TY  - THES
A1  - Balzer, Arnim
T1  - Crab flare observations with H.E.S.S. phase II
T1  - Crab Flare Observations with H.E.S.S. Phase II
N2  - The H.E.S.S. array is a third generation Imaging Atmospheric Cherenkov Telescope (IACT) array. It is located in the Khomas Highland in Namibia, and measures very high energy (VHE) gamma-rays. In Phase I, the array started data taking in 2004 with its four identical 13 m telescopes. Since then, H.E.S.S. has emerged as the most successful IACT experiment to date. Among the almost 150 sources of VHE gamma-ray radiation found so far, even the oldest detection, the Crab Nebula, keeps surprising the scientific community with unexplained phenomena such as the recently discovered very energetic flares of high energy gamma-ray radiation. During its most recent flare, which was detected by the Fermi satellite in March 2013, the Crab Nebula was simultaneously observed with the H.E.S.S. array for six nights. The results of the observations will be discussed in detail during the course of this work. During the nights of the flare, the new 24 m × 32 m H.E.S.S. II telescope was still being commissioned, but participated in the data taking for one night. To be able to reconstruct and analyze the data of the H.E.S.S. Phase II array, the algorithms and software used by the H.E.S.S. Phase I array had to be adapted. The most prominent advanced shower reconstruction technique developed by de Naurois and Rolland, the template-based model analysis, compares real shower images taken by the Cherenkov telescope cameras with shower templates obtained using a semi-analytical model. To find the best fitting image, and, therefore, the relevant parameters that describe the air shower best, a pixel-wise log-likelihood fit is done. The adaptation of this advanced shower reconstruction technique to the heterogeneous H.E.S.S. Phase II array for stereo events (i.e. air showers seen by at least two telescopes of any kind), its performance using MonteCarlo simulations as well as its application to real data will be described.
N2  - Das H.E.S.S. Experiment misst sehr hochenergetische Gammastrahlung im Khomas Hochland von Namibia. Es ist ein sogenanntes abbildendes atmosphärisches Cherenkov-Teleskopsystem welches in der 1. Phase, die im Jahr 2004 mit der Datennahme begann, aus vier identischen 13 m Spiegelteleskopen bestand. Seitdem hat sich H.E.S.S. als das erfolgreichstes Experiment in der bodengebundenen Gammastrahlungsastronomie etabliert. Selbst die älteste der mittlerweile fast 150 entdeckten Quellen von sehr hochenergetischer Gammastrahlung, der Krebsnebel, fasziniert immernoch Wissenschaftler mit neuen bisher unbekannten und unerwarteten Phänomenen. Ein Beispiel dafür sind die vor kurzem entdeckten sehr energiereichen Ausbrüche von hochenergetischer Gammastrahlung. Bei dem letzten deratigen Ausbruch des Krebsnebels im März 2013 hat das H.E.S.S. Experiment für sechs Nächte simultan mit dem Fermi-Satelliten, welcher den Ausbruch entdeckte, Daten genommen. Die Analyse der Daten, deren Ergebnis und deren Interpretation werden im Detail in dieser Arbeit vorgestellt. Während dieser Beobachtungen befand sich ein neues 24 m × 32 m großes Spiegelteleskop, das H.E.S.S. II- Teleskop, noch in seiner Inbetriebnahme, trotzdem hat es für eine dieser sechs Nächte an der Datennahme des gesamten Teleskopsystems teilgenommen. Um die Daten rekonstruieren und analysieren zu können, mussten die für die 1. Phase des Experiments entwickelten Algorithmen und die Software des H.E.S.S.- Experiments angepasst werden. Die fortschrittlichste Schauerrekonstruktionsmethode, welche von de Naurois und Rolland entwickelt wurde, basiert auf dem Vergleich von echten Schauerbildern, die mit Hilfe der Cherenkov-Kameras der einzelnen Teleskope aufgenommen wurden, mit Schauerschablonen die mit Hilfe eines semianalytischen Modells erzeugt wurden. Das am besten passende Bild und damit auch alle relevanten Schauerparameter, wird mit Hilfe einer pixelweisen Loglikelihood-Anpassung ermittelt. Die nötigen Änderungen um Multiteleskopereignisse, welche vom heterogenen H.E.S.S. Phase II Detektor gemessen wurden, mit Hilfe dieser fortschrittlichen Schauerrekonstruktionsmethode analysieren zu können, sowie die resultierenden Ergebnisse von MonteCarlo-Simulationen, als auch die Anwendung auf echte Daten, werden im Rahmen dieser Arbeit präsentiert.
KW  - Gammastrahlungsastronomie
KW  - Rekonstruktionsmethoden
KW  - Datenanalyse
KW  - Krebsnebel
KW  - gamma-ray astronomy
KW  - reconstruction methods
KW  - data analysis
KW  - Crab Nebula
Y1  - 2014
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-72545
ER  - 
TY  - JOUR
A1  - de Carvalho, Sidney J.
A1  - Metzler, Ralf
A1  - Cherstvy, Andrey G.
T1  - Critical adsorption of polyelectrolytes onto charged Janus nanospheres
JF  - Physical chemistry, chemical physics : a journal of European Chemical Societies
N2  - Based on extensive Monte Carlo simulations and analytical considerations we study the electrostatically driven adsorption of flexible polyelectrolyte chains onto charged Janus nanospheres. These net-neutral colloids are composed of two equally but oppositely charged hemispheres. The critical binding conditions for polyelectrolyte chains are analysed as function of the radius of the Janus particle and its surface charge density, as well as the salt concentration in the ambient solution. Specifically for the adsorption of finite-length polyelectrolyte chains onto Janus nanoparticles, we demonstrate that the critical adsorption conditions drastically differ when the size of the Janus particle or the screening length of the electrolyte are varied. We compare the scaling laws obtained for the adsorption-desorption threshold to the known results for uniformly charged spherical particles, observing significant disparities. We also contrast the changes to the polyelectrolyte chain conformations close to the surface of the Janus nanoparticles as compared to those for simple spherical particles. Finally, we discuss experimentally relevant physicochemical systems for which our simulations results may become important. In particular, we observe similar trends with polyelectrolyte complexation with oppositely but heterogeneously charged proteins.
Y1  - 2014
U6  - https://doi.org/10.1039/c4cp02207f
SN  - 1463-9076
SN  - 1463-9084
VL  - 16
IS  - 29
SP  - 15539
EP  - 15550
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - GEN
A1  - de Carvalho, Sidney J.
A1  - Metzler, Ralf
A1  - Cherstvy, Andrey G.
T1  - Critical adsorption of polyelectrolytes onto charged Janus nanospheres
N2  - Based on extensive Monte Carlo simulations and analytical considerations we study the electrostatically driven adsorption of flexible polyelectrolyte chains onto charged Janus nanospheres. These net-neutral colloids are composed of two equally but oppositely charged hemispheres. The critical binding conditions for polyelectrolyte chains are analysed as function of the radius of the Janus particle and its surface charge density, as well as the salt concentration in the ambient solution. Specifically for the adsorption of finite-length polyelectrolyte chains onto Janus nanoparticles, we demonstrate that the critical adsorption conditions drastically differ when the size of the Janus particle or the screening length of the electrolyte are varied. We compare the scaling laws obtained for the adsorption–desorption threshold to the known results for uniformly charged spherical particles, observing significant disparities. We also contrast the changes to the polyelectrolyte chain conformations close to the surface of the Janus nanoparticles as compared to those for simple spherical particles. Finally, we discuss experimentally relevant physico-chemical systems for which our simulations results may become important. In particular, we observe similar trends with polyelectrolyte complexation with oppositely but heterogeneously charged proteins.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 278 
Y1  - 2014
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-98783
ER  - 
TY  - JOUR
A1  - Archambault, S.
A1  - Aune, T.
A1  - Behera, B.
A1  - Beilicke, M.
A1  - Benbow, W.
A1  - Berger, K.
A1  - Bird, R.
A1  - Biteau, Jonathan
A1  - Bugaev, V.
A1  - Byrum, K.
A1  - Cardenzana, J. V.
A1  - Cerruti, M.
A1  - Chen, Xuhui
A1  - Ciupik, L.
A1  - Connolly, M. P.
A1  - Cui, Wei
A1  - Dumm, J.
A1  - Errando, M.
A1  - Falcone, A.
A1  - Federici, Simone
A1  - Feng, Q.
A1  - Finley, J. P.
A1  - Fleischhack, H.
A1  - Fortson, L.
A1  - Furniss, A.
A1  - Galante, N.
A1  - Gillanders, G. H.
A1  - Griffin, S.
A1  - Griffiths, S. T.
A1  - Grube, J.
A1  - Gyuk, G.
A1  - Hanna, D.
A1  - Holder, J.
A1  - Hughes, G.
A1  - Humensky, T. B.
A1  - Johnson, C. A.
A1  - Kaaret, P.
A1  - Kertzman, M.
A1  - Khassen, Y.
A1  - Kieda, D.
A1  - Krawczynski, H.
A1  - Krennrich, F.
A1  - Kumar, S.
A1  - Lang, M. J.
A1  - Madhavan, A. S.
A1  - Maier, G.
A1  - McCann, A.
A1  - Meagher, K.
A1  - Moriarty, P.
A1  - Mukherjee, R.
A1  - Nieto, Daniel
A1  - Ong, R. A.
A1  - Otte, A. N.
A1  - Park, N.
A1  - Pohl, Martin
A1  - Popkow, A.
A1  - Prokoph, H.
A1  - Quinn, J.
A1  - Ragan, K.
A1  - Rajotte, J.
A1  - Reyes, L. C.
A1  - Reynolds, P. T.
A1  - Richards, G. T.
A1  - Roache, E.
A1  - Sembroski, G. H.
A1  - Shahinyan, K.
A1  - Staszak, D.
A1  - Telezhinsky, Igor O.
A1  - Tucci, J. V.
A1  - Tyler, J.
A1  - Varlotta, A.
A1  - Vassiliev, V. V.
A1  - Vincent, S.
A1  - Wakely, S. P.
A1  - Weinstein, A.
A1  - Welsing, R.
A1  - Wilhelm, Alina
A1  - Williams, D. A.
A1  - Ackermann, Margit
A1  - Ajello, M.
A1  - Albert, A.
A1  - Baldini, L.
A1  - Bastieri, D.
A1  - Bellazzini, R.
A1  - Bissaldi, E.
A1  - Bregeon, Johan
A1  - Buehler, R.
A1  - Buson, S.
A1  - Caliandro, G. A.
A1  - Cameron, R. A.
A1  - Caraveo, P. A.
A1  - Cavazzuti, E.
A1  - Charles, E.
A1  - Chiang, J.
A1  - Ciprini, S.
A1  - Claus, R.
A1  - Cutini, S.
A1  - de Angelis, A.
A1  - de Palma, F.
A1  - Dermer, C. D.
A1  - Digel, S. W.
A1  - Di Venere, L.
A1  - Drell, P. S.
A1  - Favuzzi, C.
A1  - Franckowiak, A.
A1  - Fusco, P.
A1  - Gargano, F.
A1  - Gasparrini, D.
A1  - Giglietto, N.
A1  - Giordano, F.
A1  - Giroletti, M.
A1  - Grenier, I. A.
A1  - Guiriec, S.
A1  - Jogler, T.
A1  - Kuss, M.
A1  - Larsson, S.
A1  - Latronico, L.
A1  - Longo, F.
A1  - Loparco, F.
A1  - Lubrano, P.
A1  - Madejski, G. M.
A1  - Mayer, M.
A1  - Mazziotta, Mario Nicola
A1  - Michelson, P. F.
A1  - Mizuno, T.
A1  - Monzani, M. E.
A1  - Morselli, Aldo
A1  - Murgia, S.
A1  - Nuss, E.
A1  - Ohsugi, T.
A1  - Ormes, J. F.
A1  - Paneque, D.
A1  - Perkins, J. S.
A1  - Piron, F.
A1  - Pivato, G.
A1  - Raino, S.
A1  - Razzano, M.
A1  - Reimer, A.
A1  - Reimer, Olaf
A1  - Ritz, S.
A1  - Schaal, M.
A1  - Sgro, C.
A1  - Siskind, E. J.
A1  - Spinelli, P.
A1  - Takahashi, H.
A1  - Tibaldo, L.
A1  - Tinivella, M.
A1  - Troja, E.
A1  - Vianello, G.
A1  - Werner, M.
A1  - Wood, M.
T1  - Deep broadband observations of the distant gamma-ray blazar PKS 1424+240
JF  - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters
N2  - We present deep VERITAS observations of the blazar PKS 1424+240, along with contemporaneous Fermi Large Area Telescope, Swift X-ray Telescope, and Swift UV Optical Telescope data between 2009 February 19 and 2013 June 8. This blazar resides at a redshift of z >= 0.6035, displaying a significantly attenuated gamma-ray flux above 100 GeV due to photon absorption via pair-production with the extragalactic background light. We present more than 100 hr of VERITAS observations over three years, a multiwavelength light curve, and the contemporaneous spectral energy distributions. The source shows a higher flux of (2.1 +/- 0.3) x 10(-7) photons m(-2) s(-1) above 120 GeV in 2009 and 2011 as compared to the flux measured in 2013, corresponding to (1.02 +/- 0.08) x 10-7 photons m(-2) s(-1) above 120 GeV. The measured differential very high energy (VHE; E >= 100 GeV) spectral indices are Gamma = 3.8 +/- 0.3, 4.3 +/- 0.6 and 4.5 +/- 0.2 in 2009, 2011, and 2013, respectively. No significant spectral change across the observation epochs is detected. We find no evidence for variability at gamma-ray opacities of greater than tau = 2, where it is postulated that any variability would be small and occur on timescales longer than a year if hadronic cosmic-ray interactions with extragalactic photon fields provide a secondary VHE photon flux. The data cannot rule out such variability due to low statistics.
KW  - BL Lacertae objects: individual (PKS 1424+240)-cosmic background radiation
KW  - gamma rays: galaxies
Y1  - 2014
U6  - https://doi.org/10.1088/2041-8205/785/1/L16
SN  - 2041-8205
SN  - 2041-8213
VL  - 785
IS  - 1
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Ghosh, Surya K.
A1  - Cherstvy, Andrey G.
A1  - Metzler, Ralf
T1  - Deformation propagation in responsive polymer network films
JF  - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr
N2  - We study the elastic deformations in a cross-linked polymer network film triggered by the binding of submicron particles with a sticky surface, mimicking the interactions of viral pathogens with thin films of stimulus-responsive polymeric materials such as hydrogels. From extensive Langevin Dynamics simulations we quantify how far the network deformations propagate depending on the elasticity parameters of the network and the adhesion strength of the particles. We examine the dynamics of the collective area shrinkage of the network and obtain some simple relations for the associated characteristic decay lengths. A detailed analysis elucidates how the elastic energy of the network is distributed between stretching and compression modes in response to the particle binding. We also examine the force-distance curves of the repulsion or attraction interactions for a pair of sticky particles in the polymer network film as a function of the particle-particle separation. The results of this computational study provide new insight into collective phenomena in soft polymer network films and may, in particular, be applied to applications for visual detection of pathogens such as viruses via a macroscopic response of thin films of cross-linked hydrogels. (C) 2014 AIP Publishing LLC.
Y1  - 2014
U6  - https://doi.org/10.1063/1.4893056
SN  - 0021-9606
SN  - 1089-7690
VL  - 141
IS  - 7
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - JOUR
A1  - Abramowski, Attila
A1  - Aharonian, Felix A.
A1  - Benkhali, Faical  Ait
A1  - Akhperjanian, A. G.
A1  - Angüner, Ekrem Oǧuzhan
A1  - Backes, Michael
A1  - Balenderan, Shangkari
A1  - Balzer, Arnim
A1  - Barnacka, Anna
A1  - Becherini, Yvonne
A1  - Tjus, J. Becker
A1  - Berge, David
A1  - Bernhard, Sabrina
A1  - Bernlöhr, K.
A1  - Birsin, E.
A1  - Biteau, Jonathan
A1  - Boettcher, Markus
A1  - Boisson, Catherine
A1  - Bolmont, J.
A1  - Bordas, Pol
A1  - Bregeon, Johan
A1  - Brun, Francois
A1  - Brun, Pierre
A1  - Bryan, Mark
A1  - Bulik, Tomasz
A1  - Carrigan, Svenja
A1  - Casanova, Sabrina
A1  - Chadwick, Paula M.
A1  - Chakraborty, N.
A1  - Chalme-Calvet, R.
A1  - Chaves, Ryan C. G.
A1  - Chretien, M.
A1  - Colafrancesco, Sergio
A1  - Cologna, Gabriele
A1  - Conrad, Jan
A1  - Couturier, C.
A1  - Cui, Y.
A1  - Davids, I. D.
A1  - Degrange, B.
A1  - Deil, C.
A1  - dewilt, P.
A1  - Djannati-Ataï, A.
A1  - Domainko, W.
A1  - Donath, A.
A1  - Dubus, G.
A1  - Dutson, K.
A1  - Dyks, J.
A1  - Dyrda, M.
A1  - Edwards, T.
A1  - Egberts, Kathrin
A1  - Eger, P.
A1  - Espigat, P.
A1  - Farnier, C.
A1  - Fegan, S.
A1  - Feinstein, F.
A1  - Fernandes, M. V.
A1  - Fernandez, D.
A1  - Fiasson, A.
A1  - Fontaine, G.
A1  - Foerster, A.
A1  - Fuessling, M.
A1  - Gabici, S.
A1  - Gajdus, M.
A1  - Gallant, Y. A.
A1  - Garrigoux, T.
A1  - Giavitto, G.
A1  - Giebels, B.
A1  - Glicenstein, J. F.
A1  - Gottschall, D.
A1  - Grondin, M. -H.
A1  - Grudzinska, M.
A1  - Hadasch, D.
A1  - Haeffner, S.
A1  - Hahn, J.
A1  - Harris, J.
A1  - Heinzelmann, G.
A1  - Henri, G.
A1  - Hermann, G.
A1  - Hervet, O.
A1  - Hillert, A.
A1  - Hinton, James Anthony
A1  - Hofmann, W.
A1  - Hofverberg, P.
A1  - Holler, M.
A1  - Horns, D.
A1  - Ivascenko, A.
A1  - Jacholkowska, A.
A1  - Jahn, C.
A1  - Jamrozy, Marek
A1  - Janiak, M.
A1  - Jankowsky, F.
A1  - Jung-Richardt, I.
A1  - Kastendieck, M. A.
A1  - Katarzynski, Krzysztof
A1  - Katz, Uli
A1  - Kaufmann, S.
A1  - Khelifi, B.
A1  - Kieffer, M.
A1  - Klepser, S.
A1  - Klochkov, D.
A1  - Kluzniak, W.
A1  - Kolitzus, D.
A1  - Komin, Nu.
A1  - Kosack, K.
A1  - Krakau, S.
A1  - Krayzel, F.
A1  - Krueger, P. P.
A1  - Laffon, H.
A1  - Lamanna, G.
A1  - Lefaucheur, J.
A1  - Lefranc, V.
A1  - Lemiere, A.
A1  - Lemoine-Goumard, M.
A1  - Lenain, J. -P.
A1  - Lohse, T.
A1  - Lopatin, A.
A1  - Lu, C. -C.
A1  - Marandon, V.
A1  - Marcowith, Alexandre
A1  - Marx, R.
A1  - Maurin, G.
A1  - Maxted, N.
A1  - Mayer, M.
A1  - McComb, T. J. L.
A1  - Mehault, J.
A1  - Meintjes, P. J.
A1  - Menzler, U.
A1  - Meyer, M.
A1  - Mitchell, A. M. W.
A1  - Moderski, R.
A1  - Mohamed, M.
A1  - Mora, K.
A1  - Moulin, Emmanuel
A1  - Murach, T.
A1  - de Naurois, M.
A1  - Niemiec, J.
A1  - Nolan, S. J.
A1  - Oakes, L.
A1  - Odaka, H.
A1  - Ohm, S.
A1  - Opitz, B.
A1  - Ostrowski, M.
A1  - Oya, I.
A1  - Panter, M.
A1  - Parsons, R. D.
A1  - Arribas, M. Paz
A1  - Pekeur, N. W.
A1  - Pelletier, G.
A1  - Petrucci, P. -O.
A1  - Peyaud, B.
A1  - Pita, S.
A1  - Poon, H.
A1  - Puehlhofer, G.
A1  - Punch, Michael
A1  - Quirrenbach, A.
A1  - Raab, S.
A1  - Reichardt, I.
A1  - Reimer, A.
A1  - Reimer, Olaf
A1  - Renaud, M.
A1  - de los Reyes, R.
A1  - Rieger, F.
A1  - Romoli, C.
A1  - Rosier-Lees, S.
A1  - Rowell, G.
A1  - Rudak, B.
A1  - Rulten, C. B.
A1  - Sahakian, V.
A1  - Salek, D.
A1  - Sanchez, David M.
A1  - Santangelo, Andrea
A1  - Schlickeiser, R.
A1  - Schuessler, Fabian
A1  - Schulz, A.
A1  - Schwanke, U.
A1  - Schwarzburg, S.
A1  - Schwemmer, S.
A1  - Sol, H.
A1  - Spanier, F.
A1  - Spengler, G.
A1  - Spies, F.
A1  - Stawarz, L.
A1  - Steenkamp, R.
A1  - Stegmann, Christian
A1  - Stinzing, F.
A1  - Stycz, K.
A1  - Sushch, Iurii
A1  - Tavernet, J. -P.
A1  - Tavernier, T.
A1  - Taylor, A. M.
A1  - Terrier, R.
A1  - Tluczykont, M.
A1  - Trichard, C.
A1  - Valerius, K.
A1  - van Eldik, Christopher
A1  - van Soelen, B.
A1  - Vasileiadis, G.
A1  - Veh, J.
A1  - Venter, C.
A1  - Viana, A.
A1  - Vincent, P.
A1  - Vink, J.
A1  - Voelk, H. J.
A1  - Volpe, F.
A1  - Vorster, M.
A1  - Vuillaume, T.
A1  - Wagner, S. J.
A1  - Wagner, P.
A1  - Wagner, R. M.
A1  - Ward, M.
A1  - Weidinger, M.
A1  - Weitzel, Q.
A1  - White, R.
A1  - Wierzcholska, A.
A1  - Willmann, P.
A1  - Woernlein, A.
A1  - Wouters, D.
A1  - Yang, R.
A1  - Zabalza, V.
A1  - Zaborov, D.
A1  - Zacharias, M.
A1  - Zdziarski, A. A.
A1  - Zech, Alraune
A1  - Zechlin, H. -S.
A1  - Fukui, Y.
T1  - Diffuse Galactic gamma-ray emission with HESS
JF  - Physical review : D, Particles, fields, gravitation, and cosmology
N2  - Diffuse gamma-ray emission is the most prominent observable signature of celestial cosmic-ray interactions at high energies. While already being investigated at GeVenergies over several decades, assessments of diffuse gamma-ray emission at TeVenergies remain sparse. After completion of the systematic survey of the inner Galaxy, the H.E.S.S. experiment is in a prime position to observe large-scale diffuse emission at TeVenergies. Data of the H.E.S.S. Galactic Plane Survey are investigated in regions off known gamma-ray sources. Corresponding gamma-ray flux measurements were made over an extensive grid of celestial locations. Longitudinal and latitudinal profiles of the observed gamma-ray fluxes show characteristic excess emission not attributable to known gamma-ray sources. For the first time large-scale gamma-ray emission along the Galactic plane using imaging atmospheric Cherenkov telescopes has been observed. While the background subtraction technique limits the ability to recover modest variation on the scale of the H.E.S.S. field of view or larger, which is characteristic of the inverse Compton scatter-induced Galactic diffuse emission, contributions of neutral pion decay as well as emission from unresolved gamma-ray sources can be recovered in the observed signal to a large fraction. Calculations show that the minimum gamma-ray emission from pi(0) decay represents a significant contribution to the total signal. This detection is interpreted as a mix of diffuse Galactic gamma-ray emission and unresolved sources.
Y1  - 2014
U6  - https://doi.org/10.1103/PhysRevD.90.122007
SN  - 1550-7998
SN  - 1550-2368
VL  - 90
IS  - 12
PB  - American Physical Society
CY  - College Park
ER  - 
TY  - JOUR
A1  - Bauer, Maximilian
A1  - Godec, Aljaž
A1  - Metzler, Ralf
T1  - Diffusion of finite-size particles in two-dimensional channels with random wall configurations
JF  - Physical chemistry, chemical physics : PCCP ; a journal of European chemical societies
N2  - Diffusion of chemicals or tracer molecules through complex systems containing irregularly shaped channels is important in many applications. Most theoretical studies based on the famed Fick–Jacobs equation focus on the idealised case of infinitely small particles and reflecting boundaries. In this study we use numerical simulations to consider the transport of finite-size particles through asymmetrical two-dimensional channels. Additionally, we examine transient binding of the molecules to the channel walls by applying sticky boundary conditions. We consider an ensemble of particles diffusing in independent channels, which are characterised by common structural parameters. We compare our results for the long-time effective diffusion coefficient with a recent theoretical formula obtained by Dagdug and Pineda [J. Chem. Phys., 2012, 137, 024107].
KW  - anomalous diffusion
KW  - fractional dynamics
KW  - transport
KW  - nonergodicity
KW  - coefficient
Y1  - 2014
U6  - https://doi.org/10.1039/C3CP55160A
SN  - 1463-9084
SN  - 1463-9076
VL  - 16
IS  - 13
SP  - 6118
EP  - 6128
PB  - RSC Publications
CY  - Cambridge
ER  - 
TY  - GEN
A1  - Bauer, Maximilian
A1  - Godec, Aljaž
A1  - Metzler, Ralf
T1  - Diffusion of finite-size particles in two-dimensional channels with random wall configurations
N2  - Diffusion of chemicals or tracer molecules through complex systems containing irregularly shaped channels is important in many applications. Most theoretical studies based on the famed Fick–Jacobs equation focus on the idealised case of infinitely small particles and reflecting boundaries. In this study we use numerical simulations to consider the transport of finite-size particles through asymmetrical two-dimensional channels. Additionally, we examine transient binding of the molecules to the channel walls by applying sticky boundary conditions. We consider an ensemble of particles diffusing in independent channels, which are characterised by common structural parameters. We compare our results for the long-time effective diffusion coefficient with a recent theoretical formula obtained by Dagdug and Pineda [J. Chem. Phys., 2012, 137, 024107].
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 177 
KW  - anomalous diffusion
KW  - fractional dynamics
KW  - transport
KW  - nonergodicity
KW  - coefficient
Y1  - 2014
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-76199
ER  - 
TY  - JOUR
A1  - Gvaramadze, V. V.
A1  - Chene, A.-N.
A1  - Kniazev, A. Y.
A1  - Schnurr, O.
A1  - Shenar, Tomer
A1  - Sander, Andreas Alexander Christoph
A1  - Hainich, Rainer
A1  - Langer, N.
A1  - Hamann, Wolf-Rainer
A1  - Chu, Y.-H.
A1  - Gruendl, R. A.
T1  - Discovery of a new Wolf-Rayet star and a candidate star cluster in the Large Magellanic Cloud with Spitzer
JF  - Monthly notices of the Royal Astronomical Society
N2  - We report the first-ever discovery of a Wolf-Rayet (WR) star in the Large Magellanic Cloud via detection of a circular shell with the Spitzer Space Telescope. Follow-up observations with Gemini-South resolved the central star of the shell into two components separated from each other by a parts per thousand 2 arcsec (or a parts per thousand 0.5 pc in projection). One of these components turns out to be a WN3 star with H and He lines both in emission and absorption (we named it BAT99 3a using the numbering system based on extending the Breysacher et al. catalogue). Spectroscopy of the second component showed that it is a B0 V star. Subsequent spectroscopic observations of BAT99 3a with the du Pont 2.5-m telescope and the Southern African Large Telescope revealed that it is a close, eccentric binary system, and that the absorption lines are associated with an O companion star. We analysed the spectrum of the binary system using the non-LTE Potsdam WR (powr) code, confirming that the WR component is a very hot (a parts per thousand 90 kK) WN star. For this star, we derived a luminosity of log L/ L-aS (TM) = 5.45 and a mass-loss rate of 10(- 5.8) M-aS (TM) yr(- 1), and found that the stellar wind composition is dominated by helium with 20 per cent of hydrogen. Spectroscopy of the shell revealed an He iii region centred on BAT99 3a and having the same angular radius (a parts per thousand 15 arcsec) as the shell. We thereby add a new example to a rare class of high-excitation nebulae photoionized by WR stars. Analysis of the nebular spectrum showed that the shell is composed of unprocessed material, implying that the shell was swept-up from the local interstellar medium. We discuss the physical relationship between the newly identified massive stars and their possible membership of a previously unrecognized star cluster.
KW  - line: identification
KW  - binaries: spectroscopic
KW  - stars: massive
KW  - stars: Wolf-Rayet
KW  - ISM: bubbles
Y1  - 2014
U6  - https://doi.org/10.1093/mnras/stu909
SN  - 0035-8711
SN  - 1365-2966
VL  - 442
IS  - 2
SP  - 929
EP  - 945
PB  - Oxford Univ. Press
CY  - Oxford
ER  - 
TY  - JOUR
A1  - Abramowski, Attila
A1  - Aharonian, Felix A.
A1  - Benkhali, Faical  Ait
A1  - Akhperjanian, A. G.
A1  - Uner, E. O. Ang
A1  - Backes, Michael
A1  - Balenderan, Shangkari
A1  - Balzer, Arnim
A1  - Barnacka, Anna
A1  - Becherini, Yvonne
A1  - Tjus, J. Becker
A1  - Berge, David
A1  - Bernhard, Sabrina
A1  - Bernlöhr, K.
A1  - Birsin, E.
A1  - Biteau, Jonathan
A1  - Boettcher, Markus
A1  - Boisson, Catherine
A1  - Bolmont, J.
A1  - Bordas, Pol
A1  - Bregeon, Johan
A1  - Brun, Francois
A1  - Brun, Pierre
A1  - Bryan, Mark
A1  - Bulik, Tomasz
A1  - Carrigan, Svenja
A1  - Casanova, Sabrina
A1  - Chadwick, Paula M.
A1  - Chakraborty, N.
A1  - Chalme-Calvet, R.
A1  - Chaves, Ryan C. G.
A1  - Chretien, M.
A1  - Colafrancesco, Sergio
A1  - Cologna, Gabriele
A1  - Conrad, Jan
A1  - Couturier, C.
A1  - Cui, Y.
A1  - Dalton, M.
A1  - Davids, I. D.
A1  - Degrange, B.
A1  - Deil, C.
A1  - deWilt, P.
A1  - Djannati-Ataï, A.
A1  - Domainko, W.
A1  - Donath, A.
A1  - Dubus, G.
A1  - Dutson, K.
A1  - Dyks, J.
A1  - Dyrda, M.
A1  - Edwards, T.
A1  - Egberts, Kathrin
A1  - Eger, P.
A1  - Espigat, P.
A1  - Farnier, C.
A1  - Fegan, S.
A1  - Feinstein, F.
A1  - Fernandes, M. V.
A1  - Fernandez, D.
A1  - Fiasson, A.
A1  - Fontaine, G.
A1  - Foerster, A.
A1  - Fuessling, M.
A1  - Gabici, S.
A1  - Gajdus, M.
A1  - Gallant, Y. A.
A1  - Garrigoux, T.
A1  - Giavitto, G.
A1  - Giebels, B.
A1  - Glicenstein, J. F.
A1  - Gottschall, D.
A1  - Grondin, M. -H.
A1  - Grudzinska, M.
A1  - Hadasch, D.
A1  - Haeffner, S.
A1  - Hahn, J.
A1  - Harris, J.
A1  - Heinzelmann, G.
A1  - Henri, G.
A1  - Hermann, G.
A1  - Hervet, O.
A1  - Hillert, A.
A1  - Hinton, James Anthony
A1  - Hofmann, W.
A1  - Hofverberg, P.
A1  - Holler, Markus
A1  - Horns, D.
A1  - Ivascenko, A.
A1  - Jacholkowska, A.
A1  - Jahn, C.
A1  - Jamrozy, M.
A1  - Janiak, M.
A1  - Jankowsky, F.
A1  - Jung-Richardt, I.
A1  - Kastendieck, M. A.
A1  - Katarzynski, K.
A1  - Katz, U.
A1  - Kaufmann, S.
A1  - Khelifi, B.
A1  - Kieffer, M.
A1  - Klepser, S.
A1  - Klochkov, D.
A1  - Kluzniak, W.
A1  - Kolitzus, D.
A1  - Komin, Nu.
A1  - Kosack, K.
A1  - Krakau, S.
A1  - Krayzel, F.
A1  - Krueger, P. P.
A1  - Laffon, H.
A1  - Lamanna, G.
A1  - Lau, J.
A1  - Lefaucheur, J.
A1  - Lefranc, V.
A1  - Lemiere, A.
A1  - Lemoine-Goumard, M.
A1  - Lenain, J. -P.
A1  - Lohse, T.
A1  - Lopatin, A.
A1  - Lu, C. -C.
A1  - Marandon, V.
A1  - Marcowith, Alexandre
A1  - Marx, R.
A1  - Maurin, G.
A1  - Maxted, N.
A1  - Mayer, M.
A1  - McComb, T. J. L.
A1  - Mehault, J.
A1  - Meintjes, P. J.
A1  - Menzler, U.
A1  - Meyer, M.
A1  - Mitchell, A. M. W.
A1  - Moderski, R.
A1  - Mohamed, M.
A1  - Mora, K.
A1  - Moulin, Emmanuel
A1  - Murach, T.
A1  - de Naurois, M.
A1  - Niemiec, J.
A1  - Nolan, S. J.
A1  - Oakes, L.
A1  - Odaka, H.
A1  - Ohm, S.
A1  - Opitz, B.
A1  - Ostrowski, M.
A1  - Oya, I.
A1  - Panter, M.
A1  - Parsons, R. D.
A1  - Arribas, M. Paz
A1  - Pekeur, N. W.
A1  - Pelletier, G.
A1  - Petrucci, P. -O.
A1  - Peyaud, B.
A1  - Pita, S.
A1  - Poon, H.
A1  - Puehlhofer, G.
A1  - Punch, M.
A1  - Quirrenbach, A.
A1  - Raab, S.
A1  - Reichardt, I.
A1  - Reimer, A.
A1  - Reimer, O.
A1  - Renaud, M.
A1  - Reyes, R. de Los
A1  - Rieger, F.
A1  - Romoli, C.
A1  - Rosier-Lees, S.
A1  - Rowell, G.
A1  - Rudak, B.
A1  - Rulten, C. B.
A1  - Sahakian, V.
A1  - Salek, D.
A1  - Sanchez, David M.
A1  - Santangelo, Andrea
A1  - Schlickeiser, R.
A1  - Schuessler, F.
A1  - Schulz, A.
A1  - Schwanke, U.
A1  - Schwarzburg, S.
A1  - Schwemmer, S.
A1  - Sol, H.
A1  - Spanier, F.
A1  - Spengler, G.
A1  - Spies, F.
A1  - Stawarz, L.
A1  - Steenkamp, R.
A1  - Stegmann, Christian
A1  - Stinzing, F.
A1  - Stycz, K.
A1  - Sushch, Iurii
A1  - Tavernet, J. -P.
A1  - Tavernier, T.
A1  - Taylor, A. M.
A1  - Terrier, R.
A1  - Tluczykont, M.
A1  - Trichard, C.
A1  - Valerius, K.
A1  - Van Eldik, C.
A1  - van Soelen, B.
A1  - Vasileiadis, G.
A1  - Veh, J.
A1  - Venter, C.
A1  - Viana, A.
A1  - Vincent, P.
A1  - Vink, J.
A1  - Voelk, H. J.
A1  - Volpe, F.
A1  - Vorster, M.
A1  - Vuillaume, T.
A1  - Wagner, S. J.
A1  - Wagner, P.
A1  - Wagner, R. M.
A1  - Ward, M.
A1  - Weidinger, M.
A1  - Weitzel, Q.
A1  - White, R.
A1  - Wierzcholska, A.
A1  - Willmann, P.
A1  - Woernlein, A.
A1  - Wouters, D.
A1  - Yang, R.
A1  - Zabalza, V.
A1  - Zaborov, D.
A1  - Zacharias, M.
A1  - Zdziarski, A. A.
A1  - Zech, Alraune
A1  - Zechlin, H. -S.
A1  - Fukui, Y.
A1  - Sano, H.
A1  - Fukuda, T.
A1  - Yoshiike, S.
T1  - Discovery of the hard spectrum VHE gamma-ray source Hess J1641-463
JF  - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters
N2  - This Letter reports the discovery of a remarkably hard spectrum source, HESS J1641-463, by the High Energy Stereoscopic System (H.E.S.S.) in the very high energy (VHE) domain. HESS J1641-463 remained unnoticed by the usual analysis techniques due to confusion with the bright nearby source HESS J1640-465. It emerged at a significance level of 8.5 standard deviations after restricting the analysis to events with energies above 4 TeV. It shows a moderate flux level of phi(E > 1TeV) = (3.64 +/- 0.44(stat)+/- 0.73(sys)) x 10(-13) cm(-2) s(-1), corresponding to 1.8% of the Crab Nebula flux above the same energy, and a hard spectrum with a photon index of Gamma = 2.07 +/- 0.11(stat)+/- 0.20(sys). It is a point-like source, although an extension up to a Gaussian width of sigma = 3 arcmin cannot be discounted due to uncertainties in the H.E.S.S. point-spread function. The VHE gamma-ray flux of HESS J1641-463 is found to be constant over the observed period when checking time binnings from the year-by-year to the 28 minute exposure timescales. HESS J1641-463 is positionally coincident with the radio supernova remnant SNR G338.5+0.1. No X-ray candidate stands out as a clear association; however, Chandra and XMM-Newton data reveal some potential weak counterparts. Various VHE gamma-ray production scenarios are discussed. If the emission from HESS J1641-463 is produced by cosmic ray protons colliding with the ambient gas, then their spectrum must extend close to 1 PeV. This object may represent a source population contributing significantly to the galactic cosmic ray flux around the knee.
KW  - cosmic rays
KW  - gamma rays: general
KW  - ISM: individual objects (SNR G338.3-0.0, SNR G338.5+0.1)
Y1  - 2014
U6  - https://doi.org/10.1088/2041-8205/794/1/L1
SN  - 2041-8205
SN  - 2041-8213
VL  - 794
IS  - 1
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Oskinova, Lidia M.
A1  - Naze, Yael
A1  - Todt, Helge Tobias
A1  - Huenemoerder, David P.
A1  - Ignace, Richard
A1  - Hubrig, Swetlana
A1  - Hamann, Wolf-Rainer
T1  - Discovery of X-ray pulsations from a massive star
JF  - Nature Communications
N2  - X-ray emission from stars much more massive than the Sun was discovered only 35 years ago. Such stars drive fast stellar winds where shocks can develop, and it is commonly assumed that the X-rays emerge from the shock-heated plasma. Many massive stars additionally pulsate. However, hitherto it was neither theoretically predicted nor observed that these pulsations would affect their X-ray emission. All X-ray pulsars known so far are associated with degenerate objects, either neutron stars or white dwarfs. Here we report the discovery of pulsating X-rays from a non-degenerate object, the massive B-type star xi(1) CMa. This star is a variable of beta Cep-type and has a strong magnetic field. Our observations with the X-ray Multi-Mirror (XMM-Newton) telescope reveal X-ray pulsations with the same period as the fundamental stellar oscillations. This discovery challenges our understanding of stellar winds from massive stars, their X-ray emission and their magnetism.
Y1  - 2014
U6  - https://doi.org/10.1038/ncomms5024
SN  - 2041-1723
VL  - 5
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - JOUR
A1  - Toeroek, T.
A1  - Leake, J. E.
A1  - Titov, Viacheslav S.
A1  - Archontis, V.
A1  - Mikic, Z.
A1  - Linton, M. G.
A1  - Dalmasse, K.
A1  - Aulanier, Guillaume
A1  - Kliem, Bernhard
T1  - Distribution of electric currents in solar active regions
JF  - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters
KW  - magnetohydrodynamics (MHD)
KW  - Sun: corona
KW  - Sun: coronal mass ejections (CMEs)
Y1  - 2014
U6  - https://doi.org/10.1088/2041-8205/782/1/L10
SN  - 2041-8205
SN  - 2041-8213
VL  - 782
IS  - 1
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Haakh, Harald R.
A1  - Henkel, Carsten
A1  - Spagnolo, Salvatore
A1  - Rizzuto, Lucia
A1  - Passante, Roberto
T1  - Dynamical Casimir-Polder interaction between an atom and surface plasmons
JF  - Physical review : A, Atomic, molecular, and optical physics
N2  - We investigate the time-dependent Casimir-Polder potential of a polarizable two-level atom placed near a surface of arbitrary material, after a sudden change in the parameters of the system. Different initial conditions are taken into account. For an initially bare ground-state atom, the time-dependent Casimir-Polder energy reveals how the atom is "being dressed" by virtual, matter-assisted photons. We also study the transient behavior of the Casimir-Polder interaction between the atom and the surface starting from a partially dressed state, after an externally induced change in the atomic level structure or transition dipoles. The Heisenberg equations are solved through an iterative technique for both atomic and field operators in the medium-assisted electromagnetic field quantization scheme. We analyze, in particular, how the time evolution of the interaction energy depends on the optical properties of the surface, in particular on the dispersion relation of surface plasmon polaritons. The physical significance and the limits of validity of the obtained results are discussed in detail.
Y1  - 2014
U6  - https://doi.org/10.1103/PhysRevA.89.022509
SN  - 1050-2947
SN  - 1094-1622
VL  - 89
IS  - 2
PB  - American Physical Society
CY  - College Park
ER  - 
TY  - JOUR
A1  - Schreck, Simon
A1  - Pietzsch, Annette
A1  - Kunnus, Kristjan
A1  - Kennedy, Brian
A1  - Quevedo, Wilson
A1  - Miedema, Piter S.
A1  - Wernet, Philippe
A1  - Föhlisch, Alexander
T1  - Dynamics of the OH group and the electronic structure of liquid alcohols
JF  - Structural dynamics
N2  - In resonant inelastic soft x-ray scattering (RIXS) from molecular and liquid systems, the interplay of ground state structural and core-excited state dynamical contributions leads to complex spectral shapes that partially allow for ambiguous interpretations. In this work, we dissect these contributions in oxygen K-edge RIXS from liquid alcohols. We use the scattering into the electronic ground state as an accurate measure of nuclear dynamics in the intermediate core-excited state of the RIXS process. We determine the characteristic time in the core-excited state until nuclear dynamics give a measurable contribution to the RIXS spectral profiles to tau(dyn) = 1.2 +/- 0.8 fs. By detuning the excitation energy below the absorption resonance we reduce the effective scattering time below sdyn, and hence suppress these dynamical contributions to a minimum. From the corresponding RIXS spectra of liquid methanol, we retrieve the "dynamic-free" density of states and find that it is described solely by the electronic states of the free methanol molecule. From this and from the comparison of normal and deuterated methanol, we conclude that the split peak structure found in the lone-pair emission region at non-resonant excitation originates from dynamics in the O-H bond in the core-excited state. We find no evidence that this split peak feature is a signature of distinct ground state structural complexes in liquid methanol. However, we demonstrate how changes in the hydrogen bond coordination within the series of linear alcohols from methanol to hexanol affect the split peak structure in the liquid alcohols. (C) 2014 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.
Y1  - 2014
U6  - https://doi.org/10.1063/1.4897981
SN  - 2329-7778
VL  - 1
IS  - 5
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - JOUR
A1  - Richter, Marcel
A1  - Zakrevskyy, Yuriy
A1  - Eisele, Michael
A1  - Lomadze, Nino
A1  - Santer, Svetlana
A1  - von Klitzing, Regine
T1  - Effect of pH, co-monomer content, and surfactant structure on the swelling behavior of microgel-azobenzene-containing surfactant complex
JF  - Polymer : the international journal for the science and technology of polymers
N2  - The contraction/swelling transition of anionic PNIPAM-co-AAA particles can be manipulated by light using interactions with cationic azobenzene-containing surfactant. In this study the influence of pH-buffers and their concentrations, the charge density (AAA content) in microgel particles as well as the spacer length of the surfactant on the complex formation between the microgel and surfactant is investigated. It is shown that the presence of pH buffer can lead to complete blocking of the interactions in such complexes and the resulting microgel contraction/swelling response. There is a clear competition between the buffer ions and the surfactant molecules interacting with microgel particles. When working in pure water solutions with fixed concentration (charge density) of microgel, the contraction/swelling of the particles is controlled only by relative concentration (charge ratio) of the surfactant and AAA groups of the microgel. Furthermore, the particle contraction is more efficient for shorter spacer length of the surfactant. The onset point of the contraction process is not affected by the surfactant hydrophobicity. This work provides new insight into the interaction between microgel particles and photo-sensitive surfactants, which offers high potential in new sensor systems. (C) 2014 Elsevier Ltd. All rights reserved.
KW  - Hydrogel
KW  - Photosensitive surfactant
KW  - PNIPAM
Y1  - 2014
U6  - https://doi.org/10.1016/j.polymer.2014.10.027
SN  - 0032-3861
SN  - 1873-2291
VL  - 55
IS  - 25
SP  - 6513
EP  - 6518
PB  - Elsevier
CY  - Oxford
ER  - 
TY  - JOUR
A1  - Gehrig, Dominik W.
A1  - Roland, Steffen
A1  - Howard, Ian A.
A1  - Kamm, Valentin
A1  - Mangold, Hannah
A1  - Neher, Dieter
A1  - Laquai, Frederic
T1  - Efficiency-limiting processes in low-bandgap polymer:Perylene diimide photovoltaic blends
JF  - The journal of physical chemistry : C, Nanomaterials and interfaces
N2  - The charge generation and recombination processes following photo-excitation of a low-bandgap polymer:perylene diimide photovoltaic blend are investigated by transient absorption pump-probe spectroscopy covering a dynamic range from femto-to microseconds to get insight into the efficiency-limiting photophysical processes. The several tens of picoseconds, and its efficiency is only half of that in a polymer:fullerene photoinduced electron transfer from the polymer to the perylene acceptor takes up to blend. This reduces the short-circuit current. Time-delayed collection field experiments reveal that the subsequent charge separation is strongly field-dependent, limiting the fill factor and lowering the short-circuit current in polymer:PDI devices. Upon excitation of the acceptor in the low-bandgap polymer blend, the PDI exciton undergoes charge transfer on a time scale of several tens of picoseconds. However, a significant fraction of the charges generated at the interface are quickly lost because of fast geminate recombination. This reduces the short-circuit current even further, leading to a scenario in which only around 2596 of the initial photoexcitations generate free charges that can potentially contribute to the photocurrent. In summary, the key photophysical limitations of perylene diimide as an acceptor in low-bandgap polymer blends appear at the interface between the materials, with the kinetics of both charge generation and separation inhibited as compared to that of fullerenes.
Y1  - 2014
U6  - https://doi.org/10.1021/jp503366m
SN  - 1932-7447
VL  - 118
IS  - 35
SP  - 20077
EP  - 20085
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Vandewal, Koen
A1  - Albrecht, Steve
A1  - Hoke, Eric T.
A1  - Graham, Kenneth R.
A1  - Widmer, Johannes
A1  - Douglas, Jessica D.
A1  - Schubert, Marcel
A1  - Mateker, William R.
A1  - Bloking, Jason T.
A1  - Burkhard, George F.
A1  - Sellinger, Alan
A1  - Frechet, Jean M. J.
A1  - Amassian, Aram
A1  - Riede, Moritz K.
A1  - McGehee, Michael D.
A1  - Neher, Dieter
A1  - Salleo, Alberto
T1  - Efficient charge generation by relaxed charge-transfer states at organic interfaces
JF  - Nature materials
N2  - carriers on illumination. Efficient organic solar cells require a high yield for this process, combined with a minimum of energy losses. Here, we investigate the role of the lowest energy emissive interfacial charge-transfer state (CT1) in the charge generation process. We measure the quantum yield and the electric field dependence of charge generation on excitation of the charge-transfer (CT) state manifold viaweakly allowed, low-energy optical transitions. For a wide range of photovoltaic devices based on polymer: fullerene, small-molecule:C-60 and polymer: polymer blends, our study reveals that the internal quantum efficiency (IQE) is essentially independent of whether or not D, A or CT states with an energy higher than that of CT1 are excited. The best materials systems show an IQE higher than 90% without the need for excess electronic or vibrational energy.
Y1  - 2014
U6  - https://doi.org/10.1038/NMAT3807
SN  - 1476-1122
SN  - 1476-4660
VL  - 13
IS  - 1
SP  - 63
EP  - 68
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - JOUR
A1  - Albrecht, Steve
A1  - Grootoonk, Bjorn
A1  - Neubert, Sebastian
A1  - Roland, Steffen
A1  - Wordenweber, Jan
A1  - Meier, Matthias
A1  - Schlatmann, Rutger
A1  - Gordijn, Aad
A1  - Neher, Dieter
T1  - Efficient hybrid inorganic/organic tandem solar cells with tailored recombination contacts
JF  - Solar energy materials & solar cells : an international journal devoted to photovoltaic, photothermal, and photochemical solar energy conversion
N2  - In this work, the authors present a 7.5% efficient hybrid tandem solar cell with the bottom cell made of amorphous silicon and a Si-PCPDTBT:PC70BM bulk heterojunction top cell. Loss-free recombination contacts were realized by combing Al-doped ZnO with either the conducting polymer composite PEDOT:PSS or with a bilayer of ultrathin Al and MoO3. Optimization of these contacts results in tandem cells with high fill factors of 70% and an open circuit voltage close to the sum of those of the sub-cells. This is the best efficiency reported for this type of hybrid tandem cell so far. Optical and electrical device modeling suggests that the efficiency can be increased to similar to 12% on combining a donor polymer with suitable absorption onset with PCBM. We also describe proof-of-principle studies employing light trapping in hybrid tandem solar cells, suggesting that this device architecture has the potential to achieve efficiencies well above 12%. (C) 2014 Elsevier B.V. All rights reserved.
KW  - Hybrid solar cells
KW  - Tandem solar cells
KW  - Organic solar cells
KW  - Bulk heterojunction
KW  - Efficiency optimization
Y1  - 2014
U6  - https://doi.org/10.1016/j.solmat.2014.04.020
SN  - 0927-0248
SN  - 1879-3398
VL  - 127
SP  - 157
EP  - 162
PB  - Elsevier
CY  - Amsterdam
ER  - 
TY  - JOUR
A1  - Bronner, Christopher
A1  - Utecht, Manuel Martin
A1  - Haase, Anton
A1  - Saalfrank, Peter
A1  - Klamroth, Tillmann
A1  - Tegeder, Petra
T1  - Electronic structure changes during the surface-assisted formation of a graphene nanoribbon
JF  - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr
N2  - High conductivity and a tunability of the band gap make quasi-one-dimensional graphene nanoribbons (GNRs) highly interesting materials for the use in field effect transistors. Especially bottom-up fabricated GNRs possess well-defined edges which is important for the electronic structure and accordingly the band gap. In this study we investigate the formation of a sub-nanometer wide armchair GNR generated on a Au(111) surface. The on-surface synthesis is thermally activated and involves an intermediate non-aromatic polymer in which the molecular precursor forms polyanthrylene chains. Employing angle-resolved two-photon photoemission in combination with density functional theory calculations we find that the polymer exhibits two dispersing states which we attribute to the valence and the conduction band, respectively. While the band gap of the non-aromatic polymer obtained in this way is relatively large, namely 5.25 +/- 0.06 eV, the gap of the corresponding aromatic GNR is strongly reduced which we attribute to the different degree of electron delocalization in the two systems.
Y1  - 2014
U6  - https://doi.org/10.1063/1.4858855
SN  - 0021-9606
SN  - 1089-7690
VL  - 140
IS  - 2
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - JOUR
A1  - Cherstvy, Andrey G.
A1  - Teif, Vladimir B.
T1  - Electrostatic effect of H1-histone protein binding on nucleosome repeat length
JF  - Physical biology : a journal for the fundamental understanding of biological systems
N2  - Within a simple biophysical model we describe the effect of electrostatic binding of H1 histone proteins on the nucleosome repeat length in chromatin. The length of wrapped DNA optimizes its binding energy to the histone core and the elastic energy penalty of DNA wrapping. The magnitude of the effect predicted from our model is in agreement with the systematic experimental data on the linear variation of nucleosome repeat lengths with H1/nucleosome ratio (Woodcock C L et al 2006 Chromos. Res. 14 17-25). We compare our model to the data for different cell types and organisms, with a widely varying ratio of bound H1 histones per nucleosome. We underline the importance of this non-specific histone-DNA charge-balance mechanism in regulating the positioning of nucleosomes and the degree of compaction of chromatin fibers in eukaryotic cells.
KW  - electrostatics
KW  - DNA
KW  - nucleosome
Y1  - 2014
U6  - https://doi.org/10.1088/1478-3975/11/4/044001
SN  - 1478-3967
SN  - 1478-3975
VL  - 11
IS  - 4
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  -