TY  - GEN
A1  - Thiel, Kerstin
A1  - Zehbe, Rolf
A1  - Roeser, Jerômé
A1  - Strauch, Peter
A1  - Enthaler, Stephan
A1  - Thomas, Arne
T1  - A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks
N2  - A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 243 
KW  - covalent organic framework
KW  - n-heterocyclic carbenes
KW  - carbon-dioxide
KW  - intrinsic microporosity
KW  - heterogeneous catalysis
KW  - sulfoxides
KW  - reduction
KW  - complex
KW  - system
KW  - transformation
Y1  - 2013
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95118
SP  - 1848
EP  - 1856
ER  -