TY  - JOUR
A1  - Barkai, Eli
A1  - Garini, Yuval
A1  - Metzler, Ralf
T1  - Strange Kinetics of single molecules in living cells
JF  - Physics today
Y1  - 2012
SN  - 0031-9228
VL  - 65
IS  - 8
SP  - 29
EP  - 35
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - JOUR
A1  - Barbosa Pfannes, Eva Katharina
A1  - Theves, Matthias
A1  - Wegner, Christian
A1  - Beta, Carsten
T1  - Impact of the carbazole derivative wiskostatin on mechanical stability
 and dynamics of motile cells
JF  - JOURNAL OF MUSCLE RESEARCH AND CELL MOTILITY
N2  - Many essential functions in eukaryotic cells like phagocytosis, division, and motility rely on the dynamical properties of the actin cytoskeleton. A central player in the actin system is the Arp2/3 complex. Its activity is controlled by members of the WASP (Wiskott-Aldrich syndrome protein) family. In this work, we investigated the effect of the carbazole derivative wiskostatin, a recently identified N-WASP inhibitor, on actin-driven processes in motile cells of the social ameba . Drug-treated cells exhibited an altered morphology and strongly reduced pseudopod formation. However, TIRF microscopy images revealed that the overall cortical network structure remained intact. We probed the mechanical stability of wiskostatin-treated cells using a microfluidic device. While the total amount of F-actin in the cells remained constant, their stiffness was strongly reduced. Furthermore, wiskostatin treatment enhanced the resistance to fluid shear stress, while spontaneous motility as well as chemotactic motion in gradients of cAMP were reduced. Our results suggest that wiskostatin affects the mechanical integrity of the actin cortex so that its rigidity is reduced and actin-driven force generation is impaired.
KW  - Actin dynamics
KW  - Wiskostatin
KW  - Dictyostelium discoideum
Y1  - 2012
U6  - https://doi.org/10.1007/s10974-012-9287-8
SN  - 0142-4319
VL  - 33
IS  - 2
SP  - 95
EP  - 106
PB  - SPRINGER
CY  - DORDRECHT
ER  - 
TY  - JOUR
A1  - Baranac-Stojanovic, Marija
A1  - Koch, Andreas
A1  - Kleinpeter, Erich
T1  - Density Functional Calculations of the Anisotropic Effects of Borazine and 1,3,2,4-Diazadiboretidine
JF  - ChemPhysChem : a European journal of chemical physics and physical chemistry
N2  - On the basis of the nucleus-independent chemical shift (NICS) concept, the anisotropic effects of two inorganic rings, namely, borazine and planar 1,3,2,4-diazadiboretidine, are quantitatively calculated and visualized as isochemical shielding surfaces (ICSSs). Dissection of magnetic shielding values along the three Cartesian axes into contributions from s and p bonds by the natural chemical shieldingnatural bond orbital (NCSNBO) method revealed that their appearance is not a simple reflection of the extent of (anti)aromaticity.
KW  - anisotropic effects
KW  - aromaticity
KW  - B,N heterocycles
KW  - density functional calculations
KW  - NMR spectroscopy
Y1  - 2012
U6  - https://doi.org/10.1002/cphc.201200732
SN  - 1439-4235
VL  - 13
IS  - 17
SP  - 3803
EP  - 3811
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Baranac-Stojanovic, Marija
A1  - Koch, Andreas
A1  - Kleinpeter, Erich
T1  - Is the conventional interpretation of the anisotropic effects of C=C double bonds and aromatic rings in NMR spectra in terms of the p-electron shielding/deshielding contributions correct?
JF  - Chemistry - a European journal
N2  - Based on the nucleus-independent chemical shift (NICS) concept, isotropic magnetic shielding values have been computed along the three Cartesian axes for ethene, cyclobutadiene, benzene, naphthalene, and benzocyclobutadiene, starting from the molecular/ring center up to 10 angstrom away. These through-space NMR spectroscopic shielding (TSNMRS) values, which reflect the anisotropic effects, have been broken down into contributions from localized- and canonical molecular orbitals (LMOs and CMOs); these contributions revealed that the proton NMR spectroscopic chemical shifts of nuclei that are spatially close to the C?C double bond or the aromatic ring should not be explained in terms of the conventionally accepted p-electron shielding/deshielding effects. In fact, these effects followed the predictions only for the antiaromatic cyclobutadiene ring.
KW  - ab initio calculations
KW  - anisotropic effects
KW  - NMR spectroscopy
KW  - nucleus-independent chemical shift
KW  - pi interactions
Y1  - 2012
U6  - https://doi.org/10.1002/chem.201101882
SN  - 0947-6539
VL  - 18
IS  - 1
SP  - 370
EP  - 376
PB  - Wiley-Blackwell
CY  - Malden
ER  - 
TY  - JOUR
A1  - Bang, Guri
A1  - Hovi, Jon
A1  - Sprinz, Detlef F.
T1  - US presidents and the failure to ratify multilateral environmental agreements
JF  - Climate policy
N2  - Whereas the US President signed the Kyoto Protocol, the failure of the US Congress to ratify it seriously hampered subsequent international climate cooperation. This recent US trend, of signing environmental treaties but failing to ratify them, could thwart attempts to come to a future climate agreement. Two complementary explanations of this trend are proposed. First, the political system of the US has distinct institutional features that make it difficult for presidents to predict whether the Senate will give its advice and consent to multilateral environmental agreements (MEAs) and whether Congress will pass the required enabling legislation. Second, elected for a fixed term, US presidents might benefit politically from supporting MEAs even when knowing that legislative support is not forthcoming. Four policy implications are explored, concerning the scope for unilateral presidential action, the potential for bipartisan congressional support, the effectiveness of a treaty without the US, and the prospects for a deep, new climate treaty.
 Policy relevance
 Why does the failure of US ratification of multilateral environmental treaties occur? This article analyses the domestic political mechanisms involved in cases of failed US ratification. US non-participation in global environmental institutions often has serious ramifications. For example, it sharply limited Kyoto's effectiveness and seriously hampered international climate negotiations for years. Although at COP 17 in Durban the parties agreed to negotiate a new agreement by 2015, a new global climate treaty may well trigger a situation resembling the one President Clinton faced in 1997 when he signed Kyoto but never obtained support for it in the Senate. US failure to ratify could thwart future climate agreements.
KW  - enabling legislation
KW  - environmental treaties
KW  - Kyoto Protocol
KW  - political processes
KW  - ratification
KW  - United States
Y1  - 2012
U6  - https://doi.org/10.1080/14693062.2012.699788
SN  - 1469-3062
VL  - 12
IS  - 6
SP  - 755
EP  - 763
PB  - Routledge, Taylor & Francis Group
CY  - Abingdon
ER  - 
TY  - JOUR
A1  - Banerjee, Shiladitya
A1  - Kröner, Dominik
A1  - Saalfrank, Peter
T1  - Resonance Raman and vibronic absorption spectra with Duschinsky rotation from a time-dependent perspective application to beta-carotene
JF  - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr
N2  - The time-dependent approach to electronic spectroscopy, as popularized by Heller and co-workers in the 1980s, is applied here in conjunction with linear-response, time-dependent density functional theory to study vibronic absorption and resonance Raman spectra of beta-carotene, with and without a solvent. Two-state models, the harmonic and the Condon approximations are used in order to do so. A new code has been developed which includes excited state displacements, vibrational frequency shifts, and Duschinsky rotation, i.e., mode mixing, for both non-adiabatic spectroscopies. It is shown that Duschinsky rotation has a pronounced effect on the resonance Raman spectra of beta-carotene. In particular, it can explain a recently found anomalous behaviour of the so-called nu(1) peak in resonance Raman spectra [N. Tschirner, M. Schenderlein, K. Brose, E. Schlodder, M. A. Mroginski, C. Thomsen, and P. Hildebrandt, Phys. Chem. Chem. Phys. 11, 11471 (2009)], which shifts with the change in excitation wavelength.
Y1  - 2012
U6  - https://doi.org/10.1063/1.4748147
SN  - 0021-9606
VL  - 137
IS  - 22
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - JOUR
A1  - Bande, Alejandro
A1  - Horton, Brian K.
A1  - Ramirez, Juan C.
A1  - Mora, Andres
A1  - Parra, Mauricio
A1  - Stockli, Daniel F.
T1  - Clastic deposition, provenance, and sequence of Andean thrusting in the frontal Eastern Cordillera and Llanos foreland basin of Colombia
JF  - Geological Society of America bulletin
N2  - Sedimentological, provenance, and detrital thermochronological results for basin fill at the modern deformation front of the northern Andes (6 degrees N latitude) provide a long-term, Eocene to Pliocene record of foreland-basin sedimentation along the Eastern Cordillera !Janos basin boundary in Colombia. Lithofacies assemblages and paleocurrent orientations in the upward-coarsening, 5-km-thick succession of the Nunchia syncline reveal a systematic shift from craton-derived, shallow-marine distal foreland (back-bulge) accumulation in the Mirador Formation, to orogen-sourced, deltaic, and coastalinfluenced sedimentation of the distal to medial foreland (foredeep) in the Carbonera and Leon Formations, to anastomosing fluvial and distributive braided fluvial megafan systems of the proximal foreland (foredeep to wedge-top) basin in the lower and upper Guayabo Formation. These changes in depositional processes and sediment dispersal are supported by up-section variations in detrital zircon U-Pb and (U-Th)/He ages that record exhumation of evolving, compartmentalized sediment source areas in the Eastern Cordillera. The data are interpreted in terms of a progressive eastward advance in foldand-thrust deformation, with late Eocene Oligocene deformation in the axial zone of the Eastern Cordillera along the western edge of Floresta basin (Soapaga thrust), early Miocene reactivation (inversion) of the eastern margin of the Mesozoic rift system (Pajarito and Guaicaramo thrusts), and middle late Miocene propagation of a footwall shortcut fault (Vopal thrust) that created the Nunchia syncline in a wedge-top (piggyback) setting of the eastern foothills along the transition from the Eastern Cordillera to Harms foreland basin. Collectively, the data presented here for the frontal Eastern Cordillera define a general in-sequence pattern of eastwardadvancing fold-and-thrust deformation during Cenozoic east-west shortening in the Colombian Andes.
Y1  - 2012
U6  - https://doi.org/10.1130/B30412.1
SN  - 0016-7606
VL  - 124
IS  - 1-2
SP  - 59
EP  - 76
PB  - American Institute of Physics
CY  - Boulder
ER  - 
TY  - JOUR
A1  - Balderjahn, Ingo
A1  - Peyer, Mathias
T1  - Das Bewusstsein für fairen Konsum : Konzeptualisierung, Messung und Wirkung
JF  - Die Betriebswirtschaft : DBW
N2  - Die vorliegende Arbeit fokussiert auf den fairen Konsum als Teil des ethischen Konsums. Unter fairem Konsum verstehen wir Kaufentscheidungen, die unter Berücksichtigung der Einhaltung fairer Arbeits- und Geschäftsbedingungen bei der Herstellung von Produkten erfolgen. Unter Einsatz einer neu entwickelten Skala zur Messung des fairen Konsumbewusstseins können wir empirisch nachweisen, dass Produkte mit einem Fairtrade-Siegel Konsumenten einen moralischen Zusatznutzen vermitteln können, für den sie bereit sind, einen Mehrpreis zu zahlen.
N2  - The present paper focuses on fair consumption, as a part of ethical consumerism. Fair consumption means purchasing decisions made in the light of compliance with fair labor and business conditions in the manufacturing process. Using a new developed scale for the measurement of the consciousness for fair consumption, we can prove empirically that fair trade products can provide an additional moral value for consumers for which they are willingly to pay an extra charge.
T2  - The consciousness for fair consumption : conceptualization, measuring, and impacts
KW  - Conjoint Analyse
KW  - Consumer Social Responsibility
KW  - ethischer Konsum
KW  - faires Konsumbewusstsein
KW  - Fairtrade
KW  - Strukturgleichungsmodelle
KW  - Zahlungsbereitschaft
KW  - Conjoint analysis
KW  - consciousness for fair consumption
KW  - consumer social responsibility
KW  - ethical consumerism
KW  - fairtrade
KW  - structural equation modeling
KW  - willingness-to-pay
Y1  - 2012
SN  - 0342-7064
VL  - 72
IS  - 4
SP  - 343
EP  - 364
PB  - Schäffer-Poeschel
CY  - Stuttgart
ER  - 
TY  - JOUR
A1  - Balci, Kubilay
A1  - Yapar, G.
A1  - Akkaya, Y.
A1  - Akyuz, S.
A1  - Koch, Andreas
A1  - Kleinpeter, Erich
T1  - A conformational analysis and vibrational spectroscopic investigation on 1,2-bis(o-carboxyphenoxy) ethane molecule
JF  - Vibrational spectroscopy : an international journal devoted to applications of infrared and raman spectroscopy
N2  - The minima on the potential energy surface of 1,2-bis(o-carboxyphenoxy)ethane (CPE) molecule in its electronic ground state were searched by a molecular dynamics simulation performed with MM2 force field. For each of the found minimum-energy conformers, the corresponding equilibrium geometry, charge distribution, HOMO-LUMO energy gap, force field, vibrational normal modes and associated IR and Raman spectral data were determined by means of the density functional theory (DFT) based electronic structure calculations carried out by using B3LYP method and various Pople-style basis sets. The obtained theoretical data confirmed the significant effects of the intra- and inter-molecular hydrogen bonding interactions on the conformational structure, force field, and group vibrations of the molecule. The same data have also revealed that two of the determined stable conformers, both of which exhibit pseudo-crown structure, are considerably more favorable in energy to the others and accordingly provide the major contribution to the experimental spectra of CPE. In the light of the improved vibrational spectral data obtained within the "SQM FF" methodology and "Dual Scale Factors" approach for the monomer and dimer forms of these two conformers, a reliable assignment of the fundamental bands observed in the experimental room-temperature IR and Raman spectra of the molecule was given, and the sensitivities of its group vibrations to conformation, substitution and dimerization were discussed.
KW  - Glycol podands
KW  - Salicylic acid
KW  - IR and Raman spectra
KW  - SQM FF
KW  - Dual Scale Factors
Y1  - 2012
U6  - https://doi.org/10.1016/j.vibspec.2011.11.011
SN  - 0924-2031
VL  - 58
IS  - 1-2
SP  - 27
EP  - 43
PB  - Elsevier
CY  - Amsterdam
ER  - 
TY  - JOUR
A1  - Balazadeh, Salma
A1  - Jaspert, Nils
A1  - Arif, Muhammad
A1  - Müller-Röber, Bernd
A1  - Maurino, Veronica G.
T1  - Expression of ROS-responsive genes and transcription factors after metabolic formation of H2O2 in chloroplasts
JF  - Frontiers in plant science
N2  - Glycolate oxidase (GO) catalyses the oxidation of glycolate to glyoxylate, thereby consuming O-2 and producing H2O2. In this work, Arabidopsis thaliana plants expressing GO in the chloroplasts (GO plants) were used to assess the expressional behavior of reactive oxygen species (ROS)-responsive genes and transcription factors (TFs) after metabolic induction of H2O2 formation in chloroplasts. In this organelle, GO uses the glycolate derived from the oxygenase activity of RubisCO. Here, to identify genes responding to an abrupt production of H2O2 in chloroplasts we used quantitative real-time PCR (qRT-PCR) to test the expression of 187 ROS-responsive genes and 1880 TFs after transferring GO and wild-type (WT) plants grown at high CO2 levels to ambient CO2 concentration. Our data revealed coordinated expression changes of genes of specific functional networks 0.5 h after metabolic induction of H2O2 production in GO plants, including the induction of indole glucosinolate and camalexin biosynthesis genes. Comparative analysis using available microarray data suggests that signals for the induction of these genes through H2O2 may originate in the chloroplast. The TF profiling indicated an up-regulation in GO plants of a group of genes involved in the regulation of proanthocyanidin and anthocyanin biosynthesis. Moreover, the upregulation of expression of IF and IF interacting proteins affecting development (e.g., cell division, stem branching, flowering time, flower development) would impact growth and reproductive capacity, resulting in altered development under conditions that promote the formation of H2O2.
KW  - glycolate oxidase
KW  - H2O2
KW  - ROS-responsive genes
KW  - transcription factors
Y1  - 2012
U6  - https://doi.org/10.3389/fpls.2012.00234
SN  - 1664-462X
VL  - 3
PB  - Frontiers Research Foundation
CY  - Lausanne
ER  - 
TY  - JOUR
A1  - Baibolatov, Yernur
A1  - Spahn, Frank
T1  - The role of adhesion for ensembles of mesoscopic particles
JF  - Granular matter
N2  - We present a toy-model for an ensemble of adhering mesoscopic constituents in order to estimate the effect of the granular temperature on the sizes of embedded aggregates. The major goal is to illustrate the relation between the mean aggregate size and the granular temperature in dense planetary rings. For sake of simplicity we describe the collective behavior of the ensemble by means of equilibrium statistical mechanics, motivated by the stationary temperature established by the balance between a Kepler-shear driven viscous heating and inelastic cooling in these cosmic granular disks. The ensemble consists of N' equal constituents which can form cluster(s) or move like a gas-or both phases may coexist-depending on the (granular) temperature of the system. We assume the binding energy levels of a cluster E-c = -N-c gamma a to be determined by a certain contact number N-c, given by the configuration of N constituents of the aggregate (energy per contact: -gamma a). By applying canonical and grand-canonical ensembles, we show that the granular temperature T of a gas of constituents (their mean kinetic energy) controls the size distribution of the aggregates. They are the smaller the higher the granular temperature T is. A mere gas of single constituents is sustained for T >> gamma a. In the case of large clusters (low temperatures T << gamma a) the size distribution becomes a Poissonian.
KW  - Adhesion
KW  - Statistical mechanics
KW  - Planetary rings
Y1  - 2012
U6  - https://doi.org/10.1007/s10035-012-0325-4
SN  - 1434-5021
VL  - 14
IS  - 2
SP  - 197
EP  - 202
PB  - Springer
CY  - New York
ER  - 
TY  - JOUR
A1  - Baer-Henney, Dinah
A1  - van de Vijver, Ruben
T1  - Der Erwerb von Alternationen im Deutschen
Y1  - 2012
ER  - 
TY  - JOUR
A1  - Aydelott, Jennifer
A1  - Baer-Henney, Dinah
A1  - Trzaskowski, Maciej
A1  - Leech, Robert
A1  - Dick, Frederic
T1  - Sentence comprehension in competing speech dichotic sentence-word priming reveals hemispheric differences in auditory semantic processing
JF  - Language and cognitive processes
N2  - This study examined the effects of competing speech on auditory semantic comprehension using a dichotic sentence-word priming paradigm. Lexical decision performance for target words presented in spoken sentences was compared in strongly and weakly biasing semantic contexts. Targets were either congruent or incongruent with the sentential bias. Sentences were presented to one auditory channel (right or left), either in isolation or with competing speech produced by a single talker of the same gender presented simultaneously. The competing speech signal was either presented in the same auditory channel as the sentence context, or in a different auditory channel, and was either meaningful (played forward) or unintelligible (time-reversed).
 Biasing contexts presented in isolation facilitated responses to congruent targets and inhibited responses to incongruent targets, relative to a neutral baseline. Facilitation priming was reduced or eliminated by competing speech presented in the same auditory channel, supporting previous findings that semantic activation is highly sensitive to the intelligibility of the context signal. Competing speech presented in a different auditory channel affected facilitation priming differentially depending upon ear of presentation, suggesting hemispheric differences in the processing of the attended and competing signals. Results were consistent with previous claims of a right ear advantage for meaningful speech, as well as with visual word recognition findings implicating the left hemisphere in the generation of semantic predictions and the right hemisphere in the integration of newly encountered words into the sentence-level meaning. Unlike facilitation priming, inhibition was relatively robust to the energetic and informational masking effects of competing speech and was not influenced by the strength of the contextual bias or the meaningfulness of the competing signal, supporting a two-process model of sentence priming in which inhibition reflects later-stage, expectancy-driven strategic processes that may benefit from perceptual reanalysis after initial semantic activation.
KW  - Auditory language comprehension
KW  - Semantic priming
KW  - Hemispheric asymmetries
KW  - Lexical access
KW  - Multitalker environments
KW  - Competing speech
Y1  - 2012
U6  - https://doi.org/10.1080/01690965.2011.589735
SN  - 0169-0965
VL  - 27
IS  - 7-8
SP  - 1108
EP  - 1144
PB  - Wiley
CY  - Hove
ER  - 
TY  - JOUR
A1  - Awad, Duha Jawad
A1  - Koch, Andreas
A1  - Mickler, Wulfhard
A1  - Schilde, Uwe
A1  - Strauch, Peter
T1  - EPR spectroscopy of 4, 4 '-Bis(tert-butyl)-2, 2 '-bipyridine-1, 2-dithiolatocuprates(II) in host lattices with different coordination geometries
JF  - Zeitschrift für anorganische und allgemeine Chemie
N2  - A series of new heteroleptic MN2S2 transition metal complexes with M = Cu2+ for EPR measurements and as diamagnetic hosts Ni2+, Zn2+, and Pd2+ were synthesized and characterized. The ligands are N2 = 4, 4'-bis(tert-butyl)-2, 2'-bipyridine (tBu2bpy) and S2 =1, 2-dithiooxalate, (dto), 1, 2-dithiosquarate, (dtsq), maleonitrile-1, 2-dithiolate, or 1, 2-dicyanoethene-1, 2-dithiolate, (mnt). The CuII complexes were studied by EPR in solution and as powders, diamagnetically diluted in the isostructural planar [NiII(tBu2bpy)(S2)] or[PdII(tBu2bpy)(S2)] as well as in tetrahedrally coordinated[ZnII(tBu2bpy)(S2)] host structures to put steric stress on the coordination geometry of the central CuN2S2 unit. The spin density contributions for different geometries calculated from experimental parameters are compared with the electronic situation in the frontier orbital, namely in the semi-occupied molecular orbital (SOMO) of the copper complex, derived from quantum chemical calculations on different levels (EHT and DFT). One of the hosts, [NiII(tBu2bpy)(mnt)], is characterized by X-ray structure analysis to prove the coordination geometry. The complex crystallizes in a square-planar coordination mode in the monoclinic space group P21/a with Z = 4 and the unit cell parameters a = 10.4508(10) angstrom, b = 18.266(2) angstrom, c = 12.6566(12) angstrom, beta = 112.095(7)degrees. Oxidation and reductions potentials of one of the host complexes, [Ni(tBu2bpy)(mnt)], were obtained by cyclovoltammetric measurements.
KW  - 1
KW  - 2-Dithiosquarate
KW  - 1
KW  - 2-Dithiooxalate
KW  - 1
KW  - 2-Dicyanoethene-1
KW  - 2-dithiolate
KW  - 4
KW  - 4'-Bis(tert-butyl)-2
KW  - 2'-bipyridine
KW  - X-ray structure
KW  - EPR
KW  - Copper
KW  - Nickel
KW  - Zinc
Y1  - 2012
U6  - https://doi.org/10.1002/zaac.201100517
SN  - 0044-2313
VL  - 638
IS  - 6
SP  - 965
EP  - 975
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Awad, Ahmed Mahmoud Hany Aly
A1  - Gore, Rajeev
A1  - Hou, Zhe
A1  - Thomson, James
A1  - Weidlich, Matthias
T1  - An iterative approach to synthesize business process templates from
 compliance rules
JF  - INFORMATION SYSTEMS
N2  - Companies have to adhere to compliance requirements. The compliance analysis of business operations is typically a joint effort of business experts and compliance experts. Those experts need to create a common understanding of business processes to effectively conduct compliance management. In this paper, we present a technique that aims at supporting this process. We argue that process templates generated out of compliance requirements provide a basis for negotiation among business and compliance experts. We introduce a semi-automated and iterative approach to the synthesis of such process templates from compliance requirements expressed in Linear Temporal Logic (LTL). We show how generic constraints related to business process execution are incorporated and present criteria that point at underspecification. Further, we outline how such underspecification may be resolved to iteratively build up a complete specification. For the synthesis, we leverage existing work on process mining and process restructuring. However, our approach is not limited to the control-flow perspective, but also considers direct and indirect data-flow dependencies. Finally, we elaborate on the application of the derived process templates and present an implementation of our approach. (C) 2012 Elsevier Ltd. All rights reserved.
KW  - Process synthesis
KW  - Analysis of business process compliance specification
KW  - Process mining
Y1  - 2012
U6  - https://doi.org/10.1016/j.is.2012.05.001
SN  - 0306-4379
VL  - 37
IS  - 8
SP  - 714
EP  - 736
PB  - PERGAMON-ELSEVIER SCIENCE LTD
CY  - OXFORD
ER  - 
TY  - JOUR
A1  - Ast, Sandra
A1  - Rutledge, Peter J.
A1  - Todd, Matthew H.
T1  - Reversing the triazole topology in a cyclam-triazole-dye ligand gives a 10-fold brighter signal response to Zn2+ in aqueous solution
JF  - European journal of inorganic chemistry : a journal of ChemPubSoc Europe
N2  - The fluorescence response of a set of cyclam-triazole-dye ligands is controlled by the appended dye, but simple reversal of the triazole topology affords a novel probe for Zn2+ with a longer fluorescence lifetime and higher fluorescence quantum yield upon Zn2+ binding (<tau t > = 2.0 ns, Phi(f) = 0.76).
KW  - Sensors
KW  - Zinc
KW  - Click chemistry
KW  - Fluorescence
KW  - Electrochemistry
Y1  - 2012
U6  - https://doi.org/10.1002/ejic.201201072
SN  - 1434-1948
IS  - 34
SP  - 5611
EP  - 5615
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Arlen, T.
A1  - Aune, T.
A1  - Beilicke, M.
A1  - Benbow, W.
A1  - Bouvier, A.
A1  - Buckley, J. H.
A1  - Bugaev, V.
A1  - Byrum, K.
A1  - Cannon, A.
A1  - Cesarini, A.
A1  - Ciupik, L.
A1  - Collins-Hughes, E.
A1  - Connolly, M. P.
A1  - Cui, W.
A1  - Dickherber, R.
A1  - Dumm, J.
A1  - Falcone, A.
A1  - Federici, S.
A1  - Feng, Q.
A1  - Finley, J. P.
A1  - Finnegan, G.
A1  - Fortson, L.
A1  - Furniss, A.
A1  - Galante, N.
A1  - Gall, D.
A1  - Godambe, S.
A1  - Griffin, S.
A1  - Grube, J.
A1  - Gyuk, G.
A1  - Holder, J.
A1  - Huan, H.
A1  - Hughes, G.
A1  - Humensky, T. B.
A1  - Imran, A.
A1  - Kaaret, P.
A1  - Karlsson, N.
A1  - Kertzman, M.
A1  - Khassen, Y.
A1  - Kieda, D.
A1  - Krawczynski, H.
A1  - Krennrich, F.
A1  - Lee, K.
A1  - Madhavan, A. S.
A1  - Maier, G.
A1  - Majumdar, P.
A1  - McArthur, S.
A1  - McCann, A.
A1  - Moriarty, P.
A1  - Mukherjee, R.
A1  - Nelson, T.
A1  - de Bhroithe, A. O'Faolain
A1  - Ong, R. A.
A1  - Orr, M.
A1  - Otte, A. N.
A1  - Park, N.
A1  - Perkins, J. S.
A1  - Pohl, Martin
A1  - Prokoph, H.
A1  - Quinn, J.
A1  - Ragan, K.
A1  - Reyes, L. C.
A1  - Reynolds, P. T.
A1  - Roache, E.
A1  - Ruppel, J.
A1  - Saxon, D. B.
A1  - Schroedter, M.
A1  - Sembroski, G. H.
A1  - Skole, C.
A1  - Smith, A. W.
A1  - Telezhinsky, Igor O.
A1  - Tesic, G.
A1  - Theiling, M.
A1  - Thibadeau, S.
A1  - Tsurusaki, K.
A1  - Varlotta, A.
A1  - Vivier, M.
A1  - Wakely, S. P.
A1  - Ward, J. E.
A1  - Weinstein, A.
A1  - Welsing, R.
A1  - Williams, D. A.
A1  - Zitzer, B.
A1  - Pfrommer, C.
A1  - Pinzke, A.
T1  - Constraints on cosmic rays, magnetic fields, and dark matter fromgamma-ray observations of the coma cluster of galaxies with veritas and fermi
JF  - The astrophysical journal : an international review of spectroscopy and astronomical physics
N2  - Observations of radio halos and relics in galaxy clusters indicate efficient electron acceleration. Protons should likewise be accelerated and, on account of weak energy losses, can accumulate, suggesting that clusters may also be sources of very high energy (VHE; E > 100 GeV) gamma-ray emission. We report here on VHE gamma-ray observations of the Coma galaxy cluster with the VERITAS array of imaging Cerenkov telescopes, with complementing Fermi Large Area Telescope observations at GeV energies. No significant gamma-ray emission from the Coma Cluster was detected. Integral flux upper limits at the 99% confidence level were measured to be on the order of (2-5) x 10(-8) photonsm(-2) s(-1) (VERITAS, >220 GeV) and similar to 2 x 10(-6) photonsm(-2) s(-1) (Fermi, 1-3GeV), respectively. We use the gamma-ray upper limits to constrain cosmic rays (CRs) and magnetic fields in Coma. Using an analytical approach, the CR-to-thermal pressure ratio is constrained to be < 16% from VERITAS data and <1.7% from Fermi data (averaged within the virial radius). These upper limits are starting to constrain the CR physics in self-consistent cosmological cluster simulations and cap the maximum CR acceleration efficiency at structure formation shocks to be <50%. Alternatively, this may argue for non-negligible CR transport processes such as CR streaming and diffusion into the outer cluster regions. Assuming that the radio-emitting electrons of the Coma halo result from hadronic CR interactions, the observations imply a lower limit on the central magnetic field in Coma of similar to(2-5.5) mu G, depending on the radial magnetic field profile and on the gamma-ray spectral index. Since these values are below those inferred by Faraday rotation measurements in Coma (for most of the parameter space), this renders the hadronic model a very plausible explanation of the Coma radio halo. Finally, since galaxy clusters are dark matter (DM) dominated, the VERITAS upper limits have been used to place constraints on the thermally averaged product of the total self-annihilation cross section and the relative velocity of the DM particles, <sigma nu >.
KW  - cosmic rays
KW  - dark matter
KW  - galaxies: clusters: general
KW  - galaxies: clusters: individual (Coma (ACO 1656))
KW  - gamma rays: galaxies: clusters
KW  - magnetic fields
Y1  - 2012
U6  - https://doi.org/10.1088/0004-637X/757/2/123
SN  - 0004-637X
VL  - 757
IS  - 2
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Araujo, Wagner L.
A1  - Nunes-Nesi, Adriano
A1  - Nikoloski, Zoran
A1  - Sweetlove, Lee J.
A1  - Fernie, Alisdair
T1  - Metabolic control and regulation of the tricarboxylic acid cycle in photosynthetic and heterotrophic plant tissues
JF  - Plant, cell & environment : cell physiology, whole-plant physiology, community physiology
N2  - The tricarboxylic acid (TCA) cycle is a crucial component of respiratory metabolism in both photosynthetic and heterotrophic plant organs. All of the major genes of the tomato TCA cycle have been cloned recently, allowing the generation of a suite of transgenic plants in which the majority of the enzymes in the pathway are progressively decreased. Investigations of these plants have provided an almost complete view of the distribution of control in this important pathway. Our studies suggest that citrate synthase, aconitase, isocitrate dehydrogenase, succinyl CoA ligase, succinate dehydrogenase, fumarase and malate dehydrogenase have control coefficients flux for respiration of -0.4, 0.964, -0.123, 0.0008, 0.289, 0.601 and 1.76, respectively; while 2-oxoglutarate dehydrogenase is estimated to have a control coefficient of 0.786 in potato tubers. These results thus indicate that the control of this pathway is distributed among malate dehydrogenase, aconitase, fumarase, succinate dehydrogenase and 2-oxoglutarate dehydrogenase. The unusual distribution of control estimated here is consistent with specific non-cyclic flux mode and cytosolic bypasses that operate in illuminated leaves. These observations are discussed in the context of known regulatory properties of the enzymes and some illustrative examples of how the pathway responds to environmental change are given.
KW  - metabolic control analysis
KW  - metabolic regulation
KW  - respiration
KW  - Solanum lycopersicum (tomato)
KW  - TCA cycle
Y1  - 2012
U6  - https://doi.org/10.1111/j.1365-3040.2011.02332.x
SN  - 0140-7791
VL  - 35
IS  - 1
SP  - 1
EP  - 21
PB  - Wiley-Blackwell
CY  - Hoboken
ER  - 
TY  - JOUR
A1  - Apelojg, Benjamin
T1  - Recruiting - Lass den Bauch sprechen
JF  - Personalwirtschaft : Magazin für Human Resources
N2  - Personal auszuwählen ist eine verantwortungsvolle Aufgabe. Dabei ist es eigentlich ganz einfach: Bei der Entscheidung lohnt es sich, seinen Gefühlen zu vertrauen.
KW  - Personalauswahl
KW  - Bauchentscheidungen
Y1  - 2012
SN  - 0341-4698
VL  - 39
IS  - 5
SP  - 59
EP  - 62
PB  - F.A.Z.Buisness Media
CY  - Frankfurt am Main
ER  - 
TY  - JOUR
A1  - Apel, Jens K.
A1  - Cangelosi, Angelo
A1  - Ellis, Rob
A1  - Goslin, Jeremy
A1  - Fischer, Martin H.
T1  - Object affordance influences instruction span
JF  - Experimental brain research
N2  - We measured memory span for assembly instructions involving objects with handles oriented to the left or right side. Right-handed participants remembered more instructions when objects' handles were spatially congruent with the hand used in forthcoming assembly actions. No such affordance-based memory benefit was found for left-handed participants. These results are discussed in terms of motor simulation as an embodied rehearsal mechanism.
KW  - Action simulation
KW  - Affordance
KW  - Embodied cognition
KW  - Rehearsal
KW  - Sequential instruction
KW  - Working memory
Y1  - 2012
U6  - https://doi.org/10.1007/s00221-012-3251-0
SN  - 0014-4819
VL  - 223
IS  - 2
SP  - 199
EP  - 206
PB  - Springer
CY  - New York
ER  -