TY  - JOUR
A1  - Xie, Zai-Lai
A1  - Xu, Hai-Bing
A1  - Gessner, Andre
A1  - Kumke, Michael Uwe
A1  - Priebe, Magdalena
A1  - Fromm, Katharina M.
A1  - Taubert, Andreas
T1  - A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid [Bmim][N(Tf)(2)]
JF  - Journal of materials chemistry
N2  - Transparent, ion-conducting, luminescent, and flexible ionogels based on the room temperature ionic liquid (IL) 1-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide [Bmim][N(Tf)(2)], a PtEu2 chromophore, and poly(methylmethacrylate) (PMMA) have been prepared. The thermal stability of the PMMA significantly increases with IL incorporation. In particular, the onset weight loss observed at ca. 229 degrees C for pure PMMA increases to 305 degrees C with IL addition. The ionogel has a high ionic conductivity of 10(-3) S cm(-1) at 373 K and exhibits a strong emission in the red with a long average luminescence decay time of tau = 890 mu s. The resulting material is a new type of soft hybrid material featuring useful thermal, optical, and ion transport properties.
Y1  - 2012
U6  - https://doi.org/10.1039/c2jm15862k
SN  - 0959-9428
VL  - 22
IS  - 16
SP  - 8110
EP  - 8116
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - THES
A1  - Xie, Zai-Lai
T1  - Functional materials in metal-containing ionic liquids
Y1  - 2012
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Goebel, Ronald
A1  - Xie, Zai-Lai
A1  - Neumann, Mike
A1  - Günter, Christina
A1  - Loebbicke, Ruben
A1  - Kubo, Shiori
A1  - Titirici, Maria-Magdalena
A1  - Giordano, Cristina
A1  - Taubert, Andreas
T1  - Synthesis of mesoporous carbon/iron carbide hybrids with unusually high surface areas from the ionic liquid precursor [Bmim][FeCl4]
JF  - CrystEngComm
N2  - Mesoporous carbon/iron carbide hybrid materials with surface areas reaching 800 m(2) g(-1) were synthesized via an exotemplating route using monolithic mesoporous silica as template and the ionic liquid 1-butyl-3-methylimidazolium tetrachloridoferrate(III) [Bmim][FeCl4] as carbon and iron source. After heat treatment (750 degrees C under argon) of the [Bmim][FeCl4] precursor confined within the silica matrix, the silica exotemplate was removed with HF leaving the mesoporous C/Fe3C hybrid behind. The surface areas and the pore sizes depend on the exotemplate and the surface areas a significantly larger than any other surface area reported for C/Fe3C hybrid materials so far. The approach is thus a prototype for the synthesis of high-surface area iron carbide-based hybrid materials with potential application in catalysis.
Y1  - 2012
U6  - https://doi.org/10.1039/c2ce25064k
SN  - 1466-8033
VL  - 14
IS  - 15
SP  - 4946
EP  - 4951
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -