TY  - JOUR
A1  - Alrefai, Anas
A1  - Mondal, Suvendu Sekhar
A1  - Wruck, Alexander
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Brandt, Philipp
A1  - Janiak, Christoph
A1  - Schoenfeld, Sophie
A1  - Weber, Birgit
A1  - Rybakowski, Lawrence
A1  - Herrman, Carmen
A1  - Brennenstuhl, Katlen
A1  - Eidner, Sascha
A1  - Kumke, Michael Uwe
A1  - Behrens, Karsten
A1  - Günter, Christina
A1  - Müller, Holger
A1  - Holdt, Hans-Jürgen
T1  - Hydrogen-bonded supramolecular metal-imidazolate frameworks: gas sorption, magnetic and UV/Vis spectroscopic properties
JF  - Journal of Inclusion Phenomena and Macrocyclic Chemistry
N2  - By varying reaction parameters for the syntheses of the hydrogen-bonded metal-imidazolate frameworks (HIF) HIF-1 and HIF-2 (featuring 14 Zn and 14 Co atoms, respectively) to increase their yields and crystallinity, we found that HIF-1 is generated in two different frameworks, named as HIF-1a and HIF-1b. HIF-1b is isostructural to HIF-2. We determined the gas sorption and magnetic properties of HIF-2. In comparison to HIF-1a (Brunauer-Emmett-Teller (BET) surface area of 471m(2) g(-1)), HIF-2 possesses overall very low gas sorption uptake capacities [BET(CO2) surface area=85m(2) g(-1)]. Variable temperature magnetic susceptibility measurement of HIF-2 showed antiferromagnetic exchange interactions between the cobalt(II) high-spin centres at lower temperature. Theoretical analysis by density functional theory confirmed this finding. The UV/Vis-reflection spectra of HIF-1 (mixture of HIF-1a and b), HIF-2 and HIF-3 (with 14 Cd atoms) were measured and showed a characteristic absorption band centered at 340nm, which was indicative for differences in the imidazolate framework.
KW  - Gas-sorption
KW  - Ligand design
KW  - Magnetic properties
KW  - Supramolecular chemistry
KW  - Solvothermal synthesis
Y1  - 2019
U6  - https://doi.org/10.1007/s10847-019-00926-6
SN  - 1388-3127
SN  - 1573-1111
VL  - 94
IS  - 3-4
SP  - 155
EP  - 165
PB  - Springer
CY  - Dordrecht
ER  -