TY - JOUR A1 - Pikovskij, Arkadij T1 - Transition to synchrony in chiral active particles JF - Journal of physics. Complexity N2 - I study deterministic dynamics of chiral active particles in two dimensions. Particles are considered as discs interacting with elastic repulsive forces. An ensemble of particles, started from random initial conditions, demonstrates chaotic collisions resulting in their normal diffusion. This chaos is transient, as rather abruptly a synchronous collisionless state establishes. The life time of chaos grows exponentially with the number of particles. External forcing (periodic or chaotic) is shown to facilitate the synchronization transition. KW - active particles KW - chirality KW - synchronization KW - chaos KW - transient chaos Y1 - 2021 U6 - https://doi.org/10.1088/2632-072X/abdadb SN - 2632-072X VL - 2 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Holec, Jan A1 - Rybáček, Jiří A1 - Vacek, Jaroslav A1 - Karras, Manfred A1 - Bednárová, Lucie A1 - Budesinsky, Milos A1 - Slusna, Michaela A1 - Holy, Petr A1 - Schmidt, Bernd A1 - Stará, Irena G. A1 - Starý, Ivo T1 - Chirality-Controlled Self-Assembly of Amphiphilic Dibenzo[6]helicenes into Langmuir-Blodgett Thin Films JF - Chemistry - a European journal N2 - Racemic and highly enantioenriched 3-methoxycarbonyl, 3-carboxy, and 3-hydroxymethyl derivatives of dibenzo[6]helicene were prepared. The Langmuir layers of these helicenes were formed at the air-water interface and transferred onto solid substrates to afford Langmuir-Blodgett films, which were then studied by ambient atomic force microscopy and (chir)optical spectroscopy. Significant differences were found in the behaviour of the Langmuir layers as well as in the morphology, UV/Vis, electronic circular dichroism (ECD), and fluorescence spectra of the Langmuir-Blodgett thin films depending on the molecular chirality and nature of the polar group. The experimental results were supported by molecular dynamics simulations. KW - arenes KW - chirality KW - helical structures KW - Langmuir-Blodgett films KW - self-assembly Y1 - 2019 U6 - https://doi.org/10.1002/chem.201901695 SN - 0947-6539 SN - 1521-3765 VL - 25 IS - 49 SP - 11494 EP - 11502 PB - Wiley-VCH CY - Weinheim ER -