TY - GEN A1 - Raman Venkatesan, Thulasinath A1 - Frübing, Peter A1 - Gerhard, Reimund T1 - Influence of Composition and Preparation on Crystalline Phases and Morphology in Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) Relaxor-Ferroelectric Terpolymer T2 - 2018 IEEE 2nd International Conference on Dielectrics (ICD) N2 - The influence of chemical composition and crystallisation conditions on the ferroelectric and paraelectric phases and the resulting morphology in Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) terpolymer films with 55.4/37.2/7.3 mol% or with 62.2/29.4/8.4 mol% of VDF/TrFE/CFE was studied. Poly(vinylidene fluoride trifluoroethylene) (P(VDF-TrFE)) with 75/25 mol% VDF/TrFE was employed as reference material. Fourier-Transform Infrared Spectroscopy (FTIR) was used to determine the fractions of the relevant terpolymer phases, and X-Ray Diffraction (XRD) was employed to assess the crystalline morphology. The FTIR results show an increase of the fraction of paraelectric phases after annealing. On the other hand, XRD results indicate a more stable paraelectric phase in the terpolymer with higher CFE content. KW - P(VDF-TrFE-CFE) terpolymer KW - relaxor-ferroelectric polymer KW - ferroelectric and paraelectric phases KW - Curie transition Y1 - 2018 SN - 978-1-5386-6389-9 U6 - https://doi.org/10.1109/ICD.2018.8514758 PB - IEEE CY - New York ER -