TY  - JOUR
A1  - Anders, Janet
A1  - Sait, Connor R. J.
A1  - Horsley, Simon A. R.
T1  - Quantum Brownian motion for magnets
JF  - New journal of physics : the open-access journal for physics
N2  - Spin precession in magnetic materials is commonly modelled with the classical phenomenological Landau-Lifshitz-Gilbert (LLG) equation. Based on a quantized three-dimensional spin + environment Hamiltonian, we here derive a spin operator equation of motion that describes precession and includes a general form of damping that consistently accounts for memory, coloured noise and quantum statistics. The LLG equation is recovered as its classical, Ohmic approximation. We further introduce resonant Lorentzian system-reservoir couplings that allow a systematic comparison of dynamics between Ohmic and non-Ohmic regimes. Finally, we simulate the full non-Markovian dynamics of a spin in the semi-classical limit. At low temperatures, our numerical results demonstrate a characteristic reduction and flattening of the steady state spin alignment with an external field, caused by the quantum statistics of the environment. The results provide a powerful framework to explore general three-dimensional dissipation in quantum thermodynamics.
KW  - open quantum systems
KW  - coloured and quantum noise
KW  - memory effects
KW  - spin
KW  - dynamics
KW  - LLG equation
KW  - magnetisation
KW  - quantum thermodynamics
Y1  - 2022
U6  - https://doi.org/10.1088/1367-2630/ac4ef2
SN  - 1367-2630
VL  - 24
IS  - 3
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Koc, A.
A1  - Reinhardt, M.
A1  - von Reppert, Alexander
A1  - Rössle, Matthias
A1  - Leitenberger, Wolfram
A1  - Gleich, M.
A1  - Weinelt, M.
A1  - Zamponi, Flavio
A1  - Bargheer, Matias
T1  - Grueneisen-approach for the experimental determination of transient spin and phonon energies from ultrafast x-ray diffraction data: gadolinium
JF  - Journal of physics : Condensed matter
N2  - We study gadolinium thin films as a model system for ferromagnets with negative thermal expansion. Ultrashort laser pulses heat up the electronic subsystem and we follow the transient strain via ultrafast x-ray diffraction. In terms of a simple Grueneisen approach, the strain is decomposed into two contributions proportional to the thermal energy of spin and phonon subsystems. Our analysis reveals that upon femtosecond laser excitation, phonons and spins can be driven out of thermal equilibrium for several nanoseconds.
KW  - ultrafast
KW  - x-ray diffraction
KW  - magnetostriction
KW  - nonequilibrium
KW  - spin
KW  - phonon
KW  - rare earth
Y1  - 2017
U6  - https://doi.org/10.1088/1361-648X/aa7187
SN  - 0953-8984
SN  - 1361-648X
VL  - 29
SP  - 5884
EP  - 5891
PB  - IOP Publ. Ltd.
CY  - Bristol
ER  - 
TY  - JOUR
A1  - Schifferle, Lukas
A1  - Lobanov, Sergey S.
T1  - Evolution of chemical bonding and spin-pairing energy in ferropericlase across Its spin transition
JF  - ACS Earth and Space Chemistry
N2  - The evolution of chemical bonding in ferropericlase, (Mg,Fe)O, with pressure may affect the physical and chemical properties of the Earth's lower mantle. Here, we report high-pressure optical absorption spectra of single-crystalline ferropericlase ((Mg0.87Fe0.13)O) up to 135 GPa. Combined with a re-evaluation of published partial fluorescence yield X-ray absorption spectroscopy data, we show that the covalency of the Fe-O bond increases with pressure, but the iron spin transition at 57-76.5 GPa reverses this trend. The qualitative crossover in chemical bonding suggests that the spin-pairing transition weakens the Fe-O bond in ferropericlase. We find, that the spin transition in ferropericlase is caused by both the increase of the ligand field-splitting energy and the decrease in the spin-pairing energy of high-spin Fe2+.
KW  - high-pressure
KW  - diamond anvil cell
KW  - covalency
KW  - bond strength
KW  - iron
KW  - spin
KW  - transition
Y1  - 2022
U6  - https://doi.org/10.1021/acsearthspacechem.2c00014
SN  - 2472-3452
VL  - 6
IS  - 3
SP  - 788
EP  - 799
PB  - American Chemical Society
CY  - Washington
ER  -