TY  - JOUR
A1  - Mazzio, Katherine A.
A1  - Kojda, Sandrino Danny
A1  - Rubio-Govea, Rodrigo
A1  - Niederhausen, Jens
A1  - Ryll, Britta
A1  - Raja-Thulasimani, Monika
A1  - Habicht, Klaus
A1  - Raoux, Simone
T1  - P-type-to-n-type transition in hybrid AgxTe/PEDOT:PSS thermoelectric materials via stoichiometric control during solution-based synthesis
JF  - ACS applied energy materials
N2  - This work demonstrates the production of high-performing p- type and n-type hybrid AgxTe/poly(3,4-ethylenedioxythiopene):polystyrene sulfonic acid (PE-DOT:PSS) thermoelectric materials from the same Te/PEDOT:PSS parent structure during aqueous-based synthesis. All samples were solution-processed and analyzed in thin- film architectures. We were able to demonstrate a power factor of 44 mu W m(-1) K-2 for our highest-performing n-type material. In addition, we were also able to realize a 68% improvement in the power factor of our p-type compositions relative to the parent structure through manipulation of the inorganic nanostructure composition. We demonstrate control over the thermoelectric properties by varying the stoichiometry of AgxTe nanoparticles in AgxTe/PEDOT:PSS hybrid materials via a topotactic chemical transformation process at room temperature. This process offers a simple, low-temperature, and cost-effective route toward the production of both efficient n-type and p-type hybrid thermoelectric materials.
KW  - thermoelectrics
KW  - hybrid material
KW  - PEDOT:PSS
KW  - tellurium
KW  - silver
KW  - telluride
KW  - hybrid synthesis
Y1  - 2020
U6  - https://doi.org/10.1021/acsaem.0c01774
SN  - 2574-0962
VL  - 3
IS  - 11
SP  - 10734
EP  - 10743
PB  - ACS Publications
CY  - Washington, DC
ER  - 
TY  - JOUR
A1  - Cui, Qianling
A1  - Yashchenok, Alexey
A1  - Zhang, Lu
A1  - Li, Lidong
A1  - Masic, Admir
A1  - Wienskol, Gabriele
A1  - Moehwald, Helmuth
A1  - Bargheer, Matias
T1  - Fabrication of Bifunctional Gold/Gelatin Hybrid Nanocomposites and Their Application
JF  - ACS applied materials & interfaces
N2  - Herein, a facile method is presented to integrate large gold nanoflowers (similar to 80 nm) and small gold nanoparticles (2-4 nm) into a single entity, exhibiting both surface-enhanced Raman scattering (SERS) and catalytic activity. The as-prepared gold nanoflowers were coated by a gelatin layer, in which the gold precursor was adsorbed and in situ reduced into small gold nanoparticles. The thickness of the gelatin shell is controlled to less than 10 nm, ensuring that the small gold nanoparticles are still in a SERS-active range of the inner Au core. Therefore, the reaction catalyzed by these nanocomposites can be monitored in situ using label-free SERS spectroscopy. In addition, these bifunctional nanocomposites are also attractive candidates for application in SERS monitoring of bioreactions because of their excellent biocompatibility.
KW  - core-shell nanostructure
KW  - gold
KW  - hybrid material
KW  - gelatin
KW  - nanoparticles
KW  - surface-enhanced Raman scattering
Y1  - 2014
U6  - https://doi.org/10.1021/am5000068
SN  - 1944-8244
VL  - 6
IS  - 3
SP  - 1999
EP  - 2002
PB  - American Chemical Society
CY  - Washington
ER  -