TY - JOUR A1 - Wetzel, Maria A1 - Kempka, Thomas A1 - Kühn, Michael T1 - Hydraulic and mechanical impacts of pore space alterations within a sandstone quantified by a flow velocity-dependent precipitation approach JF - Materials N2 - Geochemical processes change the microstructure of rocks and thereby affect their physical behaviour at the macro scale. A micro-computer tomography (micro-CT) scan of a typical reservoir sandstone is used to numerically examine the impact of three spatial alteration patterns on pore morphology, permeability and elastic moduli by correlating precipitation with the local flow velocity magnitude. The results demonstrate that the location of mineral growth strongly affects the permeability decrease with variations by up to four orders in magnitude. Precipitation in regions of high flow velocities is characterised by a predominant clogging of pore throats and a drastic permeability reduction, which can be roughly described by the power law relation with an exponent of 20. A continuous alteration of the pore structure by uniform mineral growth reduces the permeability comparable to the power law with an exponent of four or the Kozeny-Carman relation. Preferential precipitation in regions of low flow velocities predominantly affects smaller throats and pores with a minor impact on the flow regime, where the permeability decrease is considerably below that calculated by the power law with an exponent of two. Despite their complete distinctive impact on hydraulics, the spatial precipitation patterns only slightly affect the increase in elastic rock properties with differences by up to 6.3% between the investigated scenarios. Hence, an adequate characterisation of the spatial precipitation pattern is crucial to quantify changes in hydraulic rock properties, whereas the present study shows that its impact on elastic rock parameters is limited. The calculated relations between porosity and permeability, as well as elastic moduli can be applied for upscaling micro-scale findings to reservoir-scale models to improve their predictive capabilities, what is of paramount importance for a sustainable utilisation of the geological subsurface. KW - Bentheim sandstone KW - digital rock physics KW - micro-CT KW - elastic properties KW - permeability KW - precipitation Y1 - 2020 U6 - https://doi.org/10.3390/ma13143100 SN - 1996-1944 VL - 13 IS - 14 PB - MDPI CY - Basel ER - TY - JOUR A1 - Wetzel, Maria A1 - Kempka, Thomas A1 - Kühn, Michael T1 - Quantifying rock weakening due to decreasing calcite mineral content by numerical simulations JF - Materials N2 - The quantification of changes in geomechanical properties due to chemical reactions is of paramount importance for geological subsurface utilisation, since mineral dissolution generally reduces rock stiffness. In the present study, the effective elastic moduli of two digital rock samples, the Fontainebleau and Bentheim sandstones, are numerically determined based on micro-CT images. Reduction in rock stiffness due to the dissolution of 10% calcite cement by volume out of the pore network is quantified for three synthetic spatial calcite distributions (coating, partial filling and random) using representative sub-cubes derived from the digital rock samples. Due to the reduced calcite content, bulk and shear moduli decrease by 34% and 38% in maximum, respectively. Total porosity is clearly the dominant parameter, while spatial calcite distribution has a minor impact, except for a randomly chosen cement distribution within the pore network. Moreover, applying an initial stiffness reduced by 47% for the calcite cement results only in a slightly weaker mechanical behaviour. Using the quantitative approach introduced here substantially improves the accuracy of predictions in elastic rock properties compared to general analytical methods, and further enables quantification of uncertainties related to spatial variations in porosity and mineral distribution. KW - digital rock physics KW - micro-CT KW - elastic properties KW - numerical simulation KW - chemical-mechanical interaction KW - Code_Aster KW - composite properties Y1 - 2018 U6 - https://doi.org/10.3390/ma11040542 SN - 1996-1944 VL - 11 IS - 4 PB - MDPI CY - Basel ER - TY - THES A1 - Wetzel, Maria T1 - Pore space alterations and their impact on hydraulic and mechanical rock properties quantified by numerical simulations T1 - Numerische Simulationen zum Einfluss von Porenraumveränderungen auf die Entwicklung hydraulischer und mechanischer Gesteinseigenschaften N2 - Geochemical processes such as mineral dissolution and precipitation alter the microstructure of rocks, and thereby affect their hydraulic and mechanical behaviour. Quantifying these property changes and considering them in reservoir simulations is essential for a sustainable utilisation of the geological subsurface. Due to the lack of alternatives, analytical methods and empirical relations are currently applied to estimate evolving hydraulic and mechanical rock properties associated with chemical reactions. However, the predictive capabilities of analytical approaches remain limited, since they assume idealised microstructures, and thus are not able to reflect property evolution for dynamic processes. Hence, aim of the present thesis is to improve the prediction of permeability and stiffness changes resulting from pore space alterations of reservoir sandstones. A detailed representation of rock microstructure, including the morphology and connectivity of pores, is essential to accurately determine physical rock properties. For that purpose, three-dimensional pore-scale models of typical reservoir sandstones, obtained from highly resolved micro-computed tomography (micro-CT), are used to numerically calculate permeability and stiffness. In order to adequately depict characteristic distributions of secondary minerals, the virtual samples are systematically altered and resulting trends among the geometric, hydraulic, and mechanical rock properties are quantified. It is demonstrated that the geochemical reaction regime controls the location of mineral precipitation within the pore space, and thereby crucially affects the permeability evolution. This emphasises the requirement of determining distinctive porosity-permeability relationships by means of digital pore-scale models. By contrast, a substantial impact of spatial alterations patterns on the stiffness evolution of reservoir sandstones are only observed in case of certain microstructures, such as highly porous granular rocks or sandstones comprising framework-supporting cementations. In order to construct synthetic granular samples a process-based approach is proposed including grain deposition and diagenetic cementation. It is demonstrated that the generated samples reliably represent the microstructural complexity of natural sandstones. Thereby, general limitations of imaging techniques can be overcome and various realisations of granular rocks can be flexibly produced. These can be further altered by virtual experiments, offering a fast and cost-effective way to examine the impact of precipitation, dissolution or fracturing on various petrophysical correlations. The presented research work provides methodological principles to quantify trends in permeability and stiffness resulting from geochemical processes. The calculated physical property relations are directly linked to pore-scale alterations, and thus have a higher accuracy than commonly applied analytical approaches. This will considerably improve the predictive capabilities of reservoir models, and is further relevant to assess and reduce potential risks, such as productivity or injectivity losses as well as reservoir compaction or fault reactivation. Hence, the proposed method is of paramount importance for a wide range of natural and engineered subsurface applications, including geothermal energy systems, hydrocarbon reservoirs, CO2 and energy storage as well as hydrothermal deposit exploration. N2 - Geochemische Lösungs- und Fällungsprozesse verändern die Struktur des Porenraums und können dadurch die hydraulischen und mechanischen Gesteinseigenschaften erheblich beeinflussen. Die Quantifizierung dieser Parameteränderung und ihre Berücksichtigung in Reservoirmodellen ist entscheidend für eine nachhaltige Nutzung des geologischen Untergrunds. Aufgrund fehlender Alternativen werden dafür bisher analytische Methoden genutzt. Da diese Ansätze eine idealisierte Mikrostruktur annehmen, können insbesondere Änderungen der Gesteinseigenschaften infolge von dynamischen Prozessen nicht zuverlässig abgebildet werden. Ziel der vorliegenden Doktorarbeit ist es deshalb, die Entwicklung von Gesteinspermeabilitäten und -steifigkeiten aufgrund von Porenraumveränderungen genauer vorherzusagen. Für die möglichst exakte Bestimmung physikalischer Gesteinsparameter ist eine detaillierte Darstellung der Mikrostruktur notwendig. Basierend auf mikro-computertomographischen Scans werden daher hochaufgelöste, dreidimensionale Modelle typischer Reservoirsandsteine erstellt und Gesteinspermeabilität und -steifigkeit numerisch berechnet. Um charakteristische Verteilungen von Sekundärmineralen abzubilden, wird der Porenraum dieser virtuellen Sandsteinproben systematisch verändert und die resultierenden Auswirkungen auf die granulometrischen, hydraulischen und elastischen Gesteinseigenschaften bestimmt. Die Ergebnisse zeigen deutlich, dass charakteristische Fällungsmuster unterschiedlicher geochemischer Reaktionsregime die Permeabilität erheblich beeinflussen. Folglich ist die Nutzung von porenskaligen Modellen zur Bestimmung der Porosität-Permeabilitätsbeziehungen unbedingt notwendig. Im Gegensatz dazu ist die Verteilung von Sekundärmineralen für die Gesteinssteifigkeit nur bei bestimmten Mikrostrukturen von Bedeutung, hierzu zählen hochporöse Sandsteine oder solche mit Korngerüst-stützenden Zementierungen. In der Arbeit wird außerdem ein Ansatz zur Konstruktion granularer Gesteine vorgestellt, welcher sowohl die Kornsedimentation als auch die diagenetische Verfestigung umfasst. Es wird gezeigt, dass die synthetischen Proben die mikrostrukturelle Komplexität natürlicher Reservoirsandsteine gut abbilden. Dadurch können generelle Limitationen von bildgebenden Verfahren überwunden und unterschiedlichste virtuelle Repräsentationen von granularen Gesteinen generiert werden. Die synthetischen Proben können zukünftig in virtuellen Experimenten verwendet werden, um die Auswirkungen von Lösungs- und Fällungsreaktionen auf verschiedene petrophysikalische Korrelationen zu untersuchen. Die vorgestellte Arbeit liefert methodische Grundlagen zur Quantifizierung von Permeabilitäts- und Steifigkeitsänderungen infolge geochemischer Prozesse. Die berechneten petrophysikalischen Beziehungen basieren direkt auf mikrostrukturellen Veränderungen des Porenraums. Daher bieten sie eine genauere Vorhersage der Gesteinseigenschaften als herkömmliche analytische Methoden, wodurch sich die Aussagekraft von Reservoirmodellen erheblich verbessert. Somit können Risiken, wie Produktivitäts- oder Injektivitätsverluste sowie Reservoirkompaktion oder Störungsreaktivierung, verringert werden. Die präsentierten Ergebnisse sind daher relevant für verschiedenste Bereiche der geologischen Untergrundnutzung wie CO2- oder Energiespeicherung, Geothermie, Kohlenwasserstoffgewinnung sowie die Erkundung hydrothermaler Lagerstätten. KW - digital rock physics KW - synthetic sandstone KW - permeability evolution KW - elastic rock properties KW - micro-CT KW - Digitale Gesteinsphysik KW - Elastische Gesteinseigenschaften KW - Mikro-CT KW - Permeabilitätsentwicklung KW - Synthetische Sandsteine Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-512064 ER - TY - GEN A1 - Wetzel, Maria A1 - Kempka, Thomas A1 - Kühn, Michael T1 - Quantifying rock weakening due to decreasing calcite mineral content by numerical simulations T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - The quantification of changes in geomechanical properties due to chemical reactions is of paramount importance for geological subsurface utilisation, since mineral dissolution generally reduces rock stiffness. In the present study, the effective elastic moduli of two digital rock samples, the Fontainebleau and Bentheim sandstones, are numerically determined based on micro-CT images. Reduction in rock stiffness due to the dissolution of 10% calcite cement by volume out of the pore network is quantified for three synthetic spatial calcite distributions (coating, partial filling and random) using representative sub-cubes derived from the digital rock samples. Due to the reduced calcite content, bulk and shear moduli decrease by 34% and 38% in maximum, respectively. Total porosity is clearly the dominant parameter, while spatial calcite distribution has a minor impact, except for a randomly chosen cement distribution within the pore network. Moreover, applying an initial stiffness reduced by 47% for the calcite cement results only in a slightly weaker mechanical behaviour. Using the quantitative approach introduced here substantially improves the accuracy of predictions in elastic rock properties compared to general analytical methods, and further enables quantification of uncertainties related to spatial variations in porosity and mineral distribution. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1092 KW - digital rock physics KW - micro-CT KW - elastic properties KW - numerical simulation KW - chemical-mechanical interaction KW - Code_Aster KW - composite properties Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-473089 SN - 1866-8372 IS - 1092 ER -