TY - JOUR A1 - Yadavalli, Nataraja Sekhar A1 - Saphiannikova, Marina A1 - Lomadze, Nino A1 - Goldenberg, Leonid M. A1 - Santer, Svetlana T1 - Structuring of photosensitive material below diffraction limit using far field irradiation JF - Applied physics : A, Materials science & processing N2 - In this paper, we report on in-situ atomic force microscopy (AFM) studies of topographical changes in azobenzene-containing photosensitive polymer films that are irradiated with light interference patterns. We have developed an experimental setup consisting of an AFM combined with two-beam interferometry that permits us to switch between different polarization states of the two interfering beams while scanning the illuminated area of the polymer film, acquiring corresponding changes in topography in-situ. This way, we are able to analyze how the change in topography is related to the variation of the electrical field vector within the interference pattern. It is for the first time that with a rather simple experimental approach a rigorous assignment can be achieved. By performing in-situ measurements we found that for a certain polarization combination of two interfering beams [namely for the SP (a dagger center dot, a dagger") polarization pattern] the topography forms surface relief grating with only half the period of the interference patterns. Exploiting this phenomenon we are able to fabricate surface relief structures with characteristic features measuring only 140 nm, by using far field optics with a wavelength of 491 nm. We believe that this relatively simple method could be extremely valuable to, for instance, produce structural features below the diffraction limit at high-throughput, and this could significantly contribute to the search of new fabrication strategies in electronics and photonics industry. Y1 - 2013 U6 - https://doi.org/10.1007/s00339-013-7945-3 SN - 0947-8396 SN - 1432-0630 VL - 113 IS - 2 SP - 263 EP - 272 PB - Springer CY - New York ER - TY - JOUR A1 - Yadavalli, Nataraja Sekhar A1 - Santer, Svetlana T1 - In-situ atomic force microscopy study of the mechanism of surface relief grating formation in photosensitive polymer films JF - Journal of applied physics N2 - When photosensitive azobenzene-containing polymer films are irradiated with light interference patterns, topographic variations in the film develop that follow the local distribution of the electric field vector. The exact correspondence of e.g., the vector orientation in relation to the presence of local topographic minima or maxima is in general difficult to determine. Here, we report on a systematic procedure how this can be accomplished. For this, we devise a new set-up combining an atomic force microscope and two-beam interferometry. With this set-up, it is possible to track the topography change in-situ, while at the same time changing polarization and phase of the impinging interference pattern. This is the first time that an absolute correspondence between the local distribution of electric field vectors and the local topography of the relief grating could be established exhaustively. Our setup does not require a complex mathematical post-processing and its simplicity renders it interesting for characterizing photosensitive polymer films in general. Y1 - 2013 U6 - https://doi.org/10.1063/1.4809640 SN - 0021-8979 SN - 1089-7550 VL - 113 IS - 22 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Yadavalli, Nataraja Sekhar A1 - Linde, Felix A1 - Kopyshev, Alexey A1 - Santer, Svetlana T1 - Soft matter beats hard matter - rupturing of thin metallic films induced by mass transport in photosensitive polymer films JF - ACS applied materials & interfaces N2 - The interface between thin films of metal and polymer materials play a significant role in modern flexible microelectronics viz., metal contacts on polymer substrates, printed electronics and prosthetic devices. The major emphasis in metal polymer interface is on studying how the externally applied stress in the polymer substrate leads to the deformation and cracks in metal film and vice versa. Usually, the deformation process involves strains varying over large lateral dimensions because of excessive stress at local imperfections. Here we show that the seemingly random phenomena at macroscopic scales can be rendered rather controllable at submicrometer length scales. Recently, we have created a metal polymer interface system with strains varying over periods of several hundred nanometers. This was achieved by exploiting the formation of surface relief grating (SRG) within the azobenzene containing photosensitive polymer film upon irradiation with light interference pattern. Up to a thickness of 60 nm, the adsorbed metal film adapts neatly to the forming relief, until it ultimately ruptures into an array of stripes by formation of highly regular and uniform cracks along the maxima and minima of the polymer topography. This surprising phenomenon has far-reaching implications. This is the first time a direct probe is available to estimate the forces emerging in SRG formation in glassy polymers. Furthermore, crack formation in thin metal films can be studied literally in slow motion, which could lead to substantial improvements in the design process of flexible electronics. Finally, cracks are produced uniformly and at high density, contrary to common sense. This could offer new strategies for precise nanofabrication procedures mechanical in character. KW - metal/polymer interface KW - rupturing of metal film KW - forces generated during surface relief grating formation KW - in situ atomic force microscopy KW - azobenzene KW - two beam interferometry Y1 - 2013 U6 - https://doi.org/10.1021/am4006132w SN - 1944-8244 VL - 5 IS - 16 SP - 7743 EP - 7747 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Westendorf, Christian A1 - Negrete, Jose A1 - Bae, Albert J. A1 - Sandmann, Rabea A1 - Bodenschatz, Eberhard A1 - Beta, Carsten T1 - Actin cytoskeleton of chemotactic amoebae operates close to the onset of oscillations JF - Proceedings of the National Academy of Sciences of the United States of America N2 - The rapid reorganization of the actin cytoskeleton in response to external stimuli is an essential property of many motile eukaryotic cells. Here, we report evidence that the actin machinery of chemotactic Dictyostelium cells operates close to an oscillatory instability. When averaging the actin response of many cells to a short pulse of the chemoattractant cAMP, we observed a transient accumulation of cortical actin reminiscent of a damped oscillation. At the single-cell level, however, the response dynamics ranged from short, strongly damped responses to slowly decaying, weakly damped oscillations. Furthermore, in a small subpopulation, we observed self-sustained oscillations in the cortical F-actin concentration. To substantiate that an oscillatory mechanism governs the actin dynamics in these cells, we systematically exposed a large number of cells to periodic pulse trains of different frequencies. Our results indicate a resonance peak at a stimulation period of around 20 s. We propose a delayed feedback model that explains our experimental findings based on a time-delay in the regulatory network of the actin system. To test the model, we performed stimulation experiments with cells that express GFP-tagged fusion proteins of Coronin and actin-interacting protein 1, as well as knockout mutants that lack Coronin and actin-interacting protein 1. These actin-binding proteins enhance the disassembly of actin filaments and thus allow us to estimate the delay time in the regulatory feedback loop. Based on this independent estimate, our model predicts an intrinsic period of 20 s, which agrees with the resonance observed in our periodic stimulation experiments. KW - Dictyostelium discoideum KW - microfluidics KW - caged cAMP KW - delay-differential equation Y1 - 2013 U6 - https://doi.org/10.1073/pnas.1216629110 SN - 0027-8424 VL - 110 IS - 10 SP - 3853 EP - 3858 PB - National Acad. of Sciences CY - Washington ER - TY - THES A1 - Wechakama, Maneenate T1 - Multi-messenger constraints and pressure from dark matter annihilation into electron-positron pairs T1 - Multi-Messenger-Grenzen und Druck von Dunkler Materie-Annihilation in Elektron-Positron-Paaren N2 - Despite striking evidence for the existence of dark matter from astrophysical observations, dark matter has still escaped any direct or indirect detection until today. Therefore a proof for its existence and the revelation of its nature belongs to one of the most intriguing challenges of nowadays cosmology and particle physics. The present work tries to investigate the nature of dark matter through indirect signatures from dark matter annihilation into electron-positron pairs in two different ways, pressure from dark matter annihilation and multi-messenger constraints on the dark matter annihilation cross-section. We focus on dark matter annihilation into electron-positron pairs and adopt a model-independent approach, where all the electrons and positrons are injected with the same initial energy E_0 ~ m_dm*c^2. The propagation of these particles is determined by solving the diffusion-loss equation, considering inverse Compton scattering, synchrotron radiation, Coulomb collisions, bremsstrahlung, and ionization. The first part of this work, focusing on pressure from dark matter annihilation, demonstrates that dark matter annihilation into electron-positron pairs may affect the observed rotation curve by a significant amount. The injection rate of this calculation is constrained by INTEGRAL, Fermi, and H.E.S.S. data. The pressure of the relativistic electron-positron gas is computed from the energy spectrum predicted by the diffusion-loss equation. For values of the gas density and magnetic field that are representative of the Milky Way, it is estimated that the pressure gradients are strong enough to balance gravity in the central parts if E_0 < 1 GeV. The exact value depends somewhat on the astrophysical parameters, and it changes dramatically with the slope of the dark matter density profile. For very steep slopes, as those expected from adiabatic contraction, the rotation curves of spiral galaxies would be affected on kiloparsec scales for most values of E_0. By comparing the predicted rotation curves with observations of dwarf and low surface brightness galaxies, we show that the pressure from dark matter annihilation may improve the agreement between theory and observations in some cases, but it also imposes severe constraints on the model parameters (most notably, the inner slope of the halo density profile, as well as the mass and the annihilation cross-section of dark matter particles into electron-positron pairs). In the second part, upper limits on the dark matter annihilation cross-section into electron-positron pairs are obtained by combining observed data at different wavelengths (from Haslam, WMAP, and Fermi all-sky intensity maps) with recent measurements of the electron and positron spectra in the solar neighbourhood by PAMELA, Fermi, and H.E.S.S.. We consider synchrotron emission in the radio and microwave bands, as well as inverse Compton scattering and final-state radiation at gamma-ray energies. For most values of the model parameters, the tightest constraints are imposed by the local positron spectrum and synchrotron emission from the central regions of the Galaxy. According to our results, the annihilation cross-section should not be higher than the canonical value for a thermal relic if the mass of the dark matter candidate is smaller than a few GeV. In addition, we also derive a stringent upper limit on the inner logarithmic slope α of the density profile of the Milky Way dark matter halo (α < 1 if m_dm < 5 GeV, α < 1.3 if m_dm < 100 GeV and α < 1.5 if m_dm < 2 TeV) assuming a dark matter annihilation cross-section into electron-positron pairs (σv) = 3*10^−26 cm^3 s^−1, as predicted for thermal relics from the big bang. N2 - Trotz vieler Hinweise auf die Existenz von dunkler Materie durch astrophysikalische Beobachtungen hat sich die dunkle Materie bis heute einem direkten oder indirekten Nachweis entzogen. Daher gehrt der Nachweis ihrer Existenz und die Enthüllung ihrer Natur zu einem der faszinierensten Herausforderungen der heutigen Kosmologie und Teilchenphysik. Diese Arbeit versucht die Natur von dunkler Materie durch indirekte Signaturen von der Paarzerstrahlung dunkler Materie in Elektron-Positronpaare auf zwei verschiedene Weisen zu untersuchen, nämlich anhand des Drucks durch die Paarzerstrahlung dunkler Materie und durch Grenzen des Wirkungsquerschnitts für die Paarzerstrahlung dunkler Materie aus verschiedenen Beobachtungsbereichen. Wir konzentrieren uns dabei auf die Zerstrahlung dunkler Materie in Elektron-Positron-Paare und betrachten einen modellunabhängigen Fall, bei dem alle Elektronen und Positronen mit der gleichen Anfangsenergie E_0 ~ m_dm*c^2 injiziert werden. Die Fortbewegung dieser Teilchen wird dabei bestimmt durch die Lösung der Diffusions-Verlust-Gleichung unter Berücksichtigung von inverser Compton-Streuung, Synchrotronstrahlung, Coulomb-Streuung, Bremsstrahlung und Ionisation. Der erste Teil dieser Arbeit zeigt, dass die Zerstrahlung dunkler Materie in Elektron-Positron-Paare die gemessene Rotationskurve signifikant beeinflussen kann. Die Produktionsrate ist dabei durch Daten von INTEGRAL, Fermi und H.E.S.S. begrenzt. Der Druck des relativistischen Elektron-Positron Gases wird aus dem Energiespektrum errechnet, welches durch die Diffusions-Verlust-Gleichung bestimmt ist. Für Werte der Gasdichte und des magnetischen Feldes, welche für unsere Galaxie repräsentativ sind, lässt sich abschätzen, dass für E_0 < 1 GeV die Druckgradienten stark genug sind, um Gravitationskräfte auszugleichen. Die genauen Werte hängen von den verwendeten astrophysikalischen Parametern ab, und sie ändern sich stark mit dem Anstieg des dunklen Materie-Profils. Für sehr große Anstiege, wie sie für adiabatische Kontraktion erwartet werden, werden die Rotationskurven von Spiralgalaxien auf Skalen von einegen Kiloparsek für die meisten Werte von E_0 beeinflusst. Durch Vergleich der erwarteten Rotationskurven mit Beobachtungen von Zwerggalaxien und Galaxien geringer Oberflächentemperatur zeigen wir, dass der Druck von Zerstrahlung dunkler Materie die Übereinstimmung von Theorie und Beobachtung in einigen Fällen verbessern kann. Aber daraus resultieren auch starke Grenzen für die Modellparameter - vor allem für den inneren Anstieg des Halo-Dichteprofils, sowie die Masse und den Wirkungsquerschnitt der dunklen Materie-Teilchen. Im zweiten Teil werden obere Grenzen für die Wirkungsquerschnitte der Zerstrahlung der dunkler Materie in Elektron-Positron-Paare erhalten, indem die beobachteten Daten bei unterschiedlichen Wellenlängen (von Haslam, WMAP und Fermi) mit aktuellen Messungen von Elektron-Positron Spektren in der solaren Nachbarschaft durch PAMELA, Fermi und H.E.S.S. kombiniert werden. Wir betrachten Synchrotronemission bei Radiound Mikrowellenfrequenzen, sowie inverse Compton-Streuung und Final-State-Strahlung bei Energien im Bereich der Gamma-Strahlung. Für die meisten Werte der Modellparameter werden die stärksten Schranken durch das lokale Positron-Spektrum und die Synchrotronemission im Zentrum unser Galaxie bestimmt. Nach diesen Ergebnissen sollte der Wirkungsquerschnitt für die Paarzerstrahlung nicht größer als der kanonische Wert für thermische Relikte sein, wenn die Masse der dunklen Materie-Kandidaten kleiner als einige GeV ist. Zusätzlich leiten wir eine obere Grenze für den inneren logarithmische Anstieg α des Dichteprofiles des dunklen Materie Halos unserer Galaxie ab. KW - dunkle Materie KW - Astroteilchenphysik KW - Strahlung Mechanismen KW - Galaxy Struktur KW - Rotationskurven KW - dark matter KW - astroparticle physics KW - radiation mechanisms KW - galaxy structure KW - rotation curves Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67401 ER - TY - JOUR A1 - Vlasov, Vladimir A1 - Pikovskij, Arkadij T1 - Synchronization of a Josephson junction array in terms of global variables JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider an array of Josephson junctions with a common LCR load. Application of the Watanabe-Strogatz approach [Physica D 74, 197 (1994)] allows us to formulate the dynamics of the array via the global variables only. For identical junctions this is a finite set of equations, analysis of which reveals the regions of bistability of the synchronous and asynchronous states. For disordered arrays with distributed parameters of the junctions, the problem is formulated as an integro-differential equation for the global variables; here stability of the asynchronous states and the properties of the transition synchrony-asynchrony are established numerically. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.022908 SN - 1539-3755 VL - 88 IS - 2 PB - American Physical Society CY - College Park ER - TY - THES A1 - Verma, Meetu T1 - The evolution and decay of sunspots : a hight-resolution study of flows and magnetic fields in and around sunspots Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - van Loon, J. Th. A1 - Bailey, M. A1 - Tatton, B. L. A1 - Apellaniz, Jesus Maiz A1 - Crowther, P. A. A1 - de Koter, A. A1 - Evans, C. J. A1 - Henault-Brunet, V. A1 - Howarth, I. D. A1 - Richter, Philipp A1 - Sana, Hugues A1 - Simon Díaz, Sergio A1 - Taylor, W. A1 - Walborn, N. R. T1 - The VLT-FLAMES tarantula survey IX. - the interstellar medium seen through diffuse interstellar bands and neutral sodium JF - Astronomy and astrophysics : an international weekly journal N2 - Context. The Tarantula Nebula (a.k.a. 30 Dor) is a spectacular star-forming region in the Large Magellanic Cloud (LMC), seen through gas in the Galactic disc and halo. Diffuse interstellar bands (DIBs) offer a unique probe of the diffuse, cool-warm gas in these regions. Aims. The aim is to use DIBs as diagnostics of the local interstellar conditions, whilst at the same time deriving properties of the yet-unknown carriers of these enigmatic spectral features. Methods. Spectra of over 800 early-type stars from the Very Large Telescope Flames Tarantula Survey (VFTS) were analysed. Maps were created, separately, for the Galactic and LMC absorption in the DIBs at 4428 and 6614 angstrom and - in a smaller region near the central cluster R 136 - neutral sodium (the Na ID doublet); we also measured the DIBs at 5780 and 5797 angstrom. Results. The maps show strong 4428 and 6614 angstrom DIBs in the quiescent cloud complex to the south of 30 Dor but weak absorption in the harsher environments to the north (bubbles) and near the OB associations. The Na maps show at least five kinematic components in the LMC and a shell-like structure surrounding R 136, and small-scale structure in the Milky Way. The strengths of the 4428, 5780, 5797 and 6614 angstrom DIBs are correlated, also with Na absorption and visual extinction. The strong 4428 angstrom DIB is present already at low Na column density but the 6614, 5780 and 5797 angstrom DIBs start to be detectable at subsequently larger Na column densities. Conclusions. The carriers of the 4428, 6614, 5780 and 5797 angstrom DIBs are increasingly prone to removal from irradiated gas. The relative strength of the 5780 and 5797 angstrom DIBs clearly confirm the Tarantula Nebula as well as Galactic high-latitude gas to represent a harsh radiation environment. The resilience of the 4428 angstrom DIB suggests its carrier is large, compact and neutral. Structure is detected in the distribution of cool-warm gas on scales between one and > 100 pc in the LMC and as little as 0.01 pc in the Sun's vicinity. Stellar winds from the central cluster R 136 have created an expanding shell; some infalling gas is also detected, reminiscent of a galactic "fountain". KW - ISM: individual objects: Tarantula Nebula (30 Doradus Nebula) KW - ISM: molecules KW - ISM: kinematics and dynamics KW - ISM: lines and bands KW - ISM: structure KW - local insterstellar matter Y1 - 2013 U6 - https://doi.org/10.1051/0004-6361/201220210 SN - 0004-6361 VL - 550 IS - 9 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Valori, Gherarod A1 - Demoulin, Pascal A1 - Pariat, E. A1 - Masson, S. T1 - Accuracy of magnetic energy computations JF - Astronomy and astrophysics : an international weekly journal N2 - Context. For magnetically driven events, the magnetic energy of the system is the prime energy reservoir that fuels the dynamical evolution. In the solar context, the free energy (i.e., the energy in excess of the potential field energy) is one of the main indicators used in space weather forecasts to predict the eruptivity of active regions. A trustworthy estimation of the magnetic energy is therefore needed in three-dimensional (3D) models of the solar atmosphere, e. g., in coronal fields reconstructions or numerical simulations. Aims. The expression of the energy of a system as the sum of its potential energy and its free energy (Thomson's theorem) is strictly valid when the magnetic field is exactly solenoidal. For numerical realizations on a discrete grid, this property may be only approximately fulfilled. We show that the imperfect solenoidality induces terms in the energy that can lead to misinterpreting the amount of free energy present in a magnetic configuration. Methods. We consider a decomposition of the energy in solenoidal and nonsolenoidal parts which allows the unambiguous estimation of the nonsolenoidal contribution to the energy. We apply this decomposition to six typical cases broadly used in solar physics. We quantify to what extent the Thomson theorem is not satisfied when approximately solenoidal fields are used. Results. The quantified errors on energy vary from negligible to significant errors, depending on the extent of the nonsolenoidal component of the field. We identify the main source of errors and analyze the implications of adding a variable amount of divergence to various solenoidal fields. Finally, we present pathological unphysical situations where the estimated free energy would appear to be negative, as found in some previous works, and we identify the source of this error to be the presence of a finite divergence. Conclusions. We provide a method of quantifying the effect of a finite divergence in numerical fields, together with detailed diagnostics of its sources. We also compare the efficiency of two divergence-cleaning techniques. These results are applicable to a broad range of numerical realizations of magnetic fields. KW - magnetic fields KW - methods: numerical KW - Sun: surface magnetism KW - Sun: corona Y1 - 2013 U6 - https://doi.org/10.1051/0004-6361/201220982 SN - 0004-6361 VL - 553 IS - 2 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Vahabi, Mahsa A1 - Schulz, Johannes H. P. A1 - Shokri, Babak A1 - Metzler, Ralf T1 - Area coverage of radial Levy flights with periodic boundary conditions JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider the area coverage of radial Levy flights in a finite square area with periodic boundary conditions. From simulations we show how the fractal path dimension d(f) and thus the degree of area coverage depends on the number of steps of the trajectory, the size of the area, and the resolution of the applied box counting algorithm. For sufficiently long trajectories and not too high resolution, the fractal dimension returned by the box counting method equals two, and in that sense the Levy flight fully covers the area. Otherwise, the determined fractal dimension equals the stable index of the distribution of jump lengths of the Levy flight. We provide mathematical expressions for the turnover between these two scaling regimes. As complementary methods to analyze confined Levy flights we investigate fractional order moments of the position for which we also provide scaling arguments. Finally, we study the time evolution of the probability density function and the first passage time density of Levy flights in a square area. Our findings are of interest for a general understanding of Levy flights as well as for the analysis of recorded trajectories of animals searching for food or for human motion patterns. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.87.042136 SN - 1539-3755 VL - 87 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Tu, Rui A1 - Zhang, Hongping A1 - Ge, Maorong A1 - Huang, Guanwen T1 - A real-time ionospheric model based on GNSS Precise Point Positioning JF - Advances in space research N2 - This paper proposes a method of real-time monitoring and modeling the ionospheric Total Electron Content (TEC) by Precise Point Positioning (PPP). Firstly, the ionospheric TEC and receiver's Differential Code Biases (DCB) are estimated with the undifferenced raw observation in real-time, then the ionospheric TEC model is established based on the Single Layer Model (SLM) assumption and the recovered ionospheric TEC. In this study, phase observations with high precision are directly used instead of phase smoothed code observations. In addition, the DCB estimation is separated from the establishment of the ionospheric model which will limit the impacts of the SLM assumption impacts. The ionospheric model is established at every epoch for real time application. The method is validated with three different GNSS networks on a local, regional, and global basis. The results show that the method is feasible and effective, the real-time ionosphere and DCB results are very consistent with the IGS final products, with a bias of 1-2 TECU and 0.4 ns respectively. KW - Ionospheric monitoring and modeling KW - Precise Point Positioning (PPP) KW - Real time KW - Total Electron Content (TEC) KW - Global Navigation Satellite System (GNSS) KW - Differential Code Biases (DCB) Y1 - 2013 U6 - https://doi.org/10.1016/j.asr.2013.06.015 SN - 0273-1177 SN - 1879-1948 VL - 52 IS - 6 SP - 1125 EP - 1134 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Trinh, Christopher Q. A1 - Ellis, Simon C. A1 - Bland-Hawthorn, Joss A1 - Lawrence, Jon S. A1 - Horton, Anthony J. A1 - Leon-Saval, Sergio G. A1 - Shortridge, Keith A1 - Bryant, Julia A1 - Case, Scott A1 - Colless, Matthew A1 - Couch, Warrick A1 - Freeman, Kenneth A1 - Löhmannsröben, Hans-Gerd A1 - Gers, Luke A1 - Glazebrook, Karl A1 - Haynes, Roger A1 - Lee, Steve A1 - O'Byrne, John A1 - Miziarski, Stan A1 - Roth, Martin M. A1 - Schmidt, Brian A1 - Tinney, Christopher G. A1 - Zheng, Jessica T1 - Gnosis - the first instrument to use fiber bragg gratings for OH suppression JF - The astronomical journal N2 - The near-infrared is an important part of the spectrum in astronomy, especially in cosmology because the light from objects in the early universe is redshifted to these wavelengths. However, deep near-infrared observations are extremely difficult to make from ground-based telescopes due to the bright background from the atmosphere. Nearly all of this background comes from the bright and narrow emission lines of atmospheric hydroxyl (OH) molecules. The atmospheric background cannot be easily removed from data because the brightness fluctuates unpredictably on short timescales. The sensitivity of ground-based optical astronomy far exceeds that of near-infrared astronomy because of this long-standing problem. GNOSIS is a prototype astrophotonic instrument that utilizes "OH suppression fibers" consisting of fiber Bragg gratings and photonic lanterns to suppress the 103 brightest atmospheric emission doublets between 1.47 and 1.7 mu m. GNOSIS was commissioned at the 3.9 m Anglo-Australian Telescope with the IRIS2 spectrograph to demonstrate the potential of OH suppression fibers, but may be potentially used with any telescope and spectrograph combination. Unlike previous atmospheric suppression techniques GNOSIS suppresses the lines before dispersion and in a manner that depends purely on wavelength. We present the instrument design and report the results of laboratory and on-sky tests from commissioning. While these tests demonstrated high throughput (approximate to 60%) and excellent suppression of the skylines by the OH suppression fibers, surprisingly GNOSIS produced no significant reduction in the interline background and the sensitivity of GNOSIS+IRIS2 is about the same as IRIS2. It is unclear whether the lack of reduction in the interline background is due to physical sources or systematic errors as the observations are detector noise dominated. OH suppression fibers could potentially impact ground-based astronomy at the level of adaptive optics or greater. However, until a clear reduction in the interline background and the corresponding increasing in sensitivity is demonstrated optimized OH suppression fibers paired with a fiber-fed spectrograph will at least provide a real benefit at low resolving powers. KW - atmospheric effects KW - infrared: diffuse background KW - instrumentation: miscellaneous Y1 - 2013 U6 - https://doi.org/10.1088/0004-6256/145/2/51 SN - 0004-6256 VL - 145 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Toenjes, Ralf A1 - Sokolov, Igor M. A1 - Postnikov, E. B. T1 - Non-spectral relaxation in one dimensional Ornstein-Uhlenbeck processes JF - Physical review letters N2 - The relaxation of a dissipative system to its equilibrium state often shows a multiexponential pattern with relaxation rates, which are typically considered to be independent of the initial condition. The rates follow from the spectrum of a Hermitian operator obtained by a similarity transformation of the initial Fokker-Planck operator. However, some initial conditions are mapped by this similarity transformation to functions which growat infinity. These cannot be expanded in terms of the eigenfunctions of a Hermitian operator, and show different relaxation patterns. Considering the exactly solvable examples of Gaussian and generalized Levy Ornstein-Uhlenbeck processes (OUPs) we show that the relaxation rates belong to the Hermitian spectrum only if the initial condition belongs to the domain of attraction of the stable distribution defining the noise. While for an ordinary OUP initial conditions leading to nonspectral relaxation can be considered exotic, for generalized OUPs driven by Levy noise, such initial conditions are the rule. DOI: 10.1103/PhysRevLett.110.150602 Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.150602 SN - 0031-9007 VL - 110 IS - 15 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Todt, Helge Tobias A1 - Kniazev, A. Y. A1 - Gvaramadze, V. V. A1 - Hamann, Wolf-Rainer A1 - Buckley, D. A1 - Crause, L. A1 - Crawford, S. M. A1 - Gulbis, A. A. S. A1 - Hettlage, C. A1 - Hooper, E. A1 - Husser, T. -O. A1 - Kotze, P. A1 - Loaring, N. A1 - Nordsieck, K. H. A1 - O'Donoghue, D. A1 - Pickering, T. A1 - Potter, S. A1 - Romero-Colmenero, E. A1 - Vaisanen, P. A1 - Williams, T. A1 - Wolf, M. T1 - Abell 48-a rare WN-type central star of a planetary nebula JF - Monthly notices of the Royal Astronomical Society N2 - A considerable fraction of the central stars of planetary nebulae (CSPNe) are hydrogen-deficient. Almost all of these H-deficient central stars (CSs) display spectra with strong carbon and helium lines. Most of them exhibit emission-line spectra resembling those of massive WC stars. Therefore these stars are classed as CSPNe of spectral type [WC]. Recently, quantitative spectral analysis of two emission-line CSs, PB 8 and IC 4663, revealed that these stars do not belong to the [WC] class. Instead PB 8 has been classified as [WN/WC] type and IC 4663 as [WN] type. In this work we report the spectroscopic identification of another rare [WN] star, the CS of Abell 48. We performed a spectral analysis of Abell 48 with the Potsdam Wolf-Rayet (PoWR) models for expanding atmospheres. We find that the expanding atmosphere of Abell 48 is mainly composed of helium (85 per cent by mass), hydrogen (10 per cent) and nitrogen (5 per cent). The residual hydrogen and the enhanced nitrogen abundance make this object different from the other [WN] star IC 4663. We discuss the possible origin of this atmospheric composition. KW - stars: abundances KW - stars: AGB and post-AGB KW - stars: mass-loss KW - stars: Wolf-Rayet KW - planetary nebulae: general KW - planetary nebulae: individual: PN G029.0+00.4 Y1 - 2013 U6 - https://doi.org/10.1093/mnras/stt056 SN - 0035-8711 SN - 1365-2966 VL - 430 IS - 3 SP - 2302 EP - 2312 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Tiscareno, Matthew S. A1 - Mitchell, Colin J. A1 - Murray, Carl D. A1 - Di Nino, Daiana A1 - Hedman, Matthew M. A1 - Schmidt, Jürgen A1 - Burns, Joseph A. A1 - Cuzzi, Jeffrey N. A1 - Porco, Carolyn C. A1 - Beurle, Kevin A1 - Evans, Michael W. T1 - Observations of Ejecta clouds produced by impacts onto Saturn's rings JF - Science N2 - We report observations of dusty clouds in Saturn's rings, which we interpret as resulting from impacts onto the rings that occurred between 1 and 50 hours before the clouds were observed. The largest of these clouds was observed twice; its brightness and cant angle evolved in a manner consistent with this hypothesis. Several arguments suggest that these clouds cannot be due to the primary impact of one solid meteoroid onto the rings, but rather are due to the impact of a compact stream of Saturn-orbiting material derived from previous breakup of a meteoroid. The responsible interplanetary meteoroids were initially between 1 centimeter and several meters in size, and their influx rate is consistent with the sparse prior knowledge of smaller meteoroids in the outer solar system. Y1 - 2013 U6 - https://doi.org/10.1126/science.1233524 SN - 0036-8075 VL - 340 IS - 6131 SP - 460 EP - 464 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Thomas, Philipp A1 - Matuschek, Hannes A1 - Grima, Ramon T1 - How reliable is the linear noise approximation of gene regulatory networks? JF - BMC genomics N2 - Background: The linear noise approximation (LNA) is commonly used to predict how noise is regulated and exploited at the cellular level. These predictions are exact for reaction networks composed exclusively of first order reactions or for networks involving bimolecular reactions and large numbers of molecules. It is however well known that gene regulation involves bimolecular interactions with molecule numbers as small as a single copy of a particular gene. It is therefore questionable how reliable are the LNA predictions for these systems. Results: We implement in the software package intrinsic Noise Analyzer (iNA), a system size expansion based method which calculates the mean concentrations and the variances of the fluctuations to an order of accuracy higher than the LNA. We then use iNA to explore the parametric dependence of the Fano factors and of the coefficients of variation of the mRNA and protein fluctuations in models of genetic networks involving nonlinear protein degradation, post-transcriptional, post-translational and negative feedback regulation. We find that the LNA can significantly underestimate the amplitude and period of noise-induced oscillations in genetic oscillators. We also identify cases where the LNA predicts that noise levels can be optimized by tuning a bimolecular rate constant whereas our method shows that no such regulation is possible. All our results are confirmed by stochastic simulations. Conclusion: The software iNA allows the investigation of parameter regimes where the LNA fares well and where it does not. We have shown that the parametric dependence of the coefficients of variation and Fano factors for common gene regulatory networks is better described by including terms of higher order than LNA in the system size expansion. This analysis is considerably faster than stochastic simulations due to the extensive ensemble averaging needed to obtain statistically meaningful results. Hence iNA is well suited for performing computationally efficient and quantitative studies of intrinsic noise in gene regulatory networks. Y1 - 2013 U6 - https://doi.org/10.1186/1471-2164-14-S4-S5 SN - 1471-2164 VL - 14 IS - 4 PB - BioMed Central CY - London ER - TY - JOUR A1 - Theves, Matthias A1 - Taktikos, Johannes A1 - Zaburdaev, Vasily A1 - Stark, Holger A1 - Beta, Carsten T1 - A bacterial swimmer with two alternating speeds of propagation JF - Biophysical journal N2 - We recorded large data sets of swimming trajectories of the soil bacterium Pseudomonas putida. Like other prokaryotic swimmers, P. putida exhibits a motion pattern dominated by persistent runs that are interrupted by turning events. An in-depth analysis of their swimming trajectories revealed that the majority of the turning events is characterized by an angle of phi(1) = 180 degrees (reversals). To a lesser extent, turning angles of phi(2 Sigma Sigma Sigma Sigma) = 00 are also found. Remarkably, we observed that, upon a reversal, the swimming speed changes by a factor of two on average a prominent feature of the motion pattern that, to our knowledge, has not been reported before. A theoretical model, based on the experimental values for the average run time and the rotational diffusion, recovers the mean-square displacement of P. putida if the two distinct swimming speeds are taken into account. Compared to a swimmer that moves with a constant intermediate speed, the mean-square displacement is strongly enhanced. We furthermore observed a negative dip in the directional autocorrelation at intermediate times, a feature that is only recovered in an extended model, where the nonexponential shape of the run-time distribution is taken into account. Y1 - 2013 U6 - https://doi.org/10.1016/j.bpj.2013.08.047 SN - 0006-3495 SN - 1542-0086 VL - 105 IS - 8 SP - 1915 EP - 1924 PB - Cell Press CY - Cambridge ER - TY - THES A1 - Theves, Matthias T1 - Bacterial motility and growth in open and confined environments T1 - Bacterial motility and growth in open and confined environments N2 - In the presence of a solid-liquid or liquid-air interface, bacteria can choose between a planktonic and a sessile lifestyle. Depending on environmental conditions, cells swimming in close proximity to the interface can irreversibly attach to the surface and grow into three-dimensional aggregates where the majority of cells is sessile and embedded in an extracellular polymer matrix (biofilm). We used microfluidic tools and time lapse microscopy to perform experiments with the polarly flagellated soil bacterium Pseudomonas putida (P. putida), a bacterial species that is able to form biofilms. We analyzed individual trajectories of swimming cells, both in the bulk fluid and in close proximity to a glass-liquid interface. Additionally, surface related growth during the early phase of biofilm formation was investigated. In the bulk fluid, P.putida shows a typical bacterial swimming pattern of alternating periods of persistent displacement along a line (runs) and fast reorientation events (turns) and cells swim with an average speed around 24 micrometer per second. We found that the distribution of turning angles is bimodal with a dominating peak around 180 degrees. In approximately six out of ten turning events, the cell reverses its swimming direction. In addition, our analysis revealed that upon a reversal, the cell systematically changes its swimming speed by a factor of two on average. Based on the experimentally observed values of mean runtime and rotational diffusion, we presented a model to describe the spreading of a population of cells by a run-reverse random walker with alternating speeds. We successfully recover the mean square displacement and, by an extended version of the model, also the negative dip in the directional autocorrelation function as observed in the experiments. The analytical solution of the model demonstrates that alternating speeds enhance a cells ability to explore its environment as compared to a bacterium moving at a constant intermediate speed. As compared to the bulk fluid, for cells swimming near a solid boundary we observed an increase in swimming speed at distances below d= 5 micrometer and an increase in average angular velocity at distances below d= 4 micrometer. While the average speed was maximal with an increase around 15% at a distance of d= 3 micrometer, the angular velocity was highest in closest proximity to the boundary at d=1 micrometer with an increase around 90% as compared to the bulk fluid. To investigate the swimming behavior in a confinement between two solid boundaries, we developed an experimental setup to acquire three-dimensional trajectories using a piezo driven objective mount coupled to a high speed camera. Results on speed and angular velocity were consistent with motility statistics in the presence of a single boundary. Additionally, an analysis of the probability density revealed that a majority of cells accumulated near the upper and lower boundaries of the microchannel. The increase in angular velocity is consistent with previous studies, where bacteria near a solid boundary were shown to swim on circular trajectories, an effect which can be attributed to a wall induced torque. The increase in speed at a distance of several times the size of the cell body, however, cannot be explained by existing theories which either consider the drag increase on cell body and flagellum near a boundary (resistive force theory) or model the swimming microorganism by a multipole expansion to account for the flow field interaction between cell and boundary. An accumulation of swimming bacteria near solid boundaries has been observed in similar experiments. Our results confirm that collisions with the surface play an important role and hydrodynamic interactions alone cannot explain the steady-state accumulation of cells near the channel walls. Furthermore, we monitored the number growth of cells in the microchannel under medium rich conditions. We observed that, after a lag time, initially isolated cells at the surface started to grow by division into colonies of increasing size, while coexisting with a comparable smaller number of swimming cells. After 5:50 hours, we observed a sudden jump in the number of swimming cells, which was accompanied by a breakup of bigger clusters on the surface. After approximately 30 minutes where planktonic cells dominated in the microchannel, individual swimming cells reattached to the surface. We interpret this process as an emigration and recolonization event. A number of complementary experiments were performed to investigate the influence of collective effects or a depletion of the growth medium on the transition. Similar to earlier observations on another bacterium from the same family we found that the release of cells to the swimming phase is most likely the result of an individual adaption process, where syntheses of proteins for flagellar motility are upregulated after a number of division cycles at the surface. N2 - Bakterien sind einzellige Mikroorganismen, die sich in flüssigem Medium mit Hilfe von rotierenden Flagellen, länglichen Fasern aus Proteinen, schwimmend fortbewegen. In Gegenwart einer Grenzfläche und unter günstigen Umweltbedingungen siedeln sich Bakterien an der Oberfläche an und gehen in eine sesshafte Wachstumsphase über. Die Wachstumsphase an der Oberfläche ist gekennzeichnet durch das Absondern von klebrigen, nährstoffreichen extrazellulären Substanzen, welche die Verbindung der Bakterien untereinander und mit der Oberfläche verstärken. Die entstehenden Aggregate aus extrazellulärer Matrix und Bakterien werden als Biofilm bezeichnet. In der vorliegenden Arbeit untersuchten wir ein Bodenbakterium, Pseudomonas putida (P. putida), welches in wässriger Umgebung an festen Oberflächen Biofilme ausbildet. Wir benutzten photolithographisch hergestellte Mikrokanäle und Hochgeschwindigkeits-Videomikroskopie um die Bewegung schwimmender Zellen in verschiedenen Abständen zu einer Glasoberfläche aufzunehmen. Zusätzlich wurden Daten über das parallel stattfindende Wachstum der sesshaften Zellen an der Oberfläche aufgezeichnet. Die Analyse von Trajektorien frei schwimmender Zellen zeigte, dass sich Liniensegmente, entlang derer sich die Zellen in eine konstante Richtung bewegen, mit scharfen Kehrtwendungen mit einem Winkel von 180 Grad abwechseln. Dabei änderte sich die Schwimmgeschwindigket von einem zum nächsten Segment im Mittel um einen Faktor von 2. Unsere experimentellen Daten waren die Grundlage für ein mathematisches Modell zur Beschreibung der Zellbewegung mit alternierender Geschwindigkeit. Die analytische Lösung des Modells zeigt elegant, dass eine Population von Bakterien, welche zwischen zwei Geschwindigkeiten wechseln, signifikant schneller expandiert als eine Referenzpopulation mit Bakterien konstanter Schwimmgeschwindkeit. Im Vergleich zu frei schwimmenden Bakterien beobachteten wir in der Nähe der Oberfläche eine um 15% erhöhte Schwimmgeschwindigkeit der Zellen und eine um 90 % erhöhte Winkel-geschwindigkeit. Außerdem wurde eine signifikant höhere Zelldichte in der Nähe der Grenzfläche gemessen. Während sich der Anstieg in der Winkelgeschwindigkeit durch ein Drehmoment erklären lässt, welches in Oberflächennähe auf den rotierenden Zellkörper und die rotierenden Flagellen wirkt, kann die Beschleunigung und Akkumulation der Zellen bei dem beobachteten Abstand nicht durch existierende Theorien erklärt werden. Unsere Ergebnisse lassen vermuten, dass neben hydrodynamischen Effekten auch Kollisionen mit der Oberfläche eine wichtige Rolle spielen und sich die Rotationsgeschwindigkeit der Flagellenmotoren in der Nähe einer festen Oberfläche grundsätzlich verändert. Unsere Experimente zum Zellwachstum an Oberflächen zeigten, dass sich etwa sechs Stunden nach Beginn des Experiments größere Kolonien an der Kanaloberfläche auflösen und Zellen für ca. 30 Minuten zurück in die schwimmende Phase wechseln. Ergebnisse von mehreren Vergleichsexperimenten deuten darauf hin, dass dieser Übergang nach einer festen Anzahl von Zellteilungen an der Oberfläche erfolgt und nicht durch den Verbrauch des Wachstumsmediums bedingt wird. KW - Pseudomonas putida KW - Motilität KW - Flagellenbewegung KW - Random-Walk-Theorie KW - Schwimmende Mikroorganismen KW - pseudomonas putida KW - motility KW - flagellar filaments KW - random walk KW - cell tracking Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-70313 ER - TY - JOUR A1 - Tepper-Garcia, Thor A1 - Richter, Philipp A1 - Schaye, Joop T1 - Absorption signatures of warm-hot gas at low redshift - ne viii JF - Monthly notices of the Royal Astronomical Society N2 - At z < 1 a large fraction of the baryons is thought to reside in diffuse gas that has been shock-heated to high temperatures (10 (5)-10 (6) K). Absorption by the 770.41, 780.32 A doublet of Ne viii in quasar spectra represents a unique tool to study this elusive warm-hot phase. We have developed an analytic model for the properties of Ne viii absorbers that allows for an inhomogeneous metal distribution. Our model agrees with the predictions of a simulation from the OverWhelmingly Large Simulations project indicating that the average line-of-sight metal-filling fraction within the absorbing gas is low (c(L) similar to 0.1). Most of the Ne viii in our model is produced in low-density, collisionally ionized gas (n(H) = 10(-6)-10(-4) cm(-3), T = 10 (5)-10 (6) K). Strong Ne viii absorbers (log(10)(N-NeVIII/cm(-2))14), like those recently detected by Hubble Space Telescope/Cosmic Origins Spectrograph, are found to arise in higher density gas (n(H) greater than or similar to 10(-4) cm(-3), T approximate to 5 x 10 (5) K). Ne viii cloudlets harbour only 1 per cent of the cosmic baryon budget. The baryon content of the surrounding gas (which has similar densities and temperatures as the Ne viii cloudlets) is a factor c(-1)L higher. We conclude that Ne viii absorbers are robust probes of shock-heated diffuse gas, but that spectra with signal-to-noise ratios S/N > 100 would be required to detect the bulk of the baryons in warm-hot gas. KW - methods: analytical KW - methods: numerical KW - galaxies: formation KW - intergalactic medium KW - quasars: absorption lines KW - cosmology: theory Y1 - 2013 U6 - https://doi.org/10.1093/mnras/stt1712 SN - 0035-8711 SN - 1365-2966 VL - 436 IS - 3 SP - 2063 EP - 2081 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Temirbayev, Amirkhan A. A1 - Nalibayev, Yerkebulan D. A1 - Zhanabaev, Zeinulla Zh. A1 - Ponomarenko, Vladimir I. A1 - Rosenblum, Michael T1 - Autonomous and forced dynamics of oscillator ensembles with global nonlinear coupling an experimental study JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We perform experiments with 72 electronic limit-cycle oscillators, globally coupled via a linear or nonlinear feedback loop. While in the linear case we observe a standard Kuramoto-like synchronization transition, in the nonlinear case, with increase of the coupling strength, we first observe a transition to full synchrony and then a desynchronization transition to a quasiperiodic state. However, in this state the ensemble remains coherent so that the amplitude of the mean field is nonzero, but the frequency of the mean field is larger than frequencies of all oscillators. Next, we analyze effects of common periodic forcing of the linearly or nonlinearly coupled ensemble and demonstrate regimes when the mean field is entrained by the force whereas the oscillators are not. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.87.062917 SN - 1539-3755 SN - 1550-2376 VL - 87 IS - 6 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - tAliu, E. A1 - Archambault, S. A1 - Arlen, T. A1 - Aune, T. A1 - Beilicke, M. A1 - Benbow, W. A1 - Bird, R. A1 - Bouvier, A. A1 - Bradbury, S. M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cannon, A. A1 - Cesarini, A. A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Connolly, M. P. A1 - Cui, W. A1 - Dickherber, R. A1 - Duke, C. A1 - Dumm, J. A1 - Dwarkadas, Vikram V. A1 - Errando, M. A1 - Falcone, A. A1 - Federici, Simone A1 - Feng, Q. A1 - Finley, J. P. A1 - Finnegan, G. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gall, D. A1 - Gillanders, G. H. A1 - Godambe, S. A1 - Gotthelf, E. V. A1 - Griffin, S. A1 - Grube, J. A1 - Gyuk, G. A1 - Hanna, D. A1 - Holder, J. A1 - Huan, H. A1 - Hughes, G. A1 - Humensky, T. B. A1 - Kaaret, P. A1 - Karlsson, N. A1 - Kertzman, M. A1 - Khassen, Y. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Lang, M. J. A1 - Lee, K. A1 - Madhavan, A. S. A1 - Maier, G. A1 - Majumdar, P. A1 - McArthur, S. A1 - McCann, A. A1 - Millis, J. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nelson, T. A1 - de Bhroithe, A. O'Faolain A1 - Ong, R. A. A1 - Orr, M. A1 - Otte, A. N. A1 - Pandel, D. A1 - Park, N. A1 - Perkins, J. S. A1 - Pohl, Martin A1 - Popkow, A. A1 - Prokoph, H. A1 - Quinn, J. A1 - Ragan, K. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Roache, E. A1 - Rose, H. J. A1 - Ruppel, Jens A1 - Saxon, D. B. A1 - Schroedter, M. A1 - Sembroski, G. H. A1 - Sentuerk, G. D. A1 - Skole, C. A1 - Telezhinsky, Igor O. A1 - Tesic, G. A1 - Theiling, M. A1 - Thibadeau, S. A1 - Tsurusaki, K. A1 - Tyler, J. A1 - Varlotta, A. A1 - Vassiliev, V. V. A1 - Vincent, S. A1 - Wakely, S. P. A1 - Ward, J. E. A1 - Weekes, T. C. A1 - Weinstein, A. A1 - Weisgarber, T. A1 - Welsing, R. A1 - Williams, D. A. A1 - Zitzer, B. T1 - Discovery of TeV Gamma-Ray emission toward supernova remnant SNR G78.2+2.1 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We report the discovery of an unidentified, extended source of very-high-energy gamma-ray emission, VER J2019+407, within the radio shell of the supernova remnant SNR G78.2+2.1, using 21.4 hr of data taken by the VERITAS gamma-ray observatory in 2009. These data confirm the preliminary indications of gamma-ray emission previously seen in a two-year (2007-2009) blind survey of the Cygnus region by VERITAS. VER J2019+407, which is detected at a post-trials significance of 7.5 standard deviations in the 2009 data, is localized to the northwestern rim of the remnant in a region of enhanced radio and X-ray emission. It has an intrinsic extent of 0 degrees.23 +/- 0 degrees.03(stat-0 degrees.02sys)(+0 degrees.04) and its spectrum is well-characterized by a differential power law (dN/dE = N-0 x (E/TeV)-Gamma) with a photon index of Gamma = 2.37 +/- 0.14(stat) +/- 0.20(sys) and a flux normalization of N-0 = 1.5 +/- 0.2(stat) +/- 0.4(sys) x 10(-12) photon TeV-1 cm(-2) s(-1). This yields an integral flux of 5.2 +/- 0.8(stat) +/- 1.4(sys) x 10(-12) photon cm(-2) s(-1) above 320 GeV, corresponding to 3.7% of the Crab Nebula flux. We consider the relationship of the TeV gamma-ray emission with the GeV gamma-ray emission seen from SNR G78.2+2.1 as well as that seen from a nearby cocoon of freshly accelerated cosmic rays. Multiple scenarios are considered as possible origins for the TeV gamma-ray emission, including hadronic particle acceleration at the SNR shock. KW - acceleration of particles KW - cosmic rays KW - gamma rays: general KW - ISM: supernova remnants Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/770/2/93 SN - 0004-637X VL - 770 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - THES A1 - Takey, Ali Said Ahmed T1 - The XMM-Newton/SDSS galaxy cluster survey T1 - Die XMM-Newton/SDSS Galaxienhaufen-Durchmusterung N2 - Galaxy clusters are the largest known gravitationally bound objects, their study is important for both an intrinsic understanding of their systems and an investigation of the large scale structure of the universe. The multi- component nature of galaxy clusters offers multiple observable signals across the electromagnetic spectrum. At X-ray wavelengths, galaxy clusters are simply identified as X-ray luminous, spatially extended, and extragalactic sources. X-ray observations offer the most powerful technique for constructing cluster catalogues. The main advantages of the X-ray cluster surveys are their excellent purity and completeness and the X-ray observables are tightly correlated with mass, which is indeed the most fundamental parameter of clusters. In my thesis I have conducted the 2XMMi/SDSS galaxy cluster survey, which is a serendipitous search for galaxy clusters based on the X-ray extended sources in the XMM-Newton Serendipitous Source Catalogue (2XMMi-DR3). The main aims of the survey are to identify new X-ray galaxy clusters, investigate their X-ray scaling relations, identify distant cluster candidates, and study the correlation of the X-ray and optical properties. The survey is constrained to those extended sources that are in the footprint of the Sloan Digital Sky Survey (SDSS) in order to be able to identify the optical counterparts as well as to measure their redshifts that are mandatory to measure their physical properties. The overlap area be- tween the XMM-Newton fields and the SDSS-DR7 imaging, the latest SDSS data release at the starting of the survey, is 210 deg^2. The survey comprises 1180 X-ray cluster candidates with at least 80 background-subtracted photon counts, which passed the quality control process. To measure the optical redshifts of the X-ray cluster candidates, I used three procedures; (i) cross-matching these candidates with the recent and largest optically selected cluster catalogues in the literature, which yielded the photometric redshifts of about a quarter of the X-ray cluster candidates. (ii) I developed a finding algorithm to search for overdensities of galaxies at the positions of the X-ray cluster candidates in the photometric redshift space and to measure their redshifts from the SDSS-DR8 data, which provided the photometric redshifts of 530 groups/clusters. (iii) I developed an algorithm to identify the cluster candidates associated with spectroscopically targeted Luminous Red Galaxies (LRGs) in the SDSS-DR9 and to measure the cluster spectroscopic redshift, which provided 324 groups and clusters with spectroscopic confirmation based on spectroscopic redshift of at least one LRG. In total, the optically confirmed cluster sample comprises 574 groups and clusters with redshifts (0.03 ≤ z ≤ 0.77), which is the largest X-ray selected cluster catalogue to date based on observations from the current X-ray observatories (XMM-Newton, Chandra, Suzaku, and Swift/XRT). Among the cluster sample, about 75 percent are newly X-ray discovered groups/clusters and 40 percent are new systems to the literature. To determine the X-ray properties of the optically confirmed cluster sample, I reduced and analysed their X-ray data in an automated way following the standard pipelines of processing the XMM-Newton data. In this analysis, I extracted the cluster spectra from EPIC(PN, MOS1, MOS2) images within an optimal aperture chosen to maximise the signal-to-noise ratio. The spectral fitting procedure provided the X-ray temperatures kT (0.5 - 7.5 keV) for 345 systems that have good quality X-ray data. For all the optically confirmed cluster sample, I measured the physical properties L500 (0.5 x 10^42 – 1.2 x 10^45 erg s-1 ) and M500 (1.1 x 10^13 – 4.9 x 10^14 M⊙) from an iterative procedure using published scaling relations. The present X-ray detected groups and clusters are in the low and intermediate luminosity regimes apart from few luminous systems, thanks to the XMM-Newton sensitivity and the available XMM-Newton deep fields The optically confirmed cluster sample with measurements of redshift and X-ray properties can be used for various astrophysical applications. As a first application, I investigated the LX - T relation for the first time based on a large cluster sample of 345 systems with X-ray spectroscopic parameters drawn from a single survey. The current sample includes groups and clusters with wide ranges of redshifts, temperatures, and luminosities. The slope of the relation is consistent with the published ones of nearby clusters with higher temperatures and luminosities. The derived relation is still much steeper than that predicted by self-similar evolution. I also investigated the evolution of the slope and the scatter of the LX - T relation with the cluster redshift. After excluding the low luminosity groups, I found no significant changes of the slope and the intrinsic scatter of the relation with redshift when dividing the sample into three redshift bins. When including the low luminosity groups in the low redshift subsample, I found its LX - T relation becomes after than the relation of the intermediate and high redshift subsamples. As a second application of the optically confirmed cluster sample from our ongoing survey, I investigated the correlation between the cluster X-ray and the optical parameters that have been determined in a homogenous way. Firstly, I investigated the correlations between the BCG properties (absolute magnitude and optical luminosity) and the cluster global proper- ties (redshift and mass). Secondly, I computed the richness and the optical luminosity within R500 of a nearby subsample (z ≤ 0.42, with a complete membership detection from the SDSS data) with measured X-ray temperatures from our survey. The relation between the estimated optical luminosity and richness is also presented. Finally, the correlation between the cluster optical properties (richness and luminosity) and the cluster global properties (X-ray luminosity, temperature, mass) are investigated. N2 - Im Rahmen dieser Arbeit habe ich die 2XMMi/SDSS Galaxienhaufendurchmusterung erstellt (2XMMi/SDSS galaxy cluster survey), eine Suche nach Galaxienhaufen welche auf der Detektion ausgedehnter Röntgenquellen im XMM-Newton Quellenkatalog (2XMMi-DR3) basiert. Die Hauptziele dieser Suche sind die Identifizierung bisher unbekannter röntgenheller Galaxienhaufen, die Erforschung ihrer Beziehungen zwischen Röntgenleuchtkraft und Temperatur (X-ray scaling relation), eine Entdeckung von möglichen weit entfernten Galaxienhaufen und die Beziehung zwischen Eigenschaften im Optischen und Röntgenbereich. Die Durchmusterung ist für alle Quellen der Himmelsregionen ausgelegt, die vom Sloan Digital Sky Survey (SDSS) erfasst werden. Das Ziel besteht darin, ihre optischen Gegenstücke zu finden und deren Rotverschiebungen zu bestimmen. Die gemeinsamen Himmelsareale zwischen XMM-Newton und dem Bildmaterial vom SDSS-DR7 umfassen 210 deg^2. Meine Durchmusterung enthält 1180 mögliche Galaxienhaufen mit wenigstens 80 vom Hintergrund bereinigten Photonen im Röntgenbereich, die einer Qualitätskontrolle erfolgreich standgehalten haben. Um die Rotverschiebungen der möglichen Galaxienhaufen im optischen Bereich zu bestimmen nutzte ich drei Vorgehensweisen: (i) Ein Abgleich jener Kandidaten mit den neuesten und umfangreichsten Katalogen optisch ausgewählter Galaxienhaufen, die in der Literatur verfügbar sind. (ii) Ich entwickelte einen Algorithmus, um Rotverschiebungen der optischen Gegenstücke aus Daten vom SDSS-DR8 zu ermitteln, welches zu photometrischen Rotverschiebungen von 530 Galaxiengruppen-/haufen führte. (iii) Ein weiterer von mir entwickelter Algorithmus nutzte die spektroskopischen Rotverschiebung von roten leuchtkräftigen Galaxien (LRGs) in den Daten des SDSS-DR9 und ergab 324 Gruppen und Haufen. Zusammengefasst enthält diese Probe 574 auch im optischen nachgewiesener Galaxiengruppen und -haufen mit bekannten Rotverschiebungen (0.03 ≤ z ≤ 0.77) - der zur Zeit umfangreichste Katalog von im Röntgenbereich ausgewählten Galaxienhaufen basierend auf aktuellen Röntgenbeobachtungen. Unter jenen Haufen waren ca. 75% im Röntgenbereich nicht bekannt und 40% fanden in der bisherigen Literatur noch keine Erwähnung. Um die Röntgeneigenschaften der im Optischen bestätigten Haufen zu bestimmen, war eine automatische Reduktion und Analyse der Röntgendaten unverzichtbar. Die Prozedur, welche Modelle an die Röntgenspektren anpasste, ergab Temperaturen kT von 0.5 – 7.5 keV für 345 Kandidaten. Für alle Haufen, die auch im optischen auffindbar waren, bestimmte ich die physikalischen Eigenschaften L500 (0.5 x 10^42 – 1.2 x 10^45 erg s^-1) und M500 (1.1 x 10^13 – 4.9 x 10^14 M⊙). Die Probe optisch bestätigter Galaxienhaufen mit gemessenen Rotverschiebungen und Röntgeneigenschaften kann für viele astrophysikalische Anwendungen genutzt werden. Als eine der ersten Anwendungen betrachtete ich die Beziehung zwischen LX - T; das erste Mal für eine so grosse Anzahl von 345 Objekten. Der aktuelle Katalog enthält Gruppen und Haufen, die einen grossen Bereich in Rotverschiebung, Temperatur und Helligkeit abdecken. Der Anstieg jener Beziehung ist im Einklang mit bereits publizierten Werten für nahegelegene Galaxienhaufen von hoher Temperatur und Helligkeit. Nach dem Ausschluss leuchtschwacher Gruppen und der Einteilung der Daten in drei nach Rotverschiebung geordneter Gruppen, waren keine signifikanten Änderungen von Anstieg und intrinsischer Streuung zu beobachten. Als zweite Anwendung unserer Durchmusterung, untersuchte ich die Haufen bezüglich deren Eigenschaften im Optischen und im Röntgenbereich. Zuerst betrachtete ich den Zusammenhang zwischen den Eigenschaften (absolute Helligkeit und optische Leuchkraft) der hellsten Haufengalaxie (BCG) mit denen des Haufens als Ganzem (Rotverschiebung und Masse). Danach berechnete ich die Reichhaltigkeit der Galaxienhaufen und deren optische Leuchtkraft innerhalb von R500 für eine Stichprobe nahegelegener Haufen (z ≤ 0.42, hier sind SDSS Daten noch empfindlich genug um den Grossteil der Haufengalaxien abzubilden) mit gemessenen Röntgentemperaturen. Schlussendlich konnten dieWechselwirkungen zwischen den optischen Eigenschaften (Reichhaltigkeit und Leuchtkraft) und den globalen Eigenschaften (Röntgenleuchtkraft, Temperatur und Masse) näher untersucht werden. KW - hochenergetische Astrophysik KW - Röntgenastronomie KW - Galaxienhaufen KW - high energy astrophysics KW - X-ray astronomy KW - clusters of galaxies Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-71229 ER - TY - THES A1 - Suárez Velásquez, Isabel Fernanda T1 - The contribution of the warm-hot intergalactic medium to the CMB anisotropies and distortions Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - Sturm, R. A1 - Haberl, F. A1 - Oskinova, Lida A1 - Schurch, M. P. E. A1 - Henault-Brunet, V. A1 - Gallagher, J. S. A1 - Udalski, A. T1 - Long-term evolution of the neutron-star spin period of SXP1062 JF - Astronomy and astrophysics : an international weekly journal N2 - Context. The Be/X-ray binary SXP 1062 is of especial interest owing to the large spin period of the neutron star, its large spin-down rate, and the association with a supernova remnant constraining its age. This makes the source an important probe for accretion physics. Aims. To investigate the long-term evolution of the spin period and associated spectral variations, we performed an XMM-Newton target-of-opportunity observation of SXP 1062 during X-ray outburst. Methods. Spectral and timing analysis of the XMM-Newton data was compared with previous studies, as well as complementary Swift/XRT monitoring and optical spectroscopy with the SALT telescope were obtained. Results. The spin period was measured to be P-s = (1071.01 +/- 0.16) s on 2012 Oct. 14. The X-ray spectrum is similar to that of previous observations. No convincing cyclotron absorption features, which could be indicative for a high magnetic field strength, are found. The high-resolution RGS spectra indicate the presence of emission lines, which may not completely be accounted for by the SNR emission. The comparison of multi-epoch optical spectra suggest an increasing size or density of the decretion disc around the Be star. Conclusions. SXP 1062 showed a net spin-down with an average of P-s = ( 2.27 +/- 0.44) s yr(-1) over a baseline of 915 days. KW - pulsars: individual: SXP1062 KW - galaxies: individual: Small Magellanic Cloud KW - stars: emission-line, Be KW - stars: neutron KW - X-rays: binaries Y1 - 2013 U6 - https://doi.org/10.1051/0004-6361/201321755 SN - 0004-6361 VL - 556 IS - 4 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Stoyanov, Hristiyan A1 - Kollosche, Matthias A1 - Risse, Sebastian A1 - Wache, Remi A1 - Kofod, Guggi T1 - Soft conductive elastomer materials for stretchable electronics and voltage controlled artificial muscles JF - Advanced materials N2 - Block copolymer elastomer conductors (BEC) are mixtures of block copolymers grafted with conducting polymers, which are found to support very large strains, while retaining a high level of conductivity. These novel materials may find use in stretchable electronics. The use of BEC is demonstrated in a capacitive strain sensor and in an artificial muscle of the dielectric elastomer actuator type, supporting more than 100% actuation strain and capacity strain sensitivity up to 300%. KW - soft electrical connections KW - stretchable electronics KW - elastic conductor KW - compliant electrodes Y1 - 2013 U6 - https://doi.org/10.1002/adma.201202728 SN - 0935-9648 VL - 25 IS - 4 SP - 578 EP - 583 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Stich, Michael A1 - Casal, Alfonso A1 - Beta, Carsten T1 - Stabilization of standing waves through time-delay feedback JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - Standing waves are studied as solutions of a complex Ginzburg-Landau equation subjected to local and global time-delay feedback terms. The onset is described as an instability of the uniform oscillations with respect to spatially periodic perturbations. The solution of the standing wave pattern is given analytically and studied through simulations. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.042910 SN - 1539-3755 SN - 1550-2376 VL - 88 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Sliusarenko, O. Yu. A1 - Surkov, D. A. A1 - Gonchar, V. Yu. A1 - Chechkin, Aleksei V. T1 - Stationary states in bistable system driven by Levy noise JF - European physical journal special topics N2 - We study the properties of the probability density function (PDF) of a bistable system driven by heavy tailed white symmetric L,vy noise. The shape of the stationary PDF is found analytically for the particular case of the L,vy index alpha = 1 (Cauchy noise). For an arbitrary L,vy index we employ numerical methods based on the solution of the stochastic Langevin equation and space fractional kinetic equation. In contrast to the bistable system driven by Gaussian noise, in the L,vy case, the positions of maxima of the stationary PDF do not coincide with the positions of minima of the bistable potential. We provide a detailed study of the distance between the maxima and the minima as a function of the depth of the potential and the L,vy noise parameters. Y1 - 2013 U6 - https://doi.org/10.1140/epjst/e2013-01736-0 SN - 1951-6355 VL - 216 IS - 1 SP - 133 EP - 138 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Shayduk, Roman A1 - Herzog, Marc A1 - Bojahr, Andre A1 - Schick, Daniel A1 - Gaal, Peter A1 - Leitenberger, Wolfram A1 - Navirian, Hengameh A1 - Sander, Mathias A1 - Goldshteyn, Jevgenij A1 - Vrejoiu, Ionela A1 - Bargheer, Matias T1 - Direct time-domain sampling of subterahertz coherent acoustic phonon spectra in SrTiO3 using ultrafast x-ray diffraction JF - Physical review : B, Condensed matter and materials physics N2 - We synthesize sub-THz longitudinal quasimonochromatic acoustic phonons in a SrTiO3 single crystal using a SrRuO3/SrTiO3 superlattice as an optical-acoustic transducer. The generated acoustic phonon spectrum is determined using ultrafast x-ray diffraction. The analysis of the generated phonon spectrum in the time domain reveals a k-vector dependent phonon lifetime. It is observed that even at sub-THz frequencies the phonon lifetime agrees with the 1/omega(2) power law known from Akhiezer's model for hyper sound attenuation. The observed shift of the synthesized spectrum to the higher q is discussed in the framework of nonlinear effects appearing due to the high amplitude of the synthesized phonons. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevB.87.184301 SN - 1098-0121 VL - 87 IS - 18 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Send, Sebastian A1 - Abboud, Ali A1 - Hartmann, Robert A1 - Huth, M. A1 - Leitenberger, Wolfram A1 - Pashniak, N. A1 - Schmidt, J. A1 - Strüder, Lothar A1 - Pietsch, Ullrich T1 - Characterization of a pnCCD for applications with synchrotron radiation JF - Nuclear instruments & methods in physics research : a journal on accelerators, instrumentation and techniques applied to research in nuclear and atomic physics, materials science and related fields in physics ; A, Accelerators, spectrometers, detectors and associated equipment N2 - In this work we study the response of a pnCCD by means of X-ray spectroscopy in the energy range between 6 key and 20 key and by Laue diffraction techniques. The analyses include measurements of characteristic detector parameters like energy resolution, count rate capability and effects of different gain settings. The limit of a single photon counting operation in white beam X-ray diffraction experiments is discussed with regard to the occurrence of pile-up events, for which the energy information about individual photons is lost. In case of monochromatic illumination the pnCCD can be used as a fast conventional CCD with a charge handling capacity (CHC) of about 300,000 electrons per pixel. If the CHC is exceeded, any surplus charge will spill to neighboring pixels perpendicular to the transfer direction due to electrostatic repulsion. The possibilities of increasing the number of storable electrons are investigated for different voltage settings by exposing a single pixel with X-rays generated by a microfocus X-ray source. The pixel binning mode is tested as an alternative approach that enables a pnCCD operation with significantly shorter readout times. KW - pnCCD KW - X-ray spectroscopy KW - X-ray imaging KW - Energy-dispersive Laue diffraction Y1 - 2013 U6 - https://doi.org/10.1016/j.nima.2013.01.044 SN - 0168-9002 VL - 711 IS - 5 SP - 132 EP - 142 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Schwabedal, Justus T. C. A1 - Pikovskij, Arkadij T1 - Phase description of stochastic oscillations JF - Physical review letters N2 - We introduce an invariant phase description of stochastic oscillations by generalizing the concept of standard isophases. The average isophases are constructed as sections in the state space, having a constant mean first return time. The approach allows us to obtain a global phase variable of noisy oscillations, even in the cases where the phase is ill defined in the deterministic limit. A simple numerical method for finding the isophases is illustrated for noise-induced switching between two coexisting limit cycles, and for noise-induced oscillation in an excitable system. We also discuss how to determine isophases of observed irregular oscillations, providing a basis for a refined phase description in data analysis. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.204102 SN - 0031-9007 VL - 110 IS - 20 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schulz, Johannes H. P. A1 - Chechkin, Aleksei V. A1 - Metzler, Ralf T1 - Correlated continuous time random walks - combining scale-invariance with long-range memory for spatial and temporal dynamics JF - Journal of physics : A, Mathematical and theoretical N2 - Standard continuous time random walk (CTRW) models are renewal processes in the sense that at each jump a new, independent pair of jump length and waiting time are chosen. Globally, anomalous diffusion emerges through scale-free forms of the jump length and/or waiting time distributions by virtue of the generalized central limit theorem. Here we present a modified version of recently proposed correlated CTRW processes, where we incorporate a power-law correlated noise on the level of both jump length and waiting time dynamics. We obtain a very general stochastic model, that encompasses key features of several paradigmatic models of anomalous diffusion: discontinuous, scale-free displacements as in Levy flights, scale-free waiting times as in subdiffusive CTRWs, and the long-range temporal correlations of fractional Brownian motion (FBM). We derive the exact solutions for the single-time probability density functions and extract the scaling behaviours. Interestingly, we find that different combinations of the model parameters lead to indistinguishable shapes of the emerging probability density functions and identical scaling laws. Our model will be useful for describing recent experimental single particle tracking data that feature a combination of CTRW and FBM properties. Y1 - 2013 U6 - https://doi.org/10.1088/1751-8113/46/47/475001 SN - 1751-8113 SN - 1751-8121 VL - 46 IS - 47 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Schulz, Johannes H. P. A1 - Barkai, Eli A1 - Metzler, Ralf T1 - Aging effects and population splitting in single-particle trajectoryaverages JF - Physical review letters N2 - We study time averages of single particle trajectories in scale-free anomalous diffusion processes, in which the measurement starts at some time t(a) > 0 after initiation of the process at t = 0. Using aging renewal theory, we show that for such nonstationary processes a large class of observables are affected by a unique aging function, which is independent of boundary conditions or the external forces. Moreover, we discuss the implications of aging induced population splitting: with growing age ta of the process, an increasing fraction of particles remains motionless in a measurement of fixed duration. Consequences for single biomolecule tracking in live cells are discussed. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.020602 SN - 0031-9007 SN - 1079-7114 VL - 110 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schubert, Marcel A1 - Preis, Eduard A1 - Blakesley, James C. A1 - Pingel, Patrick A1 - Scherf, Ullrich A1 - Neher, Dieter T1 - Mobility relaxation and electron trapping in a donor/acceptor copolymer JF - Physical review : B, Condensed matter and materials physics N2 - To address the nature of charge transport and the origin of severe (intrinsic) trapping in electron-transporting polymers, transient and steady-state charge transport measurements have been conducted on the prototype donor/acceptor copolymer poly[2,7-(9,9-dialkyl-fluorene)-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (PFTBTT). A charge-generation layer technique is used to selectively address transport of the desired charge carrier type, to perform time-of-flight measurements on samples with < 200 nm thickness, and to combine the time-of-flight and the photocharge extraction by linearly increasing voltage (photo-CELIV) techniques to investigate charge carrier dynamics over a wide time range. Significant trapping of free electrons is observed in the bulk of dioctyl-substituted PFTBTT (alt-PF8TBTT), introducing a strong relaxation of the charge carrier mobility with time. We used Monte-Carlo simulation to simulate the measured transient data and found that all measurements can be modeled with a single parameter set, with the charge transport behavior determined by multiple trapping and detrapping of electrons in an exponential trap distribution. The influence of the concomitant mobility relaxation on the transient photocurrent characteristics in photo-CELIV experiments is discussed and shown to explain subtle features that were seen in former publications but were not yet assigned to electron trapping. Comparable studies on PFTBTT copolymers with chemical modifications of the side chains and backbone suggest that the observed electron trapping is not caused by a distinct chemical species but rather is related to interchain interactions. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevB.87.024203 SN - 1098-0121 VL - 87 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schleussner, Carl-Friedrich A1 - Feulner, G. T1 - A volcanically triggered regime shift in the subpolar North Atlantic Ocean as a possible origin of the Little Ice Age JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - Among the climatological events of the last millennium, the Northern Hemisphere Medieval Climate Anomaly succeeded by the Little Ice Age are of exceptional importance. The origin of these regional climate anomalies remains a subject of debate and besides external influences like solar and volcanic activity, internal dynamics of the climate system might have also played a dominant role. Here, we present transient last millennium simulations of the fully coupled model of intermediate complexity Climber 3a forced with stochastically reconstructed wind-stress fields. Our results indicate that short-lived volcanic eruptions might have triggered a cascade of sea ice ocean feedbacks in the North Atlantic, ultimately leading to a persistent regime shift in the ocean circulation. We find that an increase in the Nordic Sea sea-ice extent on decadal timescales as a consequence of major volcanic eruptions in our model leads to a spin-up of the subpolar gyre and a weakened Atlantic meridional overturning circulation, eventually causing a persistent, basin-wide cooling. These results highlight the importance of regional climate feedbacks such as a regime shift in the subpolar gyre circulation for understanding the dynamics of past and future climate. Y1 - 2013 U6 - https://doi.org/10.5194/cp-9-1321-2013 SN - 1814-9324 SN - 1814-9332 VL - 9 IS - 3 SP - 1321 EP - 1330 PB - Copernicus CY - Göttingen ER - TY - THES A1 - Schleussner, Carl-Friedrich T1 - Variability and trend of the North Atlantic ocean circulation in past and future climate Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - Schick, Daniel A1 - Bojahr, Andre A1 - Herzog, Marc A1 - Gaal, P. A1 - Vrejoiu, I. A1 - Bargheer, Matias T1 - Following Strain-Induced Mosaicity Changes of Ferroelectric Thin Films by Ultrafast Reciprocal Space Mapping JF - Physical review letters N2 - We investigate coherent phonon propagation in a thin film of ferroelectric PbZr0.2Ti0.8O3 (PZT) by ultrafast x-ray diffraction experiments, which are analyzed as time-resolved reciprocal space mapping in order to observe the in-and out-of-plane structural dynamics, simultaneously. The mosaic structure of the PZT leads to a coupling of the excited out-of-plane expansion to in-plane lattice dynamics on a picosecond time scale, which is not observed for out-of-plane compression. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.095502 SN - 0031-9007 SN - 1079-7114 VL - 110 IS - 9 PB - American Physical Society CY - College Park ER - TY - THES A1 - Schick, Daniel T1 - Ultrafast lattice dynamics in photoexcited nanostructures : femtosecond X-ray diffraction with optimized evaluation schemes T1 - Ultraschnelle Gitterdynamik in optisch angeregten Nanostrukturen : Femtosekunden-Röntgendiffraktion mit optimierten Auswerteroutinen N2 - Within the course of this thesis, I have investigated the complex interplay between electron and lattice dynamics in nanostructures of perovskite oxides. Femtosecond hard X-ray pulses were utilized to probe the evolution of atomic rearrangement directly, which is driven by ultrafast optical excitation of electrons. The physics of complex materials with a large number of degrees of freedom can be interpreted once the exact fingerprint of ultrafast lattice dynamics in time-resolved X-ray diffraction experiments for a simple model system is well known. The motion of atoms in a crystal can be probed directly and in real-time by femtosecond pulses of hard X-ray radiation in a pump-probe scheme. In order to provide such ultrashort X-ray pulses, I have built up a laser-driven plasma X-ray source. The setup was extended by a stable goniometer, a two-dimensional X-ray detector and a cryogen-free cryostat. The data acquisition routines of the diffractometer for these ultrafast X-ray diffraction experiments were further improved in terms of signal-to-noise ratio and angular resolution. The implementation of a high-speed reciprocal-space mapping technique allowed for a two-dimensional structural analysis with femtosecond temporal resolution. I have studied the ultrafast lattice dynamics, namely the excitation and propagation of coherent phonons, in photoexcited thin films and superlattice structures of the metallic perovskite SrRuO3. Due to the quasi-instantaneous coupling of the lattice to the optically excited electrons in this material a spatially and temporally well-defined thermal stress profile is generated in SrRuO3. This enables understanding the effect of the resulting coherent lattice dynamics in time-resolved X-ray diffraction data in great detail, e.g. the appearance of a transient Bragg peak splitting in both thin films and superlattice structures of SrRuO3. In addition, a comprehensive simulation toolbox to calculate the ultrafast lattice dynamics and the resulting X-ray diffraction response in photoexcited one-dimensional crystalline structures was developed in this thesis work. With the powerful experimental and theoretical framework at hand, I have studied the excitation and propagation of coherent phonons in more complex material systems. In particular, I have revealed strongly localized charge carriers after above-bandgap femtosecond photoexcitation of the prototypical multiferroic BiFeO3, which are the origin of a quasi-instantaneous and spatially inhomogeneous stress that drives coherent phonons in a thin film of the multiferroic. In a structurally imperfect thin film of the ferroelectric Pb(Zr0.2Ti0.8)O3, the ultrafast reciprocal-space mapping technique was applied to follow a purely strain-induced change of mosaicity on a picosecond time scale. These results point to a strong coupling of in- and out-of-plane atomic motion exclusively mediated by structural defects. N2 - Im Rahmen dieser Arbeit habe ich mich mit den komplexen Wechselwirkungen zwischen Elektronen- und Gitterdynamik in oxidischen Perowskit-Nanostrukturen beschäftigt. Dazu wurden verschiedene Proben mit intensiven, ultrakurzen Laserpulsen angeregt. Um die zeitliche Entwicklung der induzierten atomaren Umordnung zu untersuchen, wurden Femtosekunden-Pulse harter Röntgenstrahlung genutzt. Zunächst wurde die ultraschnelle Gitterdynamik in einfachen Modellsystemen mit zeitaufgelösten Röntgendiffraktionsexperimenten untersucht, um im Anschluss ähnliche Experimente an komplexeren Materialien mit mehreren Freiheitsgraden interpretieren zu können. Die Bewegung der Atome in einem Kristall kann über Anrege-Abtast-Verfahren direkt mit gepulster, harter Röntgenstrahlung gemessen werden. Die Dauer der Röntgenpulse muss dafür einige hundert Femtosekunden kurz sein. Um diese ultrakurzen Röntgenpulse zu erzeugen, habe ich eine lasergetriebene Plasma-Röntgenquelle aufgebaut. Der Aufbau wurde um ein stabiles Goniometer, einen zweidimensionalen Röntgendetektor und einen kryogenfreien Kryostat erweitert und in Bezug auf das Signal-zu-Rausch-Verhältnis und die Winkelauflösung optimiert. Durch die Entwicklung einer schnellen Methode zur Vermessung des reziproken Raums konnte erstmals an solch einer Quelle eine zweidimensionale Strukturanalyse mit Femtosekunden-Zeitauflösung realisiert werden. Die Anregung und Ausbreitung von kohärenten Phononen habe ich in optisch angeregten Dünnfilm- und Übergitterstrukturen untersucht. Eine entscheidende Rolle spielen dabei metallische SrRuO3 Schichten. Durch die quasi-instantane Kopplung des Gitters an die optisch angeregten Elektronen in SrRuO3 wird ein räumlich und zeitlich wohldefiniertes Druckprofil erzeugt. Dadurch kann der Einfluss der resultierenden kohärenten Gitterdynamik auf die zeitaufgelösten Röntgendiffraktionsdaten im Detail verstanden werden. Beobachtet wurde z.B. das Auftreten einer transienten Aufspaltung eines Bragg-Reflexes bei Dünnfilm- und Übergitterstrukturen aus SrRuO3. Außerdem wurde eine umfangreiche Simulationsumgebung entwickelt, mit deren Hilfe die ultraschnelle Dynamik und die dazugehörigen Röntgendiffraktionssignale in optisch angeregten eindimensionalen Kristallstrukturen berechnet werden können. Der von mir entwickelte experimentelle Aufbau sowie das Simulationspaket zur Datenanalyse und -interpretation wurden anschließend für die Untersuchung kohärenter Phononen in komplexeren Materialsystemen eingesetzt. Im Speziellen konnte ich in multiferroischem BiFeO3 eine stark lokalisierte Ladungsträgerverteilung nach einer optischen Femtosekunden-Anregung nachweisen. Sie ist die Ursache für einen quasi-instantanen und räumlich inhomogenen Druck, der die kohärenten Phononen in einem dünnen Film dieses Multiferroikums erzeugt. Außerdem habe ich die ultraschnelle Vermessung des reziproken Raums angewendet, um eine verzerrungsinduzierte Veränderung der Mosaizität in einem strukturell unvollkommenen Film aus ferroelektrischem Pb(Zr0.2Ti0.8)O3 zu verfolgen. Die Ergebnisse deuten auf eine ausschließlich durch strukturelle Defekte vermittelte Kopplung der atomaren Bewegungen parallel und senkrecht zur Flächennormalen des Filmes hin. KW - ultraschnelle Röntgendiffraktion KW - Gitterdynamik KW - Nanostruktur KW - optische Anregung KW - Perowskit KW - ultrafast X-ray diffraction KW - lattice dynamics KW - nanostructure KW - photoexcitation KW - perovskite Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-68827 ER - TY - CHAP A1 - Santer, Svetlana A1 - Zakrevskyy, Yuriy T1 - Reversible light-controlled compaction of soft colloids by azobenzene containing surfactant T2 - Abstracts of papers : joint conference / The Chemical Institute of Cananda, CIC, American Chemical Society, ACS Y1 - 2013 SN - 0065-7727 VL - 245 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Salert, Beatrice Ch. D. A1 - Krueger, Hartmut A1 - Bagnich, Sergey A. A1 - Unger, Thomas A1 - Jaiser, Frank A1 - Al-Sa'di, Mahmoud A1 - Neher, Dieter A1 - Hayer, Anna A1 - Eberle, Thomas T1 - New polymer matrix system for phosphorescent organic light-emitting diodes and the role of the small molecular co-host JF - Journal of polymer science : A, Polymer chemistry N2 - A new matrix system for phosphorescent organic light-emitting diodes (OLEDs) based on an electron transporting component attached to an inert polymer backbone, an electronically neutral co-host, and a phosphorescent dye that serves as both emitter and hole conductor are presented. The inert co-host is used either as small molecules or covalently connected to the same chain as the electron-transporting host. The use of a small molecular inert co-host in the active layer is shown to be highly advantageous in comparison to a purely polymeric matrix bearing the same functionalities. Analysis of the dye phosphorescence decay in pure polymer, small molecular co-host film, and their blend lets to conclude that dye molecules distribute mostly in the small molecular co-host phase, where the co-host prevents agglomeration and self-quenching of the phosphorescence as well as energy transfer to the electron transporting units. In addition, the co-host accumulates at the anode interface where it acts as electron blocking layer and improves hole injection. This favorable phase separation between polymeric and small molecular components results in devices with efficiencies of about 47 cd/A at a luminance of 1000 cd/m(2). Investigation of OLED degradation demonstrates the presence of two time regimes: one fast component that leads to a strong decrease at short times followed by a slower decrease at longer times. Unlike the long time degradation, the efficiency loss that occurs at short times is reversible and can be recovered by annealing of the device at 180 degrees C. We also show that the long-time degradation must be related to a change of the optical and electrical bulk properties. KW - charge transport KW - conducting polymer KW - degradation KW - host-guest systems KW - light-emitting diodes KW - random copolymer KW - synthesis KW - UV-vis spectroscopy Y1 - 2013 U6 - https://doi.org/10.1002/pola.26409 SN - 0887-624X VL - 51 IS - 3 SP - 601 EP - 613 PB - Wiley-Blackwell CY - Hoboken ER - TY - BOOK A1 - Rüdiger, Günther A1 - Kitchatinov, Leonid L. A1 - Hollerbach, Rainer T1 - Magnetic processes in astrophysics : theory, simulations, experiments Y1 - 2013 SN - 978-3-527-41034-7 PB - Wiley-VCH CY - Weinheim, Bergstr. ER - TY - JOUR A1 - Rössle, Matthias A1 - Wang, C. N. A1 - Marsik, P. A1 - Yazdi-Rizi, Meghdad A1 - Kim, K. W. A1 - Dubroka, Adam A1 - Marozau, Ivan A1 - Schneider, C. W. A1 - Humlicek, J. A1 - Baeriswyl, D. A1 - Bernhard, C. T1 - Optical probe of ferroelectric order in bulk and thin-film perovskite titanates JF - Physical review : B, Condensed matter and materials physics N2 - We have measured the temperature dependence of the direct band gap Eg in SrTiO3 and BaTiO3 and related materials with quantum-paraelectric and ferroelectric properties using optical spectroscopy. We show that Eg exhibits an anomalous temperature dependence with pronounced changes in the vicinity of the ferroelectric transition that can be accounted for in terms of the Frohlich electron-phonon interaction with an optical phonon mode, the so-called soft mode. In addition, we demonstrate that these characteristic changes of Eg can be readily detected even in very thin films of SrTiO3 with a strain-induced ferroelectric order. Optical spectroscopy thus can be used as a rather sensitive probe of ferroelectric order in very thin films of these titanates and probably also in subsequent multilayers and devices. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevB.88.104110 SN - 1098-0121 VL - 88 IS - 10 PB - American Physical Society CY - College Park ER - TY - THES A1 - Rätzel, Dennis T1 - Tensorial spacetime geometries and background-independent quantum field theory T1 - Tensorielle Raumzeit-Geometrien und hintergrundunabhängige Quantenfeldtheorie N2 - Famously, Einstein read off the geometry of spacetime from Maxwell's equations. Today, we take this geometry that serious that our fundamental theory of matter, the standard model of particle physics, is based on it. However, it seems that there is a gap in our understanding if it comes to the physics outside of the solar system. Independent surveys show that we need concepts like dark matter and dark energy to make our models fit with the observations. But these concepts do not fit in the standard model of particle physics. To overcome this problem, at least, we have to be open to matter fields with kinematics and dynamics beyond the standard model. But these matter fields might then very well correspond to different spacetime geometries. This is the basis of this thesis: it studies the underlying spacetime geometries and ventures into the quantization of those matter fields independently of any background geometry. In the first part of this thesis, conditions are identified that a general tensorial geometry must fulfill to serve as a viable spacetime structure. Kinematics of massless and massive point particles on such geometries are introduced and the physical implications are investigated. Additionally, field equations for massive matter fields are constructed like for example a modified Dirac equation. In the second part, a background independent formulation of quantum field theory, the general boundary formulation, is reviewed. The general boundary formulation is then applied to the Unruh effect as a testing ground and first attempts are made to quantize massive matter fields on tensorial spacetimes. N2 - Bekanntermaßen hat Albert Einstein die Geometrie der Raumzeit an den Maxwell-Gleichungen abgelesen. Heutzutage nehmen wie diese Geometrie so ernst, dass unsere fundamentale Materietheorie, das Standardmodell der Teilchenphysik, darauf beruht. Sobald es jedoch um die Physik außerhalb des Sonnensystems geht, scheinen einige Dinge unverstanden zu sein. Unabhängige Beobachtungsreihen zeigen, dass wir Konzepte wie dunkle Materie und dunkle Energie brauchen um unsere Modelle mit den Beobachtungen in Einklang zu bringen. Diese Konzepte passen aber nicht in das Standardmodell der Teilchenphysik. Um dieses Problem zu überwinden, müssen wir zumindest offen sein für Materiefelder mit Kinematiken und Dynamiken die über das Standardmodell hinaus gehen. Diese Materiefelder könnten dann aber auch durchaus zu anderen Raumzeitgeometrien gehören. Das ist die Grundlage dieser Arbeit: sie untersucht die zugehörigen Raumzeitgeometrien und beschäftigt sich mit der Quantisierung solcher Materiefelder unabhängig von jeder Hintergrundgeometrie. Im ersten Teil dieser Arbeit werden Bedingungen identifiziert, die eine allgemeine tensorielle Geometrie erfüllen muss um als sinnvolle Raumzeitgeometrie dienen zu können. Die Kinematik masseloser und massiver Punktteilchen auf solchen Raumzeitgeometrien werden eingeführt und die physikalischen Implikationen werden untersucht. Zusätzlich werden Feldgleichungen für massive Materiefelder konstruiert, wie zum Beispiel eine modifizierte Dirac-Gleichung. Im zweiten Teil wird eine hintergrundunabhängige Formulierung der Quantenfeldtheorie, die General Boundary Formulation, betrachtet. Die General Boundary Formulation wird dann auf den Unruh-Effekt angewendet und erste Versuche werden unternommen massive Materiefelder auf tensoriellen Raumzeiten zu quantisieren. KW - Quantenfeldtheorie KW - Raumzeitgeometrie KW - Hochenergiephysik KW - Elementarteilchen KW - Unruh-Effekt KW - quantum field theory KW - spacetime geometry KW - high energy physics KW - elementary particles KW - Unruh effect Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-65731 ER - TY - JOUR A1 - Rychkov, Dmitry A1 - Rychkov, A. A1 - Efimov, N. A1 - Malygin, A. A1 - Gerhard, Reimund T1 - Higher stabilities of positive and negative charge on tetrafluoroethylene-hexafluoropropylene copolymer (FEP) electrets treated with titanium-tetrachloride vapor JF - Applied physics : A, Materials science & processing N2 - Tetrafluoroethylene-hexafluoropropylene copolymer (FEP) films were treated with titanium-tetrachloride vapor in a molecular-layer deposition process. As a result of the surface treatment, significant improvements of the thermal and temporal charge stability were observed. Charge-decay measurements revealed enhancements of the half-value temperatures and the relaxation times of positively charged FEP electrets by at least 120 A degrees C and two orders of magnitude, respectively. Beyond previous publications on fluoropolymer electrets with surface modification, we here report enhanced charge stabilities of the FEP films charged in negative as well as in positive corona discharges. Even though the improvement for negatively charged FEP films is moderate (half-value temperature about 20 A degrees C higher), our experiments show that the asymmetry in positive and negative charge stability that is typical for FEP electrets can be overcome by means of chemical surface treatments. The results are discussed in the context of the formation of modified surface layers with enhanced charge-trapping properties. Y1 - 2013 U6 - https://doi.org/10.1007/s00339-013-7821-1 SN - 0947-8396 VL - 112 IS - 2 SP - 283 EP - 287 PB - Springer CY - New York ER - TY - JOUR A1 - Richter, Philipp A1 - Fox, Andrew J. A1 - Wakker, Bart P. A1 - Lehner, Nicolas A1 - Howk, J. Christopher A1 - Bland-Hawthorn, Joss A1 - Ben Bekhti, Nadya A1 - Fechner, Cora T1 - The COS/UVES absorption survey of the magellanic stream - II. Evidence for a complex enrichment history of the stream from the fairall 9 sightline JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We present a multi-wavelength study of the Magellanic Stream (MS), a massive gaseous structure in the Local Group that is believed to represent material stripped from the Magellanic Clouds. We use ultraviolet, optical and radio data obtained with HST/COS, VLT/UVES, FUSE, GASS, and ATCA to study metal abundances and physical conditions in the Stream toward the quasar Fairall 9. Line absorption in the MS from a large number of metal ions and from molecular hydrogen is detected in up to seven absorption components, indicating the presence of multi-phase gas. From the analysis of unsaturated S II absorption, in combination with a detailed photoionization model, we obtain a surprisingly high alpha abundance in the Stream toward Fairall 9 of [S/H] = -0.30 +/- 0.04 (0.50 solar). This value is five times higher than what is found along other MS sightlines based on similar COS/UVES data sets. In contrast, the measured nitrogen abundance is found to be substantially lower ([N/H] = -1.15 +/- 0.06), implying a very low [N/alpha] ratio of -0.85 dex. The substantial differences in the chemical composition of MS toward Fairall 9 compared to other sightlines point toward a complex enrichment history of the Stream. We favor a scenario, in which the gas toward Fairall 9 was locally enriched with a elements by massive stars and then was separated from the Magellanic Clouds before the delayed nitrogen enrichment from intermediate-mass stars could set in. Our results support (but do not require) the idea that there is a metal-enriched filament in the Stream toward Fairall 9 that originates in the LMC. KW - Galaxy: evolution KW - Galaxy: halo KW - ISM: abundances KW - Magellanic Clouds KW - quasars: absorption lines Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/772/2/111 SN - 0004-637X VL - 772 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Rahmani, H. A1 - Wendt, Martin A1 - Srianand, R. A1 - Noterdaeme, P. A1 - Petitjean, P. A1 - Molaro, P. A1 - Whitmore, J. B. A1 - Murphy, M. T. A1 - Centurion, Martin A1 - Fathivavsari, H. A1 - D'Odorico, S. A1 - Evans, T. M. A1 - Levshakov, S. A. A1 - Lopez, S. A1 - Martins, C. J. A. P. A1 - Reimers, D. A1 - Vladilo, G. T1 - The UVES large program for testing fundamental physics - II. Constraints on a change in mu towards quasar HE 0027-1836 JF - Monthly notices of the Royal Astronomical Society N2 - We present an accurate analysis of the H-2 absorption lines from the z(abs) similar to 2.4018 damped Ly alpha system towards HE 0027-1836 observed with the Very Large Telescope Ultraviolet and Visual Echelle Spectrograph (VLT/UVES) as a part of the European Southern Observatory Large Programme 'The UVES large programme for testing fundamental physics' to constrain the variation of proton-to-electron mass ratio, mu m(p)/m(e). We perform cross-correlation analysis between 19 individual exposures taken over three years and the combined spectrum to check the wavelength calibration stability. We notice the presence of a possible wavelength-dependent velocity drift especially in the data taken in 2012. We use available asteroids spectra taken with UVES close to our observations to confirm and quantify this effect. We consider single-and two-component Voigt profiles to model the observed H-2 absorption profiles. We use both linear regression analysis and Voigt profile fitting where Delta mu/mu is explicitly considered as an additional fitting parameter. The two-component model is marginally favoured by the statistical indicators and we get Delta mu/mu = -2.5 +/- 8.1(stat) +/- 6.2(sys) ppm. When we apply the correction to the wavelength-dependent velocity drift, we find Delta mu/mu = -7.6 +/- 8.1(stat) +/- 6.3(sys) ppm. It will be important to check the extent to which the velocity drift we notice in this study is present in UVES data used for previous Delta mu/mu measurements. KW - intergalactic medium KW - quasars: absorption lines KW - quasars: individual: HE 0027-1836 Y1 - 2013 U6 - https://doi.org/10.1093/mnras/stt1356 SN - 0035-8711 SN - 1365-2966 VL - 435 IS - 1 SP - 861 EP - 878 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Qiu, Xunlin A1 - Holländer, Lars A1 - Wirges, Werner A1 - Gerhard, Reimund A1 - Basso, Heitor Cury T1 - Direct hysteresis measurements on ferroelectret films by means of a modified Sawyer-Tower circuit JF - Journal of applied physics N2 - Ferro- and piezo-electrets are non-polar polymer foams or film systems with internally charged cavities. Since their invention more than two decades ago, ferroelectrets have become a welcome addition to the range of piezo-, pyro-, and ferro-electric materials available for device applications. A polarization-versus-electric-field hysteresis is an essential feature of a ferroelectric material and may also be used for determining some of its main properties. Here, a modified Sawyer-Tower circuit and a combination of unipolar and bipolar voltage waveforms are employed to record hysteresis curves on cellular-foam polypropylene ferroelectret films and on tubular-channel fluoroethylenepropylene copolymer ferroelectret film systems. Internal dielectric barrier discharges (DBDs) are required for depositing the internal charges in ferroelectrets. The true amount of charge transferred during the internal DBDs is obtained from voltage measurements on a standard capacitor connected in series with the sample, but with a much larger capacitance than the sample. Another standard capacitor with a much smaller capacitance-which is, however, still considerably larger than the sample capacitance-is also connected in series as a high-voltage divider protecting the electrometer against destructive breakdown. It is shown how the DBDs inside the polymer cavities lead to phenomenological hysteresis curves that cannot be distinguished from the hysteresis loops found on other ferroic materials. The physical mechanisms behind the hysteresis behavior are described and discussed. Y1 - 2013 U6 - https://doi.org/10.1063/1.4809556 SN - 0021-8979 VL - 113 IS - 22 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Pulkkinen, Otto A1 - Metzler, Ralf T1 - Distance matters the impact of gene proximity in bacterial gene regulation JF - Physical review letters N2 - Following recent discoveries of colocalization of downstream-regulating genes in living cells, the impact of the spatial distance between such genes on the kinetics of gene product formation is increasingly recognized. We here show from analytical and numerical analysis that the distance between a transcription factor (TF) gene and its target gene drastically affects the speed and reliability of transcriptional regulation in bacterial cells. For an explicit model system, we develop a general theory for the interactions between a TF and a transcription unit. The observed variations in regulation efficiency are linked to the magnitude of the variation of the TF concentration peaks as a function of the binding site distance from the signal source. Our results support the role of rapid binding site search for gene colocalization and emphasize the role of local concentration differences. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.198101 SN - 0031-9007 VL - 110 IS - 19 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Proctor, Christopher M. A1 - Kim, Chunki A1 - Neher, Dieter A1 - Thuc-Quyen Nguyen, T1 - Nongeminate recombination and charge transport limitations in diketopyrrolopyrrole-based solution-processed small molecule solar cells JF - Advanced functional materials N2 - Charge transport and nongeminate recombination are investigated in two solution-processed small molecule bulk heterojunction solar cells consisting of diketopyrrolopyrrole (DPP)-based donor molecules, mono-DPP and bis-DPP, blended with [6,6]-phenyl-C71-butyric acid methyl ester (PCBM). While the bis-DPP system exhibits a high fill factor (62%) the mono-DPP system suffers from pronounced voltage dependent losses, which limit both the fill factor (46%) and short circuit current. A method to determine the average charge carrier density, recombination current, and effective carrier lifetime in operating solar cells as a function of applied bias is demonstrated. These results and light intensity measurements of the current-voltage characteristics indicate that the mono-DPP system is severely limited by nongeminate recombination losses. Further analysis reveals that the most significant factor leading to the difference in fill factor is the comparatively poor hole transport properties in the mono-DPP system (2 x 10(-5) cm(2) V-1 s(-1) versus 34 x 10(-5) cm(2) V-1 s(-1)). These results suggest that future design of donor molecules for organic photovoltaics should aim to increase charge carrier mobility thereby enabling faster sweep out of charge carriers before they are lost to nongeminate recombination. KW - charge transport KW - solar cells KW - photovoltaic devices KW - organic electronics KW - characterization tools Y1 - 2013 U6 - https://doi.org/10.1002/adfm.201202643 SN - 1616-301X SN - 1616-3028 VL - 23 IS - 28 SP - 3584 EP - 3594 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Pohl, Martin A1 - Eichler, David T1 - Understanding TeV-band cosmic-ray anistropy JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We investigate the temporal and spectral correlations between flux and anisotropy fluctuations of TeV-band cosmic rays in light of recent data taken with IceCube. We find that for a conventional distribution of cosmic-ray sources, the dipole anisotropy is higher than observed, even if source discreteness is taken into account. Moreover, even for a shallow distribution of galactic cosmic-ray sources and a reacceleration model, fluctuations arising from source discreteness provide a probability only of the order of 10% that the cosmic-ray anisotropy limits of the recent IceCube analysis are met. This probability estimate is nearly independent of the exact choice of source rate, but generous for a large halo size. The location of the intensity maximum far from the Galactic Center is naturally reproduced. KW - cosmic rays Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/766/1/4 SN - 0004-637X VL - 766 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Poghossian, A. A1 - Weil, M. A1 - Cherstvy, Andrey G. A1 - Schöning, M. J. T1 - Electrical monitoring of polyelectrolyte multilayer formation by means of capacitive field-effect devices JF - Analytical & bioanalytical chemistry N2 - The semiconductor field-effect platform represents a powerful tool for detecting the adsorption and binding of charged macromolecules with direct electrical readout. In this work, a capacitive electrolyte-insulator-semiconductor (EIS) field-effect sensor consisting of an Al-p-Si-SiO2 structure has been applied for real-time in situ electrical monitoring of the layer-by-layer formation of polyelectrolyte (PE) multilayers (PEM). The PEMs were deposited directly onto the SiO2 surface without any precursor layer or drying procedures. Anionic poly(sodium 4-styrene sulfonate) and cationic weak polyelectrolyte poly(allylamine hydrochloride) have been chosen as a model system. The effect of the ionic strength of the solution, polyelectrolyte concentration, number and polarity of the PE layers on the characteristics of the PEM-modified EIS sensors have been studied by means of capacitance-voltage and constant-capacitance methods. In addition, the thickness, surface morphology, roughness and wettabilityof the PE mono- and multilayers have been characterised by ellipsometry, atomic force microscopy and water contact-angle methods, respectively. To explain potential oscillations on the gate surface and signal behaviour of the capacitive field-effect EIS sensor modified with a PEM, a simplified electrostatic model that takes into account the reduced electrostatic screening of PE charges by mobile ions within the PEM has been proposed and discussed. KW - Field-effect KW - Capacitive sensor KW - Polyelectrolyte multilayer KW - Electrical monitoring KW - ConCap Y1 - 2013 U6 - https://doi.org/10.1007/s00216-013-6951-9 SN - 1618-2642 VL - 405 IS - 20 SP - 6425 EP - 6436 PB - Springer CY - Heidelberg ER - TY - THES A1 - Pingel, Patrick T1 - Morphology, charge transport properties, and molecular doping of thiophene-based organic semiconducting thin films T1 - Morphologie, Ladungstransporteigenschaften und molekulares Dotieren thiophenbasierter organischer Halbleiterschichten N2 - Organic semiconductors combine the benefits of organic materials, i.e., low-cost production, mechanical flexibility, lightweight, and robustness, with the fundamental semiconductor properties light absorption, emission, and electrical conductivity. This class of material has several advantages over conventional inorganic semiconductors that have led, for instance, to the commercialization of organic light-emitting diodes which can nowadays be found in the displays of TVs and smartphones. Moreover, organic semiconductors will possibly lead to new electronic applications which rely on the unique mechanical and electrical properties of these materials. In order to push the development and the success of organic semiconductors forward, it is essential to understand the fundamental processes in these materials. This thesis concentrates on understanding how the charge transport in thiophene-based semiconductor layers depends on the layer morphology and how the charge transport properties can be intentionally modified by doping these layers with a strong electron acceptor. By means of optical spectroscopy, the layer morphologies of poly(3-hexylthiophene), P3HT, P3HT-fullerene bulk heterojunction blends, and oligomeric polyquaterthiophene, oligo-PQT-12, are studied as a function of temperature, molecular weight, and processing conditions. The analyses rely on the decomposition of the absorption contributions from the ordered and the disordered parts of the layers. The ordered-phase spectra are analyzed using Spano’s model. It is figured out that the fraction of aggregated chains and the interconnectivity of these domains is fundamental to a high charge carrier mobility. In P3HT layers, such structures can be grown with high-molecular weight, long P3HT chains. Low and medium molecular weight P3HT layers do also contain a significant amount of chain aggregates with high intragrain mobility; however, intergranular connectivity and, therefore, efficient macroscopic charge transport are absent. In P3HT-fullerene blend layers, a highly crystalline morphology that favors the hole transport and the solar cell efficiency can be induced by annealing procedures and the choice of a high-boiling point processing solvent. Based on scanning near-field and polarization optical microscopy, the morphology of oligo-PQT-12 layers is found to be highly crystalline which explains the rather high field-effect mobility in this material as compared to low molecular weight polythiophene fractions. On the other hand, crystalline dislocations and grain boundaries are identified which clearly limit the charge carrier mobility in oligo-PQT-12 layers. The charge transport properties of organic semiconductors can be widely tuned by molecular doping. Indeed, molecular doping is a key to highly efficient organic light-emitting diodes and solar cells. Despite this vital role, it is still not understood how mobile charge carriers are induced into the bulk semiconductor upon the doping process. This thesis contains a detailed study of the doping mechanism and the electrical properties of P3HT layers which have been p-doped by the strong molecular acceptor tetrafluorotetracyanoquinodimethane, F4TCNQ. The density of doping-induced mobile holes, their mobility, and the electrical conductivity are characterized in a broad range of acceptor concentrations. A long-standing debate on the nature of the charge transfer between P3HT and F4TCNQ is resolved by showing that almost every F4TCNQ acceptor undergoes a full-electron charge transfer with a P3HT site. However, only 5% of these charge transfer pairs can dissociate and induce a mobile hole into P3HT which contributes electrical conduction. Moreover, it is shown that the left-behind F4TCNQ ions broaden the density-of-states distribution for the doping-induced mobile holes, which is due to the longrange Coulomb attraction in the low-permittivity organic semiconductors. N2 - Organische Halbleiter kombinieren die molekulare Vielfalt und Anpassbarkeit, die mechanische Flexibilität und die preisgünstige Herstellung und Verarbeitung von Kunststoffen mit fundamentalen Halbleitereigenschaften wie Lichtabsorption und -emission und elektrischer Leitfähigkeit. Unlängst finden organische Leuchtdioden Anwendung in den Displays von TV-Geräten und Smartphones. Für die weitere Entwicklung und den Erfolg organischer Halbleiter ist das Verständnis derer physikalischer Grundlagen unabdingbar. Ein für viele Bauteile fundamentaler Prozess ist der Transport von Ladungsträgern in der organischen Schicht. Die Ladungstransporteigenschaften werden maßgeblich durch die Struktur dieser Schicht bestimmt, z.B. durch den Grad der molekularen Ordnung, die molekulare Verbindung von kristallinen Domänen und durch Defekte der molekularen Packung. Mittels optischer Spektroskopie werden in dieser Arbeit die temperatur-, molekulargewichts- und lösemittelabhängigen Struktureigenschaften poly- und oligothiophenbasierter Schichten untersucht. Dabei basiert die Analyse der Absorptionsspektren auf der Zerlegung in die spezifischen Anteile geordneten und ungeordneten Materials. Es wird gezeigt, dass sich hohe Ladungsträgerbeweglichkeiten dann erreichen lassen, wenn der Anteil der geordneten Bereiche und deren molekulare Verbindung in den Schichten möglichst hoch und die energetische Unordnung in diesen Bereichen möglichst klein ist. Der Ladungstransport in organischen Halbleitern kann außerdem gezielt beeinflusst werden, indem die Ladungsträgerdichte und die elektrische Leitfähigkeit durch molekulares Dotieren, d.h. durch das Einbringen von Elektronenakzeptoren oder -donatoren, eingestellt werden. Obwohl der Einsatz dotierter Schichten essentiell für effiziente Leuchtdioden und Solarzellen ist, ist der Mechanismus, der zur Erzeugung freier Ladungsträger im organischen Halbleiter führt, derzeit unverstanden. In dieser Arbeit wird der Ladungstransfer zwischen dem prototypischen Elektronendonator P3HT und dem Akzeptor F4TCNQ untersucht. Es wird gezeigt, dass, entgegen verbreiteter Vorstellungen, fast alle F4TCNQ-Akzeptoren einen ganzzahligen Ladungstransfer mit P3HT eingehen, aber nur 5% dieser Paare dissoziieren und einen beweglichen Ladungsträger erzeugen, der zur elektrischen Leitfähigkeit beiträgt. Weiterhin wird gezeigt, dass die zurückgelassenen F4TCNQ-Akzeptorionen Fallenzustände für die beweglichen Ladungsträger darstellen und so die Ladungsträgerbeweglichkeit in P3HT bei schwacher Dotierung absinkt. Die elektrischen Kenngrößen Ladungsträgerkonzentration, Beweglichkeit und Leitfähigkeit von F4TCNQ-dotierten P3HT-Schichten werden in dieser Arbeit erstmals in weiten Bereichen verschiedener Akzeptorkonzentrationen untersucht. KW - Polythiophen KW - organische Elektronik KW - molekulares Dotieren KW - organischer Halbleiter KW - Morphologie KW - polythiohene KW - organic electronics KW - molecular doping KW - organic semiconductor KW - morphology Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69805 ER - TY - JOUR A1 - Pingel, P. A1 - Neher, Dieter T1 - Comprehensive picture of p-type doping of P3HT with the molecular acceptor F(4)TCNQ JF - Physical review : B, Condensed matter and materials physics N2 - By means of optical spectroscopy, Kelvin probe, and conductivity measurements, we study the p-type doping of the donor polymer poly(3-hexylthiophene), P3HT, with the molecular acceptor tetrafluorotetracyanoquin-odimethane, F(4)TCNQ, covering a broad range of molar doping ratios from the ppm to the percent regime. Thorough quantitative analysis of the specific near-infrared absorption bands of ionized F(4)TCNQ reveals that almost every F(4)TCNQ dopant undergoes integer charge transfer with a P3HT site. However, only about 5% of these charge carrier pairs are found to dissociate and contribute a free hole for electrical conduction. The nonlinear behavior of the conductivity on doping ratio is rationalized by a numerical mobility model that accounts for the broadening of the energetic distribution of transport sites by the Coulomb potentials of ionized F(4)TCNQ dopants. DOI: 10.1103/PhysRevB.87.115209 Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevB.87.115209 SN - 1098-0121 VL - 87 IS - 11 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Pikovskij, Arkadij T1 - Robust synchronization of spin-torque oscillators with an LC R load JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We study dynamics of a serial array of spin-torque oscillators with a parallel inductor-capacitor-resistor (LC R) load. In a large range of parameters the fully synchronous regime, where all the oscillators have the same state and the output field is maximal, is shown to be stable. However, not always such a robust complete synchronization develops from a random initial state; in many cases nontrivial clustering is observed, with a partial synchronization resulting in a quasiperiodic or chaotic mean-field dynamics. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.032812 SN - 1539-3755 SN - 1550-2376 VL - 88 IS - 3 PB - American Physical Society CY - College Park ER - TY - THES A1 - Piffl, Tilmann T1 - Models of the Galaxy and the massive spectroscopic stellar survey RAVE T1 - Modelle der Milchstrasse und die spektroskopische Himmelsdurchmusterung RAVE N2 - Numerical simulations of galaxy formation and observational Galactic Astronomy are two fields of research that study the same objects from different perspectives. Simulations try to understand galaxies like our Milky Way from an evolutionary point of view while observers try to disentangle the current structure and the building blocks of our Galaxy. Due to great advances in computational power as well as in massive stellar surveys we are now able to compare resolved stellar populations in simulations and in observations. In this thesis we use a number of approaches to relate the results of the two fields to each other. The major observational data set we refer to for this work comes from the Radial Velocity Experiment (RAVE), a massive spectroscopic stellar survey that observed almost half a million stars in the Galaxy. In a first study we use three different models of the Galaxy to generate synthetic stellar surveys that can be directly compared to the RAVE data. To do this we evaluate the RAVE selection function to great detail. Among the Galaxy models is the widely used Besancon model that performs well when individual parameter distribution are considered, but fails when we study chemodynamic correlations. The other two models are based on distributions of mass particles instead of analytical distribution functions. This is the first time that such models are converted to the space of observables and are compared to a stellar survey. We show that these models can be competitive and in some aspects superior to analytic models, because of their self-consistent dynamic history. In the case of a full cosmological simulation of disk galaxy formation we can recover features in the synthetic survey that relate to the known issues of the model and hence proof that our technique is sensitive to the global structure of the model. We argue that the next generation of cosmological galaxy formation simulations will deliver valuable models for our Galaxy. Testing these models with our approach will provide a direct connection between stellar Galactic astronomy and physical cosmology. In the second part of the thesis we use a sample of high-velocity halo stars from the RAVE data to estimate the Galactic escape speed and the virial mass of the Milky Way. In the course of this study cosmological simulations of galaxy formation also play a crucial role. Here we use them to calibrate and extensively test our analysis technique. We find the local Galactic escape speed to be 533 (+54/-41) km/s (90% confidence). With this result in combination with a simple mass model of the Galaxy we then construct an estimate of the virial mass of the Galaxy. For the mass profile of the dark matter halo we use two extreme models, a pure Navarro, Frenk & White (NFW) profile and an adiabatically contracted NFW profile. When we use statistics on the concentration parameter of these profile taken from large dissipationless cosmological simulations we obtain an estimate of the virial mass that is almost independent of the choice of the halo profile. For the mass M_340 enclosed within R_340 = 180 kpc we find 1.3 (+0.4/-0.3) x 10^12 M_sun. This value is in very good agreement with a number of other mass estimates in the literature that are based on independent data sets and analysis techniques. In the last part of this thesis we investigate a new possible channel to generate a population of Hypervelocity stars (HVSs) that is observed in the stellar halo. Commonly, it is assumed that the velocities of these stars originate from an interaction with the super-massive black hole in the Galactic center. It was suggested recently that stars stripped-off a disrupted satellite galaxy could reach similar velocities and leave the Galaxy. Here we study in detail the kinematics of tidal debris stars to investigate the probability that the observed sample of HVSs could partly originate from such a galaxy collision. We use a suite of $N$-body simulations following the encounter of a satellite galaxy with its Milky Way-type host galaxy. We quantify the typical pattern in angular and phase space formed by the debris stars and develop a simple model that predicts the kinematics of stripped-off stars. We show that the distribution of orbital energies in the tidal debris has a typical form that can be described quite accurately by a simple function. The main parameters determining the maximum energy kick a tidal debris star can get is the initial mass of the satellite and only to a lower extent its orbit. Main contributors to an unbound stellar population created in this way are massive satellites (M_sat > 10^9 M_sun). The probability that the observed HVS population is significantly contaminated by tidal debris stars appears small in the light of our results. N2 - Ein häufig verfolgter Ansatz Galaxien wie unsere Milchstraße besser zu verstehen, sind numerische Simulationen, d.h. das Nachvollziehen ihrer Entstehung und Entwicklung mit Hilfe von Computern. Dieses Vorgehen erlaubt das Betrachten solcher Objekte von einem evolutionären Standpunkt aus. Eine andere Herangehensweise verfolgt die Galaktische Astronomie, welche über Sternbeobachtungen den aktuellen Zustand der Milchstraße untersucht. Hier wird versucht, die konstitutiven Bestandteile unserer Galaxie zu erkennen, um dadurch ein besseres Verständnis ihrer Struktur zu erlangen. Die enorme Rechenleistung moderner Supercomputer und die Entwicklungssprünge im Bereich der digitalen Himmelsdurchmusterungen haben dazu geführt, dass inzwischen mit beiden Ansätzen vergleichbare Populationen von einzeln beobachtbaren Sternen studiert werden können. In der vorliegenden Arbeit werden verschiedene Möglichkeiten untersucht, die Ergebnisse dieser beiden astrophysikalischen Disziplinen, welche bislang weitgehend getrennt von einander betrieben wurden, sinnvoll zu kombinieren. Der überwiegende Teil der Beobachtungsdaten, die dabei verwendet werden, wurde im Zuge des Radial Velocity Experiments (RAVE) gesammelt, einer spektroskopischen Durchmusterung der Sterne fast des gesamten Südhimmels. Um die Daten des RAVE-Projekts statistisch auswerten zu können, musste zuerst die detaillierte Auswahlfunktion der Durchmusterung rekonstruiert werden, d.h. die Wahrscheinlichkeit, dass ein Stern von RAVE beobachtet wurde, musste, in Abhängigkeit von den Eigenschaften des Sterns, bestimmt werden. Der Hauptteil der Dissertation gliedert sich in drei weitgehend unabhängige Studien. Im ersten Teil wird die oben erwähnte Auswahlfunktion benutzt, um voraus zu sagen, was das RAVE Projekt beobachtet hätte, falls bestimmte theoretische Modelle unserer Milchstraße zu träfen. Auf diese Art und Weise umgehe ich das problematische Unterfangen, die Beobachtungsdaten zu einem physikalischen Modell zu verallgemeinern. Die Problematik hierbei liegt darin, dass astronomische Beobachtungen nicht direkt physikalisch relevante Größen, wie Massen oder Alter der Sterne, liefern, sondern scheinbare Helligkeiten oder Winkelpositionen. In dieser Studie wird der umgekehrte Weg beschritten und synthetische Beobachtungen aus den Modellen generiert. Untersucht wurden dabei sowohl klassische analytische Modelle als auch Modelle, die aus numerischen Simulationen resultieren. Letztere wurden zu ersten Mal überhaupt auf diese Art und Weise getestet und es zeigt sich, dass solche Modelle den klassischen in bestimmten Aspekten, die mit der Entwicklungsgeschichte der Milchstraße verknüpft sind, überlegen sind. Im zweiten Teil der Arbeit werden die RAVE-Daten benutzt um die Masse der Milchstraße, bzw. die Masse der in ihr enthaltenen dunklen Materie, ab zu schätzen. Zur Eichung der Analysemethode wird dabei wieder auf Ergebnisse von Simulationen zurück gegriffen, die die Entwicklung von ähnlichen Galaxien wie der Milchstraße verfolgt haben. Zuerst wird die lokale Entweichgeschwindigkeit, d.h. die Mindestgeschwindigkeit, die ein Körper benötigt, um unsere Galaxie zu verlassen, bestimmt. Die beste Abschätzung beträgt 533 (+54/-41) km/s. Anhand dieser Schätzung kann, in Kombination mit vereinfachten analytischen Modellen der Materieverteilung in unserer Galaxie, die Masse der Milchstraße innerhalb von 180 kpc auf 1,3 (+0,4/-0,3) x 10^12 Sonnenmassen bestimmt werden. Dieses Ergebnis bestätigt frühere unabhängige Massenschätzungen, die auf anderen Beobachtungsdaten und anderen Analysestrategien basieren. Im letzten Teil der Arbeit wird eine spezielle Population von Sternen im Außenbereich unserer Galaxie untersucht, sogenannte Hyperschnellläufersterne (HSS). Diese wurde in einer weiteren Himmelsdurchmusterung, dem Sloan Digital Sky Survey (SDSS), gefunden. Die Besonderheit dieser Sterne besteht in ihren extrem hohen Geschwindigkeiten oberhalb der Entweichgeschwindigkeit. Allgemein wird angenommen, dass die Sterne ihre Geschwindigkeiten im Zuge der Spaltung eines Doppelsternsystems durch Gezeitenkräfte nahe des supermassereichen Schwarzen Lochs im Zentrum der Milchstraße erreichen. Vor Kurzem wurde jedoch ein alternatives Szenario vorgeschlagen. Nach diesem können solche Sterne auch während des Einfalls einer Satellitengalaxie auf die Milchstraße entstehen. Diese Hypothese wird anhand von numerischen Simulationen, die diese Situation nachbilden, getestet. Es zeigt sich, dass HSS auf diese Weise entstehen können, aber dass die beobachtete Population höchstwahrscheinlich einen anderen Ursprung hat. KW - RAVE KW - Milchstrassenmasse KW - Hyperschnellläufersterne KW - Pseudobeobachtungen KW - RAVE KW - galactic structure KW - hypervelocity stars Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-70371 ER - TY - JOUR A1 - Pieplow, Gregor A1 - Henkel, Carsten T1 - Fully covariant radiation force on a polarizable particle JF - New journal of physics : the open-access journal for physics N2 - The electromagnetic force on a polarizable particle is calculated in a covariant framework. Local equilibrium temperatures for the electromagnetic field and the particle's dipole moment are assumed, using a relativistic formulation of the fluctuation-dissipation theorem. Two examples illustrate radiative friction forces: a particle moving through a homogeneous radiation background and above a planar interface. Previous results for arbitrary relative velocities are recovered in a compact way. Y1 - 2013 U6 - https://doi.org/10.1088/1367-2630/15/2/023027 SN - 1367-2630 VL - 15 IS - 4 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Pfannes, Eva K. A1 - Anielski, Alexander A1 - Gerhardt, Matthias A1 - Beta, Carsten T1 - Intracellular photoactivation of caged-cGMP induces myosin II and actin responses in motile cells N2 - Cyclic GMP (cGMP) is a ubiquitous second messenger in eukaryotic cells. It is assumed to regulate the association of myosin II with the cytoskeleton of motile cells. When cells of the social amoeba Dictyostelium discoideum are exposed to chemoattractants or to increased osmotic stress, intracellular cGMP levels rise, preceding the accumulation of myosin II in the cell cortex. To directly investigate the impact of intracellular cGMP on cytoskeletal dynamics in a living cell, we released cGMP inside the cell by laser-induced photo-cleavage of a caged precursor. With this approach, we could directly show in a live cell experiment that an increase in intracellular cGMP indeed induces myosin II to accumulate in the cortex. Unexpectedly, we observed for the first time that also the amount of filamentous actin in the cell cortex increases upon a rise in the cGMP concentration, independently of cAMP receptor activation and signaling. We discuss our results in the light of recent work on the cGMP signaling pathway and suggest possible links between cGMP signaling and the actin system. Y1 - 2013 UR - http://pubs.rsc.org/en/content/articlehtml/2013/ib/c3ib40109j U6 - https://doi.org/10.1039/C3IB40109J ER - TY - JOUR A1 - Pattyn, Frank A1 - Perichon, Laura A1 - Durand, Gael A1 - Favier, Lionel A1 - Gagliardini, Olivier A1 - Hindmarsh, Richard C. A. A1 - Zwinger, Thomas A1 - Albrecht, Torsten A1 - Cornford, Stephen A1 - Docquier, David A1 - Furst, Johannes J. A1 - Goldberg, Daniel A1 - Gudmundsson, Gudmundur Hilmar A1 - Humbert, Angelika A1 - Huetten, Moritz A1 - Huybrechts, Philippe A1 - Jouvet, Guillaume A1 - Kleiner, Thomas A1 - Larour, Eric A1 - Martin, Daniel A1 - Morlighem, Mathieu A1 - Payne, Anthony J. A1 - Pollard, David A1 - Rueckamp, Martin A1 - Rybak, Oleg A1 - Seroussi, Helene A1 - Thoma, Malte A1 - Wilkens, Nina T1 - Grounding-line migration in plan-view marine ice-sheet models: results of the ice2sea MISMIP3d intercomparison JF - Journal of glaciology N2 - Predictions of marine ice-sheet behaviour require models able to simulate grounding-line migration. We present results of an intercomparison experiment for plan-view marine ice-sheet models. Verification is effected by comparison with approximate analytical solutions for flux across the grounding line using simplified geometrical configurations (no lateral variations, no buttressing effects from lateral drag). Perturbation experiments specifying spatial variation in basal sliding parameters permitted the evolution of curved grounding lines, generating buttressing effects. The experiments showed regions of compression and extensional flow across the grounding line, thereby invalidating the boundary layer theory. Steady-state grounding-line positions were found to be dependent on the level of physical model approximation. Resolving grounding lines requires inclusion of membrane stresses, a sufficiently small grid size (<500 m), or subgrid interpolation of the grounding line. The latter still requires nominal grid sizes of <5 km. For larger grid spacings, appropriate parameterizations for ice flux may be imposed at the grounding line, but the short-time transient behaviour is then incorrect and different from models that do not incorporate grounding-line parameterizations. The numerical error associated with predicting grounding-line motion can be reduced significantly below the errors associated with parameter ignorance and uncertainties in future scenarios. Y1 - 2013 U6 - https://doi.org/10.3189/2013JoG12J129 SN - 0022-1430 VL - 59 IS - 215 SP - 410 EP - 422 PB - International Glaciological Society CY - Cambridge ER - TY - THES A1 - Patra, Pintu T1 - Population dynamics of bacterial persistence T1 - Populationsdynamik von Bakterielle Persistenz N2 - The life of microorganisms is characterized by two main tasks, rapid growth under conditions permitting growth and survival under stressful conditions. The environments, in which microorganisms dwell, vary in space and time. The microorganisms innovate diverse strategies to readily adapt to the regularly fluctuating environments. Phenotypic heterogeneity is one such strategy, where an isogenic population splits into subpopulations that respond differently under identical environments. Bacterial persistence is a prime example of such phenotypic heterogeneity, whereby a population survives under an antibiotic attack, by keeping a fraction of population in a drug tolerant state, the persister state. Specifically, persister cells grow more slowly than normal cells under growth conditions, but survive longer under stress conditions such as the antibiotic administrations. Bacterial persistence is identified experimentally by examining the population survival upon an antibiotic treatment and the population resuscitation in a growth medium. The underlying population dynamics is explained with a two state model for reversible phenotype switching in a cell within the population. We study this existing model with a new theoretical approach and present analytical expressions for the time scale observed in population growth and resuscitation, that can be easily used to extract underlying model parameters of bacterial persistence. In addition, we recapitulate previously known results on the evolution of such structured population under periodically fluctuating environment using our simple approximation method. Using our analysis, we determine model parameters for Staphylococcus aureus population under several antibiotics and interpret the outcome of cross-drug treatment. Next, we consider the expansion of a population exhibiting phenotype switching in a spatially structured environment consisting of two growth permitting patches separated by an antibiotic patch. The dynamic interplay of growth, death and migration of cells in different patches leads to distinct regimes in population propagation speed as a function of migration rate. We map out the region in parameter space of phenotype switching and migration rate to observe the condition under which persistence is beneficial. Furthermore, we present an extended model that allows mutation from the two phenotypic states to a resistant state. We find that the presence of persister cells may enhance the probability of resistant mutation in a population. Using this model, we explain the experimental results showing the emergence of antibiotic resistance in a Staphylococcus aureus population upon tobramycin treatment. In summary, we identify several roles of bacterial persistence, such as help in spatial expansion, development of multidrug tolerance and emergence of antibiotic resistance. Our study provides a theoretical perspective on the dynamics of bacterial persistence in different environmental conditions. These results can be utilized to design further experiments, and to develop novel strategies to eradicate persistent infections. N2 - Das Leben von Mikroorganismen kann in zwei charakteristische Phasen unterteilt werde, schnelles Wachstum unter Wachstumsbedingungen und Überleben unter schwierigen Bedingungen. Die Bedingungen, in denen sich die Mikroorganismen aufhalten, verändern sich in Raum und Zeit. Um sich schnell an die ständig wechselnden Bedingungen anzupassen entwickeln die Mikroorganismen diverse Strategien. Phänotypische Heterogenität ist eine solche Strategie, bei der sich eine isogene Popolation in Untergruppen aufteilt, die unter identischen Bedingungen verschieden reagieren. Bakterielle Persistenz ist ein Paradebeispiel einer solchen phänotypischen Heterogenität. Hierbei überlebt eine Popolation die Behandlung mit einem Antibiotikum, indem sie einen Teil der Bevölkerung in einem, dem Antibiotikum gegenüber tolerant Zustand lässt, der sogenannte "persister Zustand". Persister-Zellen wachsen unter Wachstumsbedingungen langsamer als normale Zellen, jedoch überleben sie länger in Stress-Bedingungen, wie bei Antibiotikaapplikation. Bakterielle Persistenz wird experimentell erkannt indem man überprüft ob die Population eine Behandlung mit Antibiotika überlebt und sich in einem Wachstumsmedium reaktiviert. Die zugrunde liegende Popolationsdynamik kann mit einem Zwei-Zustands-Modell für reversibles Wechseln des Phänotyps einer Zelle in der Bevölkerung erklärt werden. Wir untersuchen das bestehende Modell mit einem neuen theoretischen Ansatz und präsentieren analytische Ausdrücke für die Zeitskalen die für das Bevölkerungswachstums und die Reaktivierung beobachtet werden. Diese können dann einfach benutzt werden um die Parameter des zugrunde liegenden bakteriellen Persistenz-Modells zu bestimmen. Darüber hinaus rekapitulieren wir bisher bekannten Ergebnisse über die Entwicklung solch strukturierter Bevölkerungen unter periodisch schwankenden Bedingungen mithilfe unseres einfachen Näherungsverfahrens. Mit unserer Analysemethode bestimmen wir Modellparameter für eine Staphylococcus aureus-Popolation unter dem Einfluss mehrerer Antibiotika und interpretieren die Ergebnisse der Behandlung mit zwei Antibiotika in Folge. Als nächstes betrachten wir die Ausbreitung einer Popolation mit Phänotypen-Wechsel in einer räumlich strukturierten Umgebung. Diese besteht aus zwei Bereichen, in denen Wachstum möglich ist und einem Bereich mit Antibiotikum der die beiden trennt. Das dynamische Zusammenspiel von Wachstum, Tod und Migration von Zellen in den verschiedenen Bereichen führt zu unterschiedlichen Regimen der Populationsausbreitungsgeschwindigkeit als Funktion der Migrationsrate. Wir bestimmen die Region im Parameterraum der Phänotyp Schalt-und Migrationsraten, in der die Bedingungen Persistenz begünstigen. Darüber hinaus präsentieren wir ein erweitertes Modell, das Mutation aus den beiden phänotypischen Zuständen zu einem resistenten Zustand erlaubt. Wir stellen fest, dass die Anwesenheit persistenter Zellen die Wahrscheinlichkeit von resistenten Mutationen in einer Population erhöht. Mit diesem Modell, erklären wir die experimentell beobachtete Entstehung von Antibiotika- Resistenz in einer Staphylococcus aureus Popolation infolge einer Tobramycin Behandlung. Wir finden also verschiedene Funktionen bakterieller Persistenz. Sie unterstützt die räumliche Ausbreitung der Bakterien, die Entwicklung von Toleranz gegenüber mehreren Medikamenten und Entwicklung von Resistenz gegenüber Antibiotika. Unsere Beschreibung liefert eine theoretische Betrachtungsweise der Dynamik bakterieller Persistenz bei verschiedenen Bedingungen. Die Resultate könnten als Grundlage neuer Experimente und der Entwicklung neuer Strategien zur Ausmerzung persistenter Infekte dienen. KW - Populationsdynamik KW - Antibiotikaresistenz KW - Antibiotika-Toleranz KW - Phänotypische Heterogenität KW - population dynamics KW - drug tolerance KW - antibiotic resistance KW - phenotypic heterogeneity Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69253 ER - TY - JOUR A1 - Ovsyannikov, Ruslan A1 - Karlsson, P. A1 - Lundqvist, M. A1 - Lupulescu, C. A1 - Eberhardt, W. A1 - Föhlisch, Alexander A1 - Svensson, S. A1 - Martensson, N. T1 - Principles and operation of a new type of electron spectrometer - ArTOF JF - Journal of electron spectroscopy and related phenomena : the international journal on theoretical and experimental aspects of electron spectroscopy N2 - A new energy and angular electron analyzer ArTOF (Angular Resolved Time of Flight) is described. The analyzer is based on simultaneous measurement of flight times and angles in an advanced electron lens system. In angular modes the new analyzer combines an increase in transmission by almost three orders of magnitude with improved resolution, in comparison to standard state-of-the-art electron spectrometers. In this report we describe some design principles and we give a review of calibration and alignment procedures necessary for the use of the ArTOF on a synchrotron radiation facility. Our program scripts to handle the large datasets are also discussed. Furthermore we give a broad description of the new research fields that benefit from the use of the ArTOF and give a short summary of the first results of angle resolved photoemission measurement with ArTOF using the single-bunch X-ray pulses from the BESSY II storage ring facility. (C) 2013 Published by Elsevier B.V. KW - ARPES KW - Time of flight KW - Synchrotron KW - Electron spectroscopy Y1 - 2013 U6 - https://doi.org/10.1016/j.elspec.2013.08.005 SN - 0368-2048 SN - 1873-2526 VL - 191 IS - 12 SP - 92 EP - 103 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Oskinova, Lida A1 - Sun, W. A1 - Evans, C. J. A1 - Henault-Brunet, V. A1 - Chu, Y.-H. A1 - Gallagher, J. S. A1 - Guerrero, Martín A. A1 - Gruendl, R. A. A1 - Güdel, M. A1 - Silich, S. A1 - Chen, Y. A1 - Naze, Y. A1 - Hainich, Rainer A1 - Reyes-Iturbide, J. T1 - Discovery of x-ray emission from young suns in the small magellanic cloud JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We report the discovery of extended X-ray emission within the young star cluster NGC 602a in the Wing of the Small Magellanic Cloud (SMC) based on observations obtained with the Chandra X-Ray Observatory. X-ray emission is detected from the cluster core area with the highest stellar density and from a dusty ridge surrounding the H II region. We use a census of massive stars in the cluster to demonstrate that a cluster wind or wind-blown bubble is unlikely to provide a significant contribution to the X-ray emission detected from the central area of the cluster. We therefore suggest that X-ray emission at the cluster core originates from an ensemble of low-and solar-mass pre-main-sequence (PMS) stars, each of which would be too weak in X-rays to be detected individually. We attribute the X-ray emission from the dusty ridge to the embedded tight cluster of the newborn stars known in this area from infrared studies. Assuming that the levels of X-ray activity in young stars in the low-metallicity environment of NGC 602a are comparable to their Galactic counterparts, then the detected spatial distribution, spectral properties, and level of X-ray emission are largely consistent with those expected from low-and solar-mass PMS stars and young stellar objects (YSOs). This is the first discovery of X-ray emission attributable to PMS stars and YSOs in the SMC, which suggests that the accretion and dynamo processes in young, low-mass objects in the SMC resemble those in the Galaxy. KW - Magellanic Clouds KW - ISM: bubbles KW - H II regions KW - stars: winds, outflows KW - stars: pre-main sequence KW - X-rays: stars Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/765/1/73 SN - 0004-637X VL - 765 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Oskinova, Lida A1 - Steinke, M. A1 - Hamann, Wolf-Rainer A1 - Sander, A. A1 - Todt, Helge Tobias A1 - Liermann, Adriane T1 - One of the most massive stars in the Galaxy may have formed in isolation JF - Monthly notices of the Royal Astronomical Society N2 - Very massive stars, 100 times heavier than the sun, are rare. It is not yet known whether such stars can form in isolation or only in star clusters. The answer to this question is of fundamental importance. The central region of our Galaxy is ideal for investigating very massive stars and clusters located in the same environment. We used archival infrared images to investigate the surroundings of apparently isolated massive stars presently known in the Galactic Centre (GC). We find that two such isolated massive stars display bow shocks and hence may be 'runaways' from their birthplace. Thus, some isolated massive stars in the GC region might have been born in star clusters known in this region. However, no bow shock is detected around the isolated star WR 102ka (Peony nebula star), which is one of the most massive and luminous stars in the Galaxy. This star is located at the centre of an associated circumstellar nebula. To study whether a star cluster may be 'hidden' in the surroundings of WR 102ka, to obtain new and better spectra of this star, and to measure its radial velocity, we obtained observations with the integral-field spectrograph SINFONI at the ESO's Very Large Telescope. Our observations confirm that WR 102ka is one of the most massive stars in the Galaxy and reveal that this star is not associated with a star cluster. We suggest that WR 102ka has been born in relative isolation, outside of any massive star cluster. KW - stars: individual: WR 102ka KW - Galaxy: centre KW - infrared: stars Y1 - 2013 U6 - https://doi.org/10.1093/mnras/stt1817 SN - 0035-8711 SN - 1365-2966 VL - 436 IS - 4 SP - 3357 EP - 3365 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Ohliger, Matthias A1 - Nesme, V. A1 - Eisert, J. T1 - Efficient and feasible state tomography of quantum many-body systems JF - New journal of physics : the open-access journal for physics N2 - We present a novel method for performing quantum state tomography for many-particle systems, which are particularly suitable for estimating the states in lattice systems such as of ultra-cold atoms in optical lattices. We show that the need to measure a tomographically complete set of observables can be overcome by letting the state evolve under some suitably chosen random circuits followed by the measurement of a single observable. We generalize known results about the approximation of unitary two-designs, i.e. certain classes of random unitary matrices, by random quantum circuits and connect our findings to the theory of quantum compressed sensing. We show that for ultra-cold atoms in optical lattices established experimental techniques such as optical super-lattices, laser speckles and time-of-flight measurements are sufficient to perform fully certified, assumption-free tomography. This is possible without the need to address single sites in any step of the procedure. Combining our approach with tensor network methods-in particular, the theory of matrix product states-we identify situations where the effort of reconstruction is even constant in the number of lattice sites, allowing, in principle, to perform tomography on large-scale systems readily available in present experiments. Y1 - 2013 U6 - https://doi.org/10.1088/1367-2630/15/1/015024 SN - 1367-2630 VL - 15 IS - 5 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Nowicki, Sophie A1 - Bindschadler, Robert A. A1 - Abe-Ouchi, Ayako A1 - Aschwanden, Andy A1 - Bueler, Ed A1 - Choi, Hyeungu A1 - Fastook, Jim A1 - Granzow, Glen A1 - Greve, Ralf A1 - Gutowski, Gail A1 - Herzfeld, Ute A1 - Jackson, Charles A1 - Johnson, Jesse A1 - Khroulev, Constantine A1 - Larour, Eric A1 - Levermann, Anders A1 - Lipscomb, William H. A1 - Martin, Maria A. A1 - Morlighem, Mathieu A1 - Parizek, Byron R. A1 - Pollard, David A1 - Price, Stephen F. A1 - Ren, Diandong A1 - Rignot, Eric A1 - Saito, Fuyuki A1 - Sato, Tatsuru A1 - Seddik, Hakime A1 - Seroussi, Helene A1 - Takahashi, Kunio A1 - Walker, Ryan A1 - Wang, Wei Li T1 - Insights into spatial sensitivities of ice mass response to environmental change from the SeaRISE ice sheet modeling project II Greenland JF - Journal of geophysical research : Earth surface N2 - The Sea-level Response to Ice Sheet Evolution (SeaRISE) effort explores the sensitivity of the current generation of ice sheet models to external forcing to gain insight into the potential future contribution to sea level from the Greenland and Antarctic ice sheets. All participating models simulated the ice sheet response to three types of external forcings: a change in oceanic condition, a warmer atmospheric environment, and enhanced basal lubrication. Here an analysis of the spatial response of the Greenland ice sheet is presented, and the impact of model physics and spin-up on the projections is explored. Although the modeled responses are not always homogeneous, consistent spatial trends emerge from the ensemble analysis, indicating distinct vulnerabilities of the Greenland ice sheet. There are clear response patterns associated with each forcing, and a similar mass loss at the full ice sheet scale will result in different mass losses at the regional scale, as well as distinct thickness changes over the ice sheet. All forcings lead to an increased mass loss for the coming centuries, with increased basal lubrication and warmer ocean conditions affecting mainly outlet glaciers, while the impacts of atmospheric forcings affect the whole ice sheet. KW - Greenland KW - ice-sheet KW - sea-level KW - model KW - ensemble Y1 - 2013 U6 - https://doi.org/10.1002/jgrf.20076 SN - 2169-9003 VL - 118 IS - 2 SP - 1025 EP - 1044 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Nishikawa, Ken-Ichi A1 - Hardee, P. A1 - Zhang, B. A1 - Dutan, I. A1 - Medvedev, M. A1 - Choi, E. J. A1 - Min, K. W. A1 - Niemiec, J. A1 - Mizuno, Y. A1 - Nordlund, Ake A1 - Frederiksen, Jacob Trier A1 - Sol, H. A1 - Pohl, Martin A1 - Hartmann, D. H. T1 - Magnetic field generation in a jet-sheath plasma via the kinetic Kelvin-Helmholtz instability JF - Annales geophysicae N2 - We have investigated the generation of magnetic fields associated with velocity shear between an unmagnetized relativistic jet and an unmagnetized sheath plasma. We have examined the strong magnetic fields generated by kinetic shear (Kelvin-Helmholtz) instabilities. Compared to the previous studies using counter-streaming performed by Alves et al. (2012), the structure of the kinetic Kelvin-Helmholtz instability (KKHI) of our jet-sheath configuration is slightly different, even for the global evolution of the strong transverse magnetic field. In our simulations the major components of growing modes are the electric field E-z, perpendicular to the flow boundary, and the magnetic field B-y, transverse to the flow direction. After the B-y component is excited, an induced electric field E-x, parallel to the flow direction, becomes significant. However, other field components remain small. We find that the structure and growth rate of KKHI with mass ratios m(i)/m(e) = 1836 and m(i)/m(e) = 20 are similar. In our simulations in the nonlinear stage is not as clear as in counter-streaming cases. The growth rate for a mildly-relativistic jet case (gamma(j) = 1.5) is larger than for a relativistic jet case (gamma(j) = 15). KW - Solar physics KW - astrophysics KW - astronomy (Energetic particles) Y1 - 2013 U6 - https://doi.org/10.5194/angeo-31-1535-2013 SN - 0992-7689 VL - 31 IS - 9 SP - 1535 EP - 1541 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Nezhadhaghighi, M. Ghasemi A1 - Rajabpour, M. A. T1 - Quantum entanglement entropy and classical mutual information in long-range harmonic oscillators JF - Physical review : B, Condensed matter and materials physics N2 - We study different aspects of quantum von Neumann and Renyi entanglement entropy of one-dimensional long-range harmonic oscillators that can be described by well-defined nonlocal field theories. We show that the entanglement entropy of one interval with respect to the rest changes logarithmically with the number of oscillators inside the subsystem. This is true also in the presence of different boundary conditions. We show that the coefficients of the logarithms coming from different boundary conditions can be reduced to just two different universal coefficients. We also study the effect of the mass and temperature on the entanglement entropy of the system in different situations. The universality of our results is also confirmed by changing different parameters in the coupled harmonic oscillators. We also show that more general interactions coming from general singular Toeplitz matrices can be decomposed to our long-range harmonic oscillators. Despite the long-range nature of the couplings, we show that the area law is valid in two dimensions and the universal logarithmic terms appear if we consider subregions with sharp corners. Finally, we study analytically different aspects of the mutual information such as its logarithmic dependence to the subsystem, effect of mass, and influence of the boundary. We also generalize our results in this case to general singular Toeplitz matrices and higher dimensions. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevB.88.045426 SN - 1098-0121 SN - 1550-235X VL - 88 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Naze, Yael A1 - Oskinova, Lida A1 - Gosset, Eric T1 - A detailed x-ray investigation of zeta puppis - II. the variability on short and long timescales JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - Stellar winds are a crucial component of massive stars, but their exact properties still remain uncertain. To shed some light on this subject, we have analyzed an exceptional set of X-ray observations of zeta Puppis, one of the closest and brightest massive stars. The sensitive light curves that were derived reveal two major results. On the one hand, a slow modulation of the X-ray flux (with a relative amplitude of up to 15% over 16 hr in the 0.3-4.0 keV band) is detected. Its characteristic timescale cannot be determined with precision, but amounts from one to several days. It could be related to corotating interaction regions, known to exist in zeta Puppis from UV observations. Hour-long changes, linked to flares or to the pulsation activity, are not observed in the last decade covered by the XMM observations; the 17 hr tentative period, previously reported in a ROSAT analysis, is not confirmed either and is thus transient, at best. On the other hand, short-term changes are surprisingly small (<1% relative amplitude for the total energy band). In fact, they are compatible solely with the presence of Poisson noise in the data. This surprisingly low level of short-term variability, in view of the embedded wind-shock origin, requires a very high fragmentation of the stellar wind, for both absorbing and emitting features (>10(5) parcels, comparing with a two-dimensional wind model). This is the first time that constraints have been placed on the number of clumps in an O-type star wind and from X-ray observations. KW - stars: early-type KW - stars: individual (zeta Pup) KW - X-rays: stars Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/763/2/143 SN - 0004-637X VL - 763 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Mulansky, Mario A1 - Pikovskij, Arkadij T1 - Energy spreading in strongly nonlinear disordered lattices JF - New journal of physics : the open-access journal for physics N2 - We study the scaling properties of energy spreading in disordered strongly nonlinear Hamiltonian lattices. Such lattices consist of nonlinearly coupled local linear or nonlinear oscillators, and demonstrate a rather slow, subdiffusive spreading of initially localized wave packets. We use a fractional nonlinear diffusion equation as a heuristic model of this process, and confirm that the scaling predictions resulting from a self-similar solution of this equation are indeed applicable to all studied cases. We show that the spreading in nonlinearly coupled linear oscillators slows down compared to a pure power law, while for nonlinear local oscillators a power law is valid in the whole studied range of parameters. Y1 - 2013 U6 - https://doi.org/10.1088/1367-2630/15/5/053015 SN - 1367-2630 VL - 15 IS - 5 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Montaseri, Ghazal A1 - Yazdanpanah, Mohammad Javad A1 - Pikovskij, Arkadij A1 - Rosenblum, Michael T1 - Synchrony suppression in ensembles of coupled oscillators via adaptive vanishing feedback JF - Chaos : an interdisciplinary journal of nonlinear science N2 - Synchronization and emergence of a collective mode is a general phenomenon, frequently observed in ensembles of coupled self-sustained oscillators of various natures. In several circumstances, in particular in cases of neurological pathologies, this state of the active medium is undesirable. Destruction of this state by a specially designed stimulation is a challenge of high clinical relevance. Typically, the precise effect of an external action on the ensemble is unknown, since the microscopic description of the oscillators and their interactions are not available. We show that, desynchronization in case of a large degree of uncertainty about important features of the system is nevertheless possible; it can be achieved by virtue of a feedback loop with an additional adaptation of parameters. The adaptation also ensures desynchronization of ensembles with non-stationary, time-varying parameters. We perform the stability analysis of the feedback-controlled system and demonstrate efficient destruction of synchrony for several models, including those of spiking and bursting neurons. Y1 - 2013 U6 - https://doi.org/10.1063/1.4817393 SN - 1054-1500 VL - 23 IS - 3 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Molaro, P. A1 - Centurion, Martin A1 - Whitmore, J. B. A1 - Evans, T. M. A1 - Murphy, M. T. A1 - Agafonova, I. I. A1 - Bonifacio, P. A1 - D'Odorico, S. A1 - Levshakov, S. A. A1 - Lopez, S. A1 - Martins, C. J. A. P. A1 - Petitjean, P. A1 - Rahmani, H. A1 - Reimers, D. A1 - Srianand, R. A1 - Vladilo, G. A1 - Wendt, Martin T1 - The UVES Large Program for testing fundamental physics I. Bounds on a change in alpha towards quasar HE 221-2818 JF - Astronomy and astrophysics : an international weekly journal N2 - Context. Absorption-line systems detected in quasar spectra can be used to compare the value of the fine-structure constant, alpha, measured today on Earth with its value in distant galaxies. In recent years, some evidence has emerged of small temporal and also spatial variations in alpha on cosmological scales. These variations may reach a fractional level of approximate to 10 ppm (parts per million). Aims. To test these claims we are conducting a Large Program of observations with the Very Large Telescope's Ultraviolet and Visual Echelle Spectrograph (UVES), and are obtaining high-resolution (R approximate to 60 000) and high signal-to-noise ratio (S/N approximate to 100) UVES spectra calibrated specifically for this purpose. Here we analyse the first complete quasar spectrum from this programme, that of HE 2217-2818. Methods. We applied the many multiplet method to measure alpha in five absorption systems towards this quasar: z(abs) = 0.7866, 0.9424, 1.5558, 1.6279, and 1.6919. Results. The most precise result is obtained for the absorber at z(abs) = 1.6919 where 3 Fe II transitions and Al II lambda 1670 have high S/N and provide a wide range of sensitivities to alpha. The absorption profile is complex with several very narrow features, and it requires 32 velocity components to be fitted to the data. We also conducted a range of tests to estimate the systematic error budget. Our final result for the relative variation in alpha in this system is Delta alpha/alpha = +1.3 +/- 2.4(stat) +/- 1.0(sys) ppm. This is one of the tightest current bounds on alpha-variation from an individual absorber. A second, separate approach to the data reduction, calibration, and analysis of this system yielded a slightly different result of -3.8 +/- 2.1(stat) ppm, possibly suggesting a larger systematic error component than our tests indicated. This approach used an additional 3 Fe II transitions, parts of which were masked due to contamination by telluric features. Restricting this analysis to the Fe II transitions alone and using a modified absorption profile model gave a result that is consistent with the first approach, Delta alpha/alpha = +1.1 +/- 2.6(stat) ppm. The four other absorbers have simpler absorption profiles, with fewer and broader features, and offer transitions with a narrower range of sensitivities to alpha. They therefore provide looser bounds on Delta alpha/alpha at the greater than or similar to 10 ppm precision level. Conclusions. The absorbers towards quasar HE 2217-2818 reveal no evidence of any variation in alpha at the 3-ppm precision level (1 sigma confidence). If the recently reported 10-ppm dipolar variation in alpha across the sky is correct, the expectation at this sky position is (3.2-5.4) +/- 1.7 ppm depending on dipole model used. Our constraint of Delta alpha/alpha = +1.3 +/- 2.4(stat) +/- 1.0(sys) ppm is not inconsistent with this expectation. KW - quasars: absorption lines KW - quasars: individual: HE 2217-2818 KW - intergalactic medium KW - cosmology: miscellaneous cosmology KW - observations Y1 - 2013 U6 - https://doi.org/10.1051/0004-6361/201321351 SN - 0004-6361 VL - 555 IS - 4 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Miranda, Rodrigo A. A1 - Rempel, Erico L. A1 - Chian, Abraham C.-L. A1 - Seehafer, Norbert A1 - Toledo, Benjamin A. A1 - Munoz, Pablo R. T1 - Lagrangian coherent structures at the onset of hyperchaos in the two-dimensional Navier-Stokes equations JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We study a transition to hyperchaos in the two-dimensional incompressible Navier-Stokes equations with periodic boundary conditions and an external forcing term. Bifurcation diagrams are constructed by varying the Reynolds number, and a transition to hyperchaos (HC) is identified. Before the onset of HC, there is coexistence of two chaotic attractors and a hyperchaotic saddle. After the transition to HC, the two chaotic attractors merge with the hyperchaotic saddle, generating random switching between chaos and hyperchaos, which is responsible for intermittent bursts in the time series of energy and enstrophy. The chaotic mixing properties of the flow are characterized by detecting Lagrangian coherent structures. After the transition to HC, the flow displays complex Lagrangian patterns and an increase in the level of Lagrangian chaoticity during the bursty periods that can be predicted statistically by the hyperchaotic saddle prior to HC transition. Y1 - 2013 U6 - https://doi.org/10.1063/1.4811297 SN - 1054-1500 VL - 23 IS - 3 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Miranda, Rodrigo A. A1 - Rempel, Erico L. A1 - Chian, Abraham C.-L. A1 - Seehafer, Norbert A1 - Toledo, Benjamin A. T1 - Lagrangian coherent structures at the onset of hyperchaos in the two-dimensional Navier-Stokes equations Y1 - 2013 UR - http://dx.doi.org/10.1063/1.4811297 ER - TY - JOUR A1 - Menzel, Ralf A1 - Heuer, Axel A1 - Puhlmann, Dirk A1 - Dechoum, K. A1 - Hillery, M. A1 - Spaehn, M. J. A. A1 - Schleich, W. P. T1 - A two-photon double-slit experiment JF - Journal of modern optics N2 - We employ a photon pair created by spontaneous parametric down conversion (SPDC) where the pump laser is in the TEM01 mode to perform a Young's double-slit experiment. The signal photon illuminates the two slits and displays interference fringes in the far-field while the idler photon measured in the near-field in coincidence with the signal photon provides us with which-slit' information. We explain the results of these experiments with the help of an analytical expression for the second-order correlation function derived from an elementary model of SPDC. Our experiment emphasizes the crucial role of the mode function in the quantum theory of radiation. KW - complementarity KW - wave-particle dualism KW - Young's double-slit experiment KW - spontaneous parametric down conversion KW - TEM01 mode Y1 - 2013 U6 - https://doi.org/10.1080/09500340.2012.746400 SN - 0950-0340 VL - 60 IS - 1 SP - 86 EP - 94 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Menon, Arathy A1 - Levermann, Anders A1 - Schewe, Jacob A1 - Lehmann, J. A1 - Frieler, Katja T1 - Consistent increase in Indian monsoon rainfall and its variability across CMIP-5 models JF - Earth system dynamics N2 - The possibility of an impact of global warming on the Indian monsoon is of critical importance for the large population of this region. Future projections within the Coupled Model Intercomparison Project Phase 3 (CMIP-3) showed a wide range of trends with varying magnitude and sign across models. Here the Indian summer monsoon rainfall is evaluated in 20 CMIP-5 models for the period 1850 to 2100. In the new generation of climate models, a consistent increase in seasonal mean rainfall during the summer monsoon periods arises. All models simulate stronger seasonal mean rainfall in the future compared to the historic period under the strongest warming scenario RCP-8.5. Increase in seasonal mean rainfall is the largest for the RCP-8.5 scenario compared to other RCPs. Most of the models show a northward shift in monsoon circulation by the end of the 21st century compared to the historic period under the RCP-8.5 scenario. The interannual variability of the Indian monsoon rainfall also shows a consistent positive trend under unabated global warming. Since both the long-term increase in monsoon rainfall as well as the increase in interannual variability in the future is robust across a wide range of models, some confidence can be attributed to these projected trends. Y1 - 2013 U6 - https://doi.org/10.5194/esd-4-287-2013 SN - 2190-4979 SN - 2190-4987 VL - 4 IS - 2 SP - 287 EP - 300 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Menon, Arathy A1 - Levermann, Anders A1 - Schewe, Jacob T1 - Enhanced future variability during India's rainy season JF - Geophysical research letters N2 - The Indian summer monsoon shapes the livelihood of a large share of the world's population. About 80% of annual precipitation over India occurs during the monsoon season from June through September. Next to its seasonal mean rainfall, the day-to-day variability is crucial for the risk of flooding, national water supply, and agricultural productivity. Here we show that the latest ensemble of climate model simulations, prepared for the AR-5 of the Intergovernmental Panel on Climate Change, consistently projects significant increases in day-to-day rainfall variability under unmitigated climate change. The relative increase by the period 2071-2100 with respect to the control period 1871-1900 ranges from 13% to 50% under the strongest scenario (Representative Concentration Pathways, RCP-8.5), in the 10 models with the most realistic monsoon climatology; and 13% to 85% when all the 20 models are considered. The spread across models reduces when variability increase per degree of global warming is considered, which is independent of the scenario in most models, and is 8% +/- 4%/K on average. This consistent projection across 20 comprehensive climate models provides confidence in the results and suggests the necessity of profound adaptation measures in the case of unmitigated climate change. KW - monsoon KW - variability KW - CMIP-5 Y1 - 2013 U6 - https://doi.org/10.1002/grl.50583 SN - 0094-8276 VL - 40 IS - 12 SP - 3242 EP - 3247 PB - American Geophysical Union CY - Washington ER - TY - THES A1 - Menon, Arathy T1 - Indian summer monsoon : future variability, extreme events and effects of lagged adaptation Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - Meibom, S. A1 - Barnes, Sydney A. A1 - Covey, K. A1 - Jeffries, R. D. A1 - Matt, S. A1 - Morin, J. A1 - Palacios, A. A1 - Reiners, A. A1 - Sicilia-Aguilar, A. A1 - Irwin, J. T1 - Angular momentum evolution of cool stars: Toward a synthesis of observations and theory before and after the ZAMS JF - Astronomische Nachrichten = Astronomical notes N2 - The coexistence of fast and slowly rotating cool stars in ZAMS clusters - forming distinct sequences in the color vs. rotation period plane - is providing clues to differences in their pre main-sequence angular momentum evolution. This Cool Stars 17 splinter was dedicated to a discussion of new observational and theoretical results that may help discriminate between proposed mechanisms for early angular momentum regulation and help us explain the observed ZAMS dichotomy. KW - circumstellar matter KW - stars: late-type KW - stars: magnetic fields KW - stars: pre-main sequence KW - stars: rotation Y1 - 2013 U6 - https://doi.org/10.1002/asna.201211777 SN - 0004-6337 SN - 1521-3994 VL - 334 IS - 1-2 SP - 168 EP - 171 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Marwan, Norbert A1 - Schinkel, Stefan A1 - Kurths, Jürgen T1 - Recurrence plots 25 years later -Gaining confidence in dynamical transitions JF - epl : a letters journal exploring the frontiers of physics N2 - Recurrence-plot-based time series analysis is widely used to study changes and transitions in the dynamics of a system or temporal deviations from its overall dynamical regime. However, most studies do not discuss the significance of the detected variations in the recurrence quantification measures. In this letter we propose a novel method to add a confidence measure to the recurrence quantification analysis. We show how this approach can be used to study significant changes in dynamical systems due to a change in control parameters, chaos-order as well as chaos-chaos transitions. Finally we study and discuss climate transitions by analysing a marine proxy record for past sea surface temperature. This paper is dedicated to the 25th anniversary of the introduction of recurrence plots. Y1 - 2013 U6 - https://doi.org/10.1209/0295-5075/101/20007 SN - 0295-5075 VL - 101 IS - 2 PB - EDP Sciences CY - Mulhouse ER - TY - THES A1 - Marchenko, Dmitry T1 - Rashba effect on Dirac fermions in grahene Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - Malyar, Ivan V. A1 - Santer, Svetlana A1 - Stetsyura, Svetlana V. T1 - The effect of illumination on the parameters of the polymer layer deposited from solution onto a semiconductor substrate JF - Technical physics letters : letters to the Russian journal of applied physics N2 - The effect of illumination on the thickness and roughness of monolayers of polycationic molecules of polyethyleneimine deposited from solution onto a silicon substrate was discovered and investigated. The super-bandgap illumination of the substrate during polyethyleneimine adsorption causes a decrease in both the roughness and integral thickness of the organic layer on n- and p-Si substrates. Y1 - 2013 U6 - https://doi.org/10.1134/S1063785013070183 SN - 1063-7850 VL - 39 IS - 7 SP - 656 EP - 659 PB - Pleiades Publ. CY - New York ER - TY - JOUR A1 - Malyar, Ivan V. A1 - Gorin, Dmitry A. A1 - Santer, Svetlana A1 - Stetsyura, Svetlana V. T1 - Photocontrolled Adsorption of Polyelectrolyte Molecules on a Silicon Substrate JF - Langmuir N2 - We report on a change in the properties of monomolecular films of polyelectrolyte molecules, induced by illuminating the silicon substrate on which they adsorb. It was found that under illumination the thickness of the adsorbed layer decreases by at least 27% and at the same time the roughness is significantly reduced in comparison to a layer adsorbed without irradiation. Furthermore, the homogeneity of the film topography and the surface potential is shown to be improved by illumination. The effect is explained by a change in surface charge density under irradiation of n- and p-type silicon wafers. The altered charge density in turn induces conformational changes of the adsorbing polyelectrolyte molecules. Their photocontrolled adsorption opens new possibilities for selective manipulation of adsorbed films. This possibility is of potential importance for many applications such as the production of well-defined coatings in biosensors or microelectronics. Y1 - 2013 U6 - https://doi.org/10.1021/1a403838n SN - 0743-7463 VL - 29 IS - 32 SP - 16058 EP - 16065 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Maity, Alok Kumar A1 - Bandyopadhyay, Arnab A1 - Chattopadhyay, Sudip A1 - Chaudhuri, Jyotipratim Ray A1 - Metzler, Ralf A1 - Chaudhury, Pinaki A1 - Banik, Suman K. T1 - Quantification of noise in bifunctionality-induced post-translational modification JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We present a generic analytical scheme for the quantification of fluctuations due to bifunctionality-induced signal transduction within the members of a bacterial two-component system. The proposed model takes into account post-translational modifications in terms of elementary phosphotransfer kinetics. Sources of fluctuations due to autophosphorylation, kinase, and phosphatase activity of the sensor kinase have been considered in the model via Langevin equations, which are then solved within the framework of linear noise approximation. The resultant analytical expression of phosphorylated response regulators are then used to quantify the noise profile of biologically motivated single and branched pathways. Enhancement and reduction of noise in terms of extra phosphate outflux and influx, respectively, have been analyzed for the branched system. Furthermore, the role of fluctuations of the network output in the regulation of a promoter with random activation-deactivation dynamics has been analyzed. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.032716 SN - 1539-3755 VL - 88 IS - 3 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Lu, Guanghao A1 - Blakesley, James C. A1 - Himmelberger, Scott A1 - Pingel, Patrick A1 - Frisch, Johannes A1 - Lieberwirth, Ingo A1 - Salzmann, Ingo A1 - Oehzelt, Martin A1 - Di Pietro, Riccardo A1 - Salleo, Alberto A1 - Koch, Norbert A1 - Neher, Dieter T1 - Moderate doping leads to high performance of semiconductor/insulator polymer blend transistors JF - Nature Communications N2 - Polymer transistors are being intensively developed for next-generation flexible electronics. Blends comprising a small amount of semiconducting polymer mixed into an insulating polymer matrix have simultaneously shown superior performance and environmental stability in organic field-effect transistors compared with the neat semiconductor. Here we show that such blends actually perform very poorly in the undoped state, and that mobility and on/off ratio are improved dramatically upon moderate doping. Structural investigations show that these blend layers feature nanometre-scale semiconductor domains and a vertical composition gradient. This particular morphology enables a quasi three-dimensional spatial distribution of semiconductor pathways within the insulating matrix, in which charge accumulation and depletion via a gate bias is substantially different from neat semiconductor, and where high on-current and low off-current are simultaneously realized in the stable doped state. Adding only 5 wt% of a semiconducting polymer to a polystyrene matrix, we realized an environmentally stable inverter with gain up to 60. Y1 - 2013 U6 - https://doi.org/10.1038/ncomms2587 SN - 2041-1723 VL - 4 IS - 1-2 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Lomholt, Michael A. A1 - Lizana, Ludvig A1 - Metzler, Ralf A1 - Ambjoernsson, Tobias T1 - Microscopic origin of the logarithmic time evolution of aging processes in complex systems JF - Physical review letters N2 - There exists compelling experimental evidence in numerous systems for logarithmically slow time evolution, yet its full theoretical understanding remains elusive. We here introduce and study a generic transition process in complex systems, based on nonrenewal, aging waiting times. Each state n of the system follows a local clock initiated at t = 0. The random time tau between clock ticks follows the waiting time density psi (tau). Transitions between states occur only at local clock ticks and are hence triggered by the local forward waiting time, rather than by psi (tau). For power-law forms psi (tau) similar or equal to tau(-1-alpha) (0 < alpha < 1) we obtain a logarithmic time evolution of the state number < n(t)> similar or equal to log(t/t(0)), while for alpha > 2 the process becomes normal in the sense that < n(t)> similar or equal to t. In the intermediate range 1 < alpha < 2 we find the power-law growth < n(t)> similar or equal to t(alpha-1). Our model provides a universal description for transition dynamics between aging and nonaging states. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevLett.110.208301 SN - 0031-9007 VL - 110 IS - 20 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Liu, Rui A1 - Liu, Chang A1 - Xu, Yan A1 - Liu, Wei A1 - Kliem, Bernhard A1 - Wang, Haimin T1 - Observation of a moretown wave and wave-filament interactions associated with the renowned X9 flare on 1990 May 24 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - Using Big Bear Solar Observatory film data recently digitized at NJIT, we investigate a Moreton wave associated with an X9 flare on 1990 May 24, as well as its interactions with four filaments F1-F4 located close to the flaring region. The interaction yields interesting insight into physical properties of both the wave and the filaments. The first clear Moreton wavefront appears at the flaring-region periphery at approximately the same time as the peak of a microwave burst and the first of two gamma-ray peaks. The wavefront propagates at different speeds ranging from 1500-2600 km s(-1) in different directions, reaching as far as 600 Mm away from the flaring site. Sequential chromospheric brightenings are observed ahead of the Moreton wavefront. A slower diffuse front at 300-600 km s(-1) is observed to trail the fast Moreton wavefront about one minute after the onset. The Moreton wave decelerates to similar to 550 km s(-1) as it sweeps through F1. The wave passage results in F1's oscillation which is featured by similar to 1 mHz signals with coherent Fourier phases over the filament, the activation of F3 and F4 followed by gradual recovery, but no disturbance in F2. Different height and magnetic environment together may account for the distinct responses of the filaments to the wave passage. The wavefront bulges at F4, whose spine is oriented perpendicular to the upcoming wavefront. The deformation of the wavefront is suggested to be due to both the forward inclination of the wavefront and the enhancement of the local Alfven speed within the filament channel. KW - Sun: filaments, prominences KW - Sun: flares KW - Sun: oscillations KW - waves Y1 - 2013 U6 - https://doi.org/10.1088/0004-637X/773/2/166 SN - 0004-637X VL - 773 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Linde, Felix A1 - Yadavalli, Nataraja Sekhar A1 - Santer, Svetlana T1 - Conductivity behavior of very thin gold films ruptured by mass transport in photosensitive polymer film JF - APPLIED PHYSICS LETTERS N2 - We report on conductivity behavior of very thin gold layer deposited on a photosensitive polymer film. Under irradiation with light interference pattern, the azobenzene containing photosensitive polymer film undergoes deformation at which topography follows a distribution of intensity, resulting in the formation of a surface relief grating. This process is accompanied by a change in the shape of the polymer surface from flat to sinusoidal together with a corresponding increase in surface area. The gold layer placed above deforms along with the polymer and ruptures at a strain of 4%. The rupturing is spatially well defined, occurring at the topographic maxima and minima resulting in periodic cracks across the whole irradiated area. We have shown that this periodic micro-rupturing of a thin metal film has no significant impact on the electrical conductivity of the films. We suggest a model to explain this phenomenon and support this by additional experiments where the conductivity is measured in a process when a single nanoscopic scratch is formed with an AFM tip. Our results indicate that in flexible electronic materials consisting of a polymer support and an integrated metal circuit, nano-and micro cracks do not alter significantly the behavior of the conductivity unless the metal is disrupted completely. (C) 2013 AIP Publishing LLC. Y1 - 2013 U6 - https://doi.org/10.1063/1.4850595 SN - 0003-6951 SN - 1077-3118 VL - 103 IS - 25 PB - AMER INST PHYSICS CY - MELVILLE ER - TY - JOUR A1 - Li, Hongguang A1 - Babu, Sukumaran Santhosh A1 - Turner, Sarah T. A1 - Neher, Dieter A1 - Hollamby, Martin J. A1 - Seki, Tomohiro A1 - Yagai, Shiki A1 - Deguchi, Yonekazu A1 - Möhwald, Helmuth A1 - Nakanishi, Takashi T1 - Alkylated-C-60 based soft materials regulation of self-assembly and optoelectronic properties by chain branching JF - Journal of materials chemistry : C, Materials for optical and electronic devices N2 - Derivatization of fullerene (C-60) with branched aliphatic chains softens C-60-based materials and enables the formation of thermotropic liquid crystals and room temperature nonvolatile liquids. This work demonstrates that by carefully tuning parameters such as type, number and substituent position of the branched chains, liquid crystalline C-60 materials with mesophase temperatures suited for photovoltaic cell fabrication and room temperature nonvolatile liquid fullerenes with tunable viscosity can be obtained. In particular, compound 1, with branched chains, exhibits a smectic liquid crystalline phase extending from 84 degrees C to room temperature. Analysis of bulk heterojunction (BHJ) organic solar cells with a ca. 100 nm active layer of compound 1 and poly(3-hexylthiophene) (P3HT) as an electron acceptor and an electron donor, respectively, reveals an improved performance (power conversion efficiency, PCE: 1.6 + 0.1%) in comparison with another compound, 10 (PCE: 0.5 + 0.1%). The latter, in contrast to 1, carries linear aliphatic chains and thus forms a highly ordered solid lamellar phase at room temperature. The solar cell performance of 1 blended with P3HT approaches that of PCBM/P3HT for the same active layer thickness. This indicates that C-60 derivatives bearing branched tails are a promising class of electron acceptors in soft (flexible) photovoltaic devices. Y1 - 2013 U6 - https://doi.org/10.1039/c3tc00066d SN - 2050-7526 VL - 1 IS - 10 SP - 1943 EP - 1951 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Levermann, Anders A1 - Clark, Peter U. A1 - Marzeion, Ben A1 - Milne, Glenn A. A1 - Pollard, David A1 - Radic, Valentina A1 - Robinson, Alexander T1 - The multimillennial sea-level commitment of global warming JF - Proceedings of the National Academy of Sciences of the United States of America N2 - Global mean sea level has been steadily rising over the last century, is projected to increase by the end of this century, and will continue to rise beyond the year 2100 unless the current global mean temperature trend is reversed. Inertia in the climate and global carbon system, however, causes the global mean temperature to decline slowly even after greenhouse gas emissions have ceased, raising the question of how much sea-level commitment is expected for different levels of global mean temperature increase above preindustrial levels. Although sea-level rise over the last century has been dominated by ocean warming and loss of glaciers, the sensitivity suggested from records of past sea levels indicates important contributions should also be expected from the Greenland and Antarctic Ice Sheets. Uncertainties in the paleo-reconstructions, however, necessitate additional strategies to better constrain the sea-level commitment. Here we combine paleo-evidence with simulations from physical models to estimate the future sea-level commitment on a multimillennial time scale and compute associated regional sea-level patterns. Oceanic thermal expansion and the Antarctic Ice Sheet contribute quasi-linearly, with 0.4 m degrees C-1 and 1.2 m degrees C-1 of warming, respectively. The saturation of the contribution from glaciers is overcompensated by the nonlinear response of the Greenland Ice Sheet. As a consequence we are committed to a sea-level rise of approximately 2.3 m degrees C-1 within the next 2,000 y. Considering the lifetime of anthropogenic greenhouse gases, this imposes the need for fundamental adaptation strategies on multicentennial time scales. KW - climate change KW - climate impacts KW - sea-level change Y1 - 2013 U6 - https://doi.org/10.1073/pnas.1219414110 SN - 0027-8424 VL - 110 IS - 34 SP - 13745 EP - 13750 PB - National Acad. of Sciences CY - Washington ER - TY - JOUR A1 - Lange, J. A1 - Pohl, Martin T1 - The average GeV-band emission from gamma-ray bursts JF - Astronomy and astrophysics : an international weekly journal N2 - Aims. We analyze the emission in the 0.3-30 GeV energy range of gamma-ray bursts detected with the Fermi Gamma-ray Space Telescope. We concentrate on bursts that were previously only detected with the Gamma-Ray Burst Monitor in the keV energy range. These bursts will then be compared to the bursts that were individually detected with the Large Area Telescope at higher energies. Methods. To estimate the emission of faint GRBs we used nonstandard analysis methods and sum over many GRBs to find an average signal that is significantly above background level. We used a subsample of 99 GRBs listed in the Burst Catalog from the first two years of observation. Results. Although most are not individually detectable, the bursts not detected by the Large Area Telescope on average emit a significant flux in the energy range from 0.3 GeV to 30 GeV, but their cumulative energy fluence is only 8% of that of all GRBs. Likewise, the GeV-to-MeV flux ratio is less and the GeV-band spectra are softer. We confirm that the GeV-band emission lasts much longer than the emission found in the keV energy range. The average allsky energy flux from GRBs in the GeV band is 6.4 x 10(-4) erg cm(-2) yr(-1) or only similar to 4% of the energy flux of cosmic rays above the ankle at 10(18.6) eV. KW - methods: statistical KW - surveys KW - gamma-ray burst: general Y1 - 2013 U6 - https://doi.org/10.1051/0004-6361/201220652 SN - 0004-6361 VL - 551 IS - 1 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Lange, Ilja A1 - Kniepert, Juliane A1 - Pingel, Patrick A1 - Dumsch, Ines A1 - Allard, Sybille A1 - Janietz, Silvia A1 - Scherf, Ullrich A1 - Neher, Dieter T1 - Correlation between the open circuit voltage and the energetics of organic bulk heterojunction solar cells JF - The journal of physical chemistry letters N2 - A detailed investigation of the open circuit voltage (V-OC) of organic bulk heterojunction solar cells comprising three different donor polymers and two different fullerene-based acceptors is presented. Bias amplified charge extraction (BACE) is combined with Kelvin Probe measurements to derive information on the relevant energetics in the blend. On the example of P3HT:PC70BM the influence of composition and preparation conditions on the relevant transport levels will be shown. Moderate upward shifts of the P3HT HOMO depending on crystallinity are observed, but contrarily to common believe, the dependence of V-OC on blend composition and thermal history is found to be largely determined by the change in the PCBM LUMO energy. Following this approach, we quantified the energetic contribution to the V-OC in blends with fluorinated polymers or higher adduct fullerenes. Y1 - 2013 U6 - https://doi.org/10.1021/jz401971e SN - 1948-7185 VL - 4 IS - 22 SP - 3865 EP - 3871 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Laflamme, Simon A1 - Kollosche, Matthias A1 - Connor, Jerome J. A1 - Kofod, Guggi T1 - Robust flexible capacitive surface sensor for structural health monitoring applications JF - Journal of engineering mechanics N2 - Early detection of possible defects in civil infrastructure is vital to ensuring timely maintenance and extending structure life expectancy. The authors recently proposed a novel method for structural health monitoring based on soft capacitors. The sensor consisted of an off-the-shelf flexible capacitor that could be easily deployed over large surfaces, the main advantages being cost-effectiveness, easy installation, and allowing simple signal processing. In this paper, a capacitive sensor with tailored mechanical and electrical properties is presented, resulting in greatly improved robustness while retaining measurement sensitivity. The sensor is fabricated from a thermoplastic elastomer mixed with titanium dioxide and sandwiched between conductive composite electrodes. Experimental verifications conducted on wood and concrete specimens demonstrate the improved robustness, as well as the ability of the sensing method to diagnose and locate strain. KW - Strain gages KW - Structural health monitoring KW - Monitoring KW - Probe instruments KW - Strain gauge KW - Structural health monitoring KW - Strain monitoring KW - Capacitive sensor KW - Dielectric polymer KW - Stretchable sensor KW - Flexible membrane KW - Sensing skin Y1 - 2013 U6 - https://doi.org/10.1061/(ASCE)EM.1943-7889.0000530 SN - 0733-9399 SN - 1943-7889 VL - 139 IS - 7 SP - 879 EP - 885 PB - American Society of Civil Engineers CY - Reston ER - TY - THES A1 - Körnig, André T1 - Assembled biogenic magnetic nanoparticles : proberties of magnetosome chains and their stability against external magnetic fields Y1 - 2013 CY - Potsdam ER - TY - JOUR A1 - Könnecke, Rene A1 - Follath, R. A1 - Pontius, N. A1 - Schlappa, J. A1 - Eggenstein, F. A1 - Zeschke, T. A1 - Bischoff, P. A1 - Schmidt, J. -S. A1 - Noll, T. A1 - Trabant, C. A1 - Schreck, S. A1 - Wernet, Ph. A1 - Eisebitt, S. A1 - Senf, F. A1 - Schuessler-Langeheine, Christian A1 - Erko, A. A1 - Föhlisch, Alexander T1 - The confocal plane grating spectrometer at BESSY II JF - Journal of electron spectroscopy and related phenomena : the international journal on theoretical and experimental aspects of electron spectroscopy N2 - At BESSY II a confocal plane grating spectrometer for resonant inelastic X-ray scattering (RIXS) is currently under commissioning. The new endstation operates with a source size of 4 x 1 mu m(2) provided by its dedicated beamline. The RIXS-spectrometer covers an energy range from 50 eV to 1000 eV, providing a resolving power E/Delta E of 5000-15,000. The beamline allows full polarization control and gives a photon flux of up to 7 x 10(14) photons/s/0.1 A/0.1%bandwidth by offering a resolving power E/Delta E of 4000-12,000. KW - Resonant inelastic X-ray scattering KW - Soft X-ray monochromator KW - High transmission micro focus beamline KW - Plane grating emission spectrometer Y1 - 2013 U6 - https://doi.org/10.1016/j.elspec.2012.11.003 SN - 0368-2048 VL - 188 SP - 133 EP - 139 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - König, Tobias A1 - Papke, Thomas A1 - Kopyshev, Alexey A1 - Santer, Svetlana T1 - Atomic force microscopy nanolithography fabrication of metallic nano-slits using silicon nitride tips JF - Journal of materials science N2 - In this paper, we report on the properties of nano-slits created in metal thin films using atomic force microscope (AFM) nanolithography (AFM-NL). We demonstrate that instead of expensive diamond AFM tips, it is also possible to use low cost silicon nitride tips. It is shown that depending on the direction of scratching, nano-slits of different widths and depths can be fabricated at constant load force. We elucidate the reasons for this behavior and identify an optimal direction and load force for scratching a gold layer. Y1 - 2013 U6 - https://doi.org/10.1007/s10853-013-7188-x SN - 0022-2461 VL - 48 IS - 10 SP - 3863 EP - 3869 PB - Springer CY - New York ER - TY - JOUR A1 - Kursawe, Jochen A1 - Schulz, Johannes H. P. A1 - Metzler, Ralf T1 - Transient aging in fractional brownian and langevin-equation motion JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - Stochastic processes driven by stationary fractional Gaussian noise, that is, fractional Brownian motion and fractional Langevin-equation motion, are usually considered to be ergodic in the sense that, after an algebraic relaxation, time and ensemble averages of physical observables coincide. Recently it was demonstrated that fractional Brownian motion and fractional Langevin-equation motion under external confinement are transiently nonergodic-time and ensemble averages behave differently-from the moment when the particle starts to sense the confinement. Here we show that these processes also exhibit transient aging, that is, physical observables such as the time-averaged mean-squared displacement depend on the time lag between the initiation of the system at time t = 0 and the start of the measurement at the aging time t(a). In particular, it turns out that for fractional Langevin-equation motion the aging dependence on ta is different between the cases of free and confined motion. We obtain explicit analytical expressions for the aged moments of the particle position as well as the time-averaged mean-squared displacement and present a numerical analysis of this transient aging phenomenon. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.062124 SN - 1539-3755 SN - 1550-2376 VL - 88 IS - 6 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Kuptsov, Pavel V. A1 - Kuznetsov, Sergey P. A1 - Pikovskij, Arkadij T1 - Hyperbolic chaos at blinking coupling of noisy oscillators JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We study an ensemble of identical noisy phase oscillators with a blinking mean-field coupling, where onecluster and two-cluster synchronous states alternate. In the thermodynamic limit the population is described by a nonlinear Fokker-Planck equation. We show that the dynamics of the order parameters demonstrates hyperbolic chaos. The chaoticity manifests itself in phases of the complex mean field, which obey a strongly chaotic Bernoulli map. Hyperbolicity is confirmed by numerical tests based on the calculations of relevant invariant Lyapunov vectors and Lyapunov exponents. We show how the chaotic dynamics of the phases is slightly smeared by finite-size fluctuations. DOI: 10.1103/PhysRevE.87.032912 Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.87.032912 SN - 1539-3755 VL - 87 IS - 3 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Kunnus, Kristjan A1 - Josefsson, Ida A1 - Schreck, Simon A1 - Quevedo, Wilson A1 - Miedema, Piter S. A1 - Techert, Simone A1 - de Groot, Frank M. F. A1 - Odelius, Michael A1 - Wernet, Philippe A1 - Föhlisch, Alexander T1 - From Ligand Fields to Molecular Orbitals: Probing the Local Valence Electronic Structure of Ni2+ in Aqueous Solution with Resonant Inelastic X-ray Scattering JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry N2 - Bonding of the Ni2+(aq) complex is investigated with an unprecedented combination of resonant inelastic X-ray scattering (RIXS) measurements and ab initio calculations at the Ni L absorption edge. The spectra directly reflect the relative energies of the ligand-field and charge-transfer valence-excited states. They give element-specific access with atomic resolution to the ground-state electronic structure of the complex and allow quantification of ligand-field strength and 3d-3d electron correlation interactions in the Ni2+(aq) complex. The experimentally determined ligand-field strength is 10Dq = 1.1 eV. This and the Racah parameters characterizing 3d-3d Coulomb interactions B = 0.13 eV and C = 0.42 eV as readily derived from the measured energies match very well with the results from UV-vis spectroscopy. Our results demonstrate how L-edge RIXS can be used to complement existing spectroscopic tools for the investigation of bonding in 3d transition-metal coordination compounds in solution. The ab initio RASPT2 calculation is successfully used to simulate the L-edge RIXS spectra. Y1 - 2013 U6 - https://doi.org/10.1021/jp4100813 SN - 1520-6106 VL - 117 IS - 51 SP - 16512 EP - 16521 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Krishnan, Giri Panamoottil A1 - Bazhenov, Maxim A1 - Pikovskij, Arkadij T1 - Multipulse phase resetting curves JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - In this paper, we introduce and study systematically, in terms of phase response curves, the effect of dual-pulse excitation on the dynamics of an autonomous oscillator. Specifically, we test the deviations from linear summation of phase advances resulting from two small perturbations. We analytically derive a correction term, which generally appears for oscillators whose intrinsic dimensionality is >1. The nonlinear correction term is found to be proportional to the square of the perturbation. We demonstrate this effect in the Stuart-Landau model and in various higher dimensional neuronal models. This deviation from the superposition principle needs to be taken into account in studies of networks of pulse-coupled oscillators. Further, this deviation could be used in the verification of oscillator models via a dual-pulse excitation. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.88.042902 SN - 1539-3755 SN - 1550-2376 VL - 88 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Kralemann, Björn A1 - Pikovskij, Arkadij A1 - Rosenblum, Michael T1 - Detecting triplet locking by triplet synchronization indices JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We discuss the effect of triplet synchrony in oscillatory networks. In this state the phases and the frequencies of three coupled oscillators fulfill the conditions of a triplet locking, whereas every pair of systems remains asynchronous. We suggest an easy to compute measure, a triplet synchronization index, which can be used to detect such states from experimental data. Y1 - 2013 U6 - https://doi.org/10.1103/PhysRevE.87.052904 SN - 1539-3755 VL - 87 IS - 5 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Kralemann, Bjoern A1 - Fruehwirth, Matthias A1 - Pikovskij, Arkadij A1 - Rosenblum, Michael A1 - Kenner, Thomas A1 - Schaefer, Jochen A1 - Moser, Maximilian T1 - In vivo cardiac phase response curve elucidates human respiratory heart rate variability JF - Nature Communications N2 - Recovering interaction of endogenous rhythms from observations is challenging, especially if a mathematical model explaining the behaviour of the system is unknown. The decisive information for successful reconstruction of the dynamics is the sensitivity of an oscillator to external influences, which is quantified by its phase response curve. Here we present a technique that allows the extraction of the phase response curve from a non-invasive observation of a system consisting of two interacting oscillators-in this case heartbeat and respiration-in its natural environment and under free-running conditions. We use this method to obtain the phase-coupling functions describing cardiorespiratory interactions and the phase response curve of 17 healthy humans. We show for the first time the phase at which the cardiac beat is susceptible to respiratory drive and extract the respiratory-related component of heart rate variability. This non-invasive method for the determination of phase response curves of coupled oscillators may find application in many scientific disciplines. Y1 - 2013 U6 - https://doi.org/10.1038/ncomms3418 SN - 2041-1723 VL - 4 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Kopyshev, Alexey A1 - Galvin, Casey J. A1 - Genzer, Jan A1 - Lomadze, Nino A1 - Santer, Svetlana T1 - Opto-mechanical scission of polymer chains in photosensitive diblock-copolymer brushes JF - Langmuir N2 - In this paper we report on an opto-mechanical scission of polymer chains within photosensitive diblock-copolymer brushes grafted to flat solid substrates. We employ surface-initiated polymerization of methylmethacrylate (MMA) and t-butyl methacrylate (tBMA) to grow diblock-copolymer brushes of poly(methylmethacrylate-b-t-butyl methacrylate) following the atom transfer polymerization (ATRP) scheme. After the synthesis, deprotection of the PtBMA block yields poly(methacrylic acid) (PMAA). To render PMMA-b-PMAA copolymers photosensitive, cationic azobenzene containing surfactants are attached to the negatively charged outer PMAA block. During irradiation with an ultraviolet (UV) interference pattern, the extent of photoisomerization of the azobenzene groups varies spatially and results in a topography change of the brush, i.e., formation of surface relief gratings (SRG). The SRG formation is accompanied by local rupturing of the polymer chains in areas from which the polymer material recedes. This opto-mechanically induced scission of the polymer chains takes place at the interfaces of the two blocks and depends strongly on the UV irradiation intensity. Our results indicate that this process may be explained by employing classical continuum fracture mechanics, which might be important for tailoring the phenomenon for applying it to poststructuring of polymer brushes. Y1 - 2013 U6 - https://doi.org/10.1021/la403241t SN - 0743-7463 VL - 29 IS - 45 SP - 13967 EP - 13974 PB - American Chemical Society CY - Washington ER -