TY - JOUR A1 - Hewawasam, Tilak A1 - von Blanckenburg, Friedhelm A1 - Bouchez, Julien A1 - Dixon, Jean L. A1 - Schüssler, Jan A. A1 - Mäkeler, Ricarda T1 - Slow advance of the weathering front during deep, supply-limited saprolite formation in the tropical Highlands of Sri Lanka JF - Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society N2 - Silicate weathering - initiated by major mineralogical transformations at the base of ten meters of clay-rich saprolite generates the exceptionally low weathering flux found in streams draining the crystalline rocks of the mountainous and humid tropical Highlands of Sri Lanka. This conclusion is reached from a thorough investigation of the mineralogical, chemical, and Sr isotope compositions of samples within a regolith profile extending >10 m from surface soil through the weathering front in charnockite bedrock (a high-grade metamorphic rock), corestones formed at the weathering front, as well as from the chemical composition of the dissolved loads in nearby streams. Weatherable minerals and soluble elements are fully depleted at the top of the profile, showing that the system is supply-limited, such that weathering fluxes are controlled directly by the supply of fresh minerals. We determine the weathering rates using two independent means: (1) in situ-produced cosmogenic nuclides in surface soil and creek sediments in the close vicinity of the regolith combined with immobile element mass balance across the regolith and (2) river dissolved loads. Silicate weathering rates determined from both approaches range from 16 to 36 t km(-2) y(-1), corresponding to a weathering front advance rate of 6-14 mm ky(-1). These rates agree across the 10(1) to 10(4) - y time scales over which our rate metrics integrate, suggesting that the weathering system operates at steady state. Within error these rates are furthermore compatible with those obtained by modeling the advance rate of the weathering front from chemical gradients and mineral dissolution rates. The silicate weathering flux out of the weathering profile, measured on small creeks, amounts to 84% of the profile's export flux; the remaining 16% is contributed by non-silicate, atmospheric-derived input. The silicate weathering flux, as measured by dissolved loads in large catchments, amounts to ca. 50% of the total dissolved flux; the remainder being contributed by dust, rain, and weathering of local marble bands. Spheroidal weathering is the key processes of converting the fresh bedrock into saprolite at the weathering front. The mineralogical composition of weathering rinds shows that the sequence of mineral decomposition is: pyroxene; plagioclase; biotite; K-feldspar. Observable biotite alteration does not appear to initiate spheroidal weathering within corestones; therefore, we infer that other processes than biotite oxidation, like pyroxene oxidation, clay formation from pyroxene and plagioclase decomposition, the development of secondary porosity by plagioclase dissolution, or even microbiologic processes at depth enable the coupling between slow advance of the weathering front and slow erosion at the surface. The comparison to tectonically more active tropical landscapes lets us conclude that the combination of hard rock with tightly interlocked mineral grains and slow erosion in the absence of tectonically-induced landscape rejuvenation lead to these exceptionally low weathering rates. (C) 2013 Elsevier Ltd. All rights reserved. Y1 - 2013 U6 - https://doi.org/10.1016/j.gca.2013.05.006 SN - 0016-7037 VL - 118 IS - 10 SP - 202 EP - 230 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Behrens, Ricarda A1 - Bouchez, Julien A1 - Schuessler, Jan A. A1 - Dultz, Stefan A1 - Hewawasam, Tilak A1 - von Blanckenburg, Friedhelm T1 - Mineralogical transformations set slow weathering rates in low-porosity metamorphic bedrock on mountain slopes in a tropical climate JF - Chemical geology : official journal of the European Association for Geochemistry N2 - In the Sri Lankan Highlands erosion and chemical weathering rates are among the lowest for global mountain denudation. In this tropical humid setting, highly weathered deep saprolite profiles have developed from high-grade metamorphic charnockite during spheroidal weathering of the bedrock. The spheroidal weathering produces rounded corestones and spalled rindlets at the rock-saprolite interface. We used detailed textural, mineralogical and chemical analyses to reconstruct the sequence of weathering reactions and their causes. The first mineral attacked by weathering was found to be pyroxene initiated by in situ Fe oxidation. Volumetric calculations suggest that this oxidation leads to the generation of porosity due to the formation of micro-fractures allowing for fluid transport and subsequent dissolution of biotite and plagioclase. The rapid ensuing plagioclase weathering leads to formation of high secondary porosity in the corestone over a distance of only a few cm and eventually to the final disaggregation of bedrock to saprolite. The first secondary phases are oxides or amorphous precipitates from which secondary minerals (mainly gibbsite, kaolinite and goethite) form. As oxidation is the first weathering reaction, the supply of O-2 is a rate-limiting factor for chemical weathering. Hence, the supply of O-2 and its consumption at depth connects processes at the weathering front with those at the Earth's surface in a feedback mechanism. The strength of the feedback depends on the relative weight of advective versus diffusive transport of O-2 through the weathering profile. The feedback will be stronger with dominating diffusive transport. The low weathering rate is explained by the nature of this feedback that is ultimately dependent on the transport of O-2 through the whole regolith, and on lithological factors such as low bedrock porosity and the amount of Fe-bearing primary minerals. Tectonic quiescence in this region and low pre-development erosion rate (attributed to a dense vegetation cover) minimize the rejuvenation of the thick and cohesive regolith column, finally leading to low denudation rates. (C) 2015 Elsevier B.V. All rights reserved. KW - Weathering KW - Critical zone KW - Corestone KW - Regolith KW - Sri Lanka Y1 - 2015 U6 - https://doi.org/10.1016/j.chemgeo.2015.07.008 SN - 0009-2541 SN - 1878-5999 VL - 411 SP - 283 EP - 298 PB - Elsevier CY - Amsterdam ER -