TY - JOUR A1 - Abdrakhmatov, Kanatbek E. A1 - Walker, R. T. A1 - Campbell, G. E. A1 - Carr, A. S. A1 - Elliott, A. A1 - Hillemann, Christian A1 - Hollingsworth, J. A1 - Landgraf, Angela A1 - Mackenzie, D. A1 - Mukambayev, A. A1 - Rizza, M. A1 - Sloan, R. A. T1 - Multisegment rupture in the 11 July 1889 Chilik earthquake (M-w 8.0-8.3), Kazakh Tien Shan, interpreted from remote sensing, field survey, and paleoseismic trenching JF - Journal of geophysical research : Solid earth N2 - The 11 July 1889 Chilik earthquake (M-w 8.0-8.3) forms part of a remarkable sequence of large earthquakes in the late nineteenth and early twentieth centuries in the northern Tien Shan. Despite its importance, the source of the 1889 earthquake remains unknown, though the macroseismic epicenter is sited in the Chilik valley, similar to 100 km southeast of Almaty, Kazakhstan (similar to 2 million population). Several short fault segments that have been inferred to have ruptured in 1889 are too short on their own to account for the estimated magnitude. In this paper we perform detailed surveying and trenching of the similar to 30 km long Saty fault, one of the previously inferred sources, and find that it was formed in a single earthquake within the last 700 years, involving surface slip of up to 10 m. The scarp-forming event, likely to be the 1889 earthquake, was the only surface-rupturing event for at least 5000 years and potentially for much longer. From satellite imagery we extend the mapped length of fresh scarps within the 1889 epicentral zone to a total of similar to 175 km, which we also suggest as candidate ruptures from the 1889 earthquake. The 175 km of rupture involves conjugate oblique left-lateral and right-lateral slip on three separate faults, with step overs of several kilometers between them. All three faults were essentially invisible in the Holocene geomorphology prior to the last slip. The recurrence interval between large earthquakes on any of these faults, and presumably on other faults of the Tien Shan, may be longer than the timescale over which the landscape is reset, providing a challenge for delineating sources of future hazard. Y1 - 2016 U6 - https://doi.org/10.1002/2015JB012763 SN - 2169-9313 SN - 2169-9356 VL - 121 SP - 4615 EP - 4640 PB - American Geophysical Union CY - Washington ER - TY - THES A1 - Abon, Catherine Cristobal T1 - Radar-based rainfall retrieval for flood forecasting in a meso-scale catchment BT - the Philippines Y1 - 2015 ER - TY - JOUR A1 - Abon, Catherine Cristobal A1 - Kneis, David A1 - Crisologo, Irene A1 - Bronstert, Axel A1 - David, Carlos Primo Constantino A1 - Heistermann, Maik T1 - Evaluating the potential of radar-based rainfall estimates for streamflow and flood simulations in the Philippines JF - GEOMATICS NATURAL HAZARDS & RISK N2 - This case study evaluates the suitability of radar-based quantitative precipitation estimates (QPEs) for the simulation of streamflow in the Marikina River Basin (MRB), the Philippines. Hourly radar-based QPEs were produced from reflectivity that had been observed by an S-band radar located about 90 km from the MRB. Radar data processing and precipitation estimation were carried out using the open source library wradlib. To assess the added value of the radar-based QPE, we used spatially interpolated rain gauge observations (gauge-only (GO) product) as a benchmark. Rain gauge observations were also used to quantify rainfall estimation errors at the point scale. At the point scale, the radar-based QPE outperformed the GO product in 2012, while for 2013, the performance was similar. For both periods, estimation errors substantially increased from daily to the hourly accumulation intervals. Despite this fact, both rainfall estimation methods allowed for a good representation of observed streamflow when used to force a hydrological simulation model of the MRB. Furthermore, the results of the hydrological simulation were consistent with rainfall verification at the point scale: the radar-based QPE performed better than the GO product in 2012, and equivalently in 2013. Altogether, we could demonstrate that, in terms of streamflow simulation, the radar-based QPE can perform as good as or even better than the GO product - even for a basin such as the MRB which has a comparatively dense rain gauge network. This suggests good prospects for using radar-based QPE to simulate and forecast streamflow in other parts of the Philippines where rain gauge networks are not as dense. Y1 - 2016 U6 - https://doi.org/10.1080/19475705.2015.1058862 SN - 1947-5705 SN - 1947-5713 VL - 7 SP - 1390 EP - 1405 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Abouserie, Ahed A1 - Zehbe, Kerstin A1 - Metzner, Philipp A1 - Kelling, Alexandra A1 - Günter, Christina A1 - Schilde, Uwe A1 - Strauch, Peter A1 - Körzdörfer, Thomas A1 - Taubert, Andreas T1 - Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior JF - European journal of inorganic chemistry : a journal of ChemPubSoc Europe N2 - Six N-alkylpyridinium salts [CnPy](2)[MCl4] (n = 4 or 12 and M = Co, Cu, Zn) were synthesized, and their structure and thermal properties were studied. The [C4Py](2)[MCl4] compounds are monoclinic and crystallize in the space group P2(1)/n. The crystals of the longer chain analogues [C12Py](2)[MCl4] are triclinic and crystallize in the space group P (1) over bar. Above the melting temperature, all compounds are ionic liquids (ILs). The derivatives with the longer C12 chain exhibit liquid crystallinity and the shorter chain compounds only show a melting transition. Consistent with single-crystal analysis, electron paramagnetic resonance spectroscopy suggests that the [CuCl4](2-) ions in the Cu-based ILs have a distorted tetrahedral geometry. KW - Ionic liquids KW - Alkylpyridinium salts KW - Structure elucidation KW - Phase transitions Y1 - 2017 U6 - https://doi.org/10.1002/ejic.201700826 SN - 1434-1948 SN - 1099-0682 SP - 5640 EP - 5649 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Abouserie, Ahed A1 - Zehbe, Kerstin A1 - Metzner, Philipp A1 - Kelling, Alexandra A1 - Günter, Christina A1 - Schilde, Uwe A1 - Strauch, Peter A1 - Körzdörfer, Thomas A1 - Taubert, Andreas T1 - Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior JF - European journal of inorganic chemistry : a journal of ChemPubSoc Europe N2 - Six N-alkylpyridinium salts [CnPy](2)[MCl4] (n = 4 or 12 and M = Co, Cu, Zn) were synthesized, and their structure and thermal properties were studied. The [C4Py](2)[MCl4] compounds are monoclinic and crystallize in the space group P2(1)/n. The crystals of the longer chain analogues [C12Py](2)[MCl4] are triclinic and crystallize in the space group P (1) over bar. Above the melting temperature, all compounds are ionic liquids (ILs). The derivatives with the longer C12 chain exhibit liquid crystallinity and the shorter chain compounds only show a melting transition. Consistent with single-crystal analysis, electron paramagnetic resonance spectroscopy suggests that the [CuCl4](2-) ions in the Cu-based ILs have a distorted tetrahedral geometry. KW - Ionic liquids KW - Alkylpyridinium salts KW - Structure elucidation KW - Phase transitions Y1 - 2017 U6 - https://doi.org/10.1002/ejic.201700826 SN - 1434-1948 SN - 1099-0682 SP - 5640 EP - 5649 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Acosta, Veronica Torres A1 - Schildgen, Taylor F. A1 - Clarke, Brian A. A1 - Scherler, Dirk A1 - Bookhagen, Bodo A1 - Wittmann, Hella A1 - von Blanckenburg, Friedhelm A1 - Strecker, Manfred T1 - Effect of vegetation cover on millennial-scale landscape denudation rates in East Africa JF - Lithosphere N2 - The mechanisms by which climate and vegetation affect erosion rates over various time scales lie at the heart of understanding landscape response to climate change. Plot-scale field experiments show that increased vegetation cover slows erosion, implying that faster erosion should occur under low to moderate vegetation cover. However, demonstrating this concept over long time scales and across landscapes has proven to be difficult, especially in settings complicated by tectonic forcing and variable slopes. We investigate this problem by measuring cosmogenic Be-10-derived catchment-mean denudation rates across a range of climate zones and hillslope gradients in the Kenya Rift, and by comparing our results with those published from the Rwenzori Mountains of Uganda. We find that denudation rates from sparsely vegetated parts of the Kenya Rift are up to 0.13 mm/yr, while those from humid and more densely vegetated parts of the Kenya Rift flanks and the Rwenzori Mountains reach a maximum of 0.08 mm/yr, despite higher median hillslope gradients. While differences in lithology and recent land-use changes likely affect the denudation rates and vegetation cover values in some of our studied catchments, hillslope gradient and vegetation cover appear to explain most of the variation in denudation rates across the study area. Our results support the idea that changing vegetation cover can contribute to complex erosional responses to climate or land-use change and that vegetation cover can play an important role in determining the steady-state slopes of mountain belts through its stabilizing effects on the land surface. Y1 - 2015 U6 - https://doi.org/10.1130/L402.1 SN - 1941-8264 SN - 1947-4253 VL - 7 IS - 4 SP - 408 EP - 420 PB - American Institute of Physics CY - Boulder ER - TY - THES A1 - Adhikari, Rishi Ram T1 - Quantification of total microbial biomass and metabolic activity in subsurface sediments T1 - Quantification of total microbial biomass and metabolic activity in subsurface sediments N2 - Metabolically active microbial communities are present in a wide range of subsurface environments. Techniques like enumeration of microbial cells, activity measurements with radiotracer assays and the analysis of porewater constituents are currently being used to explore the subsurface biosphere, alongside with molecular biological analyses. However, many of these techniques reach their detection limits due to low microbial activity and abundance. Direct measurements of microbial turnover not just face issues of insufficient sensitivity, they only provide information about a single specific process but in sediments many different process can occur simultaneously. Therefore, the development of a new technique to measure total microbial activity would be a major improvement. A new tritium-based hydrogenase-enzyme assay appeared to be a promising tool to quantify total living biomass, even in low activity subsurface environments. In this PhD project total microbial biomass and microbial activity was quantified in different subsurface sediments using established techniques (cell enumeration and pore water geochemistry) as well as a new tritium-based hydrogenase enzyme assay. By using a large database of our own cell enumeration data from equatorial Pacific and north Pacific sediments and published data it was shown that the global geographic distribution of subseafloor sedimentary microbes varies between sites by 5 to 6 orders of magnitude and correlates with the sedimentation rate and distance from land. Based on these correlations, global subseafloor biomass was estimated to be 4.1 petagram-C and ~0.6 % of Earth's total living biomass, which is significantly lower than previous estimates. Despite the massive reduction in biomass the subseafloor biosphere is still an important player in global biogeochemical cycles. To understand the relationship between microbial activity, abundance and organic matter flux into the sediment an expedition to the equatorial Pacific upwelling area and the north Pacific Gyre was carried out. Oxygen respiration rates in subseafloor sediments from the north Pacific Gyre, which are deposited at sedimentation rates of 1 mm per 1000 years, showed that microbial communities could survive for millions of years without fresh supply of organic carbon. Contrary to the north Pacific Gyre oxygen was completely depleted within the upper few millimeters to centimeters in sediments of the equatorial upwelling region due to a higher supply of organic matter and higher metabolic activity. So occurrence and variability of electron acceptors over depth and sites make the subsurface a complex environment for the quantification of total microbial activity. Recent studies showed that electron acceptor processes, which were previously thought to thermodynamically exclude each other can occur simultaneously. So in many cases a simple measure of the total microbial activity would be a better and more robust solution than assays for several specific processes, for example sulfate reduction rates or methanogenesis. Enzyme or molecular assays provide a more general approach as they target key metabolic compounds. Since hydrogenase enzymes are ubiquitous in microbes, the recently developed tritium-based hydrogenase radiotracer assay is applied to quantify hydrogenase enzyme activity as a parameter of total living cell activity. Hydrogenase enzyme activity was measured in sediments from different locations (Lake Van, Barents Sea, Equatorial Pacific and Gulf of Mexico). In sediment samples that contained nitrate, we found the lowest cell specific enzyme activity around 10^(-5) nmol H_(2) cell^(-1) d^(-1). With decreasing energy yield of the electron acceptor used, cell-specific hydrogenase activity increased and maximum values of up to 1 nmol H_(2) cell^(-1) d^(-1) were found in samples with methane concentrations of >10 ppm. Although hydrogenase activity cannot be converted directly into a turnover rate of a specific process, cell-specific activity factors can be used to identify specific metabolism and to quantify the metabolically active microbial population. In another study on sediments from the Nankai Trough microbial abundance and hydrogenase activity data show that both the habitat and the activity of subseafloor sedimentary microbial communities have been impacted by seismic activities. An increase in hydrogenase activity near the fault zone revealed that the microbial community was supplied with hydrogen as an energy source and that the microbes were specialized to hydrogen metabolism. N2 - Mikrobielle Gesellschaften und ihre aktiven Stoffwechselprozesse treten in einer Vielzahl von Sedimenten unterschiedlichster Herkunft auf. In der Erforschung dieser tiefen Biosphäre werden derzeit Techniken wie Zellzählungen, Aktivitätsmessungen mit Radiotracer-Versuchen und Analysen der Porenwasserzusammensetzung angewendet, darüber hinaus auch molekularbiologische Analysen. Viele dieser Methoden stoßen an ihre Nachweisgrenze, wenn Sedimente mit geringer Zelldichte und mikrobieller Aktivität untersucht werden. Bei der Untersuchung von Stoffwechselprozessen mit herkömmlichen Techniken kommt dazu, dass von mehreren Prozessen, die zeitgleich ablaufen können, jeweils nur einer erfasst wird. Deswegen wäre die Entwicklung einer neuartigen Messtechnik für die gesamte mikrobielle Aktivität ein wesentlicher Fortschritt für die Erforschung der tiefen Biosphäre. Ein vielversprechender Ansatz, um die gesamte lebende Biomasse auch in Proben mit geringer Aktivität zu bestimmen, ist eine Hydrogenase-Enzym-Versuchsanordnung mit Tritium als quantifizierbarer Messgröße. In dieser Doktorarbeit wurde die gesamte mikrobielle Biomasse und Aktivität von unterschiedlichen Sedimentproben einerseits mit herkömmlichen Methoden (Zellzählungen, Analyse der Porenwasserzusammensetzung) als auch mit einer neu entwickelten Hydrogenase-Enzym-Versuchsanordnung quantifiziert. Mit einer großen Anzahl eigener Zellzählungsdaten von Sedimenten aus dem Äquatorialpazifik und dem Nordpazifik und ergänzenden publizierten Daten konnte gezeigt werden, dass Zellzahlen sich in ihrer globalen geographischen Verteilung je nach Bohrlokation um 5 bis 6 Größenordnungen unterscheiden. Dabei bestehen Korrelationen zur Sedimentationsrate und zur Entfernung zum Land, mit deren Hilfe sich die Gesamtbiomasse in Tiefseesedimenten zu 4,1 Petagramm-C abschätzen lässt. Das entspricht ~0,6 % der Gesamtbiomasse der Erde und ist damit erheblich weniger als in früheren Schätzungen angegeben. Trotz der Korrektur auf diesen Wert spielt die Biomasse der tiefen Biosphäre weiterhin eine erhebliche Rolle in biogeochemischen Kreisläufen. Um die Zusammenhänge zwischen Aktivität der Mikroben, der Häufigkeit ihres Auftretens und Zustrom von organischem Material zu verstehen, wurde eine Expedition ins Auftriebsgebiet des Äquatorialpazifiks und zum nordpazifischen Wirbel durchgeführt. Daten der Sauerstoffaufnahme in Sedimenten des nordpazifischen Wirbels, die mit Sedimentationsraten von 1 mm pro 1000 Jahren abgelagert werden, zeigen, dass mikrobielle Gesellschaften über Millionen von Jahren ohne Zufuhr von frischem organischen Kohlenstoff überleben konnten. Im Gegensatz zum nordpazifischen Wirbel wird in Sedimenten des äquatorialpazifischen Auftriebsgebiets Sauerstoff bei höherer mikrobieller Aktivität und Verfügbarkeit organischer Verbindungen oberflächennah in den ersten Milli- bis Zentimetern komplett umgesetzt. Auftreten und Variabilität von Elektronenakzeptoren nach Tiefe und Bohrlokation machen die tiefe Biosphäre zu einer komplexen Umgebung für die Quantifizierung der gesamten mikrobiellen Aktivität. Aktuelle Studien zeigen das verschiedene Elektronenakzeptorprozesse gleichzeitig ablaufen können, obwohl man bisher davon ausgegangen war, dass diese sich thermodynamisch ausschließen. In vielen Fällen wäre also eine einfache Methode zur Messung der gesamten mikrobiellen Aktivität eine bessere und verlässlichere Lösung aktueller Analyseaufgaben als Messungen mehrerer Einzelprozesse wie beispielsweise Sulfatreduktion und Methanogenese. Enzym-oder Molekular-Versuchsanordnungen sind ein prozessumfassender Ansatz, weil hier Schlüsselkomponenten der Stoffwechselprozesse untersucht werden. Das Hydrogenase-Enzym ist eine solche Schlüsselkomponente und in Mikroben allgegenwärtig. Deshalb kann die Quantifizierung seiner Aktivität mit der neu entwickelten Hydrogenase-Enzym-Versuchsanordnung als Parameter für die gesamte mikrobielle Aktivität der lebenden Zellen verwendet werden. Hydrogenase-Aktivitäten wurden in Sedimenten unterschiedlicher Lokationen (Vansee, Barentssee, Äquatorialpazifik, und Golf von Mexico) gemessen. In Sedimentproben, die Nitrat enthielten, haben wir mit ca. 10^(-5) nmol H_(2) cell^(-1) d^(-1) die geringste zellspezifische Hydrogenase-Aktivität gefunden. Mit geringerem Energiegewinn des genutzten Elektronenakzeptors steigt die zellspezifische Hydrogenase-Aktivität. Maximalwerte von bis zu 1 nmol H_(2) cell^(-1) d^(-1) wurden in Sedimentproben mit >10 ppm Methankonzentration gefunden. Auch wenn die Hydrogenase-Aktivität nicht direkt in die Umsatzrate eines spezifischen Prozesses konvertierbar ist, können zellspezifische Aktivitätsfaktoren verwendet werden, um die metabolisch aktive Mikrobenpopulation zu quantifizieren. In einer weiteren Studie mit Sedimenten des Nankai-Grabens zeigen Daten der Zelldichte und der Hydrogenase-Aktivität einen Einfluss von seismischen Ereignissen auf Lebensraum und Aktivität der mikrobiellen Gesellschaften. Ein Anstieg der Hydrogenase-Aktivität nahe der Verwerfungszone machte deutlich, dass die mikrobiellen Gesellschaften mit Wasserstoff als Energiequelle versorgt wurden und dass die Mikroben auf einen Wasserstoff-Stoffwechsel spezialisiert waren. KW - Hydrogenase KW - Tritium Versuchsanordnung KW - Untergrunduntersuchung der Biosphäre KW - Hydrogenase KW - Tritium Assay KW - Subsurface Biosphere Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67773 ER - TY - GEN A1 - Adhikari, Rishi Ram A1 - Glombitza, Clemens A1 - Nickel, Julia C. A1 - Anderson, Chloe H. A1 - Dunlea, Ann G. A1 - Spivack, Arthur J. A1 - Murray, Richard W. A1 - D’Hondt, Steven A1 - Kallmeyer, Jens T1 - Hydrogen utilization potential in subsurface sediments T2 - Frontiers in microbiology N2 - Subsurface microbial communities undertake many terminal electron-accepting processes, often simultaneously. Using a tritium-based assay, we measured the potential hydrogen oxidation catalyzed by hydrogenase enzymes in several subsurface sedimentary environments (Lake Van, Barents Sea, Equatorial Pacific, and Gulf of Mexico) with different predominant electron-acceptors. Hydrogenases constitute a diverse family of enzymes expressed by microorganisms that utilize molecular hydrogen as a metabolic substrate, product, or intermediate. The assay reveals the potential for utilizing molecular hydrogen and allows qualitative detection of microbial activity irrespective of the predominant electron-accepting process. Because the method only requires samples frozen immediately after recovery, the assay can be used for identifying microbial activity in subsurface ecosystems without the need to preserve live material. We measured potential hydrogen oxidation rates in all samples from multiple depths at several sites that collectively span a wide range of environmental conditions and biogeochemical zones. Potential activity normalized to total cell abundance ranges over five orders of magnitude and varies, dependent upon the predominant terminal electron acceptor. Lowest per-cell potential rates characterize the zone of nitrate reduction and highest per-cell potential rates occur in the methanogenic zone. Possible reasons for this relationship to predominant electron acceptor include (i) increasing importance of fermentation in successively deeper biogeochemical zones and (ii) adaptation of H(2)ases to successively higher concentrations of H-2 in successively deeper zones. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 447 KW - hydrogenase KW - tritium assay KW - deep biosphere KW - microbial activity KW - Lake Van KW - Barents Sea KW - Equatorial Pacific KW - Gulf of Mexico Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-407678 ER - TY - JOUR A1 - Adhikari, Rishi Ram A1 - Glombitza, Clemens A1 - Nickel, Julia C. A1 - Anderson, Chloe H. A1 - Dunlea, Ann G. A1 - Spivack, Arthur J. A1 - Murray, Richard W. A1 - Kallmeyer, Jens T1 - Hydrogen Utilization Potential in Subsurface Sediments JF - Frontiers in microbiology N2 - Subsurface microbial communities undertake many terminal electron-accepting processes, often simultaneously. Using a tritium-based assay, we measured the potential hydrogen oxidation catalyzed by hydrogenase enzymes in several subsurface sedimentary environments (Lake Van, Barents Sea, Equatorial Pacific, and Gulf of Mexico) with different predominant electron-acceptors. Hydrogenases constitute a diverse family of enzymes expressed by microorganisms that utilize molecular hydrogen as a metabolic substrate, product, or intermediate. The assay reveals the potential for utilizing molecular hydrogen and allows qualitative detection of microbial activity irrespective of the predominant electron-accepting process. Because the method only requires samples frozen immediately after recovery, the assay can be used for identifying microbial activity in subsurface ecosystems without the need to preserve live material. We measured potential hydrogen oxidation rates in all samples from multiple depths at several sites that collectively span a wide range of environmental conditions and biogeochemical zones. Potential activity normalized to total cell abundance ranges over five orders of magnitude and varies, dependent upon the predominant terminal electron acceptor. Lowest per-cell potential rates characterize the zone of nitrate reduction and highest per-cell potential rates occur in the methanogenic zone. Possible reasons for this relationship to predominant electron acceptor include (i) increasing importance of fermentation in successively deeper biogeochemical zones and (ii) adaptation of H(2)ases to successively higher concentrations of H-2 in successively deeper zones. KW - hydrogenase KW - tritium assay KW - deep biosphere KW - microbial activity KW - Lake Van KW - Barents Sea KW - Equatorial Pacific KW - Gulf of Mexico Y1 - 2016 U6 - https://doi.org/10.3389/fmicb.2016.00008 SN - 1664-302X VL - 7 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Adhikari, Rishi Ram A1 - Kallmeyer, Jens T1 - Detection and quantification of microbial activity in the subsurface N2 - The subsurface harbors a large fraction of Earth's living biomass, forming complex microbial ecosystems. Without a profound knowledge of the ongoing biologically mediated processes and their reaction to anthropogenic changes it is difficult to assess the long-term stability and feasibility of any type of geotechnical utilization, as these influence subsurface ecosystems. Despite recent advances in many areas of subsurface microbiology, the direct quantification of turnover processes is still in its infancy, mainly due to the extremely low cell abundances. We provide an overview of the currently available techniques for the quantification of microbial turnover processes and discuss their specific strengths and limitations. Most techniques employed so far have focused on specific processes, e.g. sulfate reduction or methanogenesis. Recent studies show that processes that were previously thought to exclude each other can occur simultaneously, albeit at very low rates. Without the identification of the respective processes it is impossible to quantify total microbial activity. Even in cases where all simultaneously occurring processes can be identified, the typically very low rates prevent quantification. In many cases a simple measure of total microbial activity would be a better and more robust measure than assays for several specific processes. Enzyme or molecular assays provide a more general approach as they target key metabolic compounds. Depending on the compound targeted a broader spectrum of microbial processes can be quantified. The two most promising compounds are ATP and hydrogenase, as both are ubiquitous in microbes. Technical constraints limit the applicability of currently available ATP-assays for subsurface samples. A recently developed hydrogenase radiotracer assay has the potential to become a key tool for the quantification of subsurface microbial activity. Y1 - 2010 UR - http://www.sciencedirect.com/science/journal/00092819 U6 - https://doi.org/10.1016/j.chemer.2010.05.003 SN - 0009-2819 ER - TY - JOUR A1 - Aerts, J. C. J. H. A1 - Botzen, W. J. Wouter A1 - Clarke, K. C. A1 - Cutter, S. L. A1 - Hall, J. W. A1 - Merz, Bruno A1 - Michel-Kerjan, E. A1 - Mysiak, J. A1 - Surminski, Swenja A1 - Kunreuther, H. T1 - Integrating human behaviour dynamics into flood disaster risk assessment JF - Nature climate change N2 - The behaviour of individuals, businesses, and government entities before, during, and immediately after a disaster can dramatically affect the impact and recovery time. However, existing risk-assessment methods rarely include this critical factor. In this Perspective, we show why this is a concern, and demonstrate that although initial efforts have inevitably represented human behaviour in limited terms, innovations in flood-risk assessment that integrate societal behaviour and behavioural adaptation dynamics into such quantifications may lead to more accurate characterization of risks and improved assessment of the effectiveness of risk-management strategies and investments. Such multidisciplinary approaches can inform flood-risk management policy development. Y1 - 2018 U6 - https://doi.org/10.1038/s41558-018-0085-1 SN - 1758-678X SN - 1758-6798 VL - 8 IS - 3 SP - 193 EP - 199 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Agada, S. A1 - Chen, F. A1 - Geiger, S. A1 - Toigulova, G. A1 - Agar, Susan M. A1 - Shekhar, R. A1 - Benson, Gregory S. A1 - Hehmeyer, O. A1 - Amour, Frédéric A1 - Mutti, Maria A1 - Christ, Nicolas A1 - Immenhauser, A. T1 - Numerical simulation of fluid-flow processes in a 3D high-resolution carbonate reservoir analogue JF - Petroleum geoscience N2 - A high-resolution three-dimensional (3D) outcrop model of a Jurassic carbonate ramp was used in order to perform a series of detailed and systematic flow simulations. The aim of this study was to test the impact of small- and large-scale geological features on reservoir performance and oil recovery. The digital outcrop model contains a wide range of sedimentological, diagenetic and structural features, including discontinuity surfaces, shoal bodies, mud mounds, oyster bioherms and fractures. Flow simulations are performed for numerical well testing and secondary oil recovery. Numerical well testing enables synthetic but systematic pressure responses to be generated for different geological features observed in the outcrops. This allows us to assess and rank the relative impact of specific geological features on reservoir performance. The outcome documents that, owing to the realistic representation of matrix heterogeneity, most diagenetic and structural features cannot be linked to a unique pressure signature. Instead, reservoir performance is controlled by subseismic faults and oyster bioherms acting as thief zones. Numerical simulations of secondary recovery processes reveal strong channelling of fluid flow into high-permeability layers as the primary control for oil recovery. However, appropriate reservoir-engineering solutions, such as optimizing well placement and injection fluid, can reduce channelling and increase oil recovery. Y1 - 2014 U6 - https://doi.org/10.1144/petgeo2012-096 SN - 1354-0793 VL - 20 IS - 1 SP - 125 EP - 142 PB - Geological Soc. Publ. House CY - Bath ER - TY - THES A1 - Agarwal, Ankit T1 - Unraveling spatio-temporal climatic patterns via multi-scale complex networks T1 - Aufklärung raumzeitlicher Klimamuster über komplexe Netzwerke mit mehreren Maßstäben N2 - The climate is a complex dynamical system involving interactions and feedbacks among different processes at multiple temporal and spatial scales. Although numerous studies have attempted to understand the climate system, nonetheless, the studies investigating the multiscale characteristics of the climate are scarce. Further, the present set of techniques are limited in their ability to unravel the multi-scale variability of the climate system. It is completely plausible that extreme events and abrupt transitions, which are of great interest to climate community, are resultant of interactions among processes operating at multi-scale. For instance, storms, weather patterns, seasonal irregularities such as El Niño, floods and droughts, and decades-long climate variations can be better understood and even predicted by quantifying their multi-scale dynamics. This makes a strong argument to unravel the interaction and patterns of climatic processes at different scales. With this background, the thesis aims at developing measures to understand and quantify multi-scale interactions within the climate system. In the first part of the thesis, I proposed two new methods, viz, multi-scale event synchronization (MSES) and wavelet multi-scale correlation (WMC) to capture the scale-specific features present in the climatic processes. The proposed methods were tested on various synthetic and real-world time series in order to check their applicability and replicability. The results indicate that both methods (WMC and MSES) are able to capture scale-specific associations that exist between processes at different time scales in a more detailed manner as compared to the traditional single scale counterparts. In the second part of the thesis, the proposed multi-scale similarity measures were used in constructing climate networks to investigate the evolution of spatial connections within climatic processes at multiple timescales. The proposed methods WMC and MSES, together with complex network were applied to two different datasets. In the first application, climate networks based on WMC were constructed for the univariate global sea surface temperature (SST) data to identify and visualize the SSTs patterns that develop very similarly over time and distinguish them from those that have long-range teleconnections to other ocean regions. Further investigations of climate networks on different timescales revealed (i) various high variability and co-variability regions, and (ii) short and long-range teleconnection regions with varying spatial distance. The outcomes of the study not only re-confirmed the existing knowledge on the link between SST patterns like El Niño Southern Oscillation and the Pacific Decadal Oscillation, but also suggested new insights into the characteristics and origins of long-range teleconnections. In the second application, I used the developed non-linear MSES similarity measure to quantify the multivariate teleconnections between extreme Indian precipitation and climatic patterns with the highest relevance for Indian sub-continent. The results confirmed significant non-linear influences that were not well captured by the traditional methods. Further, there was a substantial variation in the strength and nature of teleconnection across India, and across time scales. Overall, the results from investigations conducted in the thesis strongly highlight the need for considering the multi-scale aspects in climatic processes, and the proposed methods provide robust framework for quantifying the multi-scale characteristics. N2 - Das Klima ist ein komplexes Zusammenspiel verschiedener Mechanismen und Rückkopplungen auf mehreren zeitlichen und räumlichen Skalen. Viele Studien beschäftigten sich mit dem diesem System, nur wenige jedoch konzentrierten sich auf das Multiskalenverhalten des Klimas. Vor allem die bis dato verfügbaren Techniken schränkten eine vertiefte Analyse der Klimavariabilität auf unterschiedlichen Skalen ein. Von großen Interesse in der aktuellen Klimaforschung sind Extremereignisse und plötzliche Veränderungen, welche höchstwahrscheinlich aus dem Zusammenwirken von Prozessen auf unterschiedlichen Skalen hervorgehen. Um Stürme, wiederkehrende Wetterlagen, jahreszeitliche Phänomene wie El Niño, Fluten, Dürren oder Klimaschwankungen über Jahrzehnte besser zu verstehen oder sogar vorhersagen zu können, müssen wir deren Dynamik auf unterschiedlichen Skalen quantifizieren. In der vorliegenden Arbeit werden Mittel und Wege präsentiert um das Zusammenwirken auf verschiedenen Skalen im Klimasystem besser zu verstehen und zu quantifizieren. Im ersten Teil dieser Arbeit stelle ich zwei Methoden, multi-scale event synchronization (MSES) und wavelet multi-scale correlation (WMC) vor, welche skalenspezifischen Eigenschaften in klimatischen Prozessen abbilden. Die vorgestellte Methode wurde mit mehreren synthetischen und realen Zeitreihen getestet um ihre Anwendbarkeit und Reproduzierbarkeit zu überprüfen. Die Ergebnisse zeigen, dass beide Methoden Beziehungen auf unterschiedlichen zeitlichen Skalen detaillierter als traditionelle Ansätze abbilden können. Im zweiten Teil dieser Arbeit bilde ich klimatische Netzwerke mithilfe eines Maßes zur Ähnlichkeit auf Multiskalen. Dabei untersuche ich die Entwicklung von räumlichen Beziehungen um klimatische Prozesse auf mehreren Zeitskalen zu verstehen. Die Methoden WMC und MSES werden zusammen mit komplexen Netzwerken auf zwei Datensätze angewendet. In der ersten Anwendung werden klimatische Netzwerke mit WMC für univariate globale Meeresoberflächentemperaturen gebildet. Auf unterschiedlichen Zeitskalen sollen dabei kurze und lange Fernwirkungen, welche andernfalls auf einer einzigen Zeitskale unerkannt blieben, entdeckt werden. In diesem Klimanetzwerk ließ sich eine starke Variabilität über die Zeit feststellen, was auf eine skalenfreie und kleinräumige Netzstruktur auf großem, beziehungsweise kleinem Maßstab schließen lässt. Weitere Untersuchungen von Klimanetzwerken auf unterschiedlichen Zeitskalen zeigte (i) hohe Variabilität und Co-Variabilität in Regionen, und (ii) Fernbeziehungen auf kurzen und langen Entfernungen mit variabler räumlicher Distanz. Die Ergebnisse bestätigen bekannte physikalischen Wechselwirkungen und daher auch die Stärken meines Ansatzes. Dadurch ergeben sich neue Einblicke in die Klimatologie von Ozeanen, sodass beispielsweise konvektive Prozesse in der Atmosphäre eine Abhängigkeit über weite Entfernungen aufweisen können. In der zweiten Anwendung verwendeten wir das von mir entwickelte, nicht-lineare MSES Ähnlichkeitsmaß um multivariate Fernbeziehungen zwischen Starkniederschlägen und klimatischen Mustern über Indien zu quantifizieren. Unsere Ergebnisse bestätigen signifikante, nicht-lineare Einflüsse, welche von traditionellen Methoden bisher unzureichend abgebildet wurden. Des Weiteren fanden wir deutliche Schwankungen in der Stärke und in der Ausprägung von Fernbeziehungen über Indien und über Zeitskalen. Zusammenfassend zeigen die Ergebnisse dieser Fallstudien, dass Multiskalen in Klimaprozessen entschieden berücksichtigt werden müssen und dass der entwickelte methodische Rahmen adäquat die charakteristischen Prozesse quantifizieren kann. KW - complex network KW - wavelet KW - climate global and local patterns KW - extreme events KW - multiscale network KW - event synchronization KW - komplexes Netzwerk KW - Wavelet KW - globale und lokale Muster des Klimas KW - extreme Ereignisse KW - Multiskalen Netzwerk KW - Ereignissynchronisation Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-423956 ER - TY - JOUR A1 - Agarwal, Ankit A1 - Caesar, Levke A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Merz, Bruno T1 - Network-based identification and characterization of teleconnections on different scales JF - Scientific Reports N2 - Sea surface temperature (SST) patterns can – as surface climate forcing – affect weather and climate at large distances. One example is El Niño-Southern Oscillation (ENSO) that causes climate anomalies around the globe via teleconnections. Although several studies identified and characterized these teleconnections, our understanding of climate processes remains incomplete, since interactions and feedbacks are typically exhibited at unique or multiple temporal and spatial scales. This study characterizes the interactions between the cells of a global SST data set at different temporal and spatial scales using climate networks. These networks are constructed using wavelet multi-scale correlation that investigate the correlation between the SST time series at a range of scales allowing instantaneously deeper insights into the correlation patterns compared to traditional methods like empirical orthogonal functions or classical correlation analysis. This allows us to identify and visualise regions of – at a certain timescale – similarly evolving SSTs and distinguish them from those with long-range teleconnections to other ocean regions. Our findings re-confirm accepted knowledge about known highly linked SST patterns like ENSO and the Pacific Decadal Oscillation, but also suggest new insights into the characteristics and origins of long-range teleconnections like the connection between ENSO and Indian Ocean Dipole. Y1 - 2019 U6 - https://doi.org/10.1038/s41598-019-45423-5 SN - 2045-2322 VL - 9 PB - Macmillan Publishers Limited CY - London ER - TY - GEN A1 - Agarwal, Ankit A1 - Caesar, Levke A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Merz, Bruno T1 - Network-based identification and characterization of teleconnections on different scales T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - Sea surface temperature (SST) patterns can – as surface climate forcing – affect weather and climate at large distances. One example is El Niño-Southern Oscillation (ENSO) that causes climate anomalies around the globe via teleconnections. Although several studies identified and characterized these teleconnections, our understanding of climate processes remains incomplete, since interactions and feedbacks are typically exhibited at unique or multiple temporal and spatial scales. This study characterizes the interactions between the cells of a global SST data set at different temporal and spatial scales using climate networks. These networks are constructed using wavelet multi-scale correlation that investigate the correlation between the SST time series at a range of scales allowing instantaneously deeper insights into the correlation patterns compared to traditional methods like empirical orthogonal functions or classical correlation analysis. This allows us to identify and visualise regions of – at a certain timescale – similarly evolving SSTs and distinguish them from those with long-range teleconnections to other ocean regions. Our findings re-confirm accepted knowledge about known highly linked SST patterns like ENSO and the Pacific Decadal Oscillation, but also suggest new insights into the characteristics and origins of long-range teleconnections like the connection between ENSO and Indian Ocean Dipole. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 731 Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-430520 SN - 1866-8372 IS - 731 ER - TY - JOUR A1 - Agarwal, Ankit A1 - Guntu, Ravikumar A1 - Banerjee, Abhirup A1 - Gadhawe, Mayuri Ashokrao A1 - Marwan, Norbert T1 - A complex network approach to study the extreme precipitation patterns in a river basin JF - Chaos : an interdisciplinary journal of nonlinear science N2 - The quantification of spatial propagation of extreme precipitation events is vital in water resources planning and disaster mitigation. However, quantifying these extreme events has always been challenging as many traditional methods are insufficient to capture the nonlinear interrelationships between extreme event time series. Therefore, it is crucial to develop suitable methods for analyzing the dynamics of extreme events over a river basin with a diverse climate and complicated topography. Over the last decade, complex network analysis emerged as a powerful tool to study the intricate spatiotemporal relationship between many variables in a compact way. In this study, we employ two nonlinear concepts of event synchronization and edit distance to investigate the extreme precipitation pattern in the Ganga river basin. We use the network degree to understand the spatial synchronization pattern of extreme rainfall and identify essential sites in the river basin with respect to potential prediction skills. The study also attempts to quantify the influence of precipitation seasonality and topography on extreme events. The findings of the study reveal that (1) the network degree is decreased in the southwest to northwest direction, (2) the timing of 50th percentile precipitation within a year influences the spatial distribution of degree, (3) the timing is inversely related to elevation, and (4) the lower elevation greatly influences connectivity of the sites. The study highlights that edit distance could be a promising alternative to analyze event-like data by incorporating event time and amplitude and constructing complex networks of climate extremes. Y1 - 2022 U6 - https://doi.org/10.1063/5.0072520 SN - 1054-1500 SN - 1089-7682 VL - 32 IS - 1 PB - American Institute of Physics CY - Woodbury, NY ER - TY - JOUR A1 - Agarwal, Ankit A1 - Maheswaran, Rathinasamy A1 - Kurths, Jürgen A1 - Khosa, R. T1 - Wavelet Spectrum and Self-Organizing Maps-Based Approach for Hydrologic Regionalization -a Case Study in the Western United States JF - Water Resources Management N2 - Hydrologic regionalization deals with the investigation of homogeneity in watersheds and provides a classification of watersheds for regional analysis. The classification thus obtained can be used as a basis for mapping data from gauged to ungauged sites and can improve extreme event prediction. This paper proposes a wavelet power spectrum (WPS) coupled with the self-organizing map method for clustering hydrologic catchments. The application of this technique is implemented for gauged catchments. As a test case study, monthly streamflow records observed at 117 selected catchments throughout the western United States from 1951 through 2002. Further, based on WPS of each station, catchments are classified into homogeneous clusters, which provides a representative WPS pattern for the streamflow stations in each cluster. KW - Wavelet power spectrum KW - Regionalization KW - Ungauged catchments KW - K-means technique KW - Self-organizing map Y1 - 2016 U6 - https://doi.org/10.1007/s11269-016-1428-1 SN - 0920-4741 SN - 1573-1650 VL - 30 SP - 4399 EP - 4413 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Agarwal, Ankit A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Merz, Bruno A1 - Kurths, Jürgen T1 - Multi-scale event synchronization analysis for unravelling climate processes: a wavelet-based approach JF - Nonlinear processes in geophysics N2 - The temporal dynamics of climate processes are spread across different timescales and, as such, the study of these processes at only one selected timescale might not reveal the complete mechanisms and interactions within and between the (sub-) processes. To capture the non-linear interactions between climatic events, the method of event synchronization has found increasing attention recently. The main drawback with the present estimation of event synchronization is its restriction to analysing the time series at one reference timescale only. The study of event synchronization at multiple scales would be of great interest to comprehend the dynamics of the investigated climate processes. In this paper, the wavelet-based multi-scale event synchronization (MSES) method is proposed by combining the wavelet transform and event synchronization. Wavelets are used extensively to comprehend multi-scale processes and the dynamics of processes across various timescales. The proposed method allows the study of spatio-temporal patterns across different timescales. The method is tested on synthetic and real-world time series in order to check its replicability and applicability. The results indicate that MSES is able to capture relationships that exist between processes at different timescales. Y1 - 2017 U6 - https://doi.org/10.5194/npg-24-599-2017 SN - 1023-5809 VL - 24 SP - 599 EP - 611 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Agarwal, Ankit A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Merz, Bruno A1 - Kurths, Jürgen T1 - Quantifying the roles of single stations within homogeneous regions using complex network analysis JF - Journal of hydrology N2 - Regionalization and pooling stations to form homogeneous regions or communities are essential for reliable parameter transfer, prediction in ungauged basins, and estimation of missing information. Over the years, several clustering methods have been proposed for regional analysis. Most of these methods are able to quantify the study region in terms of homogeneity but fail to provide microscopic information about the interaction between communities, as well as about each station within the communities. We propose a complex network-based approach to extract this valuable information and demonstrate the potential of our approach using a rainfall network constructed from the Indian gridded daily precipitation data. The communities were identified using the network-theoretical community detection algorithm for maximizing the modularity. Further, the grid points (nodes) were classified into universal roles according to their pattern of within- and between-community connections. The method thus yields zoomed-in details of individual rainfall grids within each community. KW - Complex network KW - Event synchronization KW - Rainfall network KW - Z-P approach Y1 - 2018 U6 - https://doi.org/10.1016/j.jhydrol.2018.06.050 SN - 0022-1694 SN - 1879-2707 VL - 563 SP - 802 EP - 810 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Agarwal, Ankit A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Öztürk, Ugur A1 - Kurths, Jürgen A1 - Merz, Bruno T1 - Optimal design of hydrometric station networks based on complex network analysis JF - Hydrology and Earth System Sciences N2 - Hydrometric networks play a vital role in providing information for decision-making in water resource management. They should be set up optimally to provide as much information as possible that is as accurate as possible and, at the same time, be cost-effective. Although the design of hydrometric networks is a well-identified problem in hydrometeorology and has received considerable attention, there is still scope for further advancement. In this study, we use complex network analysis, defined as a collection of nodes interconnected by links, to propose a new measure that identifies critical nodes of station networks. The approach can support the design and redesign of hydrometric station networks. The science of complex networks is a relatively young field and has gained significant momentum over the last few years in different areas such as brain networks, social networks, technological networks, or climate networks. The identification of influential nodes in complex networks is an important field of research. We propose a new node-ranking measure – the weighted degree–betweenness (WDB) measure – to evaluate the importance of nodes in a network. It is compared to previously proposed measures used on synthetic sample networks and then applied to a real-world rain gauge network comprising 1229 stations across Germany to demonstrate its applicability. The proposed measure is evaluated using the decline rate of the network efficiency and the kriging error. The results suggest that WDB effectively quantifies the importance of rain gauges, although the benefits of the method need to be investigated in more detail. KW - identifying influential nodes KW - climate networks KW - rainfall KW - streamflow KW - synchronization KW - precipitation KW - classification KW - events Y1 - 2020 U6 - https://doi.org/10.5194/hess-24-2235-2020 SN - 1027-5606 SN - 1607-7938 VL - 24 IS - 5 SP - 2235 EP - 2251 PB - Copernicus Publ. CY - Göttingen ER - TY - GEN A1 - Agarwal, Ankit A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Öztürk, Ugur A1 - Kurths, Jürgen A1 - Merz, Bruno T1 - Optimal design of hydrometric station networks based on complex network analysis T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Hydrometric networks play a vital role in providing information for decision-making in water resource management. They should be set up optimally to provide as much information as possible that is as accurate as possible and, at the same time, be cost-effective. Although the design of hydrometric networks is a well-identified problem in hydrometeorology and has received considerable attention, there is still scope for further advancement. In this study, we use complex network analysis, defined as a collection of nodes interconnected by links, to propose a new measure that identifies critical nodes of station networks. The approach can support the design and redesign of hydrometric station networks. The science of complex networks is a relatively young field and has gained significant momentum over the last few years in different areas such as brain networks, social networks, technological networks, or climate networks. The identification of influential nodes in complex networks is an important field of research. We propose a new node-ranking measure – the weighted degree–betweenness (WDB) measure – to evaluate the importance of nodes in a network. It is compared to previously proposed measures used on synthetic sample networks and then applied to a real-world rain gauge network comprising 1229 stations across Germany to demonstrate its applicability. The proposed measure is evaluated using the decline rate of the network efficiency and the kriging error. The results suggest that WDB effectively quantifies the importance of rain gauges, although the benefits of the method need to be investigated in more detail. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 951 KW - identifying influential nodes KW - climate networks KW - rainfall KW - streamflow KW - synchronization KW - precipitation KW - classification KW - events Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-471006 SN - 1866-8372 IS - 951 ER - TY - THES A1 - Aich, Valentin T1 - Floods in the Niger River Basin in the face of global change T1 - Hochwasser im Niger Einzugsgebiet im Kontext des Globalen Wandels BT - analysis, attribution and projections BT - Analyse, Zuschreibung und Projektionen N2 - In the last decade, the number and dimensions of catastrophic flooding events in the Niger River Basin (NRB) have markedly increased. Despite the devastating impact of the floods on the population and the mainly agriculturally based economy of the riverine nations, awareness of the hazards in policy and science is still low. The urgency of this topic and the existing research deficits are the motivation for the present dissertation. The thesis is an initial detailed assessment of the increasing flood risk in the NRB. The research strategy is based on four questions regarding (1) features of the change in flood risk, (2) reasons for the change in the flood regime, (3) expected changes of the flood regime given climate and land use changes, and (4) recommendations from previous analysis for reducing the flood risk in the NRB. The question examining the features of change in the flood regime is answered by means of statistical analysis. Trend, correlation, changepoint, and variance analyses show that, in addition to the factors exposure and vulnerability, the hazard itself has also increased significantly in the NRB, in accordance with the decadal climate pattern of West Africa. The northern arid and semi-arid parts of the NRB are those most affected by the changes. As potential reasons for the increase in flood magnitudes, climate and land use changes are attributed by means of a hypothesis-testing framework. Two different approaches, based on either data analysis or simulation, lead to similar results, showing that the influence of climatic changes is generally larger compared to that of land use changes. Only in the dry areas of the NRB is the influence of land use changes comparable to that of climatic alterations. Future changes of the flood regime are evaluated using modelling results. First ensembles of statistically and dynamically downscaled climate models based on different emission scenarios are analyzed. The models agree with a distinct increase in temperature. The precipitation signal, however, is not coherent. The climate scenarios are used to drive an eco-hydrological model. The influence of climatic changes on the flood regime is uncertain due to the unclear precipitation signal. Still, in general, higher flood peaks are expected. In a next step, effects of land use changes are integrated into the model. Different scenarios show that regreening might help to reduce flood peaks. In contrast, an expansion of agriculture might enhance the flood peaks in the NRB. Similarly to the analysis of observed changes in the flood regime, the impacts of climate- and land use changes for the future scenarios are also most severe in the dry areas of the NRB. In order to answer the final research question, the results of the above analysis are integrated into a range of recommendations for science and policy on how to reduce flood risk in the NRB. The main recommendations include a stronger consideration of the enormous natural climate variability in the NRB and a focus on so called “no-regret” adaptation strategies which account for high uncertainty, as well as a stronger consideration of regional differences. Regarding the prevention and mitigation of catastrophic flooding, the most vulnerable and sensitive areas in the basin, the arid and semi-arid Sahelian and Sudano-Sahelian regions, should be prioritized. Eventually, an active, science-based and science-guided flood policy is recommended. The enormous population growth in the NRB in connection with the expected deterioration of environmental and climatic conditions is likely to enhance the region´s vulnerability to flooding. A smart and sustainable flood policy can help mitigate these negative impacts of flooding on the development of riverine societies in West Africa. N2 - Während des vergangenen Jahrzehnts nahmen die Anzahl und die Ausmaße von katastrophalen Hochwassern im Einzugsgebiet des Nigerflussess (NEZG) deutlich zu. Trotz der verheerenden Auswirkungen der Hochwasserkatastrophen auf die Menschen und die hauptsächlich auf Landwirtschaft basierende Wirtschaft der Anrainerstaaten wird das Thema von Politik und Wissenschaft noch kaum beachtet. Die vorliegende Dissertation ist die erste ausführliche Analyse des steigenden Hochwasserrisikos im NEZG. Die Forschungsstrategie basiert auf vier Fragen nach (1) der Art der Veränderungen des Hochwasserrisikos, (2) den Ursachen der Veränderungen im Hochwasserregime, (3) den zukünftigen Entwicklungen im Hochwasserregime hinsichtlich der erwartenden Klima- und Landnutzungswandel und (4) den aus den Untersuchungen abgeleiteten Empfehlungen zur Reduzierung des Hochwasserrisikos im NEZG. Die Frage nach den Merkmalen der Veränderungen im Hochwasserrisiko wurde mithilfe von statistischen Untersuchungen beantwortet. Die Analysen zeigen, dass neben den Risikofaktoren Exponiertheit und Verwundbarkeit auch die Hochwasserstände selbst im NEZG in den letzten Jahrzehnten signifikant und entsprechend der typischen dekadischen Klimamuster Westafrikas angestiegen sind. Als potentielle Ursachen des Hochwasseranstiegs werden Klima- und Landnutzungswandel untersucht. Zwei verschiedene Ansätze, basierend auf Daten sowie auf Simulationen, führen zu ähnlichen Ergebnissen und zeigen, dass der Einfluss der Klimaveränderungen im Allgemeinen größer als der des Landnutzungswandels ist. Das zukünftige Hochwasserrisiko wird anhand des öko-hydrologisches Modells SWIM abgeschätzt. Der Einfluss des Klimawandels auf das Hochwasserregime ist auf Grund des problematischen Niederschlagssignals unsicher. Tendenziell werden aber höhere Maximalabflüsse erwartet. Der Effekt der Landnutzungsänderung beeinflusst das Hochwasserverhalten ebenfalls stark, besonders in den trockenen Gebieten. Verschiedene Szenarien zeigen, dass Renaturierung hülfe, Hochwasserspitzen zu kappen. Eine Ausweitung der Agrarflächen dagegen würde die Hochwässer im NEZG weiter verstärken Zentrale Empfehlungen sind eine stärkere Einbeziehung der enorm starken natürlichen Klimavariabilität im NEZG und eine Fokussierung auf sogenannte „no-regret“ Anpassungsstrategien. Dabei sollte den verwundbarsten Regionen des Einzugsgebiets, den ariden und semi-ariden Regionen, Priorität eingeräumt werden. Die enorme Bevölkerungszunahme im NEZG verbunden mit der zu erwartenden Verschlechterung der Umwelt- und Klimabedingungen wird mit hoher Wahrscheinlichkeit auch die Verwundbarkeit bezüglich Hochwässer weiter ansteigen lassen. Eine vernünftige und nachhaltige Hochwasserpolitik kann helfen, die negativen Folgen auf die Entwicklung der Anrainerstaaten des Nigerflusses abzumindern. KW - flood KW - Niger KW - climate change KW - land use change KW - Hochwasser KW - Niger KW - Klimawandel KW - Landnutzungswandel Y1 - 2015 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-91577 ER - TY - JOUR A1 - Aich, Valentin A1 - Liersch, Stefan A1 - Vetter, T. A1 - Huang, S. A1 - Tecklenburg, J. A1 - Hoffmann, P. A1 - Koch, H. A1 - Fournet, S. A1 - Krysanova, Valentina A1 - Mueller, N. A1 - Hattermann, Fred T1 - Comparing impacts of climate change on streamflow in four large African river basins JF - Hydrology and earth system sciences : HESS N2 - This study aims to compare impacts of climate change on streamflow in four large representative African river basins: the Niger, the Upper Blue Nile, the Oubangui and the Limpopo. We set up the eco-hydrological model SWIM (Soil and Water Integrated Model) for all four basins individually. The validation of the models for four basins shows results from adequate to very good, depending on the quality and availability of input and calibration data. For the climate impact assessment, we drive the model with outputs of five bias corrected Earth system models of Coupled Model Intercomparison Project Phase 5 (CMIP5) for the representative concentration pathways (RCPs) 2.6 and 8.5. This climate input is put into the context of climate trends of the whole African continent and compared to a CMIP5 ensemble of 19 models in order to test their representativeness. Subsequently, we compare the trends in mean discharges, seasonality and hydrological extremes in the 21st century. The uncertainty of results for all basins is high. Still, climate change impact is clearly visible for mean discharges but also for extremes in high and low flows. The uncertainty of the projections is the lowest in the Upper Blue Nile, where an increase in streamflow is most likely. In the Niger and the Limpopo basins, the magnitude of trends in both directions is high and has a wide range of uncertainty. In the Oubangui, impacts are the least significant. Our results confirm partly the findings of previous continental impact analyses for Africa. However, contradictory to these studies we find a tendency for increased streamflows in three of the four basins (not for the Oubangui). Guided by these results, we argue for attention to the possible risks of increasing high flows in the face of the dominant water scarcity in Africa. In conclusion, the study shows that impact intercomparisons have added value to the adaptation discussion and may be used for setting up adaptation plans in the context of a holistic approach. Y1 - 2014 U6 - https://doi.org/10.5194/hess-18-1305-2014 SN - 1027-5606 SN - 1607-7938 VL - 18 IS - 4 SP - 1305 EP - 1321 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Aich, Valentin A1 - Liersch, Stefan A1 - Vetter, Tobias A1 - Andersson, Jafet C. M. A1 - Müller, Eva Nora A1 - Hattermann, Fred T1 - Climate or Land Use? BT - Attribution of Changes in River Flooding in the Sahel Zone JF - Water N2 - This study intends to contribute to the ongoing discussion on whether land use and land cover changes (LULC) or climate trends have the major influence on the observed increase of flood magnitudes in the Sahel. A simulation-based approach is used for attributing the observed trends to the postulated drivers. For this purpose, the ecohydrological model SWIM (Soil and Water Integrated Model) with a new, dynamic LULC module was set up for the Sahelian part of the Niger River until Niamey, including the main tributaries Sirba and Goroul. The model was driven with observed, reanalyzed climate and LULC data for the years 1950-2009. In order to quantify the shares of influence, one simulation was carried out with constant land cover as of 1950, and one including LULC. As quantitative measure, the gradients of the simulated trends were compared to the observed trend. The modeling studies showed that for the Sirba River only the simulation which included LULC was able to reproduce the observed trend. The simulation without LULC showed a positive trend for flood magnitudes, but underestimated the trend significantly. For the Goroul River and the local flood of the Niger River at Niamey, the simulations were only partly able to reproduce the observed trend. In conclusion, the new LULC module enabled some first quantitative insights into the relative influence of LULC and climatic changes. For the Sirba catchment, the results imply that LULC and climatic changes contribute in roughly equal shares to the observed increase in flooding. For the other parts of the subcatchment, the results are less clear but show, that climatic changes and LULC are drivers for the flood increase; however their shares cannot be quantified. Based on these modeling results, we argue for a two-pillar adaptation strategy to reduce current and future flood risk: Flood mitigation for reducing LULC-induced flood increase, and flood adaptation for a general reduction of flood vulnerability. Y1 - 2015 U6 - https://doi.org/10.3390/w7062796 SN - 2073-4441 VL - 7 IS - 6 SP - 2796 EP - 2820 PB - MDPI CY - Basel ER - TY - GEN A1 - Aich, Valentin A1 - Liersch, Stefan A1 - Vetter, Tobias A1 - Andersson, Jafet C. M. A1 - Müller, Eva Nora A1 - Hattermann, Fred T1 - Climate or land use? BT - Attribution of changes in river flooding in the Sahel Zone N2 - This study intends to contribute to the ongoing discussion on whether land use and land cover changes (LULC) or climate trends have the major influence on the observed increase of flood magnitudes in the Sahel. A simulation-based approach is used for attributing the observed trends to the postulated drivers. For this purpose, the ecohydrological model SWIM (Soil and Water Integrated Model) with a new, dynamic LULC module was set up for the Sahelian part of the Niger River until Niamey, including the main tributaries Sirba and Goroul. The model was driven with observed, reanalyzed climate and LULC data for the years 1950–2009. In order to quantify the shares of influence, one simulation was carried out with constant land cover as of 1950, and one including LULC. As quantitative measure, the gradients of the simulated trends were compared to the observed trend. The modeling studies showed that for the Sirba River only the simulation which included LULC was able to reproduce the observed trend. The simulation without LULC showed a positive trend for flood magnitudes, but underestimated the trend significantly. For the Goroul River and the local flood of the Niger River at Niamey, the simulations were only partly able to reproduce the observed trend. In conclusion, the new LULC module enabled some first quantitative insights into the relative influence of LULC and climatic changes. For the Sirba catchment, the results imply that LULC and climatic changes contribute in roughly equal shares to the observed increase in flooding. For the other parts of the subcatchment, the results are less clear but show, that climatic changes and LULC are drivers for the flood increase; however their shares cannot be quantified. Based on these modeling results, we argue for a two-pillar adaptation strategy to reduce current and future flood risk: Flood mitigation for reducing LULC-induced flood increase, and flood adaptation for a general reduction of flood vulnerability. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 345 KW - simulation-based attribution KW - Sahel KW - Niger River KW - climate variability KW - hydrological modeling KW - flood mitigation KW - flood adaptation Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-400115 ER - TY - JOUR A1 - Aich, Valentin A1 - Zimmermann, Alexander A1 - Elsenbeer, Helmut T1 - Quantification and interpretation of suspended-sediment discharge hysteresis patterns: How much data do we need? JF - Catena : an interdisciplinary journal of soil science, hydrology, geomorphology focusing on geoecology and landscape evolution N2 - Sediment-discharge hysteresis loops are frequently analyzed to facilitate the understanding of sediment transport processes. Hysteresis patterns, however, are often complex and their interpretation can be complicated. Particularly, quantifying hysteresis patterns remains a problematic issue. Moreover, it is currently unknown how much data is required for analyzing sediment-discharge hysteresis loops in a given area. These open questions and challenges motivated us to develop a new method for quantifying suspended-sediment hysteresis. Subsequently, we applied the new hysteresis index to three suspended-sediment and discharge datasets from a small tropical rainforest catchment. The datasets comprised a different number of events and sampling sites. Our analyses show three main findings: (1) datasets restricted to only few events, which is typical for rapid assessment surveys, were always sufficient to identify the dominating hysteresis pattern in our research area. Furthermore, some of these small datasets contained multiple-peak events that allowed identifying intra-event exhaustion effects and hence, limitations in sediment supply. (2) Datasets comprising complete hydrological years were particularly useful for analyzing seasonal dynamics of hysteresis. These analyses revealed an exhaustion of hysteresis on the inter-event scale which also points to a limited sediment supply. (3) Datasets comprising measurements from two consecutive gauges installed at the catchment outlet and on a slope within that catchment allowed analyzing the change of hysteresis patterns along the flowpath. On the slope, multiple-peak events showed a stronger intra-event exhaustion of hysteresis than at the catchment outlet. Furthermore, exhaustion of hysteresis on the inter-event scale was not evident on the slope but occurred at the catchment outlet. Our results indicate that even small sediment datasets can provide valuable insights into sediment transport processes of small catchments. Furthermore, our results may serve as a first guideline on what to expect from an analysis of hysteresis patterns for datasets of varying quality and quantity. (c) 2014 Elsevier B.V. All rights reserved. KW - Suspended sediment KW - Hysteresis index KW - Sediment monitoring KW - Overland flow KW - Tropical forest Y1 - 2014 U6 - https://doi.org/10.1016/j.catena.2014.06.020 SN - 0341-8162 SN - 1872-6887 VL - 122 SP - 120 EP - 129 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Aichner, Bernhard T1 - Aquatic macrophyte-derived biomarkers as palaeolimnological proxies on the Tibetan Plateau T1 - Biomarker von Wasserpflanzen als Klimaindikatoren auf dem tibetischen Hochplateau N2 - The Tibetan Plateau is the largest elevated landmass in the world and profoundly influences atmospheric circulation patterns such as the Asian monsoon system. Therefore this area has been increasingly in focus of palaeoenvironmental studies. This thesis evaluates the applicability of organic biomarkers for palaeolimnological purposes on the Tibetan Plateau with a focus on aquatic macrophyte-derived biomarkers. Submerged aquatic macrophytes have to be considered to significantly influence the sediment organic matter due to their high abundance in many Tibetan lakes. They can show highly 13C-enriched biomass because of their carbon metabolism and it is therefore crucial for the interpretation of δ13C values in sediment cores to understand to which extent aquatic macrophytes contribute to the isotopic signal of the sediments in Tibetan lakes and in which way variations can be explained in a palaeolimnological context. Additionally, the high abundance of macrophytes makes them interesting as potential recorders of lake water δD. Hydrogen isotope analysis of biomarkers is a rapidly evolving field to reconstruct past hydrological conditions and therefore of special relevance on the Tibetan Plateau due to the direct linkage between variations of monsoon intensity and changes in regional precipitation / evaporation balances. A set of surface sediment and aquatic macrophyte samples from the central and eastern Tibetan Plateau was analysed for composition as well as carbon and hydrogen isotopes of n-alkanes. It was shown how variable δ13C values of bulk organic matter and leaf lipids can be in submerged macrophytes even of a single species and how strongly these parameters are affected by them in corresponding sediments. The estimated contribution of the macrophytes by means of a binary isotopic model was calculated to be up to 60% (mean: 40%) to total organic carbon and up to 100% (mean: 66%) to mid-chain n-alkanes. Hydrogen isotopes of n-alkanes turned out to record δD of meteoric water of the summer precipitation. The apparent enrichment factor between water and n-alkanes was in range of previously reported ones (≈-130‰) at the most humid sites, but smaller (average: -86‰) at sites with a negative moisture budget. This indicates an influence of evaporation and evapotranspiration on δD of source water for aquatic and terrestrial plants. The offset between δD of mid- and long-chain n-alkanes was close to zero in most of the samples, suggesting that lake water as well as soil and leaf water are affected to a similar extent by those effects. To apply biomarkers in a palaeolimnological context, the aliphatic biomarker fraction of a sediment core from Lake Koucha (34.0° N; 97.2° E; eastern Tibetan Plateau) was analysed for concentrations, δ13C and δD values of compounds. Before ca. 8 cal ka BP, the lake was dominated by aquatic macrophyte-derived mid-chain n-alkanes, while after 6 cal ka BP high concentrations of a C20 highly branched isoprenoid compound indicate a predominance of phytoplankton. Those two principally different states of the lake were linked by a transition period with high abundances of microbial biomarkers. δ13C values were relatively constant for long-chain n-alkanes, while mid-chain n-alkanes showed variations between -23.5 to -12.6‰. Highest values were observed for the assumed period of maximum macrophyte growth during the late glacial and for the phytoplankton maximum during the middle and late Holocene. Therefore, the enriched values were interpreted to be caused by carbon limitation which in turn was induced by high macrophyte and primary productivity, respectively. Hydrogen isotope signatures of mid-chain n-alkanes have been shown to be able to track a previously deduced episode of reduced moisture availability between ca. 10 and 7 cal ka BP, indicated by a 20‰ shift towards higher δD values. Indications for cooler episodes at 6.0, 3.1 and 1.8 cal ka BP were gained from drops of biomarker concentrations, especially microbial-derived hopanoids, and from coincidental shifts towards lower δ13C values. Those episodes correspond well with cool events reported from other locations on the Tibetan Plateau as well as in the Northern Hemisphere. To conclude, the study of recent sediments and plants improved the understanding of factors affecting the composition and isotopic signatures of aliphatic biomarkers in sediments. Concentrations and isotopic signatures of the biomarkers in Lake Koucha could be interpreted in a palaeolimnological context and contribute to the knowledge about the history of the lake. Aquatic macrophyte-derived mid-chain n-alkanes were especially useful, due to their high abundance in many Tibetan Lakes and their ability to record major changes of lake productivity and palaeo-hydrological conditions. Therefore, they have the potential to contribute to a fuller understanding of past climate variability in this key region for atmospheric circulation systems. N2 - Das tibetische Hochplateau ist die größte gehobene Landmasse der Erde und beeinflusst maßgeblich atmosphärische Zirkulationsmuster wie den Asiatischen Monsun. Um die Auswirkungen zukünftiger Schwankungen der Monsundynamik auf das regionale Klima besser einschätzen zu können, ist es wichtig, ein fundiertes Verständnis vergangener Klimaänderungen zu entwickeln. Daher ist das Tibetplateau in den letzten Jahren mehr und mehr in den Fokus paläoklimatischer Studien gerückt. Die große Anzahl an Seen in der Region bietet ein unerschöpfliches Klimaarchiv und viele Studien haben sich bereits mit Seesedimenten zur Klimarekonstruktion befasst. Dabei wurde in erster Linie auf biologische, sedimentologische und geochemische Parameter zurückgegriffen, wohingegen organische Biomarker bisher recht selten benutzt wurden. Die vorliegende Arbeit untersucht die Anwendbarkeit dieser potentiellen Klimaindikatoren auf dem Tibetplateau. Hierbei wurde ein Schwerpunkt auf die Analyse kutikularer Blattwachse von Wasserpflanzen gelegt, da diese wegen ihres starken Auftretens in tibetischen Seen einen erheblichen Beitrag zur organischen Substanz im Sediment leisten. Um den Einfluss von Wasserpflanzen auf das Sediment über einen weiten klimatischen Gradienten zu untersuchen, wurden Oberflächensedimente und Wasserpflanzen vom zentralen und östlichen Tibetplateau auf ihre Biomarkerzusammensetzung sowie auf ihre Kohlen- und Wasserstoffisotopensignatur untersucht. Dadurch wurde das Verständnis über beeinflussende Faktoren auf diese Parameter in Sedimenten vertieft. In einem Sedimentbohrkern des Koucha-Sees (östliches Tibetplateau) konnten diese Parameter dann im Hinblick auf Änderungen der Produktivität im See sowie der hydrologischen und klimatischen Bedingungen der letzten 15000 Jahre interpretiert werden. Es zeigte sich, dass der See bis 8000 Jahre vor Heute stark mit Wasserpflanzen bewachsen war, während die letzten 6000 Jahre Algen dominierten. Mit Hilfe von Wasserstoffisotopen wurden eine Zunahme des Monsuns und steigende Niederschläge zwischen 15000 und 10000 Jahren vor Heute sowie eine relativ trockene Periode zwischen 10000 und 7000 Jahren vor Heute rekonstruiert. Durch Kombination von Biomarkerkonzentrationen sowie deren Kohlenstoffisotopensignal wurden außerdem kurzzeitige Kälteperioden um ca. 6000, 3100 und 1800 Jahren vor Heute nachgewiesen, die vorher bereits in anderen Klimaarchiven in Tibet sowie auf der nördlichen Hemisphäre belegt wurden. Mit Hilfe von organischen Biomarkern konnte so ein detailliertes Bild über die Entwicklung des Koucha-Sees seit dem letzten Glazial gewonnen werden. Organische Biomarker haben sich somit als geeignet erwiesen, einen Beitrag zur Klimarekonstruktion auf dem Tibetplateau zu leisten. KW - Biomarker KW - Isotope KW - Tibet KW - Paläolimnologie KW - Klima KW - Wasserpflanzen KW - biomarker KW - isotopes KW - Tibetan Plateau KW - palaeolimnology KW - climate KW - macrophytes Y1 - 2009 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-42095 ER - TY - JOUR A1 - Aichner, Bernhard A1 - Bussian, Bernd M. A1 - Lehnik-Habrink, Petra A1 - Hein, Sebastian T1 - Regionalized concentrations and fingerprints of polycyclic aromatic hydrocarbons (PAHs) in German forest soils JF - Environmental pollution N2 - Samples of 474 forest stands in Germany were analysed for concentrations of polycyclic aromatic hydrocarbons (PAHs) in three sampling depths. Enhanced concentrations were mainly found at spots relatively close to densely industrialized and urbanized regions and at some topographically elevated areas. Average enrichment factors between mineral soil and humic layer depend on humus type i.e. decrease from mull via moder to more Based on their compound-patterns, the observed samples could be assigned to three main clusters. For some parts of our study area a uniform assignment of samples to clusters over larger regions could be identified. For instance, samples taken at vicinity to brown-coal strip-mining districts are characterized by high relative abundances of low-molecular-weight PAHs. These results suggest that PAHs are more likely originated from local and regional emitters rather than from long-range transport and that specific source-regions can be identified based on PAH fingerprints. (C) 2015 Elsevier Ltd. All rights reserved. KW - Organic pollutants KW - PAHs KW - Soil KW - Emissions KW - Long-range transport KW - Enrichment factor KW - Humic layer KW - Mineral soil KW - O horizon Y1 - 2015 U6 - https://doi.org/10.1016/j.envpol.2015.03.026 SN - 0269-7491 SN - 1873-6424 VL - 203 SP - 31 EP - 39 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Aichner, Bernhard A1 - Feakins, Sarah J. A1 - Lee, J. E. A1 - Herzschuh, Ulrike A1 - Liu, X. T1 - High-resolution leaf wax carbon and hydrogen isotopic record of the late Holocene paleoclimate in arid Central Asia JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - Central Asia is located at the confluence of large-scale atmospheric circulation systems. It is thus likely to be highly susceptible to changes in the dynamics of those systems; however, little is still known about the regional paleoclimate history. Here we present carbon and hydrogen isotopic compositions of n-alkanoic acids from a late Holocene sediment core from Lake Karakuli (eastern Pamir, Xinjiang Province, China). Instrumental evidence and isotopeenabled climate model experiments with the Laboratoire de Meteorologie Dynamique Zoom model version 4 (LMDZ4) demonstrate that delta D values of precipitation in the region are influenced by both temperature and precipitation amount. We find that these parameters are inversely correlated on an annual scale, i.e., the climate has varied between relatively cool and wet and more warm and dry over the last 50 years. Since the isotopic signals of these changes are in the same direction and therefore additive, isotopes in precipitation are sensitive recorders of climatic changes in the region. Additionally, we infer that plants use year-round precipitation (including snowmelt), and thus leaf wax delta D values must also respond to shifts in the proportion of moisture derived from westerly storms during late winter and early spring. Downcore results give evidence for a gradual shift to cooler and wetter climates between 3.5 and 2.5 cal kyr BP, interrupted by a warm and dry episode between 3.0 and 2.7 kyr BP. Further cool and wet episodes occur between 1.9 and 1.5 and between 0.6 and 0.1 kyr BP, the latter coeval with the Little Ice Age. Warm and dry episodes from 2.5 to 1.9 and 1.5 to 0.6 kyr BP coincide with the Roman Warm Period and Medieval Climate Anomaly, respectively. Finally, we find a drying tend in recent decades. Regional comparisons lead us to infer that the strength and position of the westerlies, and wider northern hemispheric climate dynamics, control climatic shifts in arid Central Asia, leading to complex local responses. Our new archive from Lake Karakuli provides a detailed record of the local signatures of these climate transitions in the eastern Pamir. Y1 - 2015 U6 - https://doi.org/10.5194/cp-11-619-2015 SN - 1814-9324 SN - 1814-9332 VL - 11 IS - 4 SP - 619 EP - 633 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Aichner, Bernhard A1 - Herzschuh, Ulrike A1 - Wilkes, Heinz A1 - Schulz, Hans-Martin A1 - Wang, Yongbo A1 - Plessen, Birgit A1 - Mischke, Steffen A1 - Diekmann, Bernhard A1 - Zhang, Chengjun T1 - Ecological development of Lake Donggi Cona, north-eastern Tibetan Plateau, since the late glacial on basis of organic geochemical proxies and non-pollen palynomorphs JF - Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences N2 - Organic geochemical proxy data from surface sediment samples and a sediment core from Lake Donggi Cona were used to infer environmental changes on the northeastern Tibetan Plateau spanning the last 18.4 kyr. Long-chain n-alkanes dominate the aliphatic hydrocarbon fraction of the sediment extract from most surface sediment samples and the sediment core. Unsaturated mid-chain n-alkanes (nC(23:1) and nC(25:1)) have high abundances in some samples, especially in core samples from the late glacial and early Holocene. TOC contents, organic biomarker and non-pollen-palynomorph concentrations and results from organic petrologic analysis on selected samples suggest three major episodes in the history of Lake Donggi Cona. Before ca. 12.6 cal ka BP samples contain low amounts of organic matter due to cold and arid conditions during the late glacial. After 12.6 cal ka BP, relatively high contents of TOC and concentrations of Botryococcus fossils, as well as enhanced concentrations of mid-chain n-alkanes and n-alkenes suggest a higher primary and macrophyte productivity than at present This is supported by high contents of palynomorphs derived from higher plants and algae and was possibly triggered by a decrease of salinity and amelioration of climate during the early Holocene. Since 6.8 cal ka BP Lake Donggi Cona has been an oligotrophic freshwater lake. Proxy data suggest that variations in insolation drive ecological changes in the lake, with increased aquatic productivity during the early Holocene summer insolation maximum. Short-term drops of TOC contents or biomarker concentrations (at 9.9 cal ka BP, after 8.0 and between 3.5 and 1.7 cal ka BP) can possibly be related to relatively cool and dry episodes reported from other sites on the north-eastern Tibetan Plateau, which are hypothesized to occur in phase with Northern Hemisphere cooling events. KW - Biomarker KW - Holocene KW - n-alkanes KW - Total organic carbon KW - Organic matter KW - Macerals KW - Aquatic macrophytes Y1 - 2012 U6 - https://doi.org/10.1016/j.palaeo.2011.10.015 SN - 0031-0182 VL - 313 IS - 2 SP - 140 EP - 149 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Aichner, Bernhard A1 - Hilt, Sabine A1 - Perillon, Cecile A1 - Gillefalk, Mikael A1 - Sachse, Dirk T1 - Biosynthetic hydrogen isotopic fractionation factors during lipid synthesis in submerged aquatic macrophytes: Effect of groundwater discharge and salinity JF - Organic geochemistry : the international journal for rapid publication of current research in organic geochemistry and biochemistry N2 - Sedimentary lipid biomarkers have become widely used tools for reconstructing past climatic and ecological changes due to their ubiquitous occurrence in lake sediments. In particular, the hydrogen isotopic composition (expressed as delta D values) of leaf wax lipids derived from terrestrial plants has been a focus of research during the last two decades and the understanding of competing environmental and plant physiological factors influencing the delta D values has greatly improved. Comparatively less attention has been paid to lipid biomarkers derived from aquatic plants, although these compounds are abundant in many lacustrine sediments. We therefore conducted a field and laboratory experiment to study the effect of salinity and groundwater discharge on the isotopic composition of aquatic plant biomarkers. We analyzed samples of the common submerged plant species, Potamogeton pectinatus (sago pondweed), which has a wide geographic distribution and can tolerate high salinity. We tested the effect of groundwater discharge (characterized by more negative delta D values relative to lake water) and salinity on the delta D values of n-alkanes from P. pectinatus by comparing plants (i) collected from the oligotrophic freshwater Lake Stechlin (Germany) at shallow littoral depth from locations with and without groundwater discharge, and (ii) plants grown from tubers collected from the eutrophic Lake Muggelsee in nutrient solution at four salinity levels. Isotopically depleted groundwater did not have a significant influence on the delta D values of n-alkanes in Lake Stechlin P. pectinatus and calculated isotopic fractionation factors epsilon(l/w) between lake water and n-alkanes averaged -137 +/- 9%(n-C-23), -136 +/- 7%(n-C-25) and -131 +/- 6%(n-C-27), respectively. Similar epsilon values were calculated for plants from Lake Muggelsee grown in freshwater nutrient solution (-134 +/- 11% for n-C-23), while greater fractionation was observed at increased salinity values of 10 (163 +/- 12%) and 15(-172 +/- 15%). We therefore suggest an average e value of -136 +/- 9% between source water and the major n-alkanes in P. pectinatus grown under freshwater conditions. Our results demonstrate that isotopic fractionation can increase by 30-40% at salinity values 10 and 15. These results could be explained either by inhibited plant growth at higher salinity, or by metabolic adaptation to salt stress that remain to be elucidated. A potential salinity effect on dD values of aquatic lipids requires further examination, since this would impact on the interpretation of downcore isotopic data in paleohydrologic studies. (C) 2017 Elsevier Ltd. All rights reserved. Y1 - 2017 U6 - https://doi.org/10.1016/j.orggeochem.2017.07.021 SN - 0146-6380 VL - 113 SP - 10 EP - 16 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Aichner, Bernhard A1 - Makhmudov, Zafar A1 - Rajabov, Iljomjon A1 - Zhang, Qiong A1 - Pausata, Francesco Salvatore R. A1 - Werner, Martin A1 - Heinecke, Liv A1 - Kuessner, Marie L. A1 - Feakins, Sarah J. A1 - Sachse, Dirk A1 - Mischke, Steffen T1 - Hydroclimate in the Pamirs Was Driven by Changes in Precipitation-Evaporation Seasonality Since theLast Glacial Period JF - Geophysical research letters N2 - The Central Asian Pamir Mountains (Pamirs) are a high-altitude region sensitive to climatic change, with only few paleoclimatic records available. To examine the glacial-interglacial hydrological changes in the region, we analyzed the geochemical parameters of a 31-kyr record from Lake Karakul and performed a set of experiments with climate models to interpret the results. delta D values of terrestrial biomarkers showed insolation-driven trends reflecting major shifts of water vapor sources. For aquatic biomarkers, positive delta D shifts driven by changes in precipitation seasonality were observed at ca. 31-30, 28-26, and 17-14 kyr BP. Multiproxy paleoecological data and modelling results suggest that increased water availability, induced by decreased summer evaporation, triggered higher lake levels during those episodes, possibly synchronous to northern hemispheric rapid climate events. We conclude that seasonal changes in precipitation-evaporation balance significantly influenced the hydrological state of a large waterbody such as Lake Karakul, while annual precipitation amount and inflows remained fairly constant. KW - climate KW - biomarker KW - geochemistry KW - modelling KW - paleoclimate KW - hydrology Y1 - 2019 U6 - https://doi.org/10.1029/2019GL085202 SN - 0094-8276 SN - 1944-8007 VL - 46 IS - 23 SP - 13972 EP - 13983 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Aiken, John M. A1 - Aiken, Chastity A1 - Cotton, Fabrice T1 - A python library for teaching computation to seismology students JF - Seismological research letters N2 - Python is at the forefront of scientific computation for seismologists and therefore should be introduced to students interested in becoming seismologists. On its own, Python is open source and well designed with extensive libraries. However, Python code can also be executed, visualized, and communicated to others with "Jupyter Notebooks". Thus, Jupyter Notebooks are ideal for teaching students Python and scientific computation. In this article, we designed an openly available Python library and collection of Jupyter Notebooks based on defined scientific computation learning goals for seismology students. The Notebooks cover topics from an introduction to Python to organizing data, earthquake catalog statistics, linear regression, and making maps. Our Python library and collection of Jupyter Notebooks are meant to be used as course materials for an upper-division data analysis course in an Earth Science Department, and the materials were tested in a Probabilistic Seismic Hazard course. However, seismologists or anyone else who is interested in Python for data analysis and map making can use these materials. Y1 - 2018 U6 - https://doi.org/10.1785/0220170246 SN - 0895-0695 SN - 1938-2057 VL - 89 IS - 3 SP - 1165 EP - 1171 PB - Seismological Society of America CY - Albany ER - TY - JOUR A1 - Akal, Cuneyt A1 - Koralay, O. Ersin A1 - Candan, Osman A1 - Oberhänsli, Roland A1 - Chen, Fukun T1 - Geodynamic significance of the early triassic karaburun granitoid (Western Turkey) for the opening history of Neo-Tethys JF - Turkish journal of earth sciences = Türk yerbilimleri dergisi N2 - The Karaburun Peninsula, which is considered part of the Anatolide-Tauride Block of Turkey, contains clastic and carbonate sequences deposited on the northern margin of Gondwana. The Palaeozoic clastic sequence, which is intruded by the Early Triassic granitoid and tectonically overlies a Mesozoic melange sequence, can be divided into three subunits: a lower clastic subunit consisting of a sandstone-shale alternation, an upper clastic subunit consisting of black chert-bearing shales, sandstone and conglomerate, and a Permo-Carboniferous carbonate subunit. The lower Triassic Karaburun I-type granitoid has a high initial Sr-87/Sr-86 ratio (0.709021-0.709168), and low Nd-143/Nd-144 ratio (0.512004-0.512023) and epsilon Nd (-5.34 to -5.70) isotopic values. Geochronological data indicate a crystallization (intrusion) age of 247.1 +/- 2.0 Ma (Scythian). Geochemically, the acidic magmatism reflects a subduction-related continental-arc basin tectonic setting, which can be linked to the opening of the northern branch of Neo-Tethys as a continental back-arc rifting basin on the northern margin of Gondwana. This can be related to the closure through southward subduction of the Palaeotethys Ocean beneath Gondwana. KW - Karaburun KW - Neo-Tethys KW - Palaeo-Tethys KW - diorite KW - Triassic KW - magmatism Y1 - 2011 U6 - https://doi.org/10.3906/yer-1008-1 SN - 1300-0985 VL - 20 IS - 3 SP - 255 EP - 271 PB - Tübitak CY - Ankara ER - TY - JOUR A1 - Akal, Cüneyt A1 - Candan, Osman A1 - Koralay, O. Ersin A1 - Oberhänsli, Roland A1 - Chen, Fukun A1 - Prelevic, Dejan T1 - Early Triassic potassic volcanism in the Afyon Zone of the Anatolides/Turkey - implications for the rifting of the Neo-Tethys JF - International journal of earth sciences N2 - Afyon Zone, which was derived from the Anatolide-Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic basement and unconformably overlying Triassic-Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated from the underlying Silurian-Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (similar to 250 Ma) ages, which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys. KW - Meta-trachyandesite KW - Afyon Zone KW - Turkey KW - Neo-Tethys KW - Paleo-tethys Y1 - 2012 U6 - https://doi.org/10.1007/s00531-011-0654-2 SN - 1437-3254 VL - 101 IS - 1 SP - 177 EP - 194 PB - Springer CY - New York ER - TY - JOUR A1 - Al Atik, Linda A1 - Abrahamson, Norman A. A1 - Bommer, Julian J. A1 - Scherbaum, Frank A1 - Cotton, Fabrice A1 - Kuehn, Nicolas T1 - The variability of ground-motion prediction models and its components Y1 - 2010 UR - http://srl.geoscienceworld.org/ U6 - https://doi.org/10.1785/gssrl.81.5.794 SN - 0895-0695 ER - TY - THES A1 - Al-Halbouni, Djamil T1 - Photogrammetry and distinct element geomechanical modelling of sinkholes and large-scale karstic depressions T1 - Photogrammetrie und geomechanische Diskrete-Elemente-Modellierung von Erdfällen und großskaligen Karstsenken N2 - Sinkholes and depressions are typical landforms of karst regions. They pose a considerable natural hazard to infrastructure, agriculture, economy and human life in affected areas worldwide. The physio-chemical processes of sinkholes and depression formation are manifold, ranging from dissolution and material erosion in the subsurface to mechanical subsidence/failure of the overburden. This thesis addresses the mechanisms leading to the development of sinkholes and depressions by using complementary methods: remote sensing, distinct element modelling and near-surface geophysics. In the first part, detailed information about the (hydro)-geological background, ground structures, morphologies and spatio-temporal development of sinkholes and depressions at a very active karst area at the Dead Sea are derived from satellite image analysis, photogrammetry and geologic field surveys. There, clusters of an increasing number of sinkholes have been developing since the 1980s within large-scale depressions and are distributed over different kinds of surface materials: clayey mud, sandy-gravel alluvium and lacustrine evaporites (salt). The morphology of sinkholes differs depending in which material they form: Sinkholes in sandy-gravel alluvium and salt are generally deeper and narrower than sinkholes in the interbedded evaporite and mud deposits. From repeated aerial surveys, collapse precursory features like small-scale subsidence, individual holes and cracks are identified in all materials. The analysis sheds light on the ongoing hazardous subsidence process, which is driven by the base-level fall of the Dead Sea and by the dynamic formation of subsurface water channels. In the second part of this thesis, a novel, 2D distinct element geomechanical modelling approach with the software PFC2D-V5 to simulating individual and multiple cavity growth and sinkhole and large-scale depression development is presented. The approach involves a stepwise material removal technique in void spaces of arbitrarily shaped geometries and is benchmarked by analytical and boundary element method solutions for circular cavities. Simulated compression and tension tests are used to calibrate model parameters with bulk rock properties for the materials of the field site. The simulations show that cavity and sinkhole evolution is controlled by material strength of both overburden and cavity host material, the depth and relative speed of the cavity growth and the developed stress pattern in the subsurface. Major findings are: (1) A progressively deepening differential subrosion with variable growth speed yields a more fragmented stress pattern with stress interaction between the cavities. It favours multiple sinkhole collapses and nesting within large-scale depressions. (2) Low-strength materials do not support large cavities in the material removal zone, and subsidence is mainly characterised by gradual sagging into the material removal zone with synclinal bending. (3) High-strength materials support large cavity formation, leading to sinkhole formation by sudden collapse of the overburden. (4) Large-scale depression formation happens either by coalescence of collapsing holes, block-wise brittle failure, or gradual sagging and lateral widening. The distinct element based approach is compared to results from remote sensing and geophysics at the field site. The numerical simulation outcomes are generally in good agreement with derived morphometrics, documented surface and subsurface structures as well as seismic velocities. Complementary findings on the subrosion process are provided from electric and seismic measurements in the area. Based on the novel combination of methods in this thesis, a generic model of karst landform evolution with focus on sinkhole and depression formation is developed. A deepening subrosion system related to preferential flow paths evolves and creates void spaces and subsurface conduits. This subsequently leads to hazardous subsidence, and the formation of sinkholes within large-scale depressions. Finally, a monitoring system for shallow natural hazard phenomena consisting of geodetic and geophysical observations is proposed for similarly affected areas. N2 - Dolinen und Senken sind typische Landformen von Karstgebieten. Sie stellen in den betroffenen Gebieten weltweit ein erhebliches Naturrisiko für Infrastruktur, Landwirtschaft, Wirtschaft und das menschliche Leben dar. Die physikalisch-chemischen Prozesse der Entstehung solcher Senkungen sind vielfältig und reichen von Auflösung und Materialerosion im Untergrund bis zu mechanischem Absenken/Bruchs des Oberbodens. Diese Arbeit betrachtet die Mechanismen, die zur Entwicklung von Dolinen und Senken führen, anhand von verschiedenen geowissenschaftlichen Methoden:Fernerkundung, Gesteinsmechanischer Modellierung und pberflächennaher Geophysik. Im ersten Teil werden detaillierte Informationen über den geologischen Hintergrund, Bodenstrukturen, Formen und die räumlich-zeitliche Entwicklung von Senkungen an einem sehr aktiven Karstgebiet am Toten Meer zusammengetragen. Dort bilden sich seit den 1980er Jahren immer größere Ansammlungen von Erdfällen, wie diese Phänomene auch oft genannt werden. Die Form der Erdfälle unterscheidet sich je nach Material, in dem sie entstehen: Erdfälle in Sand-Kies Böden und Salz sind im Allgemeinen tiefer und schmaler als Dolinen in den Schlammablagerungen des Toten Meeres. Wiederholte Aufnahmen aus der Luft mit Hilfe von Drohnen oder Ballons helfen dabei, kleine Absenkungen, einzelne Löcher und Risse zu identifizieren. Die Ursache dieser gefährlichen Absenkungen am Toten Meer ist in dem stetigen Fall des Seespiegels und der Bildung von starken Unterwasserkanälen zu sehen, die fortlaufend Material aus dem Boden herausspülen, sog. Subrosion. Im zweiten Teil dieser Dissertation wird ein neuer, geomechanischer Modellierungsansatz zur Simulation des Wachstums von Hohlräumen im Untergrund und der Bildung von Senkungsstrukturen vorgestellt. Die Simulationen zeigen, dass die Entwicklung der Hohlräume und Erdfälle durch die Materialstärke, die Tiefe und Geschwindigkeit des Hohlraumwachstums und durch das sich bildende Spannungsmuster im Untergrund gesteuert wird. Die wichtigsten Ergebnisse der Studie sind: (1) Eine fortlaufend sich vertiefende Subrosion mit variabler Wachstumsgeschwindigkeit führt zu einem stärker fragmentierten Spannungsmuster im Boden. Es begünstigt das Bilden von ineinander verschachtelten Erdfällen (Cluster) in großen Vertiefungen. (2) Materialien mit niedriger Festigkeit (wie z.B. Schlamm) können keine großen Hohlräume bilden, und das Absinken geschieht durch ein allmähliches Absacken. (3) Materialien mit hoher Festigkeit (wie z.B. verfestigte Sande/Kiese oder Steinsalz) unterstützen die Bildung großer Hohlräume, was zu einem plötzlichen Zusammenbruch des Oberbodens führen kann. (4) Großskalige Senkungsstrukturen bilden sich entweder durch das Verschachteln von kleineren Dolinen, blockweise sprödem Versagen, oder das allmähliche Absinken mit seitlicher Erweiterung. Die Ergebnisse der numerischen Simulationen stimmen im Allgemeinen sehr gut sowohl mit den beobachteten Senkungsformen an der Oberfläche überein, als auch mit Untergrundstrukturen beobachtet durch seismische und elektrische Methoden. Basierend auf der neuartigen Methodenkombination dieser Arbeit wird ein generisches Modell der Entwicklung von Senkungsstrukturen in Karstgebieten vorgestellt. Eine sich vertiefende Subrosion entlang von unterirdischen Kanälen erzeugt Hohlräume und führt in der Folge zu diesen gefährlichen Absenkungen und zur Bildung von Erdfällen innerhalb großer Vertiefungen. KW - Photogrammetry KW - Sinkholes KW - Karst KW - Discrete Element Method KW - Geomechanical Modelling KW - Applied Geophysics KW - Natural Hazards KW - Photogrammetrie KW - Erdfälle KW - Karst KW - Diskrete-Elemente-Methode KW - Geomechanische Modellierung KW - Angewandte Geophysik KW - Naturgefahren Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432159 ER - TY - GEN A1 - Al-Halbouni, Djamil A1 - Holohan, Eoghan P. A1 - Taheri, Abbas A1 - Schöpfer, Martin P. J. A1 - Emam, Sacha A1 - Dahm, Torsten T1 - Geomechanical modelling of sinkhole development using distinct elements BT - model verification for a single void space and application to the Dead Sea area T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Mechanical and/or chemical removal of material from the subsurface may generate large subsurface cavities, the destabilisation of which can lead to ground collapse and the formation of sinkholes. Numerical simulation of the interaction of cavity growth, host material deformation and overburden collapse is desirable to better understand the sinkhole hazard but is a challenging task due to the involved high strains and material discontinuities. Here, we present 2-D distinct element method numerical simulations of cavity growth and sinkhole development. Firstly, we simulate cavity formation by quasi-static, stepwise removal of material in a single growing zone of an arbitrary geometry and depth. We benchmark this approach against analytical and boundary element method models of a deep void space in a linear elastic material. Secondly, we explore the effects of properties of different uniform materials on cavity stability and sinkhole development. We perform simulated biaxial tests to calibrate macroscopic geotechnical parameters of three model materials representative of those in which sinkholes develop at the Dead Sea shoreline: mud, alluvium and salt. We show that weak materials do not support large cavities, leading to gradual sagging or suffusion-style subsidence. Strong materials support quasi-stable to stable cavities, the overburdens of which may fail suddenly in a caprock or bedrock collapse style. Thirdly, we examine the consequences of layered arrangements of weak and strong materials. We find that these are more susceptible to sinkhole collapse than uniform materials not only due to a lower integrated strength of the overburden but also due to an inhibition of stabilising stress arching. Finally, we compare our model sinkhole geometries to observations at the Ghor Al-Haditha sinkhole site in Jordan. Sinkhole depth ∕ diameter ratios of 0.15 in mud, 0.37 in alluvium and 0.33 in salt are reproduced successfully in the calibrated model materials. The model results suggest that the observed distribution of sinkhole depth ∕ diameter values in each material type may partly reflect sinkhole growth trends. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1061 KW - rock mass KW - karst KW - dissolution KW - reflection KW - subsidence KW - subrosion KW - collapse KW - simulation KW - scale KW - fault Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-468435 SN - 1866-8372 IS - 1061 ER - TY - JOUR A1 - Al-Halbouni, Djamil A1 - Holohan, Eoghan P. A1 - Taheri, Abbas A1 - Schöpfer, Martin P. J. A1 - Emam, Sacha A1 - Dahm, Torsten T1 - Geomechanical modelling of sinkhole development using distinct elements BT - model verification for a single void space and application to the Dead Sea area JF - Solid earth N2 - Mechanical and/or chemical removal of material from the subsurface may generate large subsurface cavities, the destabilisation of which can lead to ground collapse and the formation of sinkholes. Numerical simulation of the interaction of cavity growth, host material deformation and overburden collapse is desirable to better understand the sinkhole hazard but is a challenging task due to the involved high strains and material discontinuities. Here, we present 2-D distinct element method numerical simulations of cavity growth and sinkhole development. Firstly, we simulate cavity formation by quasi-static, stepwise removal of material in a single growing zone of an arbitrary geometry and depth. We benchmark this approach against analytical and boundary element method models of a deep void space in a linear elastic material. Secondly, we explore the effects of properties of different uniform materials on cavity stability and sinkhole development. We perform simulated biaxial tests to calibrate macroscopic geotechnical parameters of three model materials representative of those in which sinkholes develop at the Dead Sea shoreline: mud, alluvium and salt. We show that weak materials do not support large cavities, leading to gradual sagging or suffusion-style subsidence. Strong materials support quasi-stable to stable cavities, the overburdens of which may fail suddenly in a caprock or bedrock collapse style. Thirdly, we examine the consequences of layered arrangements of weak and strong materials. We find that these are more susceptible to sinkhole collapse than uniform materials not only due to a lower integrated strength of the overburden but also due to an inhibition of stabilising stress arching. Finally, we compare our model sinkhole geometries to observations at the Ghor Al-Haditha sinkhole site in Jordan. Sinkhole depth / diameter ratios of 0.15 in mud, 0.37 in alluvium and 0.33 in salt are reproduced successfully in the calibrated model materials. The model results suggest that the observed distribution of sinkhole depth / diameter values in each material type may partly reflect sinkhole growth trends. Y1 - 2018 U6 - https://doi.org/10.5194/se-9-1341-2018 SN - 1869-9510 SN - 1869-9529 VL - 9 IS - 6 SP - 1341 EP - 1373 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Al-Halbouni, Djamil A1 - Holohan, Eoghan P. A1 - Taheri, Abbas A1 - Watson, Robert A. A1 - Polom, Ulrich A1 - Schoepfer, Martin P. J. A1 - Emam, Sacha A1 - Dahm, Torsten T1 - Distinct element geomechanical modelling of the formation of sinkhole clusters within large-scale karstic depressions JF - Solid earth N2 - The 2-D distinct element method (DEM) code (PFC2D_V5) is used here to simulate the evolution of subsidence-related karst landforms, such as single and clustered sinkholes, and associated larger-scale depressions. Subsurface material in the DEM model is removed progressively to produce an array of cavities; this simulates a network of subsurface groundwater conduits growing by chemical/mechanical erosion. The growth of the cavity array is coupled mechanically to the gravitationally loaded surroundings, such that cavities can grow also in part by material failure at their margins, which in the limit can produce individual collapse sinkholes. Two end-member growth scenarios of the cavity array and their impact on surface subsidence were examined in the models: (1) cavity growth at the same depth level and growth rate; (2) cavity growth at progressively deepening levels with varying growth rates. These growth scenarios are characterised by differing stress patterns across the cavity array and its overburden, which are in turn an important factor for the formation of sinkholes and uvalalike depressions. For growth scenario (1), a stable compression arch is established around the entire cavity array, hindering sinkhole collapse into individual cavities and favouring block-wise, relatively even subsidence across the whole cavity array. In contrast, for growth scenario (2), the stress system is more heterogeneous, such that local stress concentrations exist around individual cavities, leading to stress interactions and local wall/overburden fractures. Consequently, sinkhole collapses occur in individual cavities, which results in uneven, differential subsidence within a larger-scale depression. Depending on material properties of the cavity-hosting material and the overburden, the larger-scale depression forms either by sinkhole coalescence or by widespread subsidence linked geometrically to the entire cavity array. The results from models with growth scenario (2) are in close agreement with surface morphological and subsurface geophysical observations from an evaporite karst area on the eastern shore of the Dead Sea. Y1 - 2019 U6 - https://doi.org/10.5194/se-10-1219-2019 SN - 1869-9510 SN - 1869-9529 VL - 10 IS - 4 SP - 1219 EP - 1241 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Al-Mashaikhi, K. A1 - Oswald, Sascha A1 - Attinger, Sabine A1 - Büchel, G. A1 - Knöller, K. A1 - Strauch, G. T1 - Evaluation of groundwater dynamics and quality in the Najd aquifers located in the Sultanate of Oman JF - Environmental earth sciences N2 - The Najd, Oman, is located in one of the most arid environments in the world. The groundwater in this region is occurring in four different aquifers A to D of the Hadhramaut Group consisting mainly of different types of limestone and dolomite. The quality of the groundwater is dominated by the major ions sodium, calcium, magnesium, sulphate, and chloride, but the hydrochemical character is varying among the four aquifers. Mineralization within the separate aquifers increases along the groundwater flow direction from south to north-northeast up to high saline sodium-chloride water in aquifer D in the northeast area of the Najd. Environmental isotope analyses of hydrogen and oxygen were conducted to monitor the groundwater dynamics and to evaluate the recharge conditions of groundwater into the Najd aquifers. Results suggest an earlier recharge into these aquifers as well as ongoing recharge takes place in the region down to present day. Mixing of modern and submodern waters was detected by water isotopes in aquifer D in the mountain chain (Jabal) area and along the northern side of the mountain range. In addition, delta H-2 and delta O-18 variations suggest that aquifers A, B, and C are assumed to be connected by faults and fractures, and interaction between the aquifers may occur. Low tritium concentrations support the mixing assumption in the recharge area. The knowledge about the groundwater development is an important factor for the sustainable use of water resources in the Dhofar region. KW - Environmental isotopes KW - Groundwater KW - Najd aquifer KW - Oman KW - Recharge KW - Water quality Y1 - 2012 U6 - https://doi.org/10.1007/s12665-011-1331-2 SN - 1866-6280 VL - 66 IS - 4 SP - 1195 EP - 1211 PB - Springer CY - New York ER - TY - JOUR A1 - Alawi, Mashal A1 - Schneider, Beate A1 - Kallmeyer, Jens T1 - A procedure for separate recovery of extra- and intracellular DNA from a single marine sediment sample JF - Journal of microbiological methods N2 - Extracellular DNA (eDNA) is a ubiquitous biological compound in aquatic sediment and soil. Previous studies suggested that eDNA plays an important role in biogeochemical element cycling, horizontal gene transfer and stabilization of biofilm structures. Previous methods for eDNA extraction were either not suitable for oligotrophic sediments or only allowed quantification but no genetic analyses. Our procedure is based on cell detachment and eDNA liberation from sediment particles by sequential washing with an alkaline sodium phosphate buffer followed by a separation of cells and eDNA. The separated eDNA is then bound onto silica particles and purified, whereas the intracellular DNA from the separated cells is extracted using a commercial kit. The method provides extra- and intracellular DNA of high purity that is suitable for downstream applications like PCR. Extracellular DNA was extracted from organic-rich shallow sediment of the Baltic Sea, glacially influenced sediment of the Barents Sea and from the oligotrophic South Pacific Gyre. The eDNA concentration in these samples varied from 23 to 626 ng g(-1) wet weight sediment. A number of experiments were performed to verify each processing step. Although extraction efficiency is higher than other published methods, it is not fully quantitative. (C) 2014 Elsevier B.V. All rights reserved. KW - Extracellular DNA KW - eDNA KW - Intracellular DNA KW - South Pacific Gyre KW - Ancient DNA KW - Fossil DNA Y1 - 2014 U6 - https://doi.org/10.1016/j.mimet.2014.06.009 SN - 0167-7012 SN - 1872-8359 VL - 104 SP - 36 EP - 42 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Albrecht, Tanja A1 - Martin, M. A1 - Haseloff, M. A1 - Winkelmann, Ricarda A1 - Levermann, Anders T1 - Parameterization for subgrid-scale motion of ice-shelf calving fronts JF - The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union N2 - A parameterization for the motion of ice-shelf fronts on a Cartesian grid in finite-difference land-ice models is presented. The scheme prevents artificial thinning of the ice shelf at its edge, which occurs due to the finite resolution of the model. The intuitive numerical implementation diminishes numerical dispersion at the ice front and enables the application of physical boundary conditions to improve the calculation of stress and velocity fields throughout the ice-sheet-shelf system. Numerical properties of this subgrid modification are assessed in the Potsdam Parallel Ice Sheet Model (PISM-PIK) for different geometries in one and two horizontal dimensions and are verified against an analytical solution in a flow-line setup. Y1 - 2011 U6 - https://doi.org/10.5194/tc-5-35-2011 SN - 1994-0416 VL - 5 IS - 1 SP - 35 EP - 44 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Albrecht, Torsten A1 - Winkelmann, Ricarda A1 - Levermann, Anders T1 - Glacial-cycle simulations of the Antarctic Ice Sheet with the Parallel Ice Sheet Model (PISM) BT - Part 1: boundary conditions and climatic forcing JF - The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union N2 - Simulations of the glacial-interglacial history of the Antarctic Ice Sheet provide insights into dynamic threshold behavior and estimates of the ice sheet's contributions to global sea-level changes for the past, present and future. However, boundary conditions are weakly constrained, in particular at the interface of the ice sheet and the bedrock. Also climatic forcing covering the last glacial cycles is uncertain, as it is based on sparse proxy data.
We use the Parallel Ice Sheet Model (PISM) to investigate the dynamic effects of different choices of input data, e.g., for modern basal heat flux or reconstructions of past changes of sea level and surface temperature. As computational resources are limited, glacial-cycle simulations are performed using a comparably coarse model grid of 16 km and various parameterizations, e.g., for basal sliding, iceberg calving, or for past variations in precipitation and ocean temperatures. In this study we evaluate the model's transient sensitivity to corresponding parameter choices and to different boundary conditions over the last two glacial cycles and provide estimates of involved uncertainties. We also discuss isolated and combined effects of climate and sea-level forcing. Hence, this study serves as a "cookbook" for the growing community of PISM users and paleo-ice sheet modelers in general.
For each of the different model uncertainties with regard to climatic forcing, ice and Earth dynamics, and basal processes, we select one representative model parameter that captures relevant uncertainties and motivates corresponding parameter ranges that bound the observed ice volume at present. The four selected parameters are systematically varied in a parameter ensemble analysis, which is described in a companion paper. Y1 - 2020 U6 - https://doi.org/10.5194/tc-14-599-2020 SN - 1994-0416 SN - 1994-0424 VL - 14 IS - 2 SP - 599 EP - 632 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Albrich, Sergi A1 - Frijia, Gianluca A1 - Parente, Mariano A1 - Caus, Esmeralda T1 - The evolution of the earliest representatives of the genus Orbitoides: Implications for Upper Cretaceous biostratigraphy JF - Cretaceous research N2 - The biostratigraphy of Campanian-Maastrichtian carbonate platforms is largely based on the larger foraminiferal genus Orbitoides. However, while the taxonomy and the chronostratigraphic age of the younger species of this genus are well established, there are still many controversies on the earliest species. We have restudied their morphological characters using a large collection of samples from the type-localities and from continuous sections in the southern Pyrenees. Based on these new observations, the long forgotten species O. sanctae-pelagiae is reinstated, while O. dordoniensis is considered a junior synonym. Successive populations of O. hottingeri, O. sanctae-pelagiae and O. douvillei show gradual morphological changes in time marked by an increase in the size and complexity of the macrospheric embryonal apparatus, an increase of the size of the adult specimens of both generations and the progressive appearance and development of true lateral chamberlets. The Font de les Bagasses Unit in the southern Pyrenees preserves a high-resolution archive of the evolution of the earliest Orbitoides. Strontium isotope stratigraphy indicates that the oldest species, O. hottingeri, made its first appearance in the earliest Campanian, close to the Santonian-Campanian boundary, and was replaced by O. sanctae-pelagiae at a level closely corresponding to the boundary between the Placenticeras bidorsatum and Menabites delawarensis ammonite zones. (C) 2014 Elsevier Ltd. All rights reserved. KW - Larger foraminifera KW - Biostratigraphy KW - Strontium isotope stratigraphy KW - Late cretaceous KW - Orbitoides Y1 - 2014 U6 - https://doi.org/10.1016/j.cretres.2014.04.013 SN - 0195-6671 SN - 1095-998X VL - 51 SP - 22 EP - 34 PB - Elsevier CY - London ER - TY - JOUR A1 - Ali, Saleem H. A1 - Giurco, Damien A1 - Arndt, Nicholas A1 - Nickless, Edmund A1 - Brown, Graham A1 - Demetriades, Alecos A1 - Durrheim, Ray A1 - Enriquez, Maria Amelia A1 - Kinnaird, Judith A1 - Littleboy, Anna A1 - Meinert, Lawrence D. A1 - Oberhänsli, Roland A1 - Salem, Janet A1 - Schodde, Richard A1 - Schneider, Gabi A1 - Vidal, Olivier A1 - Yakovleva, Natalia T1 - Mineral supply for sustainable development requires resource governance JF - Nature : the international weekly journal of science N2 - Successful delivery of the United Nations sustainable development goals and implementation of the Paris Agreement requires technologies that utilize a wide range of minerals in vast quantities. Metal recycling and technological change will contribute to sustaining supply, but mining must continue and grow for the foreseeable future to ensure that such minerals remain available to industry. New links are needed between existing institutional frameworks to oversee responsible sourcing of minerals, trajectories for mineral exploration, environmental practices, and consumer awareness of the effects of consumption. Here we present, through analysis of a comprehensive set of data and demand forecasts, an interdisciplinary perspective on how best to ensure ecologically viable continuity of global mineral supply over the coming decades. Y1 - 2017 U6 - https://doi.org/10.1038/nature21359 SN - 0028-0836 SN - 1476-4687 VL - 543 SP - 367 EP - 372 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Alinaghi, Alireza A1 - Kruger, Frank T1 - Seismic array analysis and redetermination of depths of earthquakes in Tien-Shan: implications for strength of the crust and lithosphere JF - Geophysical journal international N2 - We have redetermined focal depths of moderate and major earthquakes with reported lower-crust and upper-mantle depths that have occurred in Tien-Shan, since the availability of broad-band array data. Records of earthquakes at global arrays have been used for identification and modelling of depth phases in order to make accurate estimation of focal depths. Our results show that half of the purportedly deep earthquakes are indeed originating from depths attributable to middle-crust and lower-crust regions. Also one exceptional event in the northern foreland of Tien-Shan in Junggar Basin is located in the upper mantle at the depth of 64 km. Such unusually deep earthquakes for intraplate continental tectonic domain are all located at the margin of Tien-Shan with its adjacent stable blocks and at least some of them have occurred where the brittle behaviour of continental rocks is not highly expected. The reverse mechanisms of all these earthquakes and their proximity to formerly subducting and later colliding and underplating stable blocks and their interactions with overlying Tien-Shan are clues to explain this extremity. KW - Earthquake source observations KW - Seismicity and tectonics KW - Body waves Y1 - 2014 U6 - https://doi.org/10.1093/gji/ggu141 SN - 0956-540X SN - 1365-246X VL - 198 IS - 2 SP - 1111 EP - 1129 PB - Oxford Univ. Press CY - Oxford ER - TY - THES A1 - Allroggen, Niklas T1 - Observation of subsurface flow from the surface : applications of ground-penetrating radar BT - non-invasive time-lapse observation of subsurface flow by using ground-penetrating radar Y1 - 2015 ER - TY - JOUR A1 - Allroggen, Niklas A1 - Beiter, Daniel A1 - Tronicke, Jens T1 - Ground-penetrating radar monitoring of fast subsurface processes JF - Geophysics N2 - Earth and environmental sciences rely on detailed information about subsurface processes. Whereas geophysical techniques typically provide highly resolved spatial images, monitoring subsurface processes is often associated with enormous effort and, therefore, is usually limited to point information in time or space. Thus, the development of spatial and temporal continuous field monitoring methods is a major challenge for the understanding of subsurface processes. We have developed a novel method for ground-penetrating-radar (GPR) reflection monitoring of subsurface flow processes under unsaturated conditions and applied it to a hydrological infiltration experiment performed across a periglacial slope deposit in northwest Luxembourg. Our approach relies on a spatial and temporal quasicontinuous data recording and processing, followed by an attribute analysis based on analyzing differences between individual time steps. The results demonstrate the ability of time-lapse GPR monitoring to visualize the spatial and temporal dynamics of preferential flow processes with a spatial resolution in the order of a few decimeters and temporal resolution in the order of a few minutes. We observe excellent agreement with water table information originating from different boreholes. This demonstrates the potential of surface-based GPR reflection monitoring to observe the spatiotemporal dynamics of water movements in the subsurface. It provides valuable, and so far not accessible, information for example in the field of hydrology and pedology that allows studying the actual subsurface processes rather than deducing them from point information. Y1 - 2020 U6 - https://doi.org/10.1190/GEO2019-0737.1 SN - 0016-8033 SN - 1942-2156 VL - 85 IS - 3 SP - A19 EP - A23 PB - Society of Exploration Geophysicists CY - Tulsa ER - TY - JOUR A1 - Allroggen, Niklas A1 - Heincke, Bjorn H. A1 - Koyan, Philipp A1 - Wheeler, Walter A1 - Ronning, Jan S. T1 - 3D ground-penetrating radar attribute classification BT - a case study from a paleokarst breccia pipe in the Billefjorden area on Spitsbergen, Svalbard JF - Geophysics N2 - Ground-penetrating radar (GPR) is a method that can provide detailed information about the near subsurface in sedimentary and carbonate environments. The classical interpretation of GPR data (e.g., based on manual feature selection) often is labor-intensive and limited by the experience of the intercally used for seismic interpretation, can provide faster, more repeatable, and less biased interpretations. We have recorded a 3D GPD data set collected across a paleokarst breccia pipe in the Billefjorden area on Spitsbergen, Svalbard. After performing advanced processing, we compare the results of a classical GPR interpretation to the results of an attribute-based classification. Our attribute classification incorporates a selection of dip and textural attributes as the input for a k-means clustering approach. Similar to the results of the classical interpretation, the resulting classes differentiate between undisturbed strata and breccias or fault zones. The classes also reveal details inside the breccia pipe that are not discerned in the classical fer that the intrapipe GPR facies result from subtle differences, such as breccia lithology, clast size, or pore-space filling. Y1 - 2022 U6 - https://doi.org/10.1190/GEO2021-0651.1 SN - 0016-8033 SN - 1942-2156 VL - 87 IS - 4 SP - WB19 EP - WB30 PB - Society of Exploration Geophysicists CY - Tulsa ER -