B receptor (ETA-R, ETB-R) functions in the control of AA and EA. Arterioles of ETB-R deficient, rescued mice [ETB (-/-)] and wild types [ETB(+/+)] were microperfused. Results. ET-1 constricted AA stronger than EA in ETB (-/-) and ETB(+/+) mice. Results in AA: ET-1 induced similar constrictions in ETB(-/-) and ETB(+/+) mice. BQ-123 (ETA-R antagonist) inhibited this response in both groups. ALA-ET-1 and IRL1620 (ETB-R agonists) had no effect on arteriolar diameter. L-NAME did neither affect basal diameters nor ET-1 responses. Results in EA: ET-1 constricted EA stronger in ETB(+/+) compared to ETB(-/-). BQ-123 inhibited the constriction completely only in ETB(-/-). ALA-ET-1 and IRL1620 constricted only arterioles of ETB(+/+) mice. L-NAME decreased basal diameter in ETB(+/+), but not in ETB(-/-) mice and increased the ET-1 response similarly in both groups. The L-NAME actions indicate a contribution of ETB-R in basal nitric oxide (NO) release in EA and suggest dilatory action of ETA-R in EA. Conclusions. ETA-R mediates vasoconstriction in AA and contributes to vasoconstriction in EA in this mouse model. ETB-R has no effect in AA but mediates basal NO release and constriction in EA. The stronger effect of ET-1 on AA supports observations of decreased glomerular filtration rate to ET-1 and indicates a potential contribution of ET-1 to the pathogenesis of kidney diseases. KW - endothelin KW - ETB receptor-deficient mouse KW - glomerular arterioles KW - renal haemodynamics Y1 - 2011 U6 - https://doi.org/10.1093/ndt/gfq534 SN - 0931-0509 VL - 26 IS - 3 SP - 779 EP - 789 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Endrun, Brigitte A1 - Lebedev, Sergei A1 - Meier, Thomas A1 - Tirel, Celine A1 - Friederich, Wolfgang T1 - Complex layered deformation within the Aegean crust and mantle revealed by seismic anisotropy JF - Nature geoscience N2 - Continental lithosphere can undergo pervasive internal deformation, often distributed over broad zones near plate boundaries. However, because of the paucity of observational constraints on three-dimensional movement at depth, patterns of flow within the lithosphere remain uncertain. Endmember models for lithospheric flow invoke deformation localized on faults or deep shear zones or, alternatively, diffuse, viscous-fluid-like flow. Here we determine seismic Rayleigh-wave anisotropy in the crust and mantle of the Aegean region, an archetypal example of continental deformation. Our data reveal a complex, depth-dependent flow pattern within the extending lithosphere. Beneath the northern Aegean Sea, fast shear wave propagation is in a North-South direction within the mantle lithosphere, parallel to the extensional component of the current strain rate field. In the south-central Aegean, where deformation is weak at present, anisotropic fabric in the lower crust runs parallel to the direction of palaeo-extension in the Miocene. The close match of orientations of regional-scale anisotropic fabric and the directions of extension during the last significant episodes of deformation implies that at least a large part of the extension in the Aegean has been taken up by distributed viscous flow in the lower crust and lithospheric mantle. Y1 - 2011 U6 - https://doi.org/10.1038/NGEO1065 SN - 1752-0894 VL - 4 IS - 3 SP - 203 EP - 207 PB - Nature Publ. Group CY - New York ER - TY - JOUR A1 - Montoya, Marisa A1 - Born, Andreas A1 - Levermann, Anders T1 - Reversed North Atlantic gyre dynamics in present and glacial climates JF - Climate dynamics : observational, theoretical and computational research on the climate system N2 - The dynamics of the North Atlantic subpolar gyre (SPG) are assessed under present and glacial boundary conditions by investigating the SPG sensitivity to surface wind-stress changes in a coupled climate model. To this end, the gyre transport is decomposed in Ekman, thermohaline, and bottom transports. Surface wind-stress variations are found to play an important indirect role in SPG dynamics through their effect on water-mass densities. Our results suggest the existence of two dynamically distinct regimes of the SPG, depending on the absence or presence of deep water formation (DWF) in the Nordic Seas and a vigorous Greenland-Scotland ridge (GSR) overflow. In the first regime, the GSR overflow is weak and the SPG strength increases with wind-stress as a result of enhanced outcropping of isopycnals in the centre of the SPG. As soon as a vigorous GSR overflow is established, its associated positive density anomalies on the southern GSR slope reduce the SPG strength. This has implications for past glacial abrupt climate changes, insofar as these can be explained through latitudinal shifts in North Atlantic DWF sites and strengthening of the North Atlantic current. Regardless of the ultimate trigger, an abrupt shift of DWF into the Nordic Seas could result both in a drastic reduction of the SPG strength and a sudden reversal in its sensitivity to wind-stress variations. Our results could provide insight into changes in the horizontal ocean circulation during abrupt glacial climate changes, which have been largely neglected up to now in model studies. Y1 - 2011 U6 - https://doi.org/10.1007/s00382-009-0729-y SN - 0930-7575 VL - 36 IS - 5-6 SP - 1107 EP - 1118 PB - Springer CY - New York ER - TY - JOUR A1 - Gebser, Martin A1 - Schaub, Torsten H. A1 - Thiele, Sven A1 - Veber, Philippe T1 - Detecting inconsistencies in large biological networks with answer set programming JF - Theory and practice of logic programming N2 - We introduce an approach to detecting inconsistencies in large biological networks by using answer set programming. To this end, we build upon a recently proposed notion of consistency between biochemical/genetic reactions and high-throughput profiles of cell activity. We then present an approach based on answer set programming to check the consistency of large-scale data sets. Moreover, we extend this methodology to provide explanations for inconsistencies by determining minimal representations of conflicts. In practice, this can be used to identify unreliable data or to indicate missing reactions. KW - answer set programming KW - bioinformatics KW - consistency KW - diagnosis Y1 - 2011 U6 - https://doi.org/10.1017/S1471068410000554 SN - 1471-0684 VL - 11 IS - 5-6 SP - 323 EP - 360 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Mengibar, M. A1 - Ganan, M. A1 - Miralles, B. A1 - Carrascosa, A. V. A1 - Martinez-Rodriguez, Adolfo J. A1 - Peter, Martin G. A1 - Heras, A. T1 - Antibacterial activity of products of depolymerization of chitosans with lysozyme and chitosanase against Campylobacter jejuni JF - Carbohydrate polymers : an international journal devoted to scientific and technological aspects of industrially important polysaccharides N2 - Chitosan has several biological properties useful for the food industry, but the most attractive is its potential use as a food preservative of natural origin due to its antimicrobial activity against a wide range of food-borne microorganisms. Among food-borne pathogens, Campylobacter jejuni and related species are recognised as the most common causes of bacterial food-borne diarrhoeal disease throughout the world. Recently, it has been demonstrated that campylobacters are highly sensitive to chitosan. Even though chitosan is known to have important functional activities, poor solubility makes them difficult to use in food and biomedical applications. Unlike chitosan, the low viscosity and good solubility of chitosan oligosaccharides (COS) make them especially attractive in an important number of useful applications. In the present work, the effect of different COS on C. jejuni was investigated. Variables such as the physicochemical characteristics of chitosan and the enzyme used in COS preparation were studied. The COS had been fractioned using ultrafiltration membranes and each fraction was characterized regarding its FA and molecular weight distribution. It has been demonstrated that the biological properties of COS on Campylobacter depend on the composition of the fraction analysed. COS prepared by enzymatic hydrolysis with chitosanase were more active against Campylobacter that lysozyme-derived COS, and this behaviour seems to be related with the acetylation of the chains. On the other hand. the 10-30 kDa fraction was the most active COS fraction, independently of the enzyme used for the hydrolysis. These results have shown that COS could be useful as antimicrobial in the control of C. jejuni. KW - Campylobacter jejuni KW - Chitooligosaccharides KW - Chitosanase KW - Lysozyme KW - Depolymerization Y1 - 2011 U6 - https://doi.org/10.1016/j.carbpol.2010.04.042 SN - 0144-8617 VL - 84 IS - 2 SP - 844 EP - 848 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Vijayakrishnan, Balakumar A1 - Issaree, Arisara A1 - Corilo, Yuri E. A1 - Ferreira, Christina Ramires A1 - Eberlin, Marcos N. A1 - Peter, Martin G. T1 - MSn of the six isomers of (GlcN)(2)(GlcNAc)(2) aminoglucan tetrasaccharides (diacetylchitotetraoses) rules of fragmentation for the sodiated molecules and application to sequence analysis of hetero-chitooligosaccharides JF - Carbohydrate polymers : an international journal devoted to scientific and technological aspects of industrially important polysaccharides N2 - The six possible isomers of di-N-acetylchitotetraoses [AADD, ADDA, ADAD, DADA, DAAD, and DDAA, where D stands for 2-amino-2-deoxy-3-D-glucose (GlcN) and A for 2-acetamido-2-deoxy-beta-D-glucose (GlcNAc)] were analyzed by ESI(+)-MSn. Collision induced dissociation via MSn experiments were performed for the sodiated molecules of m/z 769 [M+Na](+) for each isomer, and fragments were generated mainly by glycosidic bond and cross-ring cleavages. Rules of fragmentation were then established. A reducing end D residue yields the (O.2)A(4) cross-ring [M-59+Na](+) fragment of m/z 710 as the most abundant, whereas isomers containing a reducing end A prefer to lose water to form the [M-18+Na](+) ion of m/z 751, as well as abundant (O.2)A(4) cross-ring [M-101+Na](+) fragments of m/z 668 and B-3 [M-221+Na](+) ions of m/z 548. MS3 of C- and Y-type ions shows analogous fragmentation behaviour that allows identification of the reducing end next-neighbour residue. Due to gas-phase anchimeric assistance, B-type cleavage between the glycosidic oxygen and the anomeric carbon atom is favoured when the glycon is an A residue. Relative ion abundances are generally in the order B >> C > Y, but may vary depending on the next neighbour towards the non-reducing end. These fragmentation rules were used for partial sequence analysis of hetero-chitooligosaccharides of the composition D(2)A(3), D(3)A(3), D(2)A(4), D(4)A(3), and D(3)A(4). KW - Chitosan KW - Fragmentation KW - Oligosaccharides KW - Sequence analysis KW - Tandem mass spectrometry Y1 - 2011 U6 - https://doi.org/10.1016/j.carbpol.2010.04.041 SN - 0144-8617 VL - 84 IS - 2 SP - 713 EP - 726 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Voigt, Andrea A1 - Scheffler, Christiane T1 - Manual abilities of the elderly - handgrip strength, finger and thumb push strength and opening strength in age comparison JF - Journal of biological and clinical anthropology : Anthropologischer Anzeiger ; Mitteilungsorgan der Gesellschaft für Anthropologie N2 - The purpose of this paper is to display the static strength capacities of healthy adults in different age categories. A total of 279 healthy German adults at the ages of 20 to 29 years, 50 to 59 years and 60 to 69 years generated their maximum static handgrip, index finger and thumb push strength, as well as their maximum opening strength on a smooth jar lid of 85 mm diameter and on a knurled bottle lid of 31 mm with their right hand. The results show larger male strength than female strength. Significant age-induced differences appear primarily in opening strengths between the age groups 20 to 29 and 50 to 59 years in male subjects and in female opening strengths between the age groups 20 to 29 and 60 to 69 years as well as between the age groups 50 to 59 and 60 to 69 years. Of greatest interest is that elderly men show the largest opening strengths. KW - elderly KW - torque KW - handgrip strength KW - opening strength Y1 - 2011 U6 - https://doi.org/10.1127/0003-5548/2011/0090 SN - 0003-5548 VL - 68 IS - 2 SP - 167 EP - 173 PB - Schweizerbart CY - Stuttgart ER - TY - JOUR A1 - Kofod, Guggi A1 - Risse, Sebastian A1 - Stoyanov, Hristiyan A1 - McCarthy, Denis N. A1 - Sokolov, Sergey A1 - Krähnert, Ralph T1 - Broad-spectrum enhancement of polymer composite dielectric constant at ultra low volume fractions of silica-supported copper nanoparticles JF - ACS nano N2 - A new strategy for the synthesis of high permittivity polymer composites is demonstrated based on well-defined spatial distribution of ultralow amounts of conductive nanoparticles. The spatial distribution Was realized by immobilizing Cu nanoparticles within the pore system of Alia microspheres, preventing direct contact between individual Cu particles. Both Cu-loaded and unloaded silica microspheres were-then used as fillers in polymer composites prepared with thermoplastic SEBS rubber is the matrix. With a metallic Cu content of about 0.26 vol % In the compoilte, a relative increase of 94% In real permittivity was obtained. No Cu-induced relaxations were observed in the dielectric spectrum within the studied frequency range of 0.1 Hz to 1 MHz. When related to the amount of conductive nanoparticles, the obtained composites achieve the highest broad spectrum enhancement of permittivity ever reported for a polymer based composite. KW - nanocomposite KW - broad-spectrum permittivity enhancement KW - metal nanoparticles KW - uniform spatial arrangement Y1 - 2011 U6 - https://doi.org/10.1021/nn103097q SN - 1936-0851 VL - 5 IS - 3 SP - 1623 EP - 1629 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Pavesi, Laura A1 - De Matthaeis, Elvira A1 - Tiedemann, Ralph A1 - Ketmaier, Valerio T1 - Temporal population genetics and COI phylogeography of the sandhopper macarorchestia remyi (Amphipoda: Talitridae) JF - Zoological studies N2 - Laura Pavesi, Elvira De Matthaeis, Ralph Tiedemann, and Valerio Ketmaier (2011) Temporal population genetics and COI phylogeography of the sandhopper Macarorchestia remyi (Amphipoda: Talitridae). Zoological Studies 50(2): 220-229. In this study we assessed levels of genetic divergence and variability in 208 individuals of the supralittoral sandhopper Macarorchestia remyi, a species strictly associated with rotted wood stranded on sand beaches, by analyzing sequence polymorphisms in a fragment of the mitochondrial DNA (mtDNA) gene coding cytochrome oxidase subunit I (COI). The geographical distribution and ecology of the species are poorly known. The study includes 1 Tyrrhenian and 2 Adriatic populations sampled along the Italian peninsula plus a single individual found on Corfu Is. (Greece). The Tyrrhenian population was sampled monthly for 1 yr. Genetic data revealed a deep phylogeographic break between the Tyrrhenian and Adriatic populations with no shared haplotypes. The single individual collected on Corfu Is. carried the most common haplotype found in the Tyrrhenian population. A mismatch analysis could not reject the hypothesis of a sudden demographic expansion in almost all but 2 monthly samples. When compared to previous genetic data centered on a variety of Mediterranean talitrids, our results place M. remyi among those species with profound intraspecific divergence (sandhoppers) and dissimilar from beachfleas, which generally display little population genetic structuring. KW - Macarorchestia remyi KW - Talitridae KW - Cytochrome oxidase I KW - Population genetics Y1 - 2011 SN - 1021-5506 VL - 50 IS - 2 SP - 220 EP - 229 PB - Institute of Zoology, Academia Sinica CY - Taipei ER - TY - JOUR A1 - Guzman, S. A1 - Petrinovic, I. A. A1 - Brod, J. A. A1 - Hongn, Fernando D. A1 - Seggiaro, R. E. A1 - Montero, C. A1 - Carniel, Roberto A1 - Dantas, E. L. A1 - Sudo, Masafumi T1 - Petrology of the Luingo caldera (SE margin of the Puna plateau) a middle Miocene window of the arc-back arc configuration JF - Journal of volcanology and geothermal research N2 - We describe the petrographic characteristics, whole-rock geochemistry and mineral chemistry of rocks from the Pucarilla-Cerro Tipillas Volcanic Complex with emphasis on the rocks belonging to the middle Miocene Luingo caldera, located in the south-eastern portion of the Central Volcanic Zone (CVZ) of the Andes. We modelled the petrogenesis of the Luingo caldera rocks as a mixture of ca. 20% crustal magmas and 80% of mantle magmas by AFC with recharge processes. A comparison of Luingo geochemical data with the composition of Miocene-Pliocene volcanic rocks from the broad area, points to major thickening events during the middle Miocene for the western portion and during the upper Miocene for the eastern portion of the Southern CVZ. In the eastern sector (similar to 66 degrees W) the mantle source appears to change from a spinel-lherzolite type for the middle Miocene to a garnet-lherzolite type for the upper Miocene-Pliocene magmas. The areal distribution of the volcanic products led to the recognition of approximately equivalent areas covered by volcanic rocks both in the eastern and in the western Puna borders. This indicates a broad arc, which was structurally controlled at the proto-Puna/Puna margins, whose geochemical differences are related with variations in crustal thicknesses and heterogeneous mantle sources from west to east. KW - Luingo caldera KW - Central Andes KW - Miocene volcanism KW - Southern Central Volcanic Zone KW - crustal thickness Y1 - 2011 U6 - https://doi.org/10.1016/j.jvolgeores.2010.12.008 SN - 0377-0273 VL - 200 IS - 3-4 SP - 171 EP - 191 PB - Elsevier CY - Amsterdam ER -