TY  - GEN
A1  - Wolff, Christian Michael
A1  - Canil, Laura
A1  - Rehermann, Carolin
A1  - Nguyen, Ngoc Linh
A1  - Zu, Fengshuo
A1  - Ralaiarisoa, Maryline
A1  - Caprioglio, Pietro
A1  - Fiedler, Lukas
A1  - Stolterfoht, Martin
A1  - Kogikoski, Junior, Sergio
A1  - Bald, Ilko
A1  - Koch, Norbert
A1  - Unger, Eva L.
A1  - Dittrich, Thomas
A1  - Abate, Antonio
A1  - Neher, Dieter
T1  - Correction to 'Perfluorinated self-assembled monolayers enhance the stability and efficiency of inverted perovskite solar cells' (2020, 14 (2), 1445−1456)
T2  - ACS nano
Y1  - 2020
U6  - https://doi.org/10.1021/acsnano.0c08081
SN  - 1936-0851
SN  - 1936-086X
VL  - 14
IS  - 11
SP  - 16156
EP  - 16156
PB  - American Chemical Society
CY  - Washington, DC
ER  - 
TY  - JOUR
A1  - Abdoul-Carime, Hassan
A1  - Bald, Ilko
A1  - Illenberger, Eugen
A1  - Kopyra, Janina
T1  - Selective Synthesis of Ethylene and Acetylene from Dimethyl Sulfide Cold Films Controlled by Slow Electrons
JF  - The journal of physical chemistry : C, Nanomaterials and interfaces
N2  - One of the major challenges in chemical synthesis is to trigger and control a specific reaction route leading to a specific final product, while side products are avoided. Methodologies based on resonant processes at the molecular level, for example, photochemistry, offer the possibility of inducing selective reactions. Electrons at energies below the molecular ionization potential (<10 eV) are known to dissociate molecules via resonant processes with higher cross sections and specificity than photons. Here we show that even subexcitation electrons with energies as low as 1 eV produce ethylene and acetylene from dimethyl sulfide in competing reactions. However, the production of ethylene can specifically be targeted by controlling the energy of electrons (similar to 3 to 4 eV). Finally, pure ethylene is selectively desorbed by heating the substrate from 90 to 105 K. Beyond the synthesis of these versatile hydrocarbons for various industrial applications from a biogenic sulfur compound, our findings demonstrate the feasibility of electron induced selective chemistry applicable on the nanoscale.
Y1  - 2018
U6  - https://doi.org/10.1021/acs.jpcc.8b07377
SN  - 1932-7447
VL  - 122
IS  - 42
SP  - 24137
EP  - 24142
PB  - American Chemical Society
CY  - Washington
ER  -