TY  - JOUR
A1  - Mirskova, Anna N.
A1  - Adamovich, Sergey N.
A1  - Mirskov, Rudolf G.
A1  - Schilde, Uwe
T1  - Reaction of pharmacological active tris-(2-hydroxyethyl)ammonium
 4-chlorophenylsulfanylacetate with ZnCl2 or NiCl2: first conversion of a
 protic ionic liquid into metallated ionic liquid
JF  - CHEMISTRY CENTRAL JOURNAL
N2  - The reaction of pharmacological active protic ionic liquid tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate H+N(CH2CH2OH)(3) center dot (-OOCCH2SC6H4Cl-4) (1) with zinc or nickel chloride in a ratio of 2:1 affords stable at room temperature powder-like adducts [H+N(CH2CH2OH)(3)](2) center dot [M(OOCCH2SC6H4Cl-4)(2)Cl-2](2-), M = Zn (2), Ni (3). By recrystallization from aqueous alcohol compound 2 unexpectedly gives Zn(OOCCH2SC6H4Cl-4)(2) center dot 2H(2)O (4). Unlike 2, compound 3 gives crystals [N(CH2CH2OH)(3)](2)Ni2+ center dot [-OOCCH2SC6H4Cl-4](2) (5), which have a structure of metallated ionic liquid. The structure of 5 has been proved by X-ray diffraction analysis. It is the first example of the conversion of a protic ionic liquid into potentially biological active metallated ionic liquid (1 -> 3 -> 5).
Y1  - 2013
U6  - https://doi.org/10.1186/1752-153X-7-34
SN  - 1752-153X
VL  - 7
PB  - BIOMED CENTRAL LTD
CY  - LONDON
ER  - 
TY  - THES
A1  - Mirskova, Anna N.
A1  - Adamovich, Sergey N.
A1  - Mirskov, Rudolf G.
A1  - Schilde, Uwe
T1  - Reaction of pharmacological active tris-(2-hydroxyethyl) ammonium 4-chlorophenylsulfanylacetate with ZnCl2 or NiCl2: first conversion of a protic ionic liquid into metallated ionic liquid
Y1  - 2013
UR  - http://journal.chemistrycentral.com/content/pdf/1752-153X-7-34.pdf
U6  - https://doi.org/10.1186/1752-153X-7-34
ER  -