TY  - JOUR
A1  - Hörmann, Ulrich
A1  - Zeiske, Stefan
A1  - Park, Soohyung
A1  - Schultz, Thorsten
A1  - Kickhoefel, Sebastian
A1  - Scherf, Ullrich
A1  - Blumstengel, Sylke
A1  - Koch, Norbert
A1  - Neher, Dieter
T1  - Direct observation of state-filling at hybrid tin oxide/organic interfaces
JF  - Applied physics letters
N2  - Electroluminescence (EL) spectra of hybrid charge transfer states at metal oxide/organic type-II heterojunctions exhibit bias-induced spectral shifts. The reasons for this phenomenon have been discussed controversially and arguments for either electric field-induced effects or the filling of trap states at the oxide surface have been put forward. Here, we combine the results of EL and photovoltaic measurements to eliminate the unavoidable effect of the series resistance of inorganic and organic components on the total voltage drop across the hybrid device. For SnOx combined with the conjugated polymer [ladder type poly-(para-phenylene)], we find a one-to-one correspondence between the blue-shift of the EL peak and the increase of the quasi-Fermi level splitting at the hybrid heterojunction, which we unambiguously assign to state filling. Our data are resembled best by a model considering the combination of an exponential density of states with a doped semiconductor. Published under license by AIP Publishing.
Y1  - 2019
U6  - https://doi.org/10.1063/1.5082704
SN  - 0003-6951
SN  - 1077-3118
VL  - 114
IS  - 18
PB  - American Institute of Physics
CY  - Melville
ER  -