TY  - JOUR
A1  - Keckeis, Philipp
A1  - Zeller, Enriko
A1  - Jung, Carina
A1  - Besirske, Patricia
A1  - Kirner, Felizitas
A1  - Ruiz-Agudo, Cristina
A1  - Schlaad, Helmut
A1  - Cölfen, Helmut
T1  - Modular toolkit of multifunctional block copoly(2-oxazoline)s for the synthesis of nanoparticles
JF  - Chemistry - a European journal
N2  - Post-polymerization modification provides an elegant way to introduce chemical functionalities onto macromolecules to produce tailor-made materials with superior properties. This concept was adapted to well-defined block copolymers of the poly(2-oxazoline) family and demonstrated the large potential of these macromolecules as universal toolkit for numerous applications. Triblock copolymers with separated water-soluble, alkyne- and alkene-containing segments were synthesized and orthogonally modified with various low-molecular weight functional molecules by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) and thiol-ene (TE) click reactions, respectively. Representative toolkit polymers were used for the synthesis of gold, iron oxide and silica nanoparticles.
KW  - block copolymers
KW  - click chemistry
KW  - nanoparticles
KW  - ring-opening
KW  - polymerization
KW  - surfactants
Y1  - 2021
U6  - https://doi.org/10.1002/chem.202101327
SN  - 0947-6539
SN  - 1521-3765
VL  - 27
IS  - 32
SP  - 8283
EP  - 8287
PB  - Wiley-VCH
CY  - Weinheim
ER  -