TY  - JOUR
A1  - Wessig, Pablo
A1  - Gerngroß, Maik
A1  - Pape, Simon
A1  - Bruhns, Philipp
A1  - Weber, Jens
T1  - Novel porous materials based on oligospiroketals (OSK)
JF  - RSC Advances : an international journal to further the chemical sciences
N2  - New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.
KW  - microporous organic polymers
KW  - molecular rods
KW  - construction
KW  - frameworks
KW  - membranes
KW  - sorption
KW  - models
Y1  - 2014
U6  - https://doi.org/10.1039/c4ra04437a
SN  - 2046-2069
VL  - 2014
IS  - 4
SP  - 31123
EP  - 31129
ER  -