TY  - JOUR
A1  - Schmidt, Bernd
A1  - Riemer, Martin
T1  - Synthesis of Magnaldehydes B and E and Dictyobiphenyl B by Microwave-Promoted Cross-Coupling of Boronophenols
JF  - European journal of organic chemistry
N2  - Magnaldehydes B and E along with their 4'-methylated derivatives are naturally occurring 2,4'-biphenols that have been isolated from the Magnoliaceae. Herein, these natural products have been synthesized from a common intermediate, which was obtained by a microwave-promoted, hetero-geneously catalyzed, and protecting-group-free Suzuki-Miyaura coupling reaction in an aqueous medium. These reaction conditions were also successfully applied to a one-step synthesis of the slime mold metabolite dictyobiphenyl B.
KW  - Total synthesis
KW  - Natural products
KW  - Cross-coupling
KW  - Palladium
KW  - Biaryls
KW  - Phenols
Y1  - 2015
U6  - https://doi.org/10.1002/ejoc.201500350
SN  - 1434-193X
SN  - 1099-0690
IS  - 17
SP  - 3760
EP  - 3766
PB  - Wiley-VCH
CY  - Weinheim
ER  -