TY  - JOUR
A1  - Löbbicke, Ruben
A1  - Chanana, Munish
A1  - Schlaad, Helmut
A1  - Pilz-Allen, Christine
A1  - Günter, Christina
A1  - Möhwald, Helmuth
A1  - Taubert, Andreas
T1  - Polymer Brush Controlled Bioinspired Calcium Phosphate Mineralization and Bone Cell Growth
JF  - Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences
N2  - Polymer brushes on thiol-modified gold surfaces were synthesized by using terminal thiol groups for the surface initiated free radical polymerization of methacrylic acid and dimethylaminotheyl methacrylate, respectively. Atomic force microscopy shows that the resulting poly(methacrylic acid (PMAA) and poly(dimethylaminothyl methacrylate) (PDM- AEMA) brushes are homogeneous. Contact angle measurements show that the brushes are pH responsive and can reversibly be protonated and deprotonated. Mineralization of the brushes with calcium phosphate at different pH yields homogeneously mineralized surfaces, and preosteoblastic cells proliferate-on be number of living cells on the mineralized hybrid surface is ca. 3 times (P corresponding nonmineralized brushes.
Y1  - 2011
U6  - https://doi.org/10.1021/bm200991b
SN  - 1525-7797
VL  - 12
IS  - 10
SP  - 3753
EP  - 3760
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Yuan, Jiayin
A1  - ten Brummelhuis, Niels
A1  - Junginger, Mathias
A1  - Xie, Zailai
A1  - Lu, Yan
A1  - Taubert, Andreas
A1  - Schlaad, Helmut
T1  - Diversified applications of chemically modified 1,2-Polybutadiene
JF  - Macromolecular rapid communications
N2  - Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by 1-methyl imidazole resulted in the formation of polyelectrolyte copolymers consisting of mixed units of imidazolium, bromo, and double bond. These copolymers, which were soluble in water without forming aggregates, were used as stabilizers in the heterophase polymerization of styrene and were also studied for their ionic conducting properties.
KW  - emulsion polymerization
KW  - polybutadiene
KW  - polyelectrolytes
KW  - polymer modification
KW  - ring-opening polymerization
Y1  - 2011
U6  - https://doi.org/10.1002/marc.201100254
SN  - 1022-1336
VL  - 32
IS  - 15
SP  - 1157
EP  - 1162
PB  - Wiley-Blackwell
CY  - Malden
ER  -