TY - JOUR A1 - Saalfrank, Peter A1 - Nest, Mathias A1 - Andrianov, Igor V. A1 - Klamroth, Tillmann A1 - Kroner, Dominic A1 - Beyvers, Stephanie T1 - Quantum dynamics of laser-induced desorption from metal and semiconductor surfaces, and related phenomena N2 - Recent progress towards a quantum theory of laser-induced desorption and related phenomena is reviewed, for specific examples. These comprise the photodesorption of NO from Pt(111), the scanning tunnelling microscope and laser- induced desorption and switching of H at Si(100), and the electron stimulated desorption and dissociation of CO at Ru(0001). The theoretical methods used for nuclear dynamics range from open-system density matrix theory over nonadiabatically coupled multi-state models to electron-nuclear wavepackets. Also, aspects of time-dependent spectroscopy to probe ultrafast nonadiabatic processes at surfaces will be considered for the example of two-photon photoemission of solvated electrons in ice layers on Cu(111) Y1 - 2006 UR - http://iopscience.iop.org/0953-8984/18/30/S05/pdf/0953-8984_18_30_S05.pdf U6 - https://doi.org/10.1088/0953-8984/18/30/S05 SN - 1361-648X SN - 0953-8984 VL - 18 IS - 30 SP - S1425 EP - S1459 PB - IOP Publ. CY - Bristol ER - TY - JOUR A1 - Mittal, Rupal A1 - Porcas, Richard A1 - Wucknitz, Olaf A1 - Biggs, Andy D. A1 - Browne, Ian W. A. T1 - VLBI phase-reference observations of the gravitational lens JVAS B0218+357 N2 - We present the results of phase-referenced VLBA+Effelsberg observations at five frequencies of the double-image gravitational lens WAS B0218+357, made to establish the precise registration of the A and B lensed image positions. The motivation behind these observations is to investigate the anomalous variation of the image flux-density ratio (A[B) with frequency - this ratio changes by almost a factor of two over a frequency range from 1.65 GHz to 15.35 GHz. We investigate whether frequency dependent image positions, combined with a magnification gradient across the image field, could give rise to the anomaly. Our observations confirm the variation of image flux-density ratio with frequency. The results from Our phase-reference astrometry, taken together with the lens mass model of Wucknitz et al. (2004, MNRAS, 349, 14), show that shifts of the image peaks and centroids are too small to account for the observed frequency- dependent ratio Y1 - 2006 UR - http://www.edpsciences.org/docinfos/AAS/ U6 - https://doi.org/10.1051/0004-6361:20054012 ER - TY - JOUR A1 - Li, Changpin A1 - Sun, Weigang A1 - Kurths, Jürgen T1 - Synchronization of complex dynamical networks with time delays N2 - In the present paper, two kinds of dynamical complex networks are considered. The first is that elements of every node have different time delays but all nodes in Such networks have the same time-delay vector. The second is that different nodes have different time-delay vectors, and the elements of each node also have different time delays. Corresponding synchronization theorems are established. Numerical examples show the efficiency of the derived theorems. Y1 - 2006 UR - http://www.sciencedirect.com/science/journal/03784371 U6 - https://doi.org/10.1016/j.physa.2005.07.007 SN - 0378-4371 ER - TY - JOUR A1 - Leitenberger, Wolfram A1 - Pietsch, Ullrich T1 - A monolithic Fresnel bimirror for hard X-rays and its application for coherence measurements N2 - Experiments using a simple X-ray interferometer to measure the degree of spatial coherence of hard X-rays are reported. A monolithic Fresnel bimirror is used at small incidence angles to investigate synchrotron radiation in the energy interval 5-50 keV with monochromatic and white beam. The experimental setup was equivalent to a Young's double-slit experiment for hard X-rays with slit dimensions in the micrometre range. From the high-contrast interference pattern the degree of coherence was determined. Y1 - 2007 UR - http://journals.iucr.org/s/issues/2007/02/00/wl5137/wl5137.pdf U6 - https://doi.org/10.1107/S0909049507003846 SN - 0909-0495 ER - TY - JOUR A1 - Thiel, Marco A1 - Romano, Maria Carmen A1 - Kurths, Jürgen T1 - Spurious structures in recurrence plots induced by embedding N2 - In this paper we show that delay embedding produces spurious structures in a recurrence plot (RP) that are not present in the real attractor. We analyze typical sets of simulated data, such as white noise and data from the chaotic Rossler system to show the relevance of this effect. In the second part of the paper we show that the second order Renyi entropy and the correlation dimension are dynamical invariants that can be estimated from Recurrence Plots with arbitrary embedding dimension and delay Y1 - 2006 U6 - https://doi.org/10.1007/s11071-006-2010-9 ER - TY - JOUR A1 - Tino, G. M. A1 - Cacciapuoti, L. A1 - Bongs, K. A1 - Bordé, Ch. J. A1 - Bouyer, P. A1 - Dittus, H. A1 - Ertmer, W. A1 - Görlitz, A. A1 - Inguscio, M. A1 - Landragin, A. A1 - Lemonde, P. A1 - Lämmerzahl, C. A1 - Peters, A. A1 - Rasel, E. A1 - Reichel, J. A1 - Salomon, C. A1 - Schiller, S. A1 - Schleich, W. A1 - Sengstock, K. A1 - Sterr, U. A1 - Wilkens, Martin T1 - Atom interferometers and optical atomic clocks : new quantum sensors for fundamental physics experiments in space N2 - We present projects for future space missions using new quantum devices based on ultracold atoms. They will enable fundamental physics experiments testing quantum physics, physics beyond the standard model of fundamental particles and interactions, special relativity, gravitation and general relativity. Y1 - 2007 ER - TY - JOUR A1 - Goldobin, Denis S. A1 - Pikovskij, Arkadij T1 - Effects of delayed feedback on Kuramoto transition N2 - We develop a weakly nonlinear theory of the Kuramoto transition in an ensemble of globally coupled oscillators in presence of additional time-delayed coupling terms. We show that a linear delayed feedback not only controls the transition point, but effectively changes the nonlinear terms near the transition. A purely nonlinear delayed coupling does not effect the transition point, but can reduce or enhance the amplitude of collective oscillations Y1 - 2006 UR - http://www2.yukawa.kyoto-u.ac.jp/~ptpwww/link-supplement.html U6 - https://doi.org/10.1143/PTPS.161.43 SN - 0375-9687 ER - TY - JOUR A1 - Garnier, Sebastien A1 - Laschewsky, André A1 - Storsberg, J T1 - Polymeric surfactants : novel agents with exceptional properties N2 - This article presents recent progress in the field of polymeric surfactants made of permanently amphiphilic block copolymers or of stimulus-sensitive ones. We highlight key points in the design of amphiphilic macromolecules, to yield polymer surfactants with tailor-made properties, as well as recently developed and still challenging application fields for this new class of surfactants. The efficiency boosting of amphiphilic block copolymers as co-surfactants in microemulsions is discussed, as are surface modification by polymer surfactants, and stabilization of dispersions. Moreover, the use of block copolymers in nanosciences is presented, for instance as a tool for nanomaterial fabrication, or for biomedical and cosmetic applications in bio-nanotechnology. Finally, self-assembly and applications of some newly developed "exotic" amphiphilic block copolymer structures as new surface-active materials will be highlighted Y1 - 2006 UR - http://www.tsdjournal.com/ SN - 0932-3414 ER - TY - JOUR A1 - Zhang, Ning A1 - Hayer, Anna A1 - Al-Suti, Mohammed K. A1 - Al-Belushi, Rayya A. A1 - Khan, Muhammad S. A1 - Köhler, Anna T1 - The effect of delocalization on the exchange energy in meta- and para-linked Pt-containing carbazole polymers and monomers N2 - A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of S-1, T-1, and T-n. The S-1-T-1 splitting observed for the meta-linked monomer (0.4 eV) is only half of that in the para-linked monomer (0.8 eV). Upon polymerization, the exchange energy in the para- linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds. (c) 2006 American Institute of Physics Y1 - 2006 UR - http://scitation.aip.org/getpdf/servlet/ GetPDFServlet?filetype=pdf&id=JCPSA6000124000024244701000001&idtype=cvips&doi=10.1063/1.2200351&prog=normal U6 - https://doi.org/10.1063/1.2200351 ER - TY - JOUR A1 - Boccaletti, Stefano A1 - Hwang, Dong-Uk A1 - Chavez, Mario A1 - Amann, Andreas A1 - Kurths, Jürgen A1 - Pecora, Louis M. T1 - Synchronization in dynamical networks : evolution along commutative graphs N2 - Starting from an initial wiring of connections, we show that the synchronizability of a network can be significantly improved by evolving the graph along a time dependent connectivity matrix. We consider the case of connectivity matrices that commute at all times, and compare several approaches to engineer the corresponding commutative graphs. In particular, we show that synchronization in a dynamical network can be achieved even in the case in which each individual commutative graphs does not give rise to synchronized behavior Y1 - 2006 UR - http://pre.aps.org/ U6 - https://doi.org/10.1103/Physreve.74.016102 SN - 1539-3755 ER - TY - JOUR A1 - Goldobin, Denis S. A1 - Pikovskij, Arkadij T1 - Antireliability of noise-driven neurons N2 - We demonstrate, within the framework of the FitzHugh-Nagumo model, that a firing neuron can respond to a noisy driving in a nonreliable manner: the same Gaussian white noise acting on identical neurons evokes different patterns of spikes. The effect is characterized via calculations of the Lyapunov exponent and the event synchronization correlations. We construct a theory that explains the antireliability as a combined effect of a high sensitivity to noise of some stages of the dynamics and nonisochronicity of oscillations. Geometrically, the antireliability is described by a random noninvertible one-dimensional map Y1 - 2006 UR - http://pre.aps.org/ U6 - https://doi.org/10.1103/Physreve.73.061906 SN - 1539-3755 ER - TY - JOUR A1 - Anishchenko, Vadim S. A1 - Nikolaev, S A1 - Kurths, Jürgen T1 - Winding number locking on a two-dimensional torus : synchronization of quasiperiodic motions N2 - We propose a new autonomous dynamical system of dimension N=4 that demonstrates the regime of stable two- frequency motions and period-doubling bifurcations of a two-dimensional torus. It is shown that the period-doubling bifurcation of the two-dimensional torus is not followed by the resonance phenomenon, and the two-dimensional ergodic torus undergoes a period-doubling bifurcation. The interaction of two generators is also analyzed. The phenomenon of external and mutual synchronization of two-frequency oscillations is observed, for which winding number locking on a two- dimensional torus takes place Y1 - 2006 UR - http://pre.aps.org/ U6 - https://doi.org/10.1103/Physreve.73.056202 SN - 1539-3755 ER - TY - JOUR A1 - Nolte, Guido A1 - Meinecke, Frank C. A1 - Ziehe, Andreas A1 - Müller, Klaus-Robert T1 - Identifying interactions in mixed and noisy complex systems N2 - We present a technique that identifies truly interacting subsystems of a complex system from multichannel data if the recordings are an unknown linear and instantaneous mixture of the true sources. The method is valid for arbitrary noise structure. For this, a blind source separation technique is proposed that diagonalizes antisymmetrized cross- correlation or cross-spectral matrices. The resulting decomposition finds truly interacting subsystems blindly and suppresses any spurious interaction stemming from the mixture. The usefulness of this interacting source analysis is demonstrated in simulations and for real electroencephalography data Y1 - 2006 UR - http://pre.aps.org/ U6 - https://doi.org/10.1103/Physreve.73.051913 ER - TY - JOUR A1 - Raab, Corinna A1 - Wessel, Niels A1 - Schirdewan, Alexander A1 - Kurths, Jürgen T1 - Large-scale dimension densities for heart rate variability analysis N2 - In this work, we reanalyze the heart rate variability (HRV) data from the 2002 Computers in Cardiology (CiC) Challenge using the concept of large-scale dimension densities and additionally apply this technique to data of healthy persons and of patients with cardiac diseases. The large-scale dimension density (LASDID) is estimated from the time series using a normalized Grassberger-Procaccia algorithm, which leads to a suitable correction of systematic errors produced by boundary effects in the rather large scales of a system. This way, it is possible to analyze rather short, nonstationary, and unfiltered data, such as HRV. Moreover, this method allows us to analyze short parts of the data and to look for differences between day and night. The circadian changes in the dimension density enable us to distinguish almost completely between real data and computer-generated data from the CiC 2002 challenge using only one parameter. In the second part we analyzed the data of 15 patients with atrial fibrillation (AF), 15 patients with congestive heart failure (CHF), 15 elderly healthy subjects (EH), as well as 18 young and healthy persons (YH). With our method we are able to separate completely the AF (rho(mu)(ls)=0.97 +/- 0.02) group from the others and, especially during daytime, the CHF patients show significant differences from the young and elderly healthy volunteers (CHF, 0.65 +/- 0.13; EH, 0.54 +/- 0.05; YH, 0.57 +/- 0.05; p < 0.05 for both comparisons). Moreover, for the CHF patients we find no circadian changes in rho(mu)(ls) (day, 0.65 +/- 0.13; night, 0.66 +/- 0.12; n.s.) in contrast to healthy controls (day, 0.54 +/- 0.05; night, 0.61 +/- 0.05; p=0.002). Correlation analysis showed no statistical significant relation between standard HRV and circadian LASDID, demonstrating a possibly independent application of our method for clinical risk stratification Y1 - 2006 UR - http://pre.aps.org/ U6 - https://doi.org/10.1103/Physreve.73.041907 SN - 1539-3755 ER - TY - JOUR A1 - Ilnytskyi, Jaroslav A1 - Saphiannikova, Marina A1 - Neher, Dieter T1 - Photo-induced deformations in azobenzene-containing side-chain polymers : molecular dynamics study N2 - We perform molecular dynamics simulations of azobenzene containing side-chain liquid crystalline polymer subject to an external model field that mimicks the reorientations of the azobenzenes upon irradiation with polarized light. The smectic phase of the polymer is studied with the field applied parallel to the nematic director, forcing the trans isomers to reorient perpendicularly to the field (the direction of which can be assosiated with the light polarization). The coupling between the reorientation of azobenzenes and mechanical deformation of the sample is found to depend on the field strength. In a weak field the original smectic order is melted gradually with no apparent change in the simulation box shape, whereas in a strong field two regimes are observed. During the first one a rapid melting of the liquid crystalline order is accompanied by the contraction of the polymer along the field direction (the effect similar to the one observed experimentally in azopenzene containing elastomers). During the slower second regime, the smectic layers are rebuilt to accomodate the preferential direction of chromophores perperdicular to the field. Y1 - 2006 UR - http://www.icmp.lviv.ua/journal/Contents.html SN - 1607-324X ER - TY - JOUR A1 - Heinmüller, Janine A1 - Petitjean, Patrick A1 - Ledoux, Cedric A1 - Caucci, Sara A1 - Srianand, Raghunathan T1 - Kinematics and star formation activity in the z(abs)=2.03954 damped Lyman-alpha system towards PKS 0458-020 N2 - We present UVES observations of the log N(H I) = 21.7 damped Lyman-alpha system at z(abs) = 2.03954 towards the quasar PKS 0458-020. Hi Lyman-alpha emission is detected in the center of the damped Lyman-alpha absorption trough. Metallicities are derived for Mg II, Si II, P II, Cr II, Mn II, Fe II and Zn II and are found to be -1.21 +/- 0.12, - 1.28 +/- 0.20, -1.54 +/- 0.11, -1.66 +/- 0.10, -2.05 +/- 0.11, -1.87 +/- 0.11, -1.22 +/- 0.10, respectively, relative to solar. The depletion factor is therefore of the order of [Zn/Fe] = 0.65. We observe metal absorption lines to be blueshifted compared to the Lyman-alpha emission up to a maximum of similar to 100 and 200 km s(-1) for low and high- ionization species respectively. This can be interpreted either as the consequence of rotation in a large (similar to 7 kpc) disk or as the imprint of a galactic wind. The star formation rate (SFR) derived from the Lyman-alpha emission, 1.6 M-circle dot yr(-1), is compared with that estimated from the observed C II* absorption. No molecular hydrogen is detected in our data, yielding a molecular fraction log f < -6.52. This absence of H-2 can be explained as the consequence of a high ambient UV flux which is one order of magnitude larger than the radiation field in the ISM of our Galaxy and originates in the observed emitting region Y1 - 2006 UR - http://www.aanda.org/ U6 - https://doi.org/10.1051/0004-6361:20053910 SN - 0004-6361 ER - TY - JOUR A1 - Tirok, Katrin A1 - Gaedke, Ursula T1 - Spring weather determines the relative importance of ciliates, rotifers and crustaceans for the initiation of the clear-water phase in a large, deep lake N2 - Clear-water phase (CWP) is an important event in seasonal plankton succession. We examined the influence of all herbivorous zooplankton on its initiation under different weather and climatic conditions using up to 19 years of observations from the large, deep Lake Constance (Europe) and estimates of relative clearance rates. A CWP occurred regularly, even if daphnid biomass was still very low. CWP was attributed to strong grazing either by a daphnid- dominated zooplankton community or by a diverse assemblage consisting of micro- and meso-zooplankton. Both types of zooplankton communities occurred with approximately the same frequency. The timing of the CWP was unrelated to the North Atlantic Oscillation (NAO) but correlated with the wind-dependent intensity of deep vertical mixing 3 months earlier, during early spring. Less mixing enabled early growth of phytoplankton, ciliates and rotifers despite low temperatures, which prevented daphnid development at this time. This resulted in enhanced grazing of ciliates and rotifers, which increased the importance of phytoplankton less edible for most ciliates, rotifers and daphnids. Ciliates clearly dominated the grazing pressure on phytoplankton throughout spring, maintaining high biomasses together with the phytoplankton for up to 2 months. A CWP was observed when herbivores grazing on larger phytoplankton developed in addition to ciliates Y1 - 2006 ER - TY - JOUR A1 - Brilliantov, Nikolai V. A1 - Pöschel, Thorsten T1 - Breakdown of the Sonine expansion for the velocity distribution of granular gases JF - Europhysics Letters N2 - The velocity distribution of a granular gas is analyzed in terms of the Sonine polynomials expansion. We derive an analytical expression for the third Sonine coefficient a(3). In contrast to frequently used assumptions this coefficient is of the same order of magnitude as the second Sonine coefficient a(2). For small inelasticity the theoretical result is in good agreement with numerical simulations. The next-order Sonine coefficients a(4), a(5) and a(6) are determined numerically. While these coefficients are negligible for small dissipation, their magnitude grows rapidly with increasing inelasticity for 0 < epsilon less than or similar to 0.6. We conclude that this behavior of the Sonine coefficients manifests the breakdown of the Sonine polynomial expansion caused by the increasing impact of the overpopulated high-energy tail of the distribution function Y1 - 2006 UR - http://iopscience.iop.org/0295-5075/ U6 - https://doi.org/10.1209/epl/i2005-10555-6 SN - 0295-5075 VL - 74 IS - 3 SP - 424 EP - 430 ER - TY - JOUR A1 - Cramer, Marcus A1 - Eisert, Jens A1 - Plenio, Martin B. A1 - Dreißig, Julian T1 - Entanglement-area law for general bosonic harmonic lattice systems N2 - We demonstrate that the entropy of entanglement and the distillable entanglement of regions with respect to the rest of a general harmonic-lattice system in the ground or a thermal state scale at most as the boundary area of the region. This area law is rigorously proven to hold true in noncritical harmonic-lattice systems of arbitrary spatial dimension, for general finite-ranged harmonic interactions, regions of arbitrary shape, and states of nonzero temperature. For nearest-neighbor interactions-corresponding to the Klein-Gordon case-upper and lower bounds to the degree of entanglement can be stated explicitly for arbitrarily shaped regions, generalizing the findings of Phys. Rev. Lett. 94, 060503 (2005). These higher-dimensional analogs of the analysis of block entropies in the one-dimensional case show that under general conditions, one can expect an area law for the entanglement in noncritical harmonic many-body systems. The proofs make use of methods from entanglement theory, as well as of results on matrix functions of block- banded matrices. Disordered systems are also considered. We moreover construct a class of examples for which the two- point correlation length diverges, yet still an area law can be proven to hold. We finally consider the scaling of classical correlations in a classical harmonic system and relate it to a quantum lattice system with a modified interaction. We briefly comment on a general relationship between criticality and area laws for the entropy of entanglement Y1 - 2006 UR - http://pra.aps.org/ U6 - https://doi.org/10.1103/Physreva.73.012309 ER - TY - JOUR A1 - Dana, Syamal Kumar A1 - Blasius, Bernd A1 - Kurths, Jürgen T1 - Experimental evidence of anomalous phase synchronization in two diffusively coupled Chua oscillators N2 - We study the transition to phase synchronization in two diffusively coupled, nonidentical Chua oscillators. In the experiments, depending on the used parameterization, we observe several distinct routes to phase synchronization, including states of either in-phase, out-of-phase, or antiphase synchronization, which may be intersected by an intermediate desynchronization regime with large fluctuations of the frequency difference. Furthermore, we report the first experimental evidence of an anomalous transition to phase synchronization, which is characterized by an initial enlargement of the natural frequency difference with coupling strength. This results in a maximal frequency disorder at intermediate coupling levels, whereas usual phase synchronization via monotonic decrease in frequency difference sets in only for larger coupling values. All experimental results are supported by numerical simulations of two coupled Chua models Y1 - 2006 UR - http://ojps.aip.org/chaos/ U6 - https://doi.org/10.1063/1.2197168 SN - 1054-1500 ER -