TY  - JOUR
A1  - Schmidt, Bernd
A1  - Elizarov, Nelli
A1  - Riemer, Nastja
A1  - Hölter, Frank
T1  - Acetamidoarenediazonium Salts: Opportunities for Multiple Arene Functionalization
JF  - European journal of organic chemistry
N2  - Unlike their ortho counterparts, meta- and para-acetamidoanilines can be converted into the corresponding acetamidoarenediazonium salts. These offer various opportunities for multiple Pd-catalyzed arene functionalization reactions, such as Matsuda-Heck-, Suzuki-Miyaura- or Fujiwara-Moritani couplings.
KW  - Arenes
KW  - Amides
KW  - C-C coupling
KW  - Cross-coupling
KW  - Palladium
Y1  - 2015
U6  - https://doi.org/10.1002/ejoc.201500795
SN  - 1434-193X
SN  - 1099-0690
IS  - 26
SP  - 5826
EP  - 5841
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Schmidt, Bernd
A1  - Elizarov, Nelli
A1  - Schilde, Uwe
A1  - Kelling, Alexandra
T1  - Dual Role of Acetanilides: Traceless Removal of a Directing Group through Deacetylation/Diazotation and Palladium-Catalyzed C-C-Coupling Reactions
JF  - The journal of organic chemistry
N2  - The acetamide group enables regioselective oxidative ortho-C-H activation reactions, such as Pd-catalyzed acylation. The synthetic utility of these transformations can be significantly enhanced by using the acetamide as a quasi-leaving group in a subsequent conventional Pd-catalyzed coupling or cross-coupling reaction. The concept is illustrated herein for the synthesis of o-alkenyl- and o-arylphenones, which have potential for the synthesis of arylated aromatic heterocycles.
Y1  - 2015
U6  - https://doi.org/10.1021/acs.joc.5b00272
SN  - 0022-3263
VL  - 80
IS  - 9
SP  - 4223
EP  - 4234
PB  - American Chemical Society
CY  - Washington
ER  -