TY  - GEN
A1  - Krückemeier, Lisa
A1  - Rau, Uwe
A1  - Stolterfoht, Martin
A1  - Kirchartz, Thomas
T1  - How to report record open-circuit voltages in lead-halide perovskite solar cells
T2  - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe
N2  - Open-circuit voltages of lead-halide perovskite solar cells are improving rapidly and are approaching the thermodynamic limit. Since many different perovskite compositions with different bandgap energies are actively being investigated, it is not straightforward to compare the open-circuit voltages between these devices as long as a consistent method of referencing is missing. For the purpose of comparing open-circuit voltages and identifying outstanding values, it is imperative to use a unique, generally accepted way of calculating the thermodynamic limit, which is currently not the case. Here a meta-analysis of methods to determine the bandgap and a radiative limit for open-circuit voltage is presented. The differences between the methods are analyzed and an easily applicable approach based on the solar cell quantum efficiency as a general reference is proposed.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1194 
KW  - Shockley-Queisser model
KW  - bandgap
KW  - fill factor losses
KW  - nonradiative voltage losses
KW  - photovoltaics
KW  - radiative limit
KW  - recombination
Y1  - 2019
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-525289
SN  - 1866-8372
IS  - 1
ER  - 
TY  - JOUR
A1  - Krückemeier, Lisa
A1  - Rau, Uwe
A1  - Stolterfoht, Martin
A1  - Kirchartz, Thomas
T1  - How to report record open-circuit voltages in lead-halide perovskite solar cells
JF  - Advanced energy materials
N2  - Open-circuit voltages of lead-halide perovskite solar cells are improving rapidly and are approaching the thermodynamic limit. Since many different perovskite compositions with different bandgap energies are actively being investigated, it is not straightforward to compare the open-circuit voltages between these devices as long as a consistent method of referencing is missing. For the purpose of comparing open-circuit voltages and identifying outstanding values, it is imperative to use a unique, generally accepted way of calculating the thermodynamic limit, which is currently not the case. Here a meta-analysis of methods to determine the bandgap and a radiative limit for open-circuit voltage is presented. The differences between the methods are analyzed and an easily applicable approach based on the solar cell quantum efficiency as a general reference is proposed.
KW  - bandgap
KW  - fill factor losses
KW  - nonradiative voltage losses
KW  - photovoltaics
KW  - radiative limit
KW  - recombination
KW  - Shockley-Queisser model
Y1  - 2019
U6  - https://doi.org/10.1002/aenm.201902573
SN  - 1614-6832
SN  - 1614-6840
VL  - 10
IS  - 1
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Balischewski, Christian
A1  - Behrens, Karsten
A1  - Zehbe, Kerstin
A1  - Günter, Christina
A1  - Mies, Stefan
A1  - Sperlich, Eric
A1  - Kelling, Alexandra
A1  - Taubert, Andreas
T1  - Ionic liquids with more than one metal
BT  - optical and rlectrochemical properties versus d-block metal vombinations
JF  - Chemistry - a European journal
N2  - Thirteen N-butylpyridinium salts, including three monometallic [C4Py](2)[MCl4], nine bimetallic [C4Py](2)[(M1-xMxCl4)-M-a-Cl-b] and one trimetallic compound [C4Py](2)[(M1-y-zMyMz (c) Cl4)-M-a-M-b] (M=Co, Cu, Mn; x=0.25, 0.50 or 0.75 and y=z=0.33), were synthesized and their structure and thermal and electrochemical properties were studied. All compounds are ionic liquids (ILs) with melting points between 69 and 93 degrees C. X-ray diffraction proves that all ILs are isostructural. The conductivity at room temperature is between 10(-4) and 10(-8) S cm(-1). Some Cu-based ILs reach conductivities of 10(-2) S cm(-1), which is, however, probably due to IL dec. This correlates with the optical bandgap measurements indicating the formation of large bandgap semiconductors. At elevated temperatures approaching the melting points, the conductivities reach up to 1.47x10(-1) S cm(-1) at 70 degrees C. The electrochemical stability windows of the ILs are between 2.5 and 3.0 V.
KW  - bandgap
KW  - electrochemistry
KW  - ionic liquids
KW  - metal-containing ionic
KW  - liquids
KW  - tetrahalido metallates
Y1  - 2020
U6  - https://doi.org/10.1002/chem.202003097
SN  - 0947-6539
SN  - 1521-3765
VL  - 26
IS  - 72
SP  - 17504
EP  - 17513
PB  - Wiley-VCH
CY  - Weinheim
ER  -