TY - JOUR A1 - Weber, Nancy A1 - Tiersch, Brigitte A1 - Unterlass, Miriam M. A1 - Heilig, Anneliese A1 - Tauer, Klaus T1 - "Schizomorphic" Emulsion Copolymerization Particles JF - Macromolecular rapid communications N2 - Cryo-electron microscopy, atomic force microscopy, and light microscopy investigations provide experimental evidence that amphiphilic emulsion copolymerization particles change their morphology in dependence on concentration. The shape of the particles is spherical at solids content above 1%, but it changes to rod-like, ring-like, and web-like structures at lower concentrations. In addition, the shape and morphology of these particles at low concentrations are not fixed but very flexible and vary with time between spheres, flexible pearlnecklace structures, and stretched rods. KW - amphiphilic particles KW - emulsion polymerization KW - morphology Y1 - 2011 U6 - https://doi.org/10.1002/marc.201100491 SN - 1022-1336 VL - 32 IS - 23 SP - 1925 EP - 1929 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Alexiadou, Artemis T1 - A form-function mismatch? BT - The case of Greek deponents JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432235 SN - 978-3-86956-457-9 SP - 107 EP - 117 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Thiersch, Craig T1 - A note on apparent sluicing in Malagasy JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432341 SN - 978-3-86956-457-9 SP - 185 EP - 209 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Fominyam, Henry A1 - Tran, Thuan T1 - Beware of ‘discourse markers’ JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432524 SN - 978-3-86956-457-9 SP - 257 EP - 272 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Schöne, Anne-Christin A1 - Schulz, Burkhard A1 - Richau, Klaus A1 - Kratz, Karl A1 - Lendlein, Andreas T1 - Characterization of Langmuir films prepared from copolyesterurethanes based on oligo(omega-pentadecalactone) and oligo(epsilon-caprolactone)segments JF - Macromolecular chemistry and physics N2 - A series of multiblock copolymers (PDLCL) synthesized from oligo(omega-pentadecalactone) diol (OPDL) and oligo(epsilon-caprolactone) diol (OCL), which are linked by 2,2(4), 4-trimethyl-hexamethylene diisocyanate (TMDI), is investigated by the Langmuir monolayer technique at the air-water interface. Brewster angle microscopy (BAM) and spectroscopic ellipsometry are employed to characterize the polymer film morphologies in situ. PDLCL containing >= 40 wt% OCL segments form homogeneous Langmuir monofilms after spreading. The film elasticity modulus decreases with increasing amounts of OPDL segments in the copolymer. In contrast, the OCL-free polyesterurethane OPDL-TMDI cannot be spread to monomolecular films on the water surface properly, and movable slabs are observed by BAM even at low surface pressures. The results of the in situ morphological characterization clearly show that essential information concerning the reliability of Langmuir monolayer degradation (LMD) experiments cannot be obtained from the evaluation of the pi-A isotherms only. Consequently, in situ morphological characterization turns out to be indispensable for characterization of Langmuir layers before LMD experiments. KW - brewster angle microscopy KW - ellipsometry KW - Langmuir layers KW - morphology KW - polyesterurethanes Y1 - 2014 U6 - https://doi.org/10.1002/macp.201400377 SN - 1022-1352 SN - 1521-3935 VL - 215 IS - 24 SP - 2437 EP - 2445 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Ran, Niva A. A1 - Love, John A. A1 - Heiber, Michael C. A1 - Jiao, Xuechen A1 - Hughes, Michael P. A1 - Karki, Akchheta A1 - Wang, Ming A1 - Brus, Viktor V. A1 - Wang, Hengbin A1 - Neher, Dieter A1 - Ade, Harald A1 - Bazan, Guillermo C. A1 - Thuc-Quyen Nguyen, T1 - Charge generation and recombination in an organic solar cell with low energetic offsets JF - dvanced energy materials N2 - Organic bulk heterojunction (BHJ) solar cells require energetic offsets between the donor and acceptor to obtain high short-circuit currents (J(SC)) and fill factors (FF). However, it is necessary to reduce the energetic offsets to achieve high open-circuit voltages (V-OC). Recently, reports have highlighted BHJ blends that are pushing at the accepted limits of energetic offsets necessary for high efficiency. Unfortunately, most of these BHJs have modest FF values. How the energetic offset impacts the solar cell characteristics thus remains poorly understood. Here, a comprehensive characterization of the losses in a polymer:fullerene BHJ blend, PIPCP:phenyl-C61-butyric acid methyl ester (PC61BM), that achieves a high V-OC (0.9 V) with very low energy losses (E-loss = 0.52 eV) from the energy of absorbed photons, a respectable J(SC) (13 mA cm(-2)), but a limited FF (54%) is reported. Despite the low energetic offset, the system does not suffer from field-dependent generation and instead it is characterized by very fast nongeminate recombination and the presence of shallow traps. The charge-carrier losses are attributed to suboptimal morphology due to high miscibility between PIPCP and PC61BM. These results hold promise that given the appropriate morphology, the J(SC), V-OC, and FF can all be improved, even with very low energetic offsets. KW - energetic offset KW - fill factor KW - morphology KW - organic solar cells KW - recombination Y1 - 2018 U6 - https://doi.org/10.1002/aenm.201701073 SN - 1614-6832 SN - 1614-6840 VL - 8 IS - 5 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Lorenz, Antje A1 - Heide, Judith A1 - Burchert, Frank T1 - Compound naming in aphasia: effects of complexity, part of speech, and semantic transparency JF - Language, cognition and neuroscience KW - compound production KW - morphology KW - decomposition KW - lemma KW - part of speech KW - semantic transparency KW - aphasia KW - word-finding difficulties Y1 - 2014 U6 - https://doi.org/10.1080/01690965.2013.766357 SN - 2327-3798 SN - 2327-3801 VL - 29 IS - 1 SP - 88 EP - 106 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Qiu, Liang A1 - Zhang, Haoran A1 - Bick, Thomas A1 - Martin, Johannes A1 - Wendler, Petra A1 - Böker, Alexander A1 - Glebe, Ulrich A1 - Xing, Chengfen T1 - Construction of highly ordered glyco-inside nano-assemblies through RAFT dispersion polymerization of galactose-decorated monomer JF - Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition N2 - Glyco-assemblies derived from amphiphilic sugar-decorated block copolymers (ASBCs) have emerged prominently due to their wide application, for example, in biomedicine and as drug carriers. However, to efficiently construct these glyco-assemblies is still a challenge. Herein, we report an efficient technology for the synthesis of glyco-inside nano-assemblies by utilizing RAFT polymerization of a galactose-decorated methacrylate for polymerization-induced self-assembly (PISA). Using this approach, a series of highly ordered glyco-inside nano-assemblies containing intermediate morphologies were fabricated by adjusting the length of the hydrophobic glycoblock and the polymerization solids content. A specific morphology of complex vesicles was captured during the PISA process and the formation mechanism is explained by the morphology of its precursor and intermediate. Thus, this method establishes a powerful route to fabricate glyco-assemblies with tunable morphologies and variable sizes, which is significant to enable the large-scale fabrication and wide application of glyco-assemblies. KW - galactose-decorated monomer KW - glyco-inside nano-assemblies KW - morphology KW - evolution KW - PISA KW - RAFT dispersion polymerization Y1 - 2021 U6 - https://doi.org/10.1002/anie.202015692 SN - 1433-7851 SN - 1521-3773 VL - 60 IS - 20 SP - 11098 EP - 11103 PB - Wiley-VCH CY - Weinheim ER - TY - GEN A1 - Clahsen, Harald T1 - Contributions of linguistic typology to psycholinguistics N2 - This article first outlines different ways of how psycholinguists have dealt with linguistic diversity and illustrates these approaches with three familiar cases from research on language processing, language acquisition, and language disorders. The second part focuses on the role of morphology and morphological variability across languages for psycholinguistic research. The specific phenomena to be examined are to do with stem-formation morphology and inflectional classes; they illustrate how experimental research that is informed by linguistic typology can lead to new insights. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 325 KW - child language KW - past-tense KW - inflection KW - morphology KW - portuguese KW - lexicon KW - hebrew KW - rules Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-397757 ER - TY - GEN A1 - Junginger, Mathias A1 - Kübel, Christian A1 - Schacher, Felix H. A1 - Müller, Axel H. E. A1 - Taubert, Andreas T1 - Crystal structure and chemical composition of biomimetic calcium phosphate nanofibers N2 - Calcium phosphate nanofibers with a diameter of only a few nanometers and a cotton-ball-like aggregate morphology have been reported several times in the literature. Although fiber formation seems reproducible in a variety of conditions, the crystal structure and chemical composition of the fibers have been elusive. Using scanning transmission electron microscopy, low dose electron (nano)diffraction, energy-dispersive X-ray spectroscopy, and energy-filtered transmission electron microscopy, we have assigned crystal structures and chemical compositions to the fibers. Moreover, we demonstrate that the mineralization process yields true polymer/calcium phosphate hybrid materials where the block copolymer template is closely associated with the calcium phosphate. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 244 KW - air-water-interface KW - polycationic monolayer KW - mineralization beneath KW - block-copolymers KW - aqueous-solution KW - morphology KW - orthophosphates KW - biomaterials KW - nucleation KW - clusters Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95176 SP - 11301 EP - 11308 ER - TY - THES A1 - Trommer, Jochen T1 - Distributed optimality N2 - In dieser Dissertation schlage ich eine Synthese (Distributed Optimality, DO) von Optimalitätstheorie und einem derivationellen, morphologischem Asatz, Distributed Morphology (DM; Halle & Marantz, 1993) vor. Durch die Integration von OT in DM wird es möglich, Phänomene, die in DM durch sprachspezifische Regeln oder Merkmale von lexikalischen Einträge erfasst werden, auf die Interaktion von verletzbaren, universellen Constraints zurückzuführen. Andererseits leistet auch DM zwei substantielle Beiträge zu DO, Lokalität und Impoverishment. Lokalität erlaubt eine formal einfache Interpretation von DO, während sich Impoverishment als unverzichtbar erweist, um Kongruenz-Morphologie adäquat zu beschreiben. Die empirische Grundlage der Arbeit sind die komplexen Kongruenzsysteme von genetisch unterschiedlichen Sprachen. Der theoretische Schwerpunkt liegt in zwei Bereichen: Erstens, sogenannte Direkt/Invers-Markierung, für die gezeigt wird, dass eine Behandlung durch Constraints über Merkmalsrealisierung am angemessensten ist. Zweitens, die Effekte von Abfolge-Constraints, die den Satus von Affixen als Präfixe und Suffixe sowie ihre relative Reihenfolge regeln. Eine konkrete Typologie für die Abfolge von Kongruenz-Affixen auf der Basis von OT-Constraints wird vorgeschlagen. N2 - In this thesis I propose a synthesis (Distributed Optimality, DO) between Optimality Theory (OT, Prince & Smolensky, 1993) and a morphological framework in a genuine derivational tradition, namely Distributed Morphology (DM) as developed by Halle & Marantz (1993). By carrying over the apparatus of OT to DM, phenomena which are captured in DM by language-specific rules or features of lexical entries, are given a more principled account in the terms of ranked universal constraints. On the other hand, also the DM part makes two contributions, namely strong locality and impoverishment. The first gives rise to a simple formal interpretation of DO, while the latter is shown to be indispensable in any theoretically satisfying account of agreement morphology. The empirical basis of the work is given by the complex agreement morphology of genetically different languages. Theoretical focus is mainly on two areas: First, so-called direction marking which is shown to be preferably treated in terms of constraints on feature realization. Second, the effects of precedence constraints which are claimed to regulate the status of agreement affixes as prefixes or suffixes and their respective order. A universal typology for the order of agreement categories by means of OT-constraints is proposed. KW - Morphologie KW - Optimalitätstheorie KW - Flexion KW - Optimalitätstheorie KW - Affixabfolge KW - morphology KW - Optimality Theory KW - inflection KW - Distributed Morphology KW - affix order Y1 - 2001 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-0001377 ER - TY - GEN A1 - Clahsen, Harald A1 - Jessen, Anna T1 - Do bilingual children lag behind? BT - A study of morphological encoding using ERPs T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - The current study investigates how bilingual children encode and produce morphologically complex words. We employed a silent-production-plus-delayed-vocalization paradigm in which event-related brain potentials (ERPs) were recorded during silent encoding of inflected words which were subsequently cued to be overtly produced. The bilingual children's spoken responses and their ERPs were compared to previous datasets from monolingual children on the same task. We found an enhanced negativity for regular relative to irregular forms during silent production in both bilingual children's languages, replicating the ERP effect previously obtained from monolingual children. Nevertheless, the bilingual children produced more morphological errors (viz. over-regularizations) than monolingual children. We conclude that mechanisms of morphological encoding (as measured by ERPs) are parallel for bilingual and monolingual children, and that the increased over-regularization rates are due to their reduced exposure to each of the two languages (relative to monolingual children). T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 682 KW - morphology KW - event-related brain potentials KW - bilingualism Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-469727 SN - 1866-8364 IS - 682 ER - TY - JOUR A1 - Clahsen, Harald A1 - Jessen, Anna T1 - Do bilingual children lag behind? A study of morphological encoding using ERPs JF - Journal of child language N2 - The current study investigates how bilingual children encode and produce morphologically complex words. We employed a silent-production-plus-delayed-vocalization paradigm in which event-related brain potentials (ERPs) were recorded during silent encoding of inflected words which were subsequently cued to be overtly produced. The bilingual children's spoken responses and their ERPs were compared to previous datasets from monolingual children on the same task. We found an enhanced negativity for regular relative to irregular forms during silent production in both bilingual children's languages, replicating the ERP effect previously obtained from monolingual children. Nevertheless, the bilingual children produced more morphological errors (viz. over-regularizations) than monolingual children. We conclude that mechanisms of morphological encoding (as measured by ERPs) are parallel for bilingual and monolingual children, and that the increased over-regularization rates are due to their reduced exposure to each of the two languages (relative to monolingual children). KW - morphology KW - event-related brain potentials KW - bilingualism Y1 - 2019 U6 - https://doi.org/10.1017/S0305000919000321 SN - 0305-0009 SN - 1469-7602 VL - 46 IS - 5 SP - 955 EP - 979 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Farhy, Yael A1 - Verissimo, Joao Marques A1 - Clahsen, Harald T1 - Do late bilinguals access pure morphology during word recognition? BT - a masked-priming study on Hebrew as a second language JF - Bilingualism : language and cognition N2 - This study extends research on morphological processing in late bilinguals to a rarely examined language type, Semitic, by reporting results from a masked-priming experiment with 58 non-native, advanced, second-language (L2) speakers of Hebrew in comparison with native (L1) speakers. We took advantage of a case of ‘pure morphology’ in Hebrew, the so-called binyanim, which represent (essentially arbitrary) morphological classes for verbs. Our results revealed a non-native priming pattern for the L2 group, with root-priming effects restricted to non-finite prime words irrespective of binyanim type. We conclude that root extraction in L2 Hebrew word recognition is less sensitive to both morphological and morphosyntactic cues than in the L1, in line with the Shallow-Structure Hypothesis of L2 processing. KW - grammatical processing KW - morphology KW - behavioural measurements KW - healthy normal subjects KW - Hebrew Y1 - 2018 U6 - https://doi.org/10.1017/S1366728918000032 SN - 1366-7289 SN - 1469-1841 VL - 21 IS - 5 SP - 945 EP - 951 PB - Cambridge Univ. Press CY - New York ER - TY - GEN A1 - Leminen, Alina A1 - Lehtonen, Minna A1 - Bozic, Mirjana A1 - Clahsen, Harald T1 - Editorial BT - morphologically complex words in the mind/brain T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - kein abstract vorhanden T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 441 KW - morphology KW - derivation KW - inflection KW - compound KW - L2 KW - dyslexia KW - semantics KW - decomposition Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-407243 IS - 441 ER - TY - GEN A1 - Leminen, Alina A1 - Lehtonen, Minna A1 - Bozic, Mirjana A1 - Clahsen, Harald T1 - Editorial: Morphologically Complex Words in the Mind/Brain T2 - Frontiers in human neuroscienc KW - morphology KW - derivation KW - inflection KW - compound KW - L2 KW - dyslexia KW - semantics KW - decomposition Y1 - 2016 U6 - https://doi.org/10.3389/fnhum.2016.00047 SN - 1662-5161 VL - 10 SP - 150 EP - 160 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Love, John A. A1 - Chou, Shu-Hua A1 - Huang, Ye A1 - Bazan, Guillermo C. A1 - Thuc-Quyen Nguyen, T1 - Effects of solvent additive on "s-shaped" curves in solution-processed small molecule solar cells JF - Beilstein journal of organic chemistry N2 - A novel molecular chromophore, p-SIDT(FBTThCA8)(2), is introduced as an electron-donor material for bulk heterojunction (BHJ) solar cells with broad absorption and near ideal energy levels for the use in combination with common acceptor materials. It is found that films cast from chlorobenzene yield devices with strongly s-shaped current-voltage curves, drastically limiting performance. We find that addition of the common solvent additive diiodooctane, in addition to facilitating crystallization, leads to improved vertical phase separation. This yields much better performing devices, with improved curve shape, demonstrating the importance of morphology control in BHJ devices and improving the understanding of the role of solvent additives. KW - current voltage analysis KW - morphology KW - organic solar cells Y1 - 2016 U6 - https://doi.org/10.3762/bjoc.12.249 SN - 1860-5397 VL - 12 SP - 2543 EP - 2555 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften CY - Frankfurt, Main ER - TY - JOUR A1 - Häussler, Jana A1 - Mucha, Anna A1 - Schmidt, Andreas A1 - Weskott, Thomas A1 - Wierzba, Marta T1 - Experimenting with Lurchi BT - V2 and agreement violations in poetic contexts JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432553 SN - 978-3-86956-457-9 SP - 307 EP - 321 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Wischke, Christian A1 - Lendlein, Andreas T1 - Functional nanocarriers by miniaturization of polymeric materials T2 - Nanomedicine KW - function KW - microscale KW - morphology KW - nanoscale KW - polymer Y1 - 2016 U6 - https://doi.org/10.2217/nnm.16.45 SN - 1743-5889 SN - 1748-6963 VL - 11 SP - 1507 EP - 1509 PB - Future Medicine CY - London ER - TY - JOUR A1 - Kroh, Daniel A1 - Eller, Fabian A1 - Schötz, Konstantin A1 - Wedler, Stefan A1 - Perdigón-Toro, Lorena A1 - Freychet, Guillaume A1 - Wei, Qingya A1 - Dörr, Maximilian A1 - Jones, David A1 - Zou, Yingping A1 - Herzig, Eva M. A1 - Neher, Dieter A1 - Köhler, Anna T1 - Identifying the signatures of intermolecular interactions in blends of PM6 with Y6 and N4 using absorption spectroscopy JF - Advanced functional materials N2 - In organic solar cells, the resulting device efficiency depends strongly on the local morphology and intermolecular interactions of the blend film. Optical spectroscopy was used to identify the spectral signatures of interacting chromophores in blend films of the donor polymer PM6 with two state-of-the-art nonfullerene acceptors, Y6 and N4, which differ merely in the branching point of the side chain. From temperature-dependent absorption and luminescence spectroscopy in solution, it is inferred that both acceptor materials form two types of aggregates that differ in their interaction energy. Y6 forms an aggregate with a predominant J-type character in solution, while for N4 molecules the interaction is predominantly in a H-like manner in solution and freshly spin-cast film, yet the molecules reorient with respect to each other with time or thermal annealing to adopt a more J-type interaction. The different aggregation behavior of the acceptor materials is also reflected in the blend films and accounts for the different solar cell efficiencies reported with the two blends. KW - charge-transfer states KW - Frank-Condon analysis KW - morphology KW - organic solar cells Y1 - 2022 U6 - https://doi.org/10.1002/adfm.202205711 SN - 1616-301X SN - 1616-3028 VL - 32 IS - 44 PB - Wiley-VCH CY - Weinheim ER -