TY - JOUR A1 - Stiller, Burkhard A1 - Köpnick, Thomas A1 - Muzikante, I. A1 - Neilands, O. A1 - Utinans, M. A1 - Dubrovich, O. A1 - Karageorgiev, Peter A1 - Brehmer, Ludwig T1 - Optically induced switching effect of polymer containing indandione-1,3-pyridinium betaine side chains Y1 - 1999 SN - 0378-2271 ER - TY - JOUR A1 - Gustina, D. A1 - Markava, E. A1 - Muzikante, I. A1 - Stiller, Burkhard A1 - Brehmer, Ludwig T1 - Photoisomerisation process of self-assembled monolayers of some novel azobenzenes Y1 - 1999 ER - TY - BOOK A1 - Muzikante, I. A1 - Fonavs, E. A1 - Brehmer, Ludwig A1 - Stiller, Burkhard T1 - Photoinuced phenomena in corona poled polar organic films N2 - Organic materials have received considerable attention because of their large dipole moments and optical nonlinearities. The optically induced switching of material properties is important for studying the optoelectronic effects including second harmonic generation. Organic materials for photonic applications contain chromophore dipole which consist of acceptor and donor groups bridged by a delocalized pi-electron system. Both theoretical and experimental data show a reversible highly dipolar photoinduced intra molecular charge transfer in betaine type molecules accompanied by change of the sign and the value of the dipole moment. The arrangement of polar molecules in films is studied both by atom force microscopy and surface potential measurements. To understand the photo response of these materials, their spectroscopic and electrical properties are studied. The morphology and photoinduced surface potential switching of the self-assembled monolayers and polymer films are investigated. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Muzikante, I. A1 - Fonavs, E. A1 - Tokmakov, A. A1 - Cepite, D. A1 - Stiller, Burkhard A1 - Brehmer, Ludwig A1 - Neilands, O. T1 - Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain N2 - Non-linear optical and electrical properties of polymer films obtained by dipole orientation of active units are reported. Novel polar oligomer with N-(indan-1,3-dion-2-yl)pyridinium betaine (IPB) as a side group is studied. Orientation of polar groups in oligomer thin films causes an increase of the photo-induced change of surface potential on irradiation in the region of photo-induced electron transfer (PIET) where the IPB group exhibits a reversible change of the value and sign of the dipole moment. At longer wavelengths, the value of the surface potential of the oligomer may be determined by transport of photo-generated charge carriers Y1 - 2005 SN - 0370-1972 ER -