TY  - GEN
A1  - Mondal, Suvendu Sekhar
A1  - Bhunia, Asamanjoy
A1  - Demeshko, Serhiy
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Janiak, Christoph
A1  - Holdt, Hans-Jürgen
T1  - Synthesis of a Co(II)–imidazolate framework from an anionic linker precursor
BT  - gas-sorption and magnetic properties
N2  - A Co(II)–imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 235 
KW  - building-blocks
KW  - carbon-dioxide capture
KW  - exchange
KW  - ionic liquids
KW  - ionothermal synthesis
KW  - ligand
KW  - metal-organic frameworks
KW  - solvent
KW  - surface
KW  - zeolitic imidazolate frameworks
Y1  - 2013
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94424
SP  - 39
EP  - 42
ER  - 
TY  - GEN
A1  - Mondal, Suvendu Sekhar
A1  - Bhunia, Asamanjoy
A1  - Baburin, Igor A.
A1  - Jäger, Christian
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Seifert, Gotthard
A1  - Janiak, Christoph
A1  - Holdt, Hans-Jürgen
T1  - Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity
N2  - A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 233 
KW  - adsorption
KW  - capacity
KW  - carbon-dioxide capture
KW  - coordination polymer
KW  - flexibility
KW  - hydrogen storage
KW  - ligand
KW  - metal-organic frameworks
KW  - mixed-matrix membranes
KW  - separation
Y1  - 2013
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94341
SP  - 7599
EP  - 7601
ER  -