TY  - JOUR
A1  - Schwarze, Thomas
A1  - Mickler, Wulfhard
A1  - Dosche, Carsten
A1  - Flehr, Roman
A1  - Klamroth, Tillmann
A1  - Löhmannsröben, Hans-Gerd
A1  - Saalfrank, Peter
A1  - Holdt, Hans-Jürgen
T1  - Systematic investigation of photoinduced electron transfer controlled by internal charge transfer and its consequences for selective PdCl2 coordination
N2  - Fluoroionophores of fluorophore-spacer-receptor format were prepared for detection of PdCl2 by fluorescence enhancement. The fluorescent probes 1-13 consist of a fluorophore group, an alkyl spacer and a dithiomaleonitrile PdCl2 receptor. First, varying the length of the alkylene spacer (compounds 1-3) revealed a dominant through-space pathway for oxidative photoinduced electron transfer (PET) in CH2-bridged dithiomaleonitrile fluoroionophores. Second, fluorescent probes 4-9 containing two anthracene or pyrene fragments connected through CH2 bridges to the dithiomaleonitrile unit were synthesized. Modulation of the oxidation potential (EOx) through electron-withdrawing or -donating groups on the anthracene moiety regulates the thermodynamic driving force for oxidative PET (GPET) in bis(anthrylmethylthio)maleonitriles and therefore the fluorescence quantum yields (f), too. The new concept was confirmed and transferred to pyrenyl ligands, and fluorescence enhancements (FE) greater than 3.2 in the presence of PdCl2 were achieved by 7 and 8 (FE=5.4 and 5.2). Finally, for comparison, monofluorophore ligands 10-13 were synthesized.
Y1  - 2010
UR  - http://www3.interscience.wiley.com/journal/26293/home
SN  - 0947-6539
ER  - 
TY  - JOUR
A1  - Schwarze, Thomas
A1  - Dosche, Carsten
A1  - Flehr, Roman
A1  - Klamroth, Tillmann
A1  - Löhmannsröben, Hans-Gerd
A1  - Saalfrank, Peter
A1  - Cleve, Ernst
A1  - Buschmann, Hans-Jürgen
A1  - Holdt, Hans-Jürgen
T1  - Combination of a CT modulated PET and an intramolecular excimer formation to quantify PdCl2 by large fluorescence enhancement
N2  - The [6.6](9,10)anthracenophane 1 (Scheme 1) is a selective fluoroionophore for the detection of PdCl2 with a large fluorescence enhancement factor (I/I-0 > 250).
Y1  - 2010
UR  - http://pubs.rsc.org/en/content/articlehtml/2010/cc/b919973j
U6  - https://doi.org/10.1039/B919973j
SN  - 1359-7345
ER  - 
TY  - JOUR
A1  - Schwarze, Thomas
A1  - Dosche, Carsten
A1  - Flehr, Roman
A1  - Klamroth, Tillmann
A1  - Löhmannsröben, Hans-Gerd
A1  - Saalfrank, Peter
A1  - Cleve, Ernst
A1  - Buschmann, Hans-Jürgen
A1  - Holdt, Hans-Jürgen
T1  - Combination of a CT modulated PET and an intramolecular excimer formation to quantify PdCl2 by large fluorescence enhancement
Y1  - 2010
UR  - http://www.rsc.org/ej/CC/2010/b919973j.pdf
SN  - 1359-7345
ER  - 
TY  - THES
A1  - Schwarze, Thomas
T1  - Fluoroionophore für Palladiumdichlorid und Kupfer(II)
Y1  - 2009
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Schwarze, Thomas
A1  - Mueller, Holger
A1  - Dosche, Carsten
A1  - Klamroth, Tillmann
A1  - Mickler, Wulfhard
A1  - Kelling, Alexandra
T1  - Luminescence detection of open-shell transition-metal ions by photoinduced electron transfer controlled by internal charge transfer of a receptor
Y1  - 2007
UR  - http://onlinelibrary.wiley.com/doi/10.1002/ange.200603992/pdf
U6  - https://doi.org/10.1002/anie.200603992
ER  - 
TY  - JOUR
A1  - Holdt, Hans-Jürgen
A1  - Müller, Holger
A1  - Kelling, Alexandra
A1  - Drexler, Hans-Joachim
A1  - Müller, Thomas
A1  - Schwarze, Thomas
A1  - Schilde, Uwe
A1  - Starke, Ines
T1  - Mercury(II) chloride and iodide complexes of dithia- and tetrathiacrown ethers
N2  - The complexes [(HgCl2)(2)((ch)(2)30S(4)O(6))] (1), [HgCl,(mn21S(2)O(5))] (2), [HgCl2(ch18S(2)O(4))] (3) and [HgI(meb12S(2)O(2))](2)[Hg2I6] (4) have been synthesized, characterized and their crystal structures were determined. In [(HgCl2)(2)((ch)(2)3OS(4)O(6))] two HgCl2 units are discretely bonded within the ligand cavity of the 30-membered dichinoxaline-tetrathia-30-crown-10 ((ch)(2)30S(4)O(6)) forming a binuclear complex. HgCl2 forms I : I "in-cavity" complexes with the 21-membered maleonitrile-dithia-21-crown-7(mn21S(2)O(5)) ligand and the 18-membered chinoxaline- dithia-18-crown-6 (ch18S(2)O(4)) ligand, respectively. The 12-membered 4-methyl-benzo-dithia-12-crown-4 (meb12S(2)O(2)) ligand gave with two equivalents HgI2 the compound [HgI(meb12S(2)O(2))](2)[Hg2I6]. In the cation [HgI(meb12S(2)O(2))](+) meb12S(2)O(2) forms with the cation HgI+ a half-sandwich complex
Y1  - 2006
UR  - http://www3.interscience.wiley.com/cgi-bin/jhome/10005159
U6  - https://doi.org/10.1002/zaac.200500281
SN  - 0044-2313
ER  -