TY  - GEN
A1  - Fondell, Mattis
A1  - Eckert, Sebastian
A1  - Jay, Raphael Martin
A1  - Weniger, Christian
A1  - Quevedo, Wilson
A1  - Niskanen, Johannes
A1  - Kennedy, Brian
A1  - Sorgenfrei, Florian
A1  - Schick, Daniel
A1  - Giangrisostomi, Erika
A1  - Ovsyannikov, Ruslan
A1  - Adamczyk, Katrin
A1  - Huse, Nils
A1  - Wernet, Philippe
A1  - Mitzner, Rolf
A1  - Föhlisch, Alexander
T1  - Time-resolved soft X-ray absorption spectroscopy in transmission mode on liquids at MHz repetition rates
T2  - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe
N2  - We present a setup combining a liquid flatjet sample delivery and a MHz laser system for time-resolved soft X-ray absorption measurements of liquid samples at the high brilliance undulator beamline UE52-SGM at Bessy II yielding unprecedented statistics in this spectral range. We demonstrate that the efficient detection of transient absorption changes in transmission mode enables the identification of photoexcited species in dilute samples. With iron(II)-trisbipyridine in aqueous solution as a benchmark system, we present absorption measurements at various edges in the soft X-ray regime. In combination with the wavelength tunability of the laser system, the set-up opens up opportunities to study the photochemistry of many systems at low concentrations, relevant to materials sciences, chemistry, and biology.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 780 
KW  - l-edge xas
KW  - electronic-structure
KW  - molecular-structure
KW  - spin-state
KW  - dynamics
KW  - complexes
KW  - probe
KW  - water
KW  - iron(II)
KW  - spectra
Y1  - 2019
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-437529
SN  - 1866-8372
IS  - 780
ER  -